CN106433377A - Novel environmental-friendly ceramic paint - Google Patents
Novel environmental-friendly ceramic paint Download PDFInfo
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- CN106433377A CN106433377A CN201610884542.9A CN201610884542A CN106433377A CN 106433377 A CN106433377 A CN 106433377A CN 201610884542 A CN201610884542 A CN 201610884542A CN 106433377 A CN106433377 A CN 106433377A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
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Abstract
The invention discloses a novel environmental-friendly ceramic paint. The paint is prepared from polyester resin, dipentaerythritol hexaacrylate, linolenate, dodecenyl succinic anhydride, neopentyl glycol, benzoin ethyl ether, acrylic emulsion, a thioacetamide solution, paraffin, dolomite powder, bentonite, titanium dioxide, boron carbide, polyester fiber, boron fiber, hydroxypropyl methyl cellulose, ceramic fiber, a surfactant, a degassing agent, a leveling agent, a dispersing agent, a wetting agent, an adhesion force promoting agent, a catalyst, an initiator, a vertical grain agent, a toughening agent, a luster-enhancing agent, a defoaming agent, a tackifying agent, a curing agent, a preservative, an antioxidant, a light stabilizer, a heat stabilizer, an ultraviolet absorbent, an anti-settling agent, a thickening agent, a film-forming aiding agent and a flame retardant. The paint not only has excellent adhesion force and mechanical properties, but also is excellent in high temperature resistance, impact resistance and hardness, drying speed is fast, and toxic properties are little. The environmental-friendly ceramic paint has excellent comprehensive properties.
Description
【Technical field】
The invention belongs to coating preparation technology neck, and in particular to a kind of novel environment friendly pottery coating.
【Background technology】
Coating is typically based on resin or oil, and is added or be not added with face, filler, the viscous solution that is modulated with organic solvent or water
Body, also occurs in that the coating new varieties such as powdery paints for existing with solid forms.No matter form (the liquid of all kinds of coating coating varieties
Body or solid) how, at least should be made up of two or three basis.It is divided into main film forming substance；Subsidiary film forming matter
And auxiliary film forming matter.Coating can be coated on surface of bottom material and form the liquid or solid macromolecule of tough and tensile continuous film (paint film)
Material.It is once called as painting, paints.It is mainly used to be played decoration and protective effect to applying surface.Some coating also have specific work(
Can, such as high temperature resistant, cold-resistant, radioprotective etc..Coating is widely used in the aspects such as building, ship, vehicle, metallic article.Coating English
Literary fame claims：Coating products is defined：Be applied to body surface can be formed with protection decoration or property (as insulation,
Anti-corrosion, mark etc.) a class I liquid I of solid coated film or the general name of solid material.Coating type is various, purposes is extremely wide.In its people
Play an important role in economy and people's lives.Year is the important indicator of a national living standard using coating content per capita.
Special cermacis is that radio, aviation, atomic energy, metallurgy, machinery, chemistry etc. are industrial and electric with Modern appliances
The developing by leaps and bounds for advanced science technology such as sub- computer, space technology, new energy development and grow up.Used by these potteries
Primary raw material be no longer clay, Anhydrite, quartz, some bases not also using some clays or Anhydrite, but more be adopt
Pure oxide and the raw material with property, manufacturing process is also different with performance requirement.Reform and open up to the outside world 30 years
Come, Chinese pottery industrial boom, nowadays become genuine Production of Ceramics big country, consumption big country in the world.China is raw
The domestic ceramics yield of product accounts for global 70% or so, and display art ceramic yield is the 65% of the whole world, architectural pottery yield
Also Gross World Product half of the country is accounted for.China industry occupies very important status in world's building material industry.
Polyester, by polyhydric alcohol and polymer general name obtained by polyprotic acid polycondensation.Refer mainly to polyethylene terephthalate (
PET), linear thermoplastic's resins such as polybutylene terephthalate (PBT) and polyarylate are traditionally also included.It is a class
Can excellent, broad-spectrum engineering plastics.May be made as polyester fiber and mylar.Acrylic acid is important organic synthesiss original
Material and synthetic resin monomer, are the very fast vinyl monomers of polymerization speed.It is simplest unsaturated carboxylic acid, by an ethylene
Base and a carboxyl composition.Pure acrylic acid is colorless clear liquid, the penetrating odor with feature.It can be with water, alcohol, ether
Dissolve each other with chloroform, prepared by the propylene for obtaining from oil plant.Great majority are in order to manufacture acrylic acid methyl ester., ethyl ester, butyl ester, hydroxyl
The esters of acrylic acids such as ethyl ester.Acrylic acid and acrylate can be with homopolymerization and copolymerization, and its polymer is used for synthetic resin, synthesis fibre
The industrial departments such as dimension, super absorbent resin, building materials, coating.Ceramic coating is that one kind can make Organic substance react with inorganic matters,
So as to have both the novel ceramic coating of both advantages.The hardness of the ceramic coating of a new generation can reach more than 6H.High temperature resistant
400 DEG C, effect is not glued, color is multiple.And the popularization with humanity concept, and the composition of new harmonious society, design one kind
Adhesive force is good, impact resistance, the pottery of the high and fast drying of high temperature resistant, hardness are very important with environmental protection coating material.
【Content of the invention】
The present invention provides a kind of novel environment friendly pottery coating, poor, no to solve existing novel environment friendly pottery paint adhesion
The problems such as impact resistance and high temperature, hardness are low, drying is slow and toxicity is big.The coating of the present invention had both had excellent adhesive force and mechanics
Performance, but with excellent high temperature resistant, impact resistance and hardness, while rate of drying is fast and toxic is minimum, it is a kind of comprehensive
The excellent pottery environmental protection coating material of energy.
