CN106398362A - Ceramic coating - Google Patents
Ceramic coating Download PDFInfo
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- CN106398362A CN106398362A CN201610884510.9A CN201610884510A CN106398362A CN 106398362 A CN106398362 A CN 106398362A CN 201610884510 A CN201610884510 A CN 201610884510A CN 106398362 A CN106398362 A CN 106398362A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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Abstract
The invention discloses a ceramic coating. The ceramic coating is prepared from polyester resin, rosin resin, acrylic resin, maleic anhydride, tert-dodecylmercaptan, benzoin ether, an acrylic emulsion, a glutamine solution, polybutylene wax, talcum powder, bentonite, titanium dioxide, boron carbide, polyester fibers, boron fibers, hydroxypropylmethylcellulose, ceramic fibers, a surfactant, a degassing agent, a leveling agent, a dispersant, a wetting agent, an adhesion promoter, a catalyst, an initiator, a hammer finish additive, a flexibilizer, a sensitizer, a defoamer, a tackifier, a curing agent, an antiseptic, an antioxidant, a light stabilizer, a heat stabilizer, an UV absorbent, an anti-settling agent, a thickener, a film forming aid and a flame retardant. The coating material has excellent adhesion and mechanical properties, excellent high temperature resistance, impact resistance and hardness, has a fast drying rate and low toxicity, and is an excellent eco-friendly coating for ceramics.
Description
【Technical field】
The invention belongs to coating preparation technology neck is and in particular to a kind of pottery coating.
【Background technology】
Coating is typically based on resin or oil, and plus or is not added with face, filler, with the viscous solution of organic solvent or water modulation
Body, also occurs in that the coating new varieties such as powdery paints existing with solid forms.No matter form (the liquid of all kinds of coating coating varieties
Body or solid) how, at least should be made up of two or three basis.It is divided into main film forming substance；Subsidiary film forming matter
And auxiliary film forming matter.Coating can be coated on surface of bottom material and form the liquid or solid macromolecule of tough and tensile continuous film (paint film)
Material.It is once called as paint, paint.It is mainly used to play decoration and protective effect to by painting surface.Some coating also have specific work(
Can, such as high temperature resistant, cold-resistant, radioprotective etc..Coating is widely used in the aspects such as building, ship, vehicle, metallic article.Coating English
Literary fame claims：Coating products defines：Be applied to body surface can be formed have protection decoration or property (as insulation,
Anti-corrosion, mark etc.) a class I liquid I of solid coated film or the general name of solid material.Coating type is various, purposes is extremely wide.In its people
Play an important role in economy and people's lives.Year is the important indicator of a national living standard using coating content per capita.
Special cermacis is as Modern appliances, and radio, aviation, atomic energy, metallurgy, machinery, chemistry etc. are industrial and electric
The developing by leaps and bounds of advanced science technology such as sub- computer, space technology, new energy development and grow up.Used by these potteries
Primary raw material be no longer clay, Anhydrite, quartz, some bases not also using some clays or Anhydrite, but more be adopt
Oxide purely and the raw material with property, manufacturing process is also different with performance requirement.Reform and open up to the outside world 30 years
Come, Chinese pottery industrial boom, nowadays become genuine Production of Ceramics big country, consumption big country in the world.China is raw
The domestic ceramics yield produced accounts for global 70% about, and display art ceramic yield is the 65% of the whole world, architectural pottery yield
Also account for Gross World Product half of the country.China industry occupies very important status in world's building material industry.
Polyester, by polyhydric alcohol and polymer general name obtained by polyprotic acid polycondensation.Refer mainly to polyethylene terephthalate (
PET), linear thermoplastic's resins such as polybutylene terephthalate (PBT) and polyarylate are traditionally also included.It is a class
Can excellent, broad-spectrum engineering plastics.May be made as polyester fiber and mylar.The organic synthesiss that acrylic acid is important are former
Material and synthetic resin monomer, are the very fast vinyl monomers of polymerization speed.It is simplest unsaturated carboxylic acid, by an ethylene
Base and a carboxyl composition.Pure acrylic acid is colorless clear liquid, the penetrating odor with feature.It can be with water, alcohol, ether
Dissolve each other with chloroform, be by the propylene preparation obtaining from oil plant.Great majority are in order to manufacture acrylic acid methyl ester., ethyl ester, butyl ester, hydroxyl
The esters of acrylic acids such as ethyl ester.Acrylic acid and acrylate can be with homopolymerization and copolymerization, and its polymer is used for synthetic resin, synthesis fibre
The industrial departments such as dimension, super absorbent resin, building materials, coating.Ceramic coating is that one kind can make Organic substance react with inorganic matters,
Thus having had both the novel ceramic coating of both advantages.The hardness of the ceramic coating of a new generation can reach more than 6H.High temperature resistant
400 DEG C, do not glue effect, color is multiple.And the popularization with humanity concept, and the composition of new harmonious society, design one kind
Adhesive force is good, impact resistance, high temperature resistant, hardness are high and fast drying pottery environmental protection coating material is very important.
【Content of the invention】
The present invention provides a kind of pottery coating, to solve that existing pottery paint adhesion is poor, not impact resistance and high temperature, hardness
Low, slow and toxicity big the problems such as is dried.The coating of the present invention had both had excellent adhesive force and mechanical property, had excellent again
High temperature resistant, impact resistance and hardness, rate of drying is fast and toxic is minimum simultaneously, is a kind of pottery environmental protection of excellent combination property
Coating.
