CN106433346A - One-coat paint for polyolefin materials and preparation method thereof - Google Patents

One-coat paint for polyolefin materials and preparation method thereof Download PDF

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Publication number
CN106433346A
CN106433346A CN201610576875.5A CN201610576875A CN106433346A CN 106433346 A CN106433346 A CN 106433346A CN 201610576875 A CN201610576875 A CN 201610576875A CN 106433346 A CN106433346 A CN 106433346A
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China
Prior art keywords
coating
parts
curing agent
material according
component
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Pending
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CN201610576875.5A
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Inventor
薛芳
刘书巧
刘萍
李伟
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JIANGSU ZUYI COATING CO Ltd
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JIANGSU ZUYI COATING CO Ltd
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Priority to CN201610576875.5A priority Critical patent/CN106433346A/en
Publication of CN106433346A publication Critical patent/CN106433346A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • C08K3/36Silica
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/47Levelling agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a one-coat paint for polyolefin materials and a preparation method thereof. The paint is prepared from the following components by weight: 55-65 parts of special modified hydroxyl resin, 25-35 parts of high weather resistant pigment, 3-6 parts of a dispersant, 0.5-1 part of a leveling agent, 0.1-0.5 part of a drier, 1-2 parts of a light stabilizer, 1-2 parts of a light absorber, and 10-15 parts of a solvent. The paint film formed by the one-coat paint provided by the invention has good appearance and excellent adhesion on the surfaces of polyolefin materials. Compared with the prior art, the coating process is simplified, and the coating cost is saved. The traditional coating process combines PP primer and color paint, and according to the product provided by the invention, a layer of color paint is sprayed directly.

Description

A kind of coating of bottom surface unification for polyolefine material and preparation method thereof
Technical field
The present invention relates to a kind of car paint, particularly relate to the coating of a kind of bottom surface unification for polyolefine material.
Background technology
The high speed development of Automobile Industry in China, drives the Automobile Insurance in China thick stick market demand persistently to increase substantially.Before 20 years, Car front/rear collision bumper be with metal material based on, be pressed into U-type groove steel, surface treatment with the steel plate stamping that thickness is more than 3 millimeters Chromium plating, rivets with longitudinal beam or welds together, having one section of bigger gap with vehicle body, and seeming is an additional portion up Part.With the development of auto industry, bumper has also moved towards on the road of innovation as a kind of important safety device.Modern It car front/rear collision bumper, in addition to keeping original defencive function, also to be pursued harmonious with car body moulding and unified, pursue The lightweight of itself.In order to reach this purpose, the emerging plastics of having used of bumper before and after current car, people are referred to as plastics insurance Thick stick.Plastic bumper is made up of three parts such as outside plate, padded coaming and crossbeams.Wherein outside plate and padded coaming plastics system Becoming, crossbeam thickness is that the flat cold-rolled sheet of 1.5 millimeter is stamped to form U-type groove;Outside plate and padded coaming are attached on crossbeam, Crossbeam and longitudinal beam screw joints, can disassemble at any time.The plastics that this plastic bumper uses, generally use poly- Ester system and polypropylene-based bi-material, use injection moulding to make.Plastic bumper has intensity, rigidity and dicoration, from See in safety, during collision scenario accident, can play cushioning effect, car body before and after protection, from the appearance, can be naturally Ground is combined at one piece with car body, completely integral, has good dicoration, becomes the vitals of decoration car external form.
With the development of coating equipment, more advanced application techniques constantly occurs, the application level of automobile is corresponding also Improve a lot.Plastic bumper has good intensity, rigidity and dicoration.From safety, when crashing Cushioning effect can be played, car body and pedestrains safety before and after protection;From the appearance, high-quality spraying technology can be naturally enough Being combined together with car body, having good dicoration, this just has certain require that to coating cost and technique.