For solving above technical problem, the present invention is employed the following technical solutions：
A kind of novel environment friendly pottery coating, in units of weight, including following raw material：Polyester resin 135-178 part, two seasons penta
Six acrylate 55-79 part of tetrol, linolenate 34-48 part, dodecenylsuccinic acid acid anhydride 22-31 part, neopentyl glycol 19-24
Part, benzoin ethyl ether 12-18 part, acrylic emulsion 28-42 part, thioacetyl amine aqueous solution 22-32 part, paraffin 21-45 part, white clouds
Stone powder 5-10 part, bentonite 4-7 part, titanium dioxide 3-6 part, boron carbide 3-5 part, polyester fiber 4-6 part, boron fibre 3-4 part, hydroxyl
Propyl methocel 4-7 part, ceramic fibre 2-4 part, surfactant 0.4-0.7 part, degasser 0.3-0.6 part, levelling agent
0.3-0.8 part, dispersant 0.5-0.9 part, wetting agent 0.3-0.5 part, adhesion promoter 0.2-0.4 part, catalyst 0.1-0.2
Part, initiator 0.2-0.3 part, vertical stricture of vagina agent 0.4-0.6 part, toughener 0.3-0.5 part, optical brightener 0.3-0.5 part, defoamer 0.3-
0.6 part, viscosifier 0.3-0.5 part, firming agent 0.9-1.8 part, preservative 0.2-0.4 part, antioxidant 0.2-0.5 part, light stable
Agent 0.1-0.2 part, heat stabilizer 0.2-0.4 part, UV absorbent 0.1-0.3 part, anti-settling agent 0.4-0.7 part, thickening agent
0.3-0.5 part, coalescents 0.3-0.6 part, fire retardant 1-1.4 part；
The dispersant is dispersant NNO；
The wetting agent is wetting agent X-405；
The adhesion promoter is adhesion promoter HF-1；
The catalyst is vanadic anhydride；
The initiator is two isopropylformic acid. of azo（Acrylic acid ethylene glycol）Ester；
The vertical stricture of vagina agent is mallear stria agent H-863；
The toughener is MBS terpolymer；
The viscosifier are propyl trimethoxy silicane；
The firming agent is p-hydroxybenzenyl sulfonate；
The preservative is Liquid BPF -369；
The antioxidant is antioxidant AT-330；
The light stabilizer is light stabilizer HS-3101；
The UV absorbent is oxybenzoic acid phenyl ester；
The thickening agent is carrageenan；
The coalescents are propylene glycol methyl ether acetate；
The fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 12-24 part, 2,
2- dimethyl-trimethylene dimethylacrylate 10-15 part, APP 8-13 part, neopentyl glycol 5-12 part, carbamide 6-
10 parts, barium hydroxide 3-6 part, antimony oxide 5-9 part, aluminium oxide 2-5 part, bentonite 2-4 part, penetrating agent 0.5-1 part, synergistic
Agent 0.4-0.6 part；
The penetrating agent is fatty alcohol-polyoxyethylene ether
The synergist is ammonium sulfate；
The preparation method of the novel environment friendly pottery coating, comprises the following steps：
S1：By polyester resin, dipentaerythritol acrylate, linolenate, dodecenylsuccinic acid acid anhydride, paraffin, dolomite
Powder, bentonite, titanium dioxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surface activity
Agent, degasser, levelling agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, in microwave power be
152-185W, it is to stir 2.8-3h, prepared mixture a under 2200-2700r/min that temperature is 93-97 DEG C, rotating speed；
S2：To in mixture a obtained in step S1, add neopentyl glycol, benzoin ethyl ether, acrylic emulsion, thioacetamide molten
Liquid, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 128-167W in microwave power, and temperature is 122-126 DEG C, to turn
Speed is for stirring 3.3-5.1h, prepared mixture b under 400-600r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in mixture b obtained in step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 160-230W in microwave power, and temperature is 108-112 DEG C,
Rotating speed is to stir 1.5-3h, prepared mixture c under 300-500r/min；
The preparation method of the heat stabilizer, comprises the following steps：
S31：The active hargil waste water that bentonite and concentration are 18% is 2.5 by weight:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：Pasty material A obtained in step S31 is added in the inorganic mixed acid that concentration is 23%, the inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
Shape material A is 3.4 with the weight ratio of inorganic mixed acid:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight ratio of pasty material A is 2:158,94 DEG C are heated to, are maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：Pasty material B obtained in step S32 is carried out filter pressing under pressure is for 0.93MPa, prepared moisture content is 47% filter
Cake A；
S34：Add water stirring and dissolving to filter cake A obtained in step S33, amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h to precipitate solution completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：Filter cake B obtained in step S34 is added water stirring and dissolving, amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, the sodium hydroxide solution that concentration is 15% is added, slurry material C is obtained；
S36：Slurry material C obtained in step S35 is carried out filter pressing under pressure is for 0.96MPa, prepared moisture content is 44% filter cake
C；
S37：Filter cake C obtained in step S36 is placed in centrifuge, filter cake C is removed water under centrifugal rotational speed is for 6000r/min and is contained
Water rate is crushing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：Alkaline hargil obtained in step S37 is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：Slurry material D obtained in step S38 is carried out filter pressing under pressure is for 0.92MPa, prepared moisture content is 42% filter cake
D；
S310：Filter cake D obtained in step S39 is placed in centrifuge, under centrifugal rotational speed is for 6000r/min, removes water to filter cake D
Moisture content is crushing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of the fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, to stir
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 are added in mixture A obtained in step S3-1,
3- propylidene dimethylacrylate, neopentyl glycol, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is to stir 2h, prepared mixture B at 140W, temperature is 86 DEG C；
S3-3：Mixture B obtained in step S3-2 is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：Mixture c obtained in step S3 is melt extruded by extruder at 112-116 DEG C, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：Lamellar body obtained in step S4 is sheared using cutting knife, prepared pelletizing；
S6：150-170 mesh sieve, prepared novel environment friendly pottery coating is crossed after pelletizing obtained in step S5 is crushed.