For solving above technical problem, the present invention employs the following technical solutions：
A kind of pottery coating, in units of weight, including following raw material：Polyester resin 130-180 part, rosin resin 50-70
Part, acrylic resin 30-50 part, maleic anhydride 18-32 part, tert-dodecylmercaotan 16-25 part, benzoin ethyl ether 12-
18 parts, acrylic emulsion 27-42 part, glutamine solution 20-32 part, polybutene wax 22-45 part, Pulvis Talci 5-10 part, swelling
Native 4-7 part, titanium dioxide 3-6 part, boron carbide 3-5 part, polyester fiber 4-6 part, boron fibre 3-4 part, hydroxypropyl methyl cellulose
4-7 part, ceramic fibre 2-4 part, surfactant 0.4-0.7 part, degasser 0.3-0.6 part, levelling agent 0.3-0.8 part, dispersion
Agent 0.5-0.9 part, wetting agent 0.3-0.5 part, adhesion promoter 0.2-0.4 part, catalyst 0.1-0.2 part, initiator 0.2-
0.3 part, vertical stricture of vagina agent 0.4-0.6 part, toughener 0.3-0.5 part, optical brightener 0.3-0.5 part, defoamer 0.3-0.6 part, viscosifier
0.3-0.5 part, firming agent 0.9-1.8 part, preservative 0.2-0.4 part, antioxidant 0.2-0.5 part, light stabilizer 0.1-0.2 part,
Heat stabilizer 0.2-0.4 part, UV absorbent 0.1-0.3 part, anti-settling agent 0.4-0.7 part, thickening agent 0.3-0.5 part, film forming
Auxiliary agent 0.3-0.6 part, fire retardant 1-1.4 part；
Described dispersant is dispersant NNO；
Described wetting agent is wetting agent X-405；
Described adhesion promoter is adhesion promoter HF-1；
Described catalyst is vanadic anhydride；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is mallear stria agent H-863；
Described toughener is MBS terpolymer；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is p-hydroxybenzenyl sulfonate；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester；
Described thickening agent is carrageenan；
Described coalescents are propylene glycol methyl ether acetate；
Described fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 12-24 part, 2,
2- dimethyl-trimethylene dimethylacrylate 10-15 part, APP 8-13 part, tetramethylolmethane 5-12 part, carbamide 6-
10 parts, barium hydroxide 3-6 part, antimony oxide 5-9 part, aluminium oxide 2-5 part, bentonite 2-4 part, penetrating agent 0.5-1 part, synergistic
Agent 0.4-0.6 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described pottery coating, comprises the following steps：
S1：By polyester resin, rosin resin, acrylic resin, maleic anhydride, polybutene wax, Pulvis Talci, bentonite, two
Titanium oxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surfactant, degasser, stream
Flat agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, are 140-180W in microwave power, temperature is
92-96 DEG C, rotating speed is to stir 3-3.5h, prepared mixture a under 2000-2600r/min；
S2：Tert-dodecylmercaotan, benzoin ethyl ether, acrylic emulsion, glutamy is added in the mixture a being obtained to step S1
Amine aqueous solution, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 120-160W in microwave power, and temperature is 118-126
DEG C, rotating speed is to stir 3.2-4.8h, prepared mixture b under 400-600r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 150-220W in microwave power, and temperature is 102-108 DEG C,
Rotating speed is to stir 2.2-3.8h, prepared mixture c under 200-400r/min；
The preparation method of described heat stabilizer, comprises the following steps：
S31：By bentonite and concentration be 18% active hargil waste water by weight for 2.5:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：The pasty material A that step S31 is obtained is added in the inorganic mixed acid that concentration is 23%, described inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
The weight of shape material A and inorganic mixed acid is than for 3.4:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight of pasty material A is than for 2:158, it is heated to 94 DEG C, be maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：The pasty material B that step S32 is obtained carries out filter pressing under pressure is for 0.93MPa, and prepared moisture content is 47% filter
Cake A；
S34：The filter cake A being obtained to step S33 adds water stirring and dissolving, and amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h so that solution is precipitated completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：The filter cake B that step S34 is obtained adds water stirring and dissolving, and amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, add the sodium hydroxide solution that concentration is 15%, slurry material C is obtained；
S36：The slurry material C that step S35 is obtained carries out filter pressing under pressure is for 0.96MPa, and prepared moisture content is 44% filter cake
C；
S37：The filter cake C that step S36 is obtained is placed in centrifuge, removes water to filter cake C and contain under centrifugal rotational speed is for 6000r/min
Water rate is pulverizing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：The alkaline hargil that step S37 is obtained is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：The slurry material D that step S38 is obtained carries out filter pressing under pressure is for 0.92MPa, and prepared moisture content is 42% filter cake
D；
S310：The filter cake D that step S39 is obtained is placed in centrifuge, removes water to filter cake D under centrifugal rotational speed is for 6000r/min
Moisture content is pulverizing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of described fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, stirring
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 is added in the mixture A being obtained to step S3-1,
3- propylidene dimethylacrylate, tetramethylolmethane, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is 140W, and temperature stirs 2h, prepared mixture B at being 86 DEG C；
S3-3：The mixture B that step S3-2 is obtained is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112-116 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 150-170 mesh sieve, prepared pottery coating after pulverizing.
Further, described surfactant is Tween 80.
Further, described degasser is stearic acid.
Further, described levelling agent is polydimethylsiloxane.
Further, described optical brightener is optical brightener LD-608.
Further, described defoamer is defoamer MSDS.
Further, described anti-settling agent is modified hydrogenated Oleum Ricini.
