CN106432579A - High-gloss wear resistant aqueous oil polish and preparation method thereof - Google Patents
High-gloss wear resistant aqueous oil polish and preparation method thereof Download PDFInfo
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- CN106432579A CN106432579A CN201610562908.0A CN201610562908A CN106432579A CN 106432579 A CN106432579 A CN 106432579A CN 201610562908 A CN201610562908 A CN 201610562908A CN 106432579 A CN106432579 A CN 106432579A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/16—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising curable or polymerisable compounds
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/18—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/12—Defoamers
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
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Abstract
The invention discloses a high-gloss wear resistant aqueous oil polish and a preparation method thereof. The aqueous oil polish comprises, by weight, 20-30% of synthetic emulsion A, 15-25% of synthetic emulsion B, 10-20% of alkali-soluble resin, 5-8% of a film forming assistant, 10-15% of a wax emulsion, 0.5-2.5% of an antifoaming agent, 0-0.5% of a wear resisting agent and 5-10% of water. The oil polish has the advantages of small smell of a solvent on package printing, less residual of the solvent, good adhesion fastness, high transparence, good glossiness, high wear resistance, good printability, and no bonding property at a high temperature.
Description
Technical field
The invention belongs to fine chemicals and its preparing technical field, particularly to a kind of highlight wear-resistant water-based glaze oil and
Its preparation method.
Background technology
With the development of scientific and technological progress and society, serious from environmental problem day for the survival of mankind, environmental conservation is
Through becoming the subject under discussion of global common concern.
Paper wrappings will be used in medical outer package, beverage/food outer package, tobacco and wine outer package etc. field.At this
On a little housing materials, it usually needs the identification information such as the multiple picture and text of chromatography, trade mark, in order to protect these identification informations in carrying
During be not worn, need printing these picture and text, cover layer of transparent thin film or painting again above the identification information such as trade mark
Cover one layer of good coating of light transmission, so that protection picture and text surface.Thin film is poor due to degradability, is unfavorable for that waste and old material reclaims again
Using slowly will being eliminated.The main still solvent based product of a large amount of outer package oil polishes using at present.Because solvent-borne type produces
Product contain a large amount of solvents, and waste of resource, have an effect on the healthy of operating worker and pollutant atmosphere simultaneously.
Recently as the enhancing of the increasingly strict of environmental regulation and people's environmental consciousness, the emission request of VOC is also got over
Come higher, national industrial policies also encourage solvent-borne type glazing paint industry to develop to water solublity glazing paint direction.Aqueouss glazing
Oil is a kind of new oil polish as disperse medium for the water consumption substitution organic solvent, has pollution-free, safe and reliable, mechanicalness
Can be excellent, the advantages of the compatibility is good easily modified, it is a kind of new environment amenable material, but water in the market
Property oil polish in terms of properties of product with solvent based product also there is a certain distance, the adhesive force of such as aqueous product, painting
The aspects such as layer hardness, glossiness, chemical-resistant, thermostability still can not reach the performance of solvent borne glazing oil product, and these are poor
Away from also needing to us, water lustering oil product is constantly gone to improve, to meet the demand in market.
Content of the invention
It is an object of the invention to provide a kind of highlight wear-resistant water-based glaze oil and preparation method thereof.To solve prior art
Present in the problems referred to above.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of highlight wear-resistant water-based glaze oil, by weight percentage this water lustering oil are composed of the following components：Synthesis A breast
Liquid 20%～30%, synthesizes B emulsion 15%～25%, alkali soluble resin 10%～20%, coalescents 5%-8%, wax emulsion
10%～15%, defoamer 0.5%～2.5%, anti-wear agent 0%～0.5%, water 5%～10%.