Further, the surfactant is Tween 80.
Further, the degasser is stearic acid.
Further, the levelling agent is polydimethylsiloxane.
Further, the optical brightener is optical brightener LD-608.
Further, the defoamer is defoamer MSDS.
Further, the anti-settling agent is modified hydrogenated Oleum Ricini.
The invention has the advantages that：
The coating of the present invention had both had excellent adhesive force and mechanical property, and with excellent high temperature resistant, impact resistance and hardness,
While rate of drying is fast and toxic is minimum, it is a kind of pottery environmental protection coating material of excellent combination property.
【Specific embodiment】
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the protection of the present invention
Scope, but do not limit the scope of the invention.
In an embodiment, the novel environment friendly pottery coating, in units of weight, including following raw material：Polyester resin
135-178 part, dipentaerythritol acrylate 55-79 part, linolenate 34-48 part, dodecenylsuccinic acid acid anhydride 22-31
Part, neopentyl glycol 19-24 part, benzoin ethyl ether 12-18 part, acrylic emulsion 28-42 part, thioacetyl amine aqueous solution 22-32 part,
Paraffin 21-45 part, dolomite dusts 5-10 part, bentonite 4-7 part, titanium dioxide 3-6 part, boron carbide 3-5 part, polyester fiber 4-6
Part, boron fibre 3-4 part, hydroxypropyl methyl cellulose 4-7 part, ceramic fibre 2-4 part, surfactant 0.4-0.7 part, degasser
0.3-0.6 part, levelling agent 0.3-0.8 part, dispersant 0.5-0.9 part, wetting agent 0.3-0.5 part, adhesion promoter 0.2-0.4
Part, catalyst 0.1-0.2 part, initiator 0.2-0.3 part, vertical stricture of vagina agent 0.4-0.6 part, toughener 0.3-0.5 part, optical brightener 0.3-
0.5 part, defoamer 0.3-0.6 part, viscosifier 0.3-0.5 part, firming agent 0.9-1.8 part, preservative 0.2-0.4 part, antioxidant
0.2-0.5 part, light stabilizer 0.1-0.2 part, heat stabilizer 0.2-0.4 part, UV absorbent 0.1-0.3 part, anti-settling agent
0.4-0.7 part, thickening agent 0.3-0.5 part, coalescents 0.3-0.6 part, fire retardant 1-1.4 part；
The surfactant is Tween 80；
The degasser is stearic acid；
The levelling agent is polydimethylsiloxane；
The dispersant is dispersant NNO；
The wetting agent is wetting agent X-405；
The adhesion promoter is adhesion promoter HF-1；
The catalyst is vanadic anhydride；
The initiator is two isopropylformic acid. of azo（Acrylic acid ethylene glycol）Ester；
The vertical stricture of vagina agent is mallear stria agent H-863；
The toughener is MBS terpolymer；
The optical brightener is optical brightener LD-608；
The defoamer is defoamer MSDS；
The viscosifier are propyl trimethoxy silicane；
The firming agent is p-hydroxybenzenyl sulfonate；
The preservative is Liquid BPF -369；
The antioxidant is antioxidant AT-330；
The light stabilizer is light stabilizer HS-3101；
The UV absorbent is oxybenzoic acid phenyl ester；
The anti-settling agent is modified hydrogenated Oleum Ricini；
The thickening agent is carrageenan；
The coalescents are propylene glycol methyl ether acetate；
The fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 12-24 part, 2,
2- dimethyl-trimethylene dimethylacrylate 10-15 part, APP 8-13 part, neopentyl glycol 5-12 part, carbamide 6-
10 parts, barium hydroxide 3-6 part, antimony oxide 5-9 part, aluminium oxide 2-5 part, bentonite 2-4 part, penetrating agent 0.5-1 part, synergistic
Agent 0.4-0.6 part；
The penetrating agent is fatty alcohol-polyoxyethylene ether
The synergist is ammonium sulfate；
The preparation method of the novel environment friendly pottery coating, comprises the following steps：
S1：By polyester resin, dipentaerythritol acrylate, linolenate, dodecenylsuccinic acid acid anhydride, paraffin, dolomite
Powder, bentonite, titanium dioxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surface activity
Agent, degasser, levelling agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, in microwave power be
152-185W, it is to stir 2.8-3h, prepared mixture a under 2200-2700r/min that temperature is 93-97 DEG C, rotating speed；
S2：To in mixture a obtained in step S1, add neopentyl glycol, benzoin ethyl ether, acrylic emulsion, thioacetamide molten
Liquid, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 128-167W in microwave power, and temperature is 122-126 DEG C, to turn
Speed is for stirring 3.3-5.1h, prepared mixture b under 400-600r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in mixture b obtained in step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 160-230W in microwave power, and temperature is 108-112 DEG C,
Rotating speed is to stir 1.5-3h, prepared mixture c under 300-500r/min；
The preparation method of the heat stabilizer, comprises the following steps：
S31：The active hargil waste water that bentonite and concentration are 18% is 2.5 by weight:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：Pasty material A obtained in step S31 is added in the inorganic mixed acid that concentration is 23%, the inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
Shape material A is 3.4 with the weight ratio of inorganic mixed acid:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight ratio of pasty material A is 2:158,94 DEG C are heated to, are maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：Pasty material B obtained in step S32 is carried out filter pressing under pressure is for 0.93MPa, prepared moisture content is 47% filter
Cake A；
S34：Add water stirring and dissolving to filter cake A obtained in step S33, amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h to precipitate solution completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：Filter cake B obtained in step S34 is added water stirring and dissolving, amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, the sodium hydroxide solution that concentration is 15% is added, slurry material C is obtained；
S36：Slurry material C obtained in step S35 is carried out filter pressing under pressure is for 0.96MPa, prepared moisture content is 44% filter cake
C；
S37：Filter cake C obtained in step S36 is placed in centrifuge, filter cake C is removed water under centrifugal rotational speed is for 6000r/min and is contained
Water rate is crushing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：Alkaline hargil obtained in step S37 is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：Slurry material D obtained in step S38 is carried out filter pressing under pressure is for 0.92MPa, prepared moisture content is 42% filter cake
D；
S310：Filter cake D obtained in step S39 is placed in centrifuge, under centrifugal rotational speed is for 6000r/min, removes water to filter cake D
Moisture content is crushing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of the fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, to stir
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 are added in mixture A obtained in step S3-1,
3- propylidene dimethylacrylate, neopentyl glycol, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is to stir 2h, prepared mixture B at 140W, temperature is 86 DEG C；
S3-3：Mixture B obtained in step S3-2 is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：Mixture c obtained in step S3 is melt extruded by extruder at 112-116 DEG C, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：Lamellar body obtained in step S4 is sheared using cutting knife, prepared pelletizing；
S6：150-170 mesh sieve, prepared novel environment friendly pottery coating is crossed after pelletizing obtained in step S5 is crushed.