Material for bumper is mainly PP class plastics, and its major defect is that polarity is little, crystallinity big, surface Tension force is little, wetability difference, smooth surface, and generally the polarity by using modified class PP to change bumper base material ensures application matter Amount.MODIFIED PP material category conventional at present has PP+EPDM-T10, PP+EPDM-T15, PP+EPDM-T20, PP+EPDM-T30. Talcous addition can reduce the degree of crystallinity of base material so that the solvent in coating easily dissolves or swelling substrate surface, improves and applies The tack of material, makes coating performance be improved.But it is as talcous increase, melting means (the i.e. mobility of material.Melting means drops Low, it is not easy to fill up when mold filling;For bumper, the good fluidity product percent of pass in forming process is just high), lack Mouth impact strength (affecting the toughness of bumper), shrinkage factor (affecting the dimensional stability of bumper) reduce, bending modulus (impact The rigidity of bumper) increase with the increase of amount of talc.So the rigidity to be accomplished of selecting materials of bumper reaches with toughness Balance guarantee mass of foundation.By years of researches and test, it was demonstrated that PP+EPDM-T20 is at rigidity and toughness, coating The aspects such as energy, cost all have certain advantage., bumper base material trade mark disunity more in conjunction with company's vehicle, raw material producer Numerous situations, by integrating the base material unifying bumper, to reach to control the purpose of bumper base material cost.
It is 55~80 DEG C that current bumper coating dries temperature range.Bumper coating is composite coating, i.e. priming paint+colored paint Or priming paint+two kinds of colored paint+varnish, priming paint has again bi-component and one pack system 2 kinds, colored paint many employings one pack system or two-component coating, Varnish many employings two-component coating.After bi-component priming paint baking, there is preferable covering power and tack, can be to surface after film forming The defects such as particle carry out grinding process, are particularly well-suited to the poor situation of bumper outward appearance.Bi-component priming paint is under wet film state Electric conductivity poor, do not toast such as priming paint or toast bad, spraying colored paint then can affect the adhesive force of colored paint, and thickness requires not Less than 15 μm.One-component primers wet film electric conductivity is relatively good, be suitable for automatic machine spraying, and film-forming temperature is low or does not affect the end without baking Paint and the tack of colored paint, and thickness is relatively thin, typically about the 5 μm performances that just can reach as bi-component priming paint.Therefore One-component primers is better than bi-component priming paint at aspects such as construction, equipment investment, the saving energy, environmental protection, the maintenances of paint delivery tube road, And be easily obtained good coating surface state, but the coating process of bumper can not be simplified.
Content of the invention
The invention mainly includes provide for coordinating bumper Industry Quick Development to need a kind of reliable in quality, The simple coating of coating process, by the use of this coating, simplifies coating process, joint to be reached for bumper manufacturing enterprise The about purpose of painting cost.
The purpose of the present invention can be reached by following measures:A kind of coating of the bottom surface unification for polyolefine material, Being made up of coating itself, curing agent part and diluent, wherein, the weight of three is than for 3-4:1:Coating described in 1 itself by under The component stating mass parts is formulated:
Component Mass fraction
Resin 55~65 parts
Pigment 25~35 parts
Anti-settling agent 0.3~0.6 part
Dispersant 3~6 parts
Levelling agent 0.5~1 part
Drier 0.1~0.5 part
Light stabilizer 1~2 part
Light absorber 1~2 part
Solvent 10~15 parts
Described curing agent part is formulated by the component of following mass parts:
Component Mass fraction
Curing agent 41 parts
Organic solvent 59 parts
It when this product uses, coating itself, curing agent part is mixed and stirred in proportion uniformly or is adjusted to executing of needs Work viscosity, then can be with the method construction of spraying.Wherein coating part itself and the weight ratio of curing agent part are 3:1.
Resin in the present invention uses the resin LR-7643 resin of Mitsubishi.
Pigment in the present invention is Du Pont 901 titanium white.
Dispersant in the present invention is BYK101.
Levelling agent in the present invention is fluorin modified crylic acid ester EFKA3777.