Described A body emulsion is：
(1) pre-emulsification：Pre-emulsification：In 1000mL tetra- neck equipped with motor stirrer, thermometer, condensing tube and Dropping funnel
Add compound emulsifying agent and deionized water in flask, stir 5-10 minute at 40-45 DEG C, add mix monomer C, stirring
15-30 minute, obtains emulsion；Described compound emulsifying agent is SDS (sodium lauryl sulphate) and (OP-10) alkyl phenol polyoxy
Vinyl Ether compares 1 according to weight:2 ratio compounds, and described mix monomer C is methyl methacrylate, acrylic acid methyl ester., methyl
The mixture that two or more monomer of butyl acrylate, butyl acrylate compounds according to identical weight ratio；
(2) seeded emulsion polymerization：Deca initiator solution, is warmed up to 75-80 DEG C, 40-60 minute completion of dropping, insulation
30-50 minute, prepared seed emulsion；Described initiator is one of potassium peroxydisulfate, sodium peroxydisulfate, Ammonium persulfate.；
(3) emulsion polymerization：Mix monomer D and initiator are added in above-mentioned four-neck flask by Deca mode respectively, protects
Hold reaction temperature constant, 3-4 hour completion of dropping, add initiator, carry out under the same conditions reacting 30 minutes, then add one
Part initiator solution, reacts 30 minutes, filters, discharging, obtains a kind of milky A emulsion in blue light；Described mix monomer D
For methyl methacrylate, acrylic acid methyl ester., butyl methacrylate, butyl acrylate, acrylic acid, methacrylic acid, methyl
2-(Acryloyloxy)ethanol, 2-(Acryloyloxy)ethanol, Hydroxypropyl methacrylate, Hydroxypropyl acrylate, methacrylate and third
The mixture that two or more monomer of olefin(e) acid hydroxy butyl ester compounds according to identical weight ratio, described initiator is persulfuric acid
One of potassium, sodium peroxydisulfate, Ammonium persulfate.；
Described B body emulsion is：
(1) pre-emulsification：In the 1000mL four-neck flask equipped with motor stirrer, thermometer, condensing tube and Dropping funnel
Add compound emulsifying agent and deionized water, at 40-45 DEG C, stir 5-10 minute, add mix monomer E, stirring 15-30 divides
Clock, obtains emulsion；Described compound emulsifying agent is polyoxyethylene sorbitan fatty acid ester (T-20, T-40, T-60 and T-
80) and polyoxyethylene sorbitan fatty acid ester (molecular weight be 200-2000) compares 1 according to weight:2 ratio compounds, described
Mix monomer E be methyl methacrylate, acrylic acid methyl ester., butyl methacrylate, butyl acrylate, acrylic acid ethylene glycol
The mixture that two or more monomer of ester, methyl styrene and styrene compounds according to identical weight ratio；
(2) seeded emulsion polymerization：Deca initiator solution, is warmed up to 80-85 DEG C, 40-60 minute completion of dropping, insulation
40-60 minute, prepared seed emulsion；Described initiator is one of potassium peroxydisulfate, sodium peroxydisulfate, Ammonium persulfate.；
(3) emulsion polymerization：Mix monomer F and initiator are added in above-mentioned four-neck flask by Deca mode respectively, protects
Hold reaction temperature constant, 4-5 hour completion of dropping, add initiator, carry out under the same conditions reacting 30 minutes, then add one
Part initiator solution, reacts 30 minutes, filters, discharging, obtains a kind of milky B emulsion in blue light, described mix monomer F
For methyl methacrylate, acrylic acid methyl ester., acrylic acid, methacrylic acid, hydroxyethyl methylacrylate, 2-(Acryloyloxy)ethanol,
Hydroxypropyl methacrylate, Hydroxypropyl acrylate, methacrylate, hy-droxybutyl, vinyl acetate, methylbenzene second
, according to the compounding mixture of identical weight ratio, described initiator is persulfuric acid for alkene and two or more monomer of styrene
One of potassium, sodium peroxydisulfate, Ammonium persulfate..