Embodiment 1
A kind of novel environment friendly pottery coating, in units of weight, including following raw material：150 parts of polyester resin, dipentaerythritol
Six 58 parts of acrylate, 38 parts of linolenate, 25 parts of dodecenylsuccinic acid acid anhydride, 20 parts of neopentyl glycol, 16 parts of benzoin ethyl ether,
35 parts of acrylic emulsion, 25 parts of thioacetyl amine aqueous solution, 35 parts of paraffin, 8 parts of dolomite dusts, 6 parts of bentonite, 5 parts of titanium dioxide,
4 parts of boron carbide, 5 parts of polyester fiber, 3 parts of boron fibre, 6 parts of hydroxypropyl methyl cellulose, 3 parts of ceramic fibre, surfactant 0.6
Part, 0.5 part of degasser, 0.6 part of levelling agent, 0.7 part of dispersant, 0.4 part of wetting agent, 0.3 part of adhesion promoter, catalyst
0.1 part, 0.2 part of initiator, hang down 0.5 part of stricture of vagina agent, 0.4 part of toughener, 0.4 part of optical brightener, 0.5 part of defoamer, viscosifier 0.4
Part, 1.5 parts of firming agent, 0.3 part of preservative, 0.4 part of antioxidant, 0.1 part of light stabilizer, 0.3 part of heat stabilizer, ultra-violet absorption
0.2 part of agent, 0.6 part of anti-settling agent, 0.4 part of thickening agent, 0.5 part of coalescents, 1.2 parts of fire retardant；
The surfactant is Tween 80；
The degasser is stearic acid；
The levelling agent is polydimethylsiloxane；
The dispersant is dispersant NNO；
The wetting agent is wetting agent X-405；
The adhesion promoter is adhesion promoter HF-1；
The catalyst is vanadic anhydride；
The initiator is two isopropylformic acid. of azo（Acrylic acid ethylene glycol）Ester；
The vertical stricture of vagina agent is mallear stria agent H-863；
The toughener is MBS terpolymer；
The optical brightener is optical brightener LD-608；
The defoamer is defoamer MSDS；
The viscosifier are propyl trimethoxy silicane；
The firming agent is p-hydroxybenzenyl sulfonate；
The preservative is Liquid BPF -369；
The antioxidant is antioxidant AT-330；
The light stabilizer is light stabilizer HS-3101；
The UV absorbent is oxybenzoic acid phenyl ester；
The anti-settling agent is modified hydrogenated Oleum Ricini；
The thickening agent is carrageenan；
The coalescents are propylene glycol methyl ether acetate；
The fire retardant in units of weight portion, including following raw material：18 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 12 parts of 3- propylidene dimethylacrylate, 12 parts of APP, 9 parts of neopentyl glycol, 8 parts of carbamide, barium hydroxide 5
Part, 7 parts of antimony oxide, 4 parts of aluminium oxide, 3 parts of bentonite, 0.8 part of penetrating agent, 0.5 part of synergist；
The penetrating agent is fatty alcohol-polyoxyethylene ether
The synergist is ammonium sulfate；
The preparation method of the novel environment friendly pottery coating, comprises the following steps：
S1：By polyester resin, dipentaerythritol acrylate, linolenate, dodecenylsuccinic acid acid anhydride, paraffin, dolomite
Powder, bentonite, titanium dioxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surface activity
Agent, degasser, levelling agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, in microwave power be
172W, it is to stir 2.9h, prepared mixture a under 2500r/min that temperature is 95 DEG C, rotating speed；
S2：To in mixture a obtained in step S1, add neopentyl glycol, benzoin ethyl ether, acrylic emulsion, thioacetamide molten
Liquid, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 150W in microwave power, and temperature is that 125 DEG C, rotating speed is
4.2h, prepared mixture b is stirred under 500r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in mixture b obtained in step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 200W in microwave power, and temperature is that 110 DEG C, rotating speed is
2.3h, prepared mixture c is stirred under 400r/min；
The preparation method of the heat stabilizer, comprises the following steps：
S31：The active hargil waste water that bentonite and concentration are 18% is 2.5 by weight:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：Pasty material A obtained in step S31 is added in the inorganic mixed acid that concentration is 23%, the inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
Shape material A is 3.4 with the weight ratio of inorganic mixed acid:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight ratio of pasty material A is 2:158,94 DEG C are heated to, are maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：Pasty material B obtained in step S32 is carried out filter pressing under pressure is for 0.93MPa, prepared moisture content is 47% filter
Cake A；
S34：Add water stirring and dissolving to filter cake A obtained in step S33, amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h to precipitate solution completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：Filter cake B obtained in step S34 is added water stirring and dissolving, amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, the sodium hydroxide solution that concentration is 15% is added, slurry material C is obtained；
S36：Slurry material C obtained in step S35 is carried out filter pressing under pressure is for 0.96MPa, prepared moisture content is 44% filter cake
C；
S37：Filter cake C obtained in step S36 is placed in centrifuge, filter cake C is removed water under centrifugal rotational speed is for 6000r/min and is contained
Water rate is crushing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：Alkaline hargil obtained in step S37 is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：Slurry material D obtained in step S38 is carried out filter pressing under pressure is for 0.92MPa, prepared moisture content is 42% filter cake
D；
S310：Filter cake D obtained in step S39 is placed in centrifuge, under centrifugal rotational speed is for 6000r/min, removes water to filter cake D
Moisture content is crushing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of the fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, to stir
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 are added in mixture A obtained in step S3-1,
3- propylidene dimethylacrylate, neopentyl glycol, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is to stir 2h, prepared mixture B at 140W, temperature is 86 DEG C；
S3-3：Mixture B obtained in step S3-2 is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：Mixture c obtained in step S3 is melt extruded by extruder at 115 DEG C, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：Lamellar body obtained in step S4 is sheared using cutting knife, prepared pelletizing；
S6：160 mesh sieve, prepared novel environment friendly pottery coating is crossed after pelletizing obtained in step S5 is crushed.