The invention has the advantages that：
The coating of the present invention had both had excellent adhesive force and mechanical property, had excellent high temperature resistant, impact resistance and hardness again,
Rate of drying is fast and toxic is minimum simultaneously, is a kind of pottery environmental protection coating material of excellent combination property.
【Specific embodiment】
For ease of more fully understanding the present invention, it is illustrated by following examples, these embodiments belong to the protection of the present invention
Scope, but do not limit the scope of the invention.
In an embodiment, described pottery coating, in units of weight, including following raw material：Polyester resin 130-180
Part, rosin resin 50-70 part, acrylic resin 30-50 part, maleic anhydride 18-32 part, tert-dodecylmercaotan 16-25
Part, benzoin ethyl ether 12-18 part, acrylic emulsion 27-42 part, glutamine solution 20-32 part, polybutene wax 22-45 part, cunning
Stone powder 5-10 part, bentonite 4-7 part, titanium dioxide 3-6 part, boron carbide 3-5 part, polyester fiber 4-6 part, boron fibre 3-4 part, hydroxyl
Propyl methocel 4-7 part, ceramic fibre 2-4 part, surfactant 0.4-0.7 part, degasser 0.3-0.6 part, levelling agent
0.3-0.8 part, dispersant 0.5-0.9 part, wetting agent 0.3-0.5 part, adhesion promoter 0.2-0.4 part, catalyst 0.1-0.2
Part, initiator 0.2-0.3 part, vertical stricture of vagina agent 0.4-0.6 part, toughener 0.3-0.5 part, optical brightener 0.3-0.5 part, defoamer 0.3-
0.6 part, viscosifier 0.3-0.5 part, firming agent 0.9-1.8 part, preservative 0.2-0.4 part, antioxidant 0.2-0.5 part, light stable
Agent 0.1-0.2 part, heat stabilizer 0.2-0.4 part, UV absorbent 0.1-0.3 part, anti-settling agent 0.4-0.7 part, thickening agent
0.3-0.5 part, coalescents 0.3-0.6 part, fire retardant 1-1.4 part；
Described surfactant is Tween 80；
Described degasser is stearic acid；
Described levelling agent is polydimethylsiloxane；
Described dispersant is dispersant NNO；
Described wetting agent is wetting agent X-405；
Described adhesion promoter is adhesion promoter HF-1；
Described catalyst is vanadic anhydride；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is mallear stria agent H-863；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer MSDS；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is p-hydroxybenzenyl sulfonate；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester；
Described anti-settling agent is modified hydrogenated Oleum Ricini；
Described thickening agent is carrageenan；
Described coalescents are propylene glycol methyl ether acetate；
Described fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 12-24 part, 2,
2- dimethyl-trimethylene dimethylacrylate 10-15 part, APP 8-13 part, tetramethylolmethane 5-12 part, carbamide 6-
10 parts, barium hydroxide 3-6 part, antimony oxide 5-9 part, aluminium oxide 2-5 part, bentonite 2-4 part, penetrating agent 0.5-1 part, synergistic
Agent 0.4-0.6 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described pottery coating, comprises the following steps：
S1：By polyester resin, rosin resin, acrylic resin, maleic anhydride, polybutene wax, Pulvis Talci, bentonite, two
Titanium oxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surfactant, degasser, stream
Flat agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, are 140-180W in microwave power, temperature is
92-96 DEG C, rotating speed is to stir 3-3.5h, prepared mixture a under 2000-2600r/min；
S2：Tert-dodecylmercaotan, benzoin ethyl ether, acrylic emulsion, glutamy is added in the mixture a being obtained to step S1
Amine aqueous solution, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 120-160W in microwave power, and temperature is 118-126
DEG C, rotating speed is to stir 3.2-4.8h, prepared mixture b under 400-600r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 150-220W in microwave power, and temperature is 102-108 DEG C,
Rotating speed is to stir 2.2-3.8h, prepared mixture c under 200-400r/min；
The preparation method of described heat stabilizer, comprises the following steps：
S31：By bentonite and concentration be 18% active hargil waste water by weight for 2.5:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：The pasty material A that step S31 is obtained is added in the inorganic mixed acid that concentration is 23%, described inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
The weight of shape material A and inorganic mixed acid is than for 3.4:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight of pasty material A is than for 2:158, it is heated to 94 DEG C, be maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：The pasty material B that step S32 is obtained carries out filter pressing under pressure is for 0.93MPa, and prepared moisture content is 47% filter
Cake A；
S34：The filter cake A being obtained to step S33 adds water stirring and dissolving, and amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h so that solution is precipitated completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：The filter cake B that step S34 is obtained adds water stirring and dissolving, and amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, add the sodium hydroxide solution that concentration is 15%, slurry material C is obtained；
S36：The slurry material C that step S35 is obtained carries out filter pressing under pressure is for 0.96MPa, and prepared moisture content is 44% filter cake
C；
S37：The filter cake C that step S36 is obtained is placed in centrifuge, removes water to filter cake C and contain under centrifugal rotational speed is for 6000r/min
Water rate is pulverizing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：The alkaline hargil that step S37 is obtained is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：The slurry material D that step S38 is obtained carries out filter pressing under pressure is for 0.92MPa, and prepared moisture content is 42% filter cake
D；
S310：The filter cake D that step S39 is obtained is placed in centrifuge, removes water to filter cake D under centrifugal rotational speed is for 6000r/min
Moisture content is pulverizing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of described fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, stirring
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 is added in the mixture A being obtained to step S3-1,
3- propylidene dimethylacrylate, tetramethylolmethane, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is 140W, and temperature stirs 2h, prepared mixture B at being 86 DEG C；
S3-3：The mixture B that step S3-2 is obtained is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112-116 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 150-170 mesh sieve, prepared pottery coating after pulverizing.