Drier in the present invention is Tao Shi T-12.
Light stabilizer in the present invention is the 1130 of BASF.
Light absorber in the present invention is the 292 of BASF.
Anti-settling agent in the present invention is the aerosil A-200 of Degussa.
Organic solvent in the present invention uses EEP, PMA, butyl acetate, ethyl acetate, solvent naphtha.
Curing agent in the present invention uses the 3390 of Bayer.
The coating of bottom surface unification is formulated by the following method:
(1) resin, dispersant, partial solvent, anti-settling agent and titanium dioxide pigment are pressed formula rate and add in clean container, High-speed stirred uniformly arrives sand milling afterwards and is ground to fineness less than 15 microns;
(2) under high speed state, levelling agent, drier, light stabilizer, light absorber and remaining set are added while stirring The solvent of part;
(3) after all adding, high-speed stirred 10-15min.
Curing agent is formulated by the following method:Curing agent is mixed with organic solvent.
First above-mentioned paint component second is mixed by formula ratio with curing agent component first during construction, then want according to construction Seeking the diluent latting drown using 10-20%, regulation viscosity is to working viscosity further, and then even application is on workpiece to be coated.
The coating of the bottom surface unification of the present invention has the characteristics that:
(1) coating of the present invention uses the hydroxy resin of special modification, can give the excellent dicoration of paint film, ground attached The property and film forming;
(2) coating of the present invention possesses good process based prediction model;
(3) coating of the present invention has good application property, engineering time and construction cost can be greatly shortened;
(4) coating of the present invention has excellent guarantor's light, Bao Se and weatherability;
(5) coating of the bottom surface unification of the present invention is compared with traditional coating, by realizing reducing operational procedure, saves energy Source, improves efficiency.The present invention has more specific aim, clear and definite compared to traditional product directive property, has the demand in broader market And prospect.
Detailed description of the invention
Below in conjunction with embodiment, the present invention will be further described.
Embodiment 1
The coating weight component of the present embodiment bottom surface unification:Resin 55 parts, solvent 10 parts, dispersant 3 parts, anti-settling agent 0.3 Part, pigment 25 parts, levelling agent 0.5 part, drier 0.1 part, light stabilizer 1 part, light absorber 1 part.
The preparation method of coating itself is as follows:
(1) add 55 parts of resins in clean container, stir while add 5 parts of solvents, 3 parts of dispersants, 0.3 portion of anti-settling agent, 25 parts of pigment, stir 30 minutes after adding under middle high shear force, then arrive sand milling and are ground to fineness micro-less than 15 Rice;
(2) it is sequentially added into 0.5 part of levelling agent while stirring, 0.1 part of drier, 1 part of light stabilizer, 1 part of light absorber, 5 Part organic solvent, stirs;
(3), after material adds, middle high shear force stirs 10-15 minute;
(4), after stirring terminates, stand after waiting bubble collapse stand-by;
Curing agent component preparation method:In proportion by 41 parts and 59 parts organic solvent mixing of curing agent, low-shearing force stirs Uniformly i.e. obtain curing agent component.
During use, paint component and curing agent component press 3:The weight proportion mixing of 1, low-shearing force stirs, and adds suitable Amount diluent carries out viscosity adjustment, stirs, after 250 mesh filter-cloth filterings, is sprayed on tinplate, places thermostatic constant wet chamber (23 ± 2 DEG C, 50 ± 5%) dry and selects corresponding regulating time by technical indicator, recording all technical and be shown in Table one.
Embodiment 2
The coating weight component of the present embodiment bottom surface unification:Resin 60 parts, organic solvent 12.5 parts, dispersant 4.5 parts, anti- Heavy agent 0.45 part, pigment 30 parts, levelling agent 0.75 part, drier 0.3 part, light stabilizer 1.5 parts, light absorber 1.5 parts.