Embodiment 2
A kind of novel environment friendly pottery coating, in units of weight, including following raw material：135 parts of polyester resin, dipentaerythritol
Six 55 parts of acrylate, 34 parts of linolenate, 22 parts of dodecenylsuccinic acid acid anhydride, 19 parts of neopentyl glycol, 12 parts of benzoin ethyl ether,
28 parts of acrylic emulsion, 22 parts of thioacetyl amine aqueous solution, 21 parts of paraffin, 6 parts of dolomite dusts, 4 parts of bentonite, 3 parts of titanium dioxide,
3 parts of boron carbide, 4 parts of polyester fiber, 3 parts of boron fibre, 4 parts of hydroxypropyl methyl cellulose, 2 parts of ceramic fibre, surfactant 0.5
Part, 0.3 part of degasser, 0.3 part of levelling agent, 0.5 part of dispersant, 0.3 part of wetting agent, 0.2 part of adhesion promoter, catalyst
0.1 part, 0.2 part of initiator, hang down 0.4 part of stricture of vagina agent, 0.3 part of toughener, 0.3 part of optical brightener, 0.3 part of defoamer, viscosifier 0.3
Part, 0.9 part of firming agent, 0.2 part of preservative, 0.2 part of antioxidant, 0.1 part of light stabilizer, 0.2 part of heat stabilizer, ultra-violet absorption
0.1 part of agent, 0.4 part of anti-settling agent, 0.3 part of thickening agent, 0.3 part of coalescents, 1 part of fire retardant；
The surfactant is Tween 80；
The degasser is stearic acid；
The levelling agent is polydimethylsiloxane；
The dispersant is dispersant NNO；
The wetting agent is wetting agent X-405；
The adhesion promoter is adhesion promoter HF-1；
The catalyst is vanadic anhydride；
The initiator is two isopropylformic acid. of azo（Acrylic acid ethylene glycol）Ester；
The vertical stricture of vagina agent is mallear stria agent H-863；
The toughener is MBS terpolymer；
The optical brightener is optical brightener LD-608；
The defoamer is defoamer MSDS；
The viscosifier are propyl trimethoxy silicane；
The firming agent is p-hydroxybenzenyl sulfonate；
The preservative is Liquid BPF -369；
The antioxidant is antioxidant AT-330；
The light stabilizer is light stabilizer HS-3101；
The UV absorbent is oxybenzoic acid phenyl ester；
The anti-settling agent is modified hydrogenated Oleum Ricini；
The thickening agent is carrageenan；
The coalescents are propylene glycol methyl ether acetate；
The fire retardant in units of weight portion, including following raw material：12 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 12 parts of 3- propylidene dimethylacrylate, 8 parts of APP, 5 parts of neopentyl glycol, 6 parts of carbamide, barium hydroxide 3
Part, 6 parts of antimony oxide, 2 parts of aluminium oxide, 2 parts of bentonite, 0.6 part of penetrating agent, 0.4 part of synergist；
The penetrating agent is fatty alcohol-polyoxyethylene ether
The synergist is ammonium sulfate；
The preparation method of the novel environment friendly pottery coating, comprises the following steps：
S1：By polyester resin, dipentaerythritol acrylate, linolenate, dodecenylsuccinic acid acid anhydride, paraffin, dolomite
Powder, bentonite, titanium dioxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surface activity
Agent, degasser, levelling agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, in microwave power be
152W, it is to stir 3h, prepared mixture a under 2200r/min that temperature is 93 DEG C, rotating speed；
S2：To in mixture a obtained in step S1, add neopentyl glycol, benzoin ethyl ether, acrylic emulsion, thioacetamide molten
Liquid, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 128W in microwave power, and temperature is that 122 DEG C, rotating speed is
5.1h, prepared mixture b is stirred under 400r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in mixture b obtained in step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 160W in microwave power, and temperature is that 108 DEG C, rotating speed is
3h, prepared mixture c is stirred under 300r/min；
The preparation method of the heat stabilizer, comprises the following steps：
S31：The active hargil waste water that bentonite and concentration are 18% is 2.5 by weight:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：Pasty material A obtained in step S31 is added in the inorganic mixed acid that concentration is 23%, the inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
Shape material A is 3.4 with the weight ratio of inorganic mixed acid:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight ratio of pasty material A is 2:158,94 DEG C are heated to, are maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：Pasty material B obtained in step S32 is carried out filter pressing under pressure is for 0.93MPa, prepared moisture content is 47% filter
Cake A；
S34：Add water stirring and dissolving to filter cake A obtained in step S33, amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h to precipitate solution completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：Filter cake B obtained in step S34 is added water stirring and dissolving, amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, the sodium hydroxide solution that concentration is 15% is added, slurry material C is obtained；
S36：Slurry material C obtained in step S35 is carried out filter pressing under pressure is for 0.96MPa, prepared moisture content is 44% filter cake
C；
S37：Filter cake C obtained in step S36 is placed in centrifuge, filter cake C is removed water under centrifugal rotational speed is for 6000r/min and is contained
Water rate is crushing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：Alkaline hargil obtained in step S37 is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：Slurry material D obtained in step S38 is carried out filter pressing under pressure is for 0.92MPa, prepared moisture content is 42% filter cake
D；
S310：Filter cake D obtained in step S39 is placed in centrifuge, under centrifugal rotational speed is for 6000r/min, removes water to filter cake D
Moisture content is crushing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of the fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, to stir