Embodiment 1
A kind of pottery coating, in units of weight, including following raw material：150 parts of polyester resin, 58 parts of rosin resin, propylene
38 parts of acid resin, 25 parts of maleic anhydride, 20 parts of tert-dodecylmercaotan, 16 parts of benzoin ethyl ether, 35 parts of acrylic emulsion,
25 parts of glutamine solution, 35 parts of polybutene wax, 8 parts of Pulvis Talci, 6 parts of bentonite, 5 parts of titanium dioxide, 4 parts of boron carbide, polyester
5 parts of fiber, 3 parts of boron fibre, 6 parts of hydroxypropyl methyl cellulose, 3 parts of ceramic fibre, 0.6 part of surfactant, degasser 0.5
Part, 0.6 part of levelling agent, 0.7 part of dispersant, 0.4 part of wetting agent, 0.3 part of adhesion promoter, 0.1 part of catalyst, initiator
0.2 part, vertical 0.5 part of stricture of vagina agent, 0.4 part of toughener, 0.4 part of optical brightener, 0.5 part of defoamer, 0.4 part of viscosifier, firming agent 1.5
Part, 0.3 part of preservative, 0.4 part of antioxidant, 0.1 part of light stabilizer, 0.3 part of heat stabilizer, 0.2 part of UV absorbent, anti-settling
0.6 part of agent, 0.4 part of thickening agent, 0.5 part of coalescents, 1.2 parts of fire retardant；
Described surfactant is Tween 80；
Described degasser is stearic acid；
Described levelling agent is polydimethylsiloxane；
Described dispersant is dispersant NNO；
Described wetting agent is wetting agent X-405；
Described adhesion promoter is adhesion promoter HF-1；
Described catalyst is vanadic anhydride；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is mallear stria agent H-863；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer MSDS；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is p-hydroxybenzenyl sulfonate；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester；
Described anti-settling agent is modified hydrogenated Oleum Ricini；
Described thickening agent is carrageenan；
Described coalescents are propylene glycol methyl ether acetate；
Described fire retardant in units of weight portion, including following raw material：18 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 12 parts of 3- propylidene dimethylacrylate, 12 parts of APP, 9 parts of tetramethylolmethane, 8 parts of carbamide, barium hydroxide 5
Part, 7 parts of antimony oxide, 4 parts of aluminium oxide, 3 parts of bentonite, 0.8 part of penetrating agent, 0.5 part of synergist；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described pottery coating, comprises the following steps：
S1：By polyester resin, rosin resin, acrylic resin, maleic anhydride, polybutene wax, Pulvis Talci, bentonite, two
Titanium oxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surfactant, degasser, stream
Flat agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, are 160W in microwave power, and temperature is 95
DEG C, rotating speed is to stir 3.2h, prepared mixture a under 2500r/min；
S2：Tert-dodecylmercaotan, benzoin ethyl ether, acrylic emulsion, glutamy is added in the mixture a being obtained to step S1
Amine aqueous solution, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 150W in microwave power, temperature is 122 DEG C, rotating speed is
3.9h, prepared mixture b is stirred under 500r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 200W in microwave power, and temperature is 106 DEG C, and rotating speed is
3h, prepared mixture c is stirred under 300r/min；
The preparation method of described heat stabilizer, comprises the following steps：
S31：By bentonite and concentration be 18% active hargil waste water by weight for 2.5:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：The pasty material A that step S31 is obtained is added in the inorganic mixed acid that concentration is 23%, described inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
The weight of shape material A and inorganic mixed acid is than for 3.4:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight of pasty material A is than for 2:158, it is heated to 94 DEG C, be maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：The pasty material B that step S32 is obtained carries out filter pressing under pressure is for 0.93MPa, and prepared moisture content is 47% filter
Cake A；
S34：The filter cake A being obtained to step S33 adds water stirring and dissolving, and amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h so that solution is precipitated completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：The filter cake B that step S34 is obtained adds water stirring and dissolving, and amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, add the sodium hydroxide solution that concentration is 15%, slurry material C is obtained；
S36：The slurry material C that step S35 is obtained carries out filter pressing under pressure is for 0.96MPa, and prepared moisture content is 44% filter cake
C；
S37：The filter cake C that step S36 is obtained is placed in centrifuge, removes water to filter cake C and contain under centrifugal rotational speed is for 6000r/min
Water rate is pulverizing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：The alkaline hargil that step S37 is obtained is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：The slurry material D that step S38 is obtained carries out filter pressing under pressure is for 0.92MPa, and prepared moisture content is 42% filter cake
D；
S310：The filter cake D that step S39 is obtained is placed in centrifuge, removes water to filter cake D under centrifugal rotational speed is for 6000r/min
Moisture content is pulverizing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of described fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, stirring
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 is added in the mixture A being obtained to step S3-1,
3- propylidene dimethylacrylate, tetramethylolmethane, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is 140W, and temperature stirs 2h, prepared mixture B at being 86 DEG C；
S3-3：The mixture B that step S3-2 is obtained is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 115 DEG C by extruder, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 160 mesh sieve, prepared pottery coating after pulverizing.