The preparation method of coating itself is as follows:
(1) add 60 parts of resins in clean container, stir while add 5 parts of organic solvents, 4.5 parts of dispersants, 0.45 part Anti-settling agent, 30 parts of pigment, stir 30 minutes after adding under middle high shear force, then arrives sand milling and is ground to fineness little In 15 microns;
(2) being sequentially added into 0.75 part of levelling agent, 0.3 part of drier, 1.5 parts of light stabilizers while stirring, 1.5 parts of light absorb Agent, 7.5 parts of organic solvents, stir;
(3), after material adds, middle high shear force stirs 10-15 minute;
(4), after stirring terminates, stand after waiting bubble collapse stand-by;
Curing agent component preparation method:In proportion by 41 parts and 59 parts organic solvent mixing of curing agent, low-shearing force stirs Uniformly i.e. obtain curing agent component.
During use, paint component and curing agent component press 3:The weight proportion mixing of 1, low-shearing force stirs, and adds suitable Amount diluent carries out viscosity adjustment, stirs, after 250 mesh filter-cloth filterings, is sprayed on tinplate, places thermostatic constant wet chamber (23 ± 2 DEG C, 50 ± 5%) dry and selects corresponding regulating time by technical indicator, recording all technical and be shown in Table one.
Embodiment 3
The coating weight component of the present embodiment bottom surface unification:Resin 65 parts, organic solvent 15 parts, dispersant 6 parts, anti-settling agent 0.6 part, pigment 35 parts, levelling agent 1 part, drier 0.5 part, light stabilizer 2 parts, light absorber 2 parts.
The preparation method of coating itself is as follows:
(1) add 65 parts of resins in clean container, stir while add 5 parts of organic solvents, 6 parts of dispersants, 0.6 part anti-settling Agent, 35 parts of pigment, stir 30 minutes after adding under middle high shear force, then arrives sand milling and is ground being less than 15 to fineness Micron;
(2) it is sequentially added into 1 part of levelling agent while stirring, 0.5 part of drier, 2 parts of light stabilizers, 2 parts of light absorbers, 10 parts Organic solvent, stirs;
(3), after material adds, middle high shear force stirs 10-15 minute;
(4), after stirring terminates, stand after waiting bubble collapse stand-by;
Curing agent component preparation method:In proportion by 41 parts and 59 parts organic solvent mixing of curing agent, low-shearing force stirs Uniformly i.e. obtain curing agent component.
During use, paint component and curing agent component press 3:The weight proportion mixing of 1, low-shearing force stirs, and adds suitable Amount diluent carries out viscosity adjustment, stirs, after 250 mesh filter-cloth filterings, is sprayed on tinplate, places thermostatic constant wet chamber (23 ± 2 DEG C, 50 ± 5%) dry and selects corresponding regulating time by technical indicator, recording all technical and be shown in Table one.
With reference to the countries concerned or professional standard, carrying out performance detection to embodiments above, result is as follows:
Table one

Claims (13)

1. the coating for the bottom surface unification of polyolefine material, it is characterised in that:By coating itself, curing agent part and dilute Releasing agent composition, wherein, the weight of three ratio is for 3-4:1:1, described coating itself is formulated by the component of following mass parts:
Component Mass fraction Resin 55~65 parts Pigment 25~35 parts Anti-settling agent 0.3~0.6 part Dispersant 3~6 parts Levelling agent 0.5~1 part Drier 0.1~0.5 part Light stabilizer 1~2 part Light absorber 1~2 part Solvent 10~15 parts
Described curing agent component is formulated by the component of following mass parts:
Component Mass fraction Curing agent 41 parts Organic solvent 59 parts.
2. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation applies Material resin used itself is the hydroxy resin of special modification.
3. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation applies Material pigment used itself is high durable pigment, including one in rutile titanium white, carbon black, iron oxide red, iron oxide yellow, organic pigment or Several.
4. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation applies Material dispersant used itself is macromolecule dispersing agent, including modified polyacrylate high polymer, modified polyacrylate and second One or more in alkenyl copolymers, the alkanolamine of high molecular weight carboxylic, fatty acid modified polyester mixing with arbitrary proportion Close.
5. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation applies Material anti-settling agent used itself is gas phase bentonite, silica, one or more in polyamide.
6. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation applies Material levelling agent used itself, including organic silicon modified by polyether polymer, organic silicon modified by polyether, modified polyorganosiloxane, fluorine carbon One or more in the polyacrylate of modification, acrylic acid-Organosiliconcopolymere are with the mixing of arbitrary proportion.
7. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation applies Material drier used itself, including the mixing with arbitrary proportion of one or more in metal oxide, slaine, metallic soap Close.
8. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation applies Material light stabilizer used itself is BTA mixture.
9. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation applies Material light absorber used itself is hindered amine light stabilizer.
10. the coating of a kind of bottom surface unification for polyolefine material according to claim 1, it is characterised in that:Preparation Coating solvent used itself is each kind solvent, including the mixing with arbitrary proportion of one or more in aromatic hydrocarbon, esters, ketone Close.
The coating of 11. a kind of bottom surface unifications for polyolefine material according to claim 1, it is characterised in that:Preparation Curing agent used by curing agent is all kinds of high-solid lower-viscosity PICs.
The coating of 12. a kind of bottom surface unifications for polyolefine material according to claim 1, it is characterised in that:Preparation Organic solvent used by curing agent, including one or more in aromatic hydrocarbon, esters are with the mixing of arbitrary proportion.
13. 1 kinds of coating for the bottom surface unification of polyolefine material, it is characterised in that:Prepared by the method for being prepared as follows:
(1) resin is added in clean container, be sequentially added into partial solvent, dispersant, anti-settling agent, pigment while stirring, add After complete under middle high shear force uniform stirring 30 minutes, then arrive sand milling be ground to fineness be less than 15 microns;
(2) being sequentially added into levelling agent, drier, light stabilizer, light absorber, the solvent of residue component while stirring, stirring is all Even;
(3), after material adds, middle high shear force stirs 10-15 minute;
(4), after stirring terminates, stand and i.e. obtain coating itself after waiting bubble collapse;
(5) mixing curing agent and organic solvent in proportion, low-shearing force stirs and i.e. obtains curing agent component;
(6), after mixing coating itself, curing agent component, diluent by proportioning, low-shearing force stirs, 250 mesh filter cloth mistakes Filter.
CN201610576875.5A 2016-07-20 2016-07-20 One-coat paint for polyolefin materials and preparation method thereof Pending CN106433346A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964368A (en) * 2017-12-07 2018-04-27 江苏足迹涂料有限公司 Bottom surface unification coating and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08157769A (en) * 1994-12-05 1996-06-18 Chugoku Marine Paints Ltd Water-base coating composition for wooden material
CN101235239A (en) * 2008-02-22 2008-08-06 江苏足迹涂料有限公司 Special-purpose dope for polyolefin material
CN101613564A (en) * 2009-07-23 2009-12-30 东南大学 A kind of protective coating for aerogenerator vanes and preparation method
CN102108250A (en) * 2011-03-07 2011-06-29 株洲飞鹿涂料有限责任公司 Waterborne one coat anticorrosive paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08157769A (en) * 1994-12-05 1996-06-18 Chugoku Marine Paints Ltd Water-base coating composition for wooden material
CN101235239A (en) * 2008-02-22 2008-08-06 江苏足迹涂料有限公司 Special-purpose dope for polyolefin material
CN101613564A (en) * 2009-07-23 2009-12-30 东南大学 A kind of protective coating for aerogenerator vanes and preparation method
CN102108250A (en) * 2011-03-07 2011-06-29 株洲飞鹿涂料有限责任公司 Waterborne one coat anticorrosive paint and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964368A (en) * 2017-12-07 2018-04-27 江苏足迹涂料有限公司 Bottom surface unification coating and preparation method thereof

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Application publication date: 20170222