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 are added in mixture A obtained in step S3-1,
3- propylidene dimethylacrylate, neopentyl glycol, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is to stir 2h, prepared mixture B at 140W, temperature is 86 DEG C；
S3-3：Mixture B obtained in step S3-2 is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：Mixture c obtained in step S3 is melt extruded by extruder at 112 DEG C, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：Lamellar body obtained in step S4 is sheared using cutting knife, prepared pelletizing；
S6：150 mesh sieve, prepared novel environment friendly pottery coating is crossed after pelletizing obtained in step S5 is crushed.
Embodiment 3
A kind of novel environment friendly pottery coating, in units of weight, including following raw material：178 parts of polyester resin, dipentaerythritol
Six 79 parts of acrylate, 48 parts of linolenate, 31 parts of dodecenylsuccinic acid acid anhydride, 24 parts of neopentyl glycol, 18 parts of benzoin ethyl ether,
42 parts of acrylic emulsion, 32 parts of thioacetyl amine aqueous solution, 45 parts of paraffin, 10 parts of dolomite dusts, 7 parts of bentonite, titanium dioxide 6
Part, 5 parts of boron carbide, 6 parts of polyester fiber, 4 parts of boron fibre, 7 parts of hydroxypropyl methyl cellulose, 4 parts of ceramic fibre, surfactant
0.7 part, 0.6 part of degasser, 0.8 part of levelling agent, 0.9 part of dispersant, 0.5 part of wetting agent, 0.4 part of adhesion promoter, catalysis
0.2 part of agent, 0.3 part of initiator, 0.6 part of vertical stricture of vagina agent, 0.5 part of toughener, 0.5 part of optical brightener, 0.6 part of defoamer, viscosifier 0.5
Part, 1.8 parts of firming agent, 0.4 part of preservative, 0.5 part of antioxidant, 0.2 part of light stabilizer, 0.4 part of heat stabilizer, ultra-violet absorption
0.3 part of agent, 0.7 part of anti-settling agent, 0.5 part of thickening agent, 0.6 part of coalescents, 1.4 parts of fire retardant；
The surfactant is Tween 80；
The degasser is stearic acid；
The levelling agent is polydimethylsiloxane；
The dispersant is dispersant NNO；
The wetting agent is wetting agent X-405；
The adhesion promoter is adhesion promoter HF-1；
The catalyst is vanadic anhydride；
The initiator is two isopropylformic acid. of azo（Acrylic acid ethylene glycol）Ester；
The vertical stricture of vagina agent is mallear stria agent H-863；
The toughener is MBS terpolymer；
The optical brightener is optical brightener LD-608；
The defoamer is defoamer MSDS；
The viscosifier are propyl trimethoxy silicane；
The firming agent is p-hydroxybenzenyl sulfonate；
The preservative is Liquid BPF -369；
The antioxidant is antioxidant AT-330；
The light stabilizer is light stabilizer HS-3101；
The UV absorbent is oxybenzoic acid phenyl ester；
The anti-settling agent is modified hydrogenated Oleum Ricini；
The thickening agent is carrageenan；
The coalescents are propylene glycol methyl ether acetate；
The fire retardant in units of weight portion, including following raw material：24 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 15 parts of 3- propylidene dimethylacrylate, 13 parts of APP, 12 parts of neopentyl glycol, 10 parts of carbamide, barium hydroxide
6 parts, 9 parts of antimony oxide, 5 parts of aluminium oxide, 4 parts of bentonite, 1 part of penetrating agent, 0.6 part of synergist；
The penetrating agent is fatty alcohol-polyoxyethylene ether
The synergist is ammonium sulfate；
The preparation method of the novel environment friendly pottery coating, comprises the following steps：
S1：By polyester resin, dipentaerythritol acrylate, linolenate, dodecenylsuccinic acid acid anhydride, paraffin, dolomite
Powder, bentonite, titanium dioxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surface activity
Agent, degasser, levelling agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, in microwave power be
185W, it is to stir 2.8h, prepared mixture a under 2700r/min that temperature is 97 DEG C, rotating speed；
S2：To in mixture a obtained in step S1, add neopentyl glycol, benzoin ethyl ether, acrylic emulsion, thioacetamide molten
Liquid, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 167W in microwave power, and temperature is that 126 DEG C, rotating speed is
3.3h, prepared mixture b is stirred under 600r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in mixture b obtained in step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 230W in microwave power, and temperature is that 112 DEG C, rotating speed is
1.5h, prepared mixture c is stirred under 500r/min；
The preparation method of the heat stabilizer, comprises the following steps：
S31：The active hargil waste water that bentonite and concentration are 18% is 2.5 by weight:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：Pasty material A obtained in step S31 is added in the inorganic mixed acid that concentration is 23%, the inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
Shape material A is 3.4 with the weight ratio of inorganic mixed acid:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight ratio of pasty material A is 2:158,94 DEG C are heated to, are maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：Pasty material B obtained in step S32 is carried out filter pressing under pressure is for 0.93MPa, prepared moisture content is 47% filter
Cake A；
S34：Add water stirring and dissolving to filter cake A obtained in step S33, amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h to precipitate solution completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：Filter cake B obtained in step S34 is added water stirring and dissolving, amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, the sodium hydroxide solution that concentration is 15% is added, slurry material C is obtained；
S36：Slurry material C obtained in step S35 is carried out filter pressing under pressure is for 0.96MPa, prepared moisture content is 44% filter cake