Embodiment 2
A kind of pottery coating, in units of weight, including following raw material：135 parts of polyester resin, 52 parts of rosin resin, propylene
32 parts of acid resin, 18 parts of maleic anhydride, 16 parts of tert-dodecylmercaotan, 12 parts of benzoin ethyl ether, 30 parts of acrylic emulsion,
20 parts of glutamine solution, 22 parts of polybutene wax, 6 parts of Pulvis Talci, 4 parts of bentonite, 3 parts of titanium dioxide, 3 parts of boron carbide, polyester
4 parts of fiber, 3 parts of boron fibre, 4 parts of hydroxypropyl methyl cellulose, 2 parts of ceramic fibre, 0.5 part of surfactant, degasser 0.3
Part, 0.3 part of levelling agent, 0.5 part of dispersant, 0.3 part of wetting agent, 0.2 part of adhesion promoter, 0.1 part of catalyst, initiator
0.2 part, vertical 0.4 part of stricture of vagina agent, 0.3 part of toughener, 0.3 part of optical brightener, 0.3 part of defoamer, 0.3 part of viscosifier, firming agent 0.9
Part, 0.2 part of preservative, 0.2 part of antioxidant, 0.1 part of light stabilizer, 0.2 part of heat stabilizer, 0.1 part of UV absorbent, anti-settling
0.4 part of agent, 0.3 part of thickening agent, 0.3 part of coalescents, 1 part of fire retardant；
Described surfactant is Tween 80；
Described degasser is stearic acid；
Described levelling agent is polydimethylsiloxane；
Described dispersant is dispersant NNO；
Described wetting agent is wetting agent X-405；
Described adhesion promoter is adhesion promoter HF-1；
Described catalyst is vanadic anhydride；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is mallear stria agent H-863；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer MSDS；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is p-hydroxybenzenyl sulfonate；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester；
Described anti-settling agent is modified hydrogenated Oleum Ricini；
Described thickening agent is carrageenan；
Described coalescents are propylene glycol methyl ether acetate；
Described fire retardant in units of weight portion, including following raw material：12 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 12 parts of 3- propylidene dimethylacrylate, 8 parts of APP, 5 parts of tetramethylolmethane, 6 parts of carbamide, barium hydroxide 3
Part, 6 parts of antimony oxide, 2 parts of aluminium oxide, 2 parts of bentonite, 0.6 part of penetrating agent, 0.4 part of synergist；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described pottery coating, comprises the following steps：
S1：By polyester resin, rosin resin, acrylic resin, maleic anhydride, polybutene wax, Pulvis Talci, bentonite, two
Titanium oxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surfactant, degasser, stream
Flat agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, are 145W in microwave power, and temperature is 92
DEG C, rotating speed is to stir 3.5h, prepared mixture a under 2000r/min；
S2：Tert-dodecylmercaotan, benzoin ethyl ether, acrylic emulsion, glutamy is added in the mixture a being obtained to step S1
Amine aqueous solution, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 120W in microwave power, temperature is 118- DEG C, rotating speed
For stirring 4.8h, prepared mixture b under 400r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 150W in microwave power, and temperature is 103 DEG C, and rotating speed is
3.8h, prepared mixture c is stirred under 200r/min；
The preparation method of described heat stabilizer, comprises the following steps：
S31：By bentonite and concentration be 18% active hargil waste water by weight for 2.5:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：The pasty material A that step S31 is obtained is added in the inorganic mixed acid that concentration is 23%, described inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
The weight of shape material A and inorganic mixed acid is than for 3.4:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight of pasty material A is than for 2:158, it is heated to 94 DEG C, be maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：The pasty material B that step S32 is obtained carries out filter pressing under pressure is for 0.93MPa, and prepared moisture content is 47% filter
Cake A；
S34：The filter cake A being obtained to step S33 adds water stirring and dissolving, and amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h so that solution is precipitated completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：The filter cake B that step S34 is obtained adds water stirring and dissolving, and amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, add the sodium hydroxide solution that concentration is 15%, slurry material C is obtained；
S36：The slurry material C that step S35 is obtained carries out filter pressing under pressure is for 0.96MPa, and prepared moisture content is 44% filter cake
C；
S37：The filter cake C that step S36 is obtained is placed in centrifuge, removes water to filter cake C and contain under centrifugal rotational speed is for 6000r/min
Water rate is pulverizing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：The alkaline hargil that step S37 is obtained is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：The slurry material D that step S38 is obtained carries out filter pressing under pressure is for 0.92MPa, and prepared moisture content is 42% filter cake
D；
S310：The filter cake D that step S39 is obtained is placed in centrifuge, removes water to filter cake D under centrifugal rotational speed is for 6000r/min
Moisture content is pulverizing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of described fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, stirring
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 is added in the mixture A being obtained to step S3-1,
3- propylidene dimethylacrylate, tetramethylolmethane, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is 140W, and temperature stirs 2h, prepared mixture B at being 86 DEG C；
S3-3：The mixture B that step S3-2 is obtained is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112 DEG C by extruder, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 150 mesh sieve, prepared pottery coating after pulverizing.