Further, described alkali soluble resin is Styrene-acrylic copolymer, and acid number is 160-200, copolymer glass
Flower stabilizes to 80 DEG C -105 DEG C；Described coalescents are 2,2,4- trimethyl -1,3- pentanediol mono isobutyrate；Described wax
Emulsion is the nonionic emulsion of oxidized high-density polyethylene wax, anionic vinyl-acetate copolymer emulsion, modified paraffin
Anionic emulsion, the nonionic wax emulsion of modified poly ethylene, nonionic Petiolus Trachycarpi wax emulsion, modified polypropylene waxes non-
One of ion-type emulsion or two kinds.
Further, described defoamer is special polyethers nonionic defoamer.
Further, described anti-wear agent be nano-alumina dispersions, surface treatment nano silicon oxide dispersion pulp, receive
Rice oxidation zinc dispersion in one or two.
Further, described a kind of highlight wear-resistant water-based glaze oil, preparation method is as follows：A emulsion 20% will be synthesized successively
～30%, synthesize B emulsion 15%～25%, alkali soluble resin 10%～20%, deionized water 5%～10% is added to high-speed stirring
Mix in the rustless steel container of device, under 40 DEG C of bath temperatures, open stirring, mixing speed is 800-1000 rev/min, keep 1-
1.5 hour；Then anti-wear agent 0%～0.5%, coalescents 5%-8%, wax emulsion 10%～15%, defoamer are sequentially added
0.5%～2.5%, mixing speed is brought up to 1200-1500 rev/min, after stirring 30-60 minute, with ammonia or bicarbonate
Sodium adjusts the pH value of emulsion, is allowed to PH=8.5, filters, and wear-resisting high glaze water lustering oil is obtained.
Beneficial effects of the present invention：Solvent odor in packages printing for the oil polish of the present invention is little, and solvent residual amount is few,
Attachment fastness is good, and transparency is high, and glossiness is good, and wearability is strong, and printing is good, will not bonding under high temperature.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail.
A kind of highlight wear-resistant water-based glaze oil, by weight percentage this water lustering oil are composed of the following components：Synthesis A breast
Liquid 20%～30%, synthesizes B emulsion 15%～25%, alkali soluble resin 10%～20%, coalescents 5%-8%, wax emulsion
10%～15%, defoamer 0.5%～2.5%, anti-wear agent 0%～0.5%, water 5%～10%.
Wherein, described alkali soluble resin is Styrene-acrylic copolymer, and acid number is 160-200, and copolymer sparkling is steady
It is set to 80 DEG C -105 DEG C；Described coalescents are 2,2,4- trimethyl -1,3- pentanediol mono isobutyrate；Described wax emulsion
For the nonionic emulsion of oxidized high-density polyethylene wax, anionic vinyl-acetate copolymer emulsion, modified paraffin the moon
Ion-type emulsion, the nonionic wax emulsion of modified poly ethylene, nonionic Petiolus Trachycarpi wax emulsion, the nonionic of modified polypropylene waxes
One of type emulsion or two kinds.
Described defoamer is special polyethers nonionic defoamer.
Described anti-wear agent is nano-alumina dispersions, the nano silicon oxide dispersion pulp of surface treatment, nano zine oxide
In dispersion one or two.