C；
S37：Filter cake C obtained in step S36 is placed in centrifuge, filter cake C is removed water under centrifugal rotational speed is for 6000r/min and is contained
Water rate is crushing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：Alkaline hargil obtained in step S37 is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：Slurry material D obtained in step S38 is carried out filter pressing under pressure is for 0.92MPa, prepared moisture content is 42% filter cake
D；
S310：Filter cake D obtained in step S39 is placed in centrifuge, under centrifugal rotational speed is for 6000r/min, removes water to filter cake D
Moisture content is crushing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of the fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, to stir
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 are added in mixture A obtained in step S3-1,
3- propylidene dimethylacrylate, neopentyl glycol, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is to stir 2h, prepared mixture B at 140W, temperature is 86 DEG C；
S3-3：Mixture B obtained in step S3-2 is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：Mixture c obtained in step S3 is melt extruded by extruder at 116 DEG C, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：Lamellar body obtained in step S4 is sheared using cutting knife, prepared pelletizing；
S6：170 mesh sieve, prepared novel environment friendly pottery coating is crossed after pelletizing obtained in step S5 is crushed.
Obtained in detection embodiment 1-3, the performance indications of novel environment friendly pottery coating, as a result as shown in the table.
As seen from the above table：The coating of the present invention had both had excellent adhesive force and mechanical property, and with excellent resistance to height
Temperature, impact resistance and hardness, while rate of drying is fast and toxic is minimum, it is that a kind of pottery of excellent combination property is applied with environmental protection
Material.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanations, for the present invention affiliated technology neck
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made,
The scope of patent protection that the present invention is determined should be all considered as belonging to by the claims that is submitted to.
Claims (7)
1. a kind of novel environment friendly pottery coating, it is characterised in that in units of weight, including following raw material：Polyester resin
135-178 part, dipentaerythritol acrylate 55-79 part, linolenate 34-48 part, dodecenylsuccinic acid acid anhydride 22-31
Part, neopentyl glycol 19-24 part, benzoin ethyl ether 12-18 part, acrylic emulsion 28-42 part, thioacetyl amine aqueous solution 22-32 part,
Paraffin 21-45 part, dolomite dusts 5-10 part, bentonite 4-7 part, titanium dioxide 3-6 part, boron carbide 3-5 part, polyester fiber 4-6
Part, boron fibre 3-4 part, hydroxypropyl methyl cellulose 4-7 part, ceramic fibre 2-4 part, surfactant 0.4-0.7 part, degasser
0.3-0.6 part, levelling agent 0.3-0.8 part, dispersant 0.5-0.9 part, wetting agent 0.3-0.5 part, adhesion promoter 0.2-0.4
Part, catalyst 0.1-0.2 part, initiator 0.2-0.3 part, vertical stricture of vagina agent 0.4-0.6 part, toughener 0.3-0.5 part, optical brightener 0.3-
0.5 part, defoamer 0.3-0.6 part, viscosifier 0.3-0.5 part, firming agent 0.9-1.8 part, preservative 0.2-0.4 part, antioxidant
0.2-0.5 part, light stabilizer 0.1-0.2 part, heat stabilizer 0.2-0.4 part, UV absorbent 0.1-0.3 part, anti-settling agent
0.4-0.7 part, thickening agent 0.3-0.5 part, coalescents 0.3-0.6 part, fire retardant 1-1.4 part；
The dispersant is dispersant NNO；
The wetting agent is wetting agent X-405；
The adhesion promoter is adhesion promoter HF-1；
The catalyst is vanadic anhydride；
The initiator is two isopropylformic acid. of azo（Acrylic acid ethylene glycol）Ester；
The vertical stricture of vagina agent is mallear stria agent H-863；
The toughener is MBS terpolymer；
The viscosifier are propyl trimethoxy silicane；
The firming agent is p-hydroxybenzenyl sulfonate；
The preservative is Liquid BPF -369；
The antioxidant is antioxidant AT-330；
The light stabilizer is light stabilizer HS-3101；
The UV absorbent is oxybenzoic acid phenyl ester；
The thickening agent is carrageenan；
The coalescents are propylene glycol methyl ether acetate；
The fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 12-24 part, 2,
2- dimethyl-trimethylene dimethylacrylate 10-15 part, APP 8-13 part, neopentyl glycol 5-12 part, carbamide 6-
10 parts, barium hydroxide 3-6 part, antimony oxide 5-9 part, aluminium oxide 2-5 part, bentonite 2-4 part, penetrating agent 0.5-1 part, synergistic
Agent 0.4-0.6 part；
The penetrating agent is fatty alcohol-polyoxyethylene ether
The synergist is ammonium sulfate；
The preparation method of the novel environment friendly pottery coating, comprises the following steps：
S1：By polyester resin, dipentaerythritol acrylate, linolenate, dodecenylsuccinic acid acid anhydride, paraffin, dolomite
Powder, bentonite, titanium dioxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surface activity
Agent, degasser, levelling agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, in microwave power be
152-185W, it is to stir 2.8-3h, prepared mixture a under 2200-2700r/min that temperature is 93-97 DEG C, rotating speed；
S2：To in mixture a obtained in step S1, add neopentyl glycol, benzoin ethyl ether, acrylic emulsion, thioacetamide molten
Liquid, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 128-167W in microwave power, and temperature is 122-126 DEG C, to turn
Speed is for stirring 3.3-5.1h, prepared mixture b under 400-600r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in mixture b obtained in step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 160-230W in microwave power, and temperature is 108-112 DEG C,