Embodiment 3
A kind of pottery coating, in units of weight, including following raw material：175 parts of polyester resin, 68 parts of rosin resin, propylene
50 parts of acid resin, 32 parts of maleic anhydride, 24 parts of tert-dodecylmercaotan, 18 parts of benzoin ethyl ether, 42 parts of acrylic emulsion,
32 parts of glutamine solution, 45 parts of polybutene wax, 10 parts of Pulvis Talci, 7 parts of bentonite, 6 parts of titanium dioxide, 5 parts of boron carbide, polyester
6 parts of fiber, 4 parts of boron fibre, 7 parts of hydroxypropyl methyl cellulose, 4 parts of ceramic fibre, 0.7 part of surfactant, degasser 0.6
Part, 0.8 part of levelling agent, 0.9 part of dispersant, 0.5 part of wetting agent, 0.4 part of adhesion promoter, 0.2 part of catalyst, initiator
0.3 part, vertical 0.6 part of stricture of vagina agent, 0.5 part of toughener, 0.5 part of optical brightener, 0.6 part of defoamer, 0.5 part of viscosifier, firming agent 1.8
Part, 0.4 part of preservative, 0.5 part of antioxidant, 0.2 part of light stabilizer, 0.4 part of heat stabilizer, 0.3 part of UV absorbent, anti-settling
0.7 part of agent, 0.5 part of thickening agent, 0.6 part of coalescents, 1.4 parts of fire retardant；
Described surfactant is Tween 80；
Described degasser is stearic acid；
Described levelling agent is polydimethylsiloxane；
Described dispersant is dispersant NNO；
Described wetting agent is wetting agent X-405；
Described adhesion promoter is adhesion promoter HF-1；
Described catalyst is vanadic anhydride；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is mallear stria agent H-863；
Described toughener is MBS terpolymer；
Described optical brightener is optical brightener LD-608；
Described defoamer is defoamer MSDS；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is p-hydroxybenzenyl sulfonate；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester；
Described anti-settling agent is modified hydrogenated Oleum Ricini；
Described thickening agent is carrageenan；
Described coalescents are propylene glycol methyl ether acetate；
Described fire retardant in units of weight portion, including following raw material：24 parts of 3-M2BOL acetass, 2,2- bis-
Methyl isophthalic acid, 15 parts of 3- propylidene dimethylacrylate, 13 parts of APP, 12 parts of tetramethylolmethane, 10 parts of carbamide, barium hydroxide
6 parts, 9 parts of antimony oxide, 5 parts of aluminium oxide, 4 parts of bentonite, 1 part of penetrating agent, 0.6 part of synergist；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described pottery coating, comprises the following steps：
S1：By polyester resin, rosin resin, acrylic resin, maleic anhydride, polybutene wax, Pulvis Talci, bentonite, two
Titanium oxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surfactant, degasser, stream
Flat agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, are 180W in microwave power, and temperature is 96
DEG C, rotating speed is to stir 3h, prepared mixture a under 2600r/min；
S2：Tert-dodecylmercaotan, benzoin ethyl ether, acrylic emulsion, glutamy is added in the mixture a being obtained to step S1
Amine aqueous solution, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 160W in microwave power, temperature is 126 DEG C, rotating speed is
3.2h, prepared mixture b is stirred under 600r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 220W in microwave power, and temperature is 108 DEG C, and rotating speed is
2.2h, prepared mixture c is stirred under 400r/min；
The preparation method of described heat stabilizer, comprises the following steps：
S31：By bentonite and concentration be 18% active hargil waste water by weight for 2.5:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：The pasty material A that step S31 is obtained is added in the inorganic mixed acid that concentration is 23%, described inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
The weight of shape material A and inorganic mixed acid is than for 3.4:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight of pasty material A is than for 2:158, it is heated to 94 DEG C, be maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：The pasty material B that step S32 is obtained carries out filter pressing under pressure is for 0.93MPa, and prepared moisture content is 47% filter
Cake A；
S34：The filter cake A being obtained to step S33 adds water stirring and dissolving, and amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h so that solution is precipitated completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：The filter cake B that step S34 is obtained adds water stirring and dissolving, and amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, add the sodium hydroxide solution that concentration is 15%, slurry material C is obtained；
S36：The slurry material C that step S35 is obtained carries out filter pressing under pressure is for 0.96MPa, and prepared moisture content is 44% filter cake
C；
S37：The filter cake C that step S36 is obtained is placed in centrifuge, removes water to filter cake C and contain under centrifugal rotational speed is for 6000r/min
Water rate is pulverizing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：The alkaline hargil that step S37 is obtained is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：The slurry material D that step S38 is obtained carries out filter pressing under pressure is for 0.92MPa, and prepared moisture content is 42% filter cake
D；
S310：The filter cake D that step S39 is obtained is placed in centrifuge, removes water to filter cake D under centrifugal rotational speed is for 6000r/min
Moisture content is pulverizing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of described fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, stirring
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 is added in the mixture A being obtained to step S3-1,
3- propylidene dimethylacrylate, tetramethylolmethane, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is 140W, and temperature stirs 2h, prepared mixture B at being 86 DEG C；
S3-3：The mixture B that step S3-2 is obtained is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 116 DEG C by extruder, and passes through crusher film-making,
Lamellar body is obtained after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 170 mesh sieve, prepared pottery coating after pulverizing.
The performance indications of the pottery coating that detection embodiment 1-3 is obtained, result is as shown in the table.
As seen from the above table：The coating of the present invention had both had excellent adhesive force and mechanical property, had excellent resistance to height again
Temperature, impact resistance and hardness, rate of drying is fast and toxic is minimum simultaneously, is that a kind of pottery environmental protection of excellent combination property applies
Material.
Above content it cannot be assumed that the present invention be embodied as be confined to these explanations, the affiliated technology neck for the present invention
For the those of ordinary skill in domain, without departing from the inventive concept of the premise, some simple deduction or replace can also be made,
The scope of patent protection that the present invention is determined all should be considered as belonging to by the claims submitted to.