Highlight wear-resistant water-based glaze oil preparation method provided in an embodiment of the present invention, its concrete handling process is as follows：
Step 101, A body emulsion：
(1) pre-emulsification：Pre-emulsification：In 1000mL tetra- neck equipped with motor stirrer, thermometer, condensing tube and Dropping funnel
Add compound emulsifying agent and deionized water in flask, stir 5-10 minute at 40-45 DEG C, add mix monomer C, stirring
15-30 minute, obtains emulsion；Described compound emulsifying agent is SDS (sodium lauryl sulphate) and (OP-10) alkyl phenol polyoxy
Vinyl Ether compares 1 according to weight:2 ratio compounds, and described mix monomer C is methyl methacrylate, acrylic acid methyl ester., methyl
The mixture that two or more monomer of butyl acrylate, butyl acrylate compounds according to identical weight ratio；
(2) seeded emulsion polymerization：Deca initiator solution, is warmed up to 75-80 DEG C, 40-60 minute completion of dropping, insulation
30-50 minute, prepared seed emulsion；Described initiator is one of potassium peroxydisulfate, sodium peroxydisulfate, Ammonium persulfate.；
(3) emulsion polymerization：Mix monomer D and initiator are added in above-mentioned four-neck flask by Deca mode respectively, protects
Hold reaction temperature constant, 3-4 hour completion of dropping, add initiator, carry out under the same conditions reacting 30 minutes, then add one
Part initiator solution, reacts 30 minutes, filters, discharging, obtains a kind of milky A emulsion in blue light；Described mix monomer D
For methyl methacrylate, acrylic acid methyl ester., butyl methacrylate, butyl acrylate, acrylic acid, methacrylic acid, methyl
2-(Acryloyloxy)ethanol, 2-(Acryloyloxy)ethanol, Hydroxypropyl methacrylate, Hydroxypropyl acrylate, methacrylate and third
The mixture that two or more monomer of olefin(e) acid hydroxy butyl ester compounds according to identical weight ratio, described initiator is persulfuric acid
One of potassium, sodium peroxydisulfate, Ammonium persulfate.；
Step 102, B body emulsion：
(1) pre-emulsification：In the 1000mL four-neck flask equipped with motor stirrer, thermometer, condensing tube and Dropping funnel
Add compound emulsifying agent and deionized water, at 40-45 DEG C, stir 5-10 minute, add mix monomer E, stirring 15-30 divides
Clock, obtains emulsion；Described compound emulsifying agent is polyoxyethylene sorbitan fatty acid ester (T-20, T-40, T-60 and T-
80) and polyoxyethylene sorbitan fatty acid ester (molecular weight be 200-2000) compares 1 according to weight:2 ratio compounds, described
Mix monomer E be methyl methacrylate, acrylic acid methyl ester., butyl methacrylate, butyl acrylate, acrylic acid ethylene glycol
The mixture that two or more monomer of ester, methyl styrene and styrene compounds according to identical weight ratio；
(2) seeded emulsion polymerization：Deca initiator solution, is warmed up to 80-85 DEG C, 40-60 minute completion of dropping, insulation
40-60 minute, prepared seed emulsion；Described initiator is one of potassium peroxydisulfate, sodium peroxydisulfate, Ammonium persulfate.；
(3) emulsion polymerization：Mix monomer F and initiator are added in above-mentioned four-neck flask by Deca mode respectively, protects
Hold reaction temperature constant, 4-5 hour completion of dropping, add initiator, carry out under the same conditions reacting 30 minutes, then add one
Part initiator solution, reacts 30 minutes, filters, discharging, obtains a kind of milky B emulsion in blue light, described mix monomer F
For methyl methacrylate, acrylic acid methyl ester., acrylic acid, methacrylic acid, hydroxyethyl methylacrylate, 2-(Acryloyloxy)ethanol,
Hydroxypropyl methacrylate, Hydroxypropyl acrylate, methacrylate, hy-droxybutyl, vinyl acetate, methylbenzene second
, according to the compounding mixture of identical weight ratio, described initiator is persulfuric acid for alkene and two or more monomer of styrene
One of potassium, sodium peroxydisulfate, Ammonium persulfate.；
Step 103, will synthesize A emulsion 20%～30% successively, synthesize B emulsion 15%～25%, and alkali soluble resin 10%～
20%, deionized water 5%～10% is added in the rustless steel container with high speed agitator, under 40 DEG C of bath temperatures, opens
Stirring, mixing speed is 800-1000 rev/min, keeps 1-1.5 hour；Then sequentially add anti-wear agent 0%～0.5%, become
Film auxiliary agent 5%-8%, wax emulsion 10%～15%, defoamer 0.5%～2.5%, mixing speed is brought up to 1200-1500
Rev/min, after stirring 30-60 minute, adjust the pH value of emulsion with ammonia or sodium bicarbonate, be allowed to PH=8.5, filter, be obtained
Wear-resisting high glaze water lustering oil.