Rotating speed is to stir 1.5-3h, prepared mixture c under 300-500r/min；
The preparation method of the heat stabilizer, comprises the following steps：
S31：The active hargil waste water that bentonite and concentration are 18% is 2.5 by weight:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：Pasty material A obtained in step S31 is added in the inorganic mixed acid that concentration is 23%, the inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
Shape material A is 3.4 with the weight ratio of inorganic mixed acid:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight ratio of pasty material A is 2:158,94 DEG C are heated to, are maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：Pasty material B obtained in step S32 is carried out filter pressing under pressure is for 0.93MPa, prepared moisture content is 47% filter
Cake A；
S34：Add water stirring and dissolving to filter cake A obtained in step S33, amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h to precipitate solution completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：Filter cake B obtained in step S34 is added water stirring and dissolving, amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, the sodium hydroxide solution that concentration is 15% is added, slurry material C is obtained；
S36：Slurry material C obtained in step S35 is carried out filter pressing under pressure is for 0.96MPa, prepared moisture content is 44% filter cake
C；
S37：Filter cake C obtained in step S36 is placed in centrifuge, filter cake C is removed water under centrifugal rotational speed is for 6000r/min and is contained
Water rate is crushing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：Alkaline hargil obtained in step S37 is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：Slurry material D obtained in step S38 is carried out filter pressing under pressure is for 0.92MPa, prepared moisture content is 42% filter cake
D；
S310：Filter cake D obtained in step S39 is placed in centrifuge, under centrifugal rotational speed is for 6000r/min, removes water to filter cake D
Moisture content is crushing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of the fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, to stir
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 are added in mixture A obtained in step S3-1,
3- propylidene dimethylacrylate, neopentyl glycol, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is to stir 2h, prepared mixture B at 140W, temperature is 86 DEG C；
S3-3：Mixture B obtained in step S3-2 is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：Mixture c obtained in step S3 is melt extruded by extruder at 112-116 DEG C, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：Lamellar body obtained in step S4 is sheared using cutting knife, prepared pelletizing；
S6：150-170 mesh sieve, prepared novel environment friendly pottery coating is crossed after pelletizing obtained in step S5 is crushed.
2. novel environment friendly pottery coating according to claim 1, it is characterised in that the surfactant be.
3. novel environment friendly pottery coating according to claim 1, it is characterised in that the degasser be.
4. novel environment friendly pottery coating according to claim 1, it is characterised in that the levelling agent be
Alkane.
5. novel environment friendly pottery coating according to claim 1, it is characterised in that the optical brightener be
608.
6. novel environment friendly pottery coating according to claim 1, it is characterised in that the defoamer be.
7. novel environment friendly pottery coating according to claim 1, it is characterised in that the anti-settling agent be
Oil.
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| CN201610884542.9A CN106433377A (en) | 2016-10-11 | 2016-10-11 | Novel environmental-friendly ceramic paint |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610884542.9A CN106433377A (en) | 2016-10-11 | 2016-10-11 | Novel environmental-friendly ceramic paint |
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ID=58173156
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234580A (en) * | 2020-03-23 | 2020-06-05 | 福建省盛荣生态花卉研究院有限责任公司 | Special anticorrosive paint for ceramics and preparation method thereof |
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| CN102875851A (en) * | 2012-09-12 | 2013-01-16 | 山东长星集团有限公司 | Environment-friendly flame retardant |
| CN104177648A (en) * | 2014-08-03 | 2014-12-03 | 马晓权 | Tire flame retardant |
| CN104371747A (en) * | 2014-09-30 | 2015-02-25 | 滁州斯迈特复合材料有限公司 | Fire retardant for air-conditioning cabinet |
| CN105885300A (en) * | 2016-06-25 | 2016-08-24 | 张莘蔓 | Novel environment-friendly PVC (polyvinyl chloride) heat stabilizer |
| CN105949969A (en) * | 2016-06-27 | 2016-09-21 | 广西平果宝信涂料有限公司 | Sand-textured weather-resistant powder coating and preparation method thereof |
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2016
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Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875851A (en) * | 2012-09-12 | 2013-01-16 | 山东长星集团有限公司 | Environment-friendly flame retardant |
| CN104177648A (en) * | 2014-08-03 | 2014-12-03 | 马晓权 | Tire flame retardant |
| CN104371747A (en) * | 2014-09-30 | 2015-02-25 | 滁州斯迈特复合材料有限公司 | Fire retardant for air-conditioning cabinet |
| CN105885300A (en) * | 2016-06-25 | 2016-08-24 | 张莘蔓 | Novel environment-friendly PVC (polyvinyl chloride) heat stabilizer |
| CN105949969A (en) * | 2016-06-27 | 2016-09-21 | 广西平果宝信涂料有限公司 | Sand-textured weather-resistant powder coating and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234580A (en) * | 2020-03-23 | 2020-06-05 | 福建省盛荣生态花卉研究院有限责任公司 | Special anticorrosive paint for ceramics and preparation method thereof |
| CN111234580B (en) * | 2020-03-23 | 2021-06-29 | 潮州市德科陶瓷有限公司 | Special anticorrosive paint for ceramics and preparation method thereof |
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Application publication date: 20170222 |