Claims (7)
1. a kind of pottery coating is it is characterised in that in units of weight, including following raw material：Polyester resin 130-180 part,
Rosin resin 50-70 part, acrylic resin 30-50 part, maleic anhydride 18-32 part, tert-dodecylmercaotan 16-25 part,
Benzoin ethyl ether 12-18 part, acrylic emulsion 27-42 part, glutamine solution 20-32 part, polybutene wax 22-45 part, Talcum
Powder 5-10 part, bentonite 4-7 part, titanium dioxide 3-6 part, boron carbide 3-5 part, polyester fiber 4-6 part, boron fibre 3-4 part, hydroxypropyl
Ylmethyl cellulose 4-7 part, ceramic fibre 2-4 part, surfactant 0.4-0.7 part, degasser 0.3-0.6 part, levelling agent
0.3-0.8 part, dispersant 0.5-0.9 part, wetting agent 0.3-0.5 part, adhesion promoter 0.2-0.4 part, catalyst 0.1-0.2
Part, initiator 0.2-0.3 part, vertical stricture of vagina agent 0.4-0.6 part, toughener 0.3-0.5 part, optical brightener 0.3-0.5 part, defoamer 0.3-
0.6 part, viscosifier 0.3-0.5 part, firming agent 0.9-1.8 part, preservative 0.2-0.4 part, antioxidant 0.2-0.5 part, light stable
Agent 0.1-0.2 part, heat stabilizer 0.2-0.4 part, UV absorbent 0.1-0.3 part, anti-settling agent 0.4-0.7 part, thickening agent
0.3-0.5 part, coalescents 0.3-0.6 part, fire retardant 1-1.4 part；
Described dispersant is dispersant NNO；
Described wetting agent is wetting agent X-405；
Described adhesion promoter is adhesion promoter HF-1；
Described catalyst is vanadic anhydride；
Described initiator is azo two isopropylformic acid.（Acrylic acid ethylene glycol）Ester；
Described vertical stricture of vagina agent is mallear stria agent H-863；
Described toughener is MBS terpolymer；
Described viscosifier are propyl trimethoxy silicane；
Described firming agent is p-hydroxybenzenyl sulfonate；
Described preservative is Liquid BPF -369；
Described antioxidant is antioxidant AT-330；
Described light stabilizer is light stabilizer HS-3101；
Described UV absorbent is oxybenzoic acid phenyl ester；
Described thickening agent is carrageenan；
Described coalescents are propylene glycol methyl ether acetate；
Described fire retardant in units of weight portion, including following raw material：3-M2BOL acetass 12-24 part, 2,
2- dimethyl-trimethylene dimethylacrylate 10-15 part, APP 8-13 part, tetramethylolmethane 5-12 part, carbamide 6-
10 parts, barium hydroxide 3-6 part, antimony oxide 5-9 part, aluminium oxide 2-5 part, bentonite 2-4 part, penetrating agent 0.5-1 part, synergistic
Agent 0.4-0.6 part；
Described penetrating agent is fatty alcohol-polyoxyethylene ether
Described synergist is ammonium sulfate；
The preparation method of described pottery coating, comprises the following steps：
S1：By polyester resin, rosin resin, acrylic resin, maleic anhydride, polybutene wax, Pulvis Talci, bentonite, two
Titanium oxide, boron carbide, polyester fiber, boron fibre, hydroxypropyl methyl cellulose, ceramic fibre, surfactant, degasser, stream
Flat agent, dispersant, wetting agent, adhesion promoter, catalyst, initiator mixing, are 140-180W in microwave power, temperature is
92-96 DEG C, rotating speed is to stir 3-3.5h, prepared mixture a under 2000-2600r/min；
S2：Tert-dodecylmercaotan, benzoin ethyl ether, acrylic emulsion, glutamy is added in the mixture a being obtained to step S1
Amine aqueous solution, vertical stricture of vagina agent, toughener, optical brightener, defoamer, viscosifier, are 120-160W in microwave power, and temperature is 118-126
DEG C, rotating speed is to stir 3.2-4.8h, prepared mixture b under 400-600r/min；
S3：Firming agent, preservative, antioxidant, light stabilizer, heat stabilizer, ultraviolet is added in the mixture b being obtained to step S2
Light absorbers, anti-settling agent, thickening agent, coalescents, fire retardant, are 150-220W in microwave power, and temperature is 102-108 DEG C,
Rotating speed is to stir 2.2-3.8h, prepared mixture c under 200-400r/min；
The preparation method of described heat stabilizer, comprises the following steps：
S31：By bentonite and concentration be 18% active hargil waste water by weight for 2.5:16 mixing, are 600r/ in rotating speed
Stir under min, prepared pasty material A；
S32：The pasty material A that step S31 is obtained is added in the inorganic mixed acid that concentration is 23%, described inorganic mixed acid
For the oxalic acid of concentration 15wt%, the phosphoric acid of concentration 32wt%, concentration 20wt% sulphuric acid by volume 4:5:The mixed acid of 7 compositions, slurry
The weight of shape material A and inorganic mixed acid is than for 3.4:17, under rotating speed is for 600r/min add ammonium sulfide stirring, ammonium sulfide with
The weight of pasty material A is than for 2:158, it is heated to 94 DEG C, be maintained at reaction 1.5h, prepared pasty material B at 94 DEG C；
S33：The pasty material B that step S32 is obtained carries out filter pressing under pressure is for 0.93MPa, and prepared moisture content is 47% filter
Cake A；
S34：The filter cake A being obtained to step S33 adds water stirring and dissolving, and amount of water is 7.8 times of filter cake A weight, and stirring and dissolving is filtered
Cake A adds bodied ferric sulfate stirring 1.3h so that solution is precipitated completely afterwards, and precipitate is carried out filter pressing under pressure is for 0.93MPa,
Prepared moisture content is 46% filter cake B；
S35：The filter cake B that step S34 is obtained adds water stirring and dissolving, and amount of water is 6.8 times of filter cake B weight, and stirring and dissolving is filtered