Described above to the disclosed embodiments, makes professional and technical personnel in the field be capable of or real using the present invention
Apply example.Multiple modifications to these embodiments will be apparent from for those skilled in the art, institute herein
The General Principle of definition can be real in other embodiments in the case of the spirit or scope without departing from the embodiment of the present invention
Existing.Therefore, the embodiment of the present invention is not intended to be limited to the embodiments shown herein, and be to fit to disclosed herein
Principle and the consistent scope the widest of features of novelty.
Claims (6)
1. a kind of highlight wear-resistant water-based glaze oil is it is characterised in that this water lustering oil is by following components group by weight percentage
Become：Synthesis A emulsion 20%～30%, synthesizes B emulsion 15%～25%, alkali soluble resin 10%～20%, coalescents 5%-
8%, wax emulsion 10%～15%, defoamer 0.5%～2.5%, anti-wear agent 0%～0.5%, water 5%～10%.
2. as claimed in claim 1 a kind of highlight wear-resistant water-based glaze oil it is characterised in that described A body emulsion is：
(1) pre-emulsification：1000mL four-neck flask equipped with motor stirrer, thermometer, condensing tube and Dropping funnel adds
Compound emulsifying agent and deionized water, stir 5-10 minute at 40-45 DEG C, add mix monomer C, stir 15-30 minute, obtain
To emulsion；Described compound emulsifying agent is SDS (sodium lauryl sulphate) and (OP-10) alkylphenol polyoxyethylene is according to weight
Amount compares 1:2 ratio compounds, described mix monomer C is methyl methacrylate, acrylic acid methyl ester., butyl methacrylate,
The mixture that two or more monomer of butyl acrylate compounds according to identical weight ratio；
(2) seeded emulsion polymerization：Deca initiator solution, is warmed up to 75-80 DEG C, 40-60 minute completion of dropping, is incubated 30-50
Minute, prepared seed emulsion；Described initiator is one of potassium peroxydisulfate, sodium peroxydisulfate, Ammonium persulfate.；
(3) emulsion polymerization：Mix monomer D and initiator are added in above-mentioned four-neck flask by Deca mode respectively, keeps anti-
Should be temperature-resistant, 3-4 hour completion of dropping, add initiator, carry out under the same conditions reacting 30 minutes, then add portion and draw
Send out agent solution, react 30 minutes, filter, discharging, obtain a kind of milky A emulsion in blue light；Described mix monomer D is first
Base acrylic acid methyl ester., acrylic acid methyl ester., butyl methacrylate, butyl acrylate, acrylic acid, methacrylic acid, metering system
Sour hydroxyl ethyl ester, 2-(Acryloyloxy)ethanol, Hydroxypropyl methacrylate, Hydroxypropyl acrylate, methacrylate and acrylic acid
The mixture that two or more monomer of hydroxy butyl ester compounds according to identical weight ratio, described initiator is potassium peroxydisulfate,
One of sodium peroxydisulfate, Ammonium persulfate.；
Described B body emulsion is：
(1) pre-emulsification：1000mL four-neck flask equipped with motor stirrer, thermometer, condensing tube and Dropping funnel adds
Compound emulsifying agent and deionized water, stir 5-10 minute at 40-45 DEG C, add mix monomer E, stir 15-30 minute, obtain
To emulsion；Described compound emulsifying agent be polyoxyethylene sorbitan fatty acid ester (T-20, T-40, T-60 and T-80) and
Polyoxyethylene sorbitan fatty acid ester (molecular weight is 200-2000) compares 1 according to weight:2 ratio compounds, and described is mixed
Conjunction monomer E be methyl methacrylate, acrylic acid methyl ester., butyl methacrylate, butyl acrylate, acrylic acid glycol ester,
Methyl styrene and two or more monomer of styrene are according to the compounding mixture of identical weight ratio；
(2) seeded emulsion polymerization：Deca initiator solution, is warmed up to 80-85 DEG C, 40-60 minute completion of dropping, is incubated 40-60
Minute, prepared seed emulsion；Described initiator is one of potassium peroxydisulfate, sodium peroxydisulfate, Ammonium persulfate.；
(3) emulsion polymerization：Mix monomer F and initiator are added in above-mentioned four-neck flask by Deca mode respectively, keeps anti-
Should be temperature-resistant, 4-5 hour completion of dropping, add initiator, carry out under the same conditions reacting 30 minutes, then add portion and draw
Send out agent solution, react 30 minutes, filter, discharging, obtain a kind of milky B emulsion in blue light, described mix monomer F is first
Base acrylic acid methyl ester., acrylic acid methyl ester., acrylic acid, methacrylic acid, hydroxyethyl methylacrylate, 2-(Acryloyloxy)ethanol, methyl
Hydroxypropyl acrylate, Hydroxypropyl acrylate, methacrylate, hy-droxybutyl, vinyl acetate, methyl styrene and
The mixture that two or more monomer of styrene compounds according to identical weight ratio, described initiator is potassium peroxydisulfate,
One of sodium peroxydisulfate, Ammonium persulfate..