After cake A is complete, add the sodium hydroxide solution that concentration is 15%, slurry material C is obtained；
S36：The slurry material C that step S35 is obtained carries out filter pressing under pressure is for 0.96MPa, and prepared moisture content is 44% filter cake
C；
S37：The filter cake C that step S36 is obtained is placed in centrifuge, removes water to filter cake C and contain under centrifugal rotational speed is for 6000r/min
Water rate is pulverizing after 3.5%, and gained ground product crosses 500 mesh sieves, and alkalescence hargil is obtained；
S38：The alkaline hargil that step S37 is obtained is made into the solution that concentration is 13.4%, adds alkaline hargil quality 30.1%
Poly amic acid ester, stirring reaction 60min under rotating speed 500r/min, slurry material D is obtained；
S39：The slurry material D that step S38 is obtained carries out filter pressing under pressure is for 0.92MPa, and prepared moisture content is 42% filter cake
D；
S310：The filter cake D that step S39 is obtained is placed in centrifuge, removes water to filter cake D under centrifugal rotational speed is for 6000r/min
Moisture content is pulverizing after 3%, and gained ground product crosses 600 mesh sieves, prepared heat stabilizer；
The preparation method of described fire retardant, comprises the following steps：
S3-1：APP, 142 parts of water are added in microwave reactor, is 120W in microwave power, temperature is 55 DEG C, stirring
Rotating speed is to stir 6min, prepared mixture A under 500r/min；
S3-2：3-M2BOL acetass, 2,2- dimethyl -1 is added in the mixture A being obtained to step S3-1,
3- propylidene dimethylacrylate, tetramethylolmethane, carbamide, barium hydroxide, antimony oxide, aluminium oxide, bentonite, infiltration
Agent, synergist, are 500r/min in speed of agitator, and microwave power is 140W, and temperature stirs 2h, prepared mixture B at being 86 DEG C；
S3-3：The mixture B that step S3-2 is obtained is cooled to after room temperature, precipitate is filtered, under rotating speed is for 5000r/min
Centrifugal drying to water content is 2.8%, prepared fire retardant；
S4：The mixture c that step S3 is obtained is melt extruded at 112-116 DEG C by extruder, and passes through crusher
Film-making, is obtained lamellar body after cooling；
S5：The lamellar body that step S4 is obtained adopts cutting knife to shear, prepared pelletizing；
S6：The pelletizing that step S5 is obtained crosses 150-170 mesh sieve, prepared pottery coating after pulverizing.
2. according to claim 1 pottery coating it is characterised in that described surfactant is Tween 80.
3. according to claim 1 pottery coating it is characterised in that described degasser is stearic acid.
4. according to claim 1 pottery coating it is characterised in that described levelling agent is polydimethylsiloxane.
5. according to claim 1 pottery coating it is characterised in that described optical brightener is optical brightener LD-608.
6. according to claim 1 pottery coating it is characterised in that described defoamer is defoamer MSDS.
7. according to claim 1 pottery coating it is characterised in that described anti-settling agent be modified hydrogenated Oleum Ricini.
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| CN201610884510.9A CN106398362A (en) | 2016-10-11 | 2016-10-11 | Ceramic coating |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610884510.9A CN106398362A (en) | 2016-10-11 | 2016-10-11 | Ceramic coating |
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| CN106398362A true CN106398362A (en) | 2017-02-15 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112247491A (en) * | 2020-10-23 | 2021-01-22 | 苏州航菱微精密组件有限公司 | Chip packaging detection equipment rack processing and welding method |
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|---|---|---|---|---|
| CN102875851A (en) * | 2012-09-12 | 2013-01-16 | 山东长星集团有限公司 | Environment-friendly flame retardant |
| CN104177648A (en) * | 2014-08-03 | 2014-12-03 | 马晓权 | Tire flame retardant |
| CN104371747A (en) * | 2014-09-30 | 2015-02-25 | 滁州斯迈特复合材料有限公司 | Fire retardant for air-conditioning cabinet |
| CN105885300A (en) * | 2016-06-25 | 2016-08-24 | 张莘蔓 | Novel environment-friendly PVC (polyvinyl chloride) heat stabilizer |
| CN105949969A (en) * | 2016-06-27 | 2016-09-21 | 广西平果宝信涂料有限公司 | Sand-textured weather-resistant powder coating and preparation method thereof |
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2016
- 2016-10-11 CN CN201610884510.9A patent/CN106398362A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102875851A (en) * | 2012-09-12 | 2013-01-16 | 山东长星集团有限公司 | Environment-friendly flame retardant |
| CN104177648A (en) * | 2014-08-03 | 2014-12-03 | 马晓权 | Tire flame retardant |
| CN104371747A (en) * | 2014-09-30 | 2015-02-25 | 滁州斯迈特复合材料有限公司 | Fire retardant for air-conditioning cabinet |
| CN105885300A (en) * | 2016-06-25 | 2016-08-24 | 张莘蔓 | Novel environment-friendly PVC (polyvinyl chloride) heat stabilizer |
| CN105949969A (en) * | 2016-06-27 | 2016-09-21 | 广西平果宝信涂料有限公司 | Sand-textured weather-resistant powder coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112247491A (en) * | 2020-10-23 | 2021-01-22 | 苏州航菱微精密组件有限公司 | Chip packaging detection equipment rack processing and welding method |
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Application publication date: 20170215 |