3. as claimed in claim 1 a kind of highlight wear-resistant water-based glaze oil it is characterised in that described alkali soluble resin is benzene second
Alkene-acrylic copolymer, acid number is 160-200, and copolymer glass transformation temperature is 80 DEG C -105 DEG C；Described coalescents are
2,2,4- trimethyl -1,3- pentanediol mono isobutyrate；Described wax emulsion is the nonionic of oxidized high-density polyethylene wax
Emulsion, anionic vinyl-acetate copolymer emulsion, the anionic emulsion of modified paraffin, the nonionic of modified poly ethylene
One of type wax emulsion, nonionic Petiolus Trachycarpi wax emulsion, nonionic emulsion of modified polypropylene waxes or two kinds.
4. as claimed in claim 1 a kind of highlight wear-resistant water-based glaze oil it is characterised in that described defoamer is special polyethers
Class nonionic defoamer.
5. as claimed in claim 1 a kind of highlight wear-resistant water-based glaze oil it is characterised in that described anti-wear agent is nano oxidized
Aluminum dispersion, the nano silicon oxide dispersion pulp of surface treatment, in nano oxidized zinc dispersion one or two.
6. as claimed in claim 1 a kind of highlight wear-resistant water-based glaze oil it is characterised in that preparation method is as follows：To close successively
Become A emulsion 20%～30%, synthesize B emulsion 15%～25%, alkali soluble resin 10%～20%, deionized water 5%～10% adds
To in the rustless steel container with high speed agitator, under 40 DEG C of bath temperatures, open stirring, mixing speed is 800-1000
Rev/min, keep 1-1.5 hour；Then anti-wear agent 0%～0.5%, coalescents 5%-8%, wax emulsion 10% are sequentially added
～15%, defoamer 0.5%～2.5%, mixing speed is brought up to 1200-1500 rev/min, after stirring 30-60 minute, uses
Ammonia or the pH value of sodium bicarbonate regulation emulsion, are allowed to PH=8.5, filter, wear-resisting high glaze water lustering oil is obtained.
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| CN107384088A (en) * | 2017-09-26 | 2017-11-24 | 广东兴艺数字印刷股份有限公司 | One kind printing environment-friendly water-based buffing oil anti-scratching wearproof coating and preparation method thereof |
| CN107419596A (en) * | 2017-06-17 | 2017-12-01 | 常州环际商贸有限公司 | A kind of printed matter oil polish |
| CN107474737A (en) * | 2017-08-15 | 2017-12-15 | 南宁东印时代广告有限公司 | A kind of paster making oil polish and preparation method thereof |
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| CN108385435A (en) * | 2018-02-05 | 2018-08-10 | 力嘉包装（东莞）有限公司 | Water-based gloss oil and its preparation method and application |
| CN108774914A (en) * | 2018-06-30 | 2018-11-09 | 福建长信纸业包装有限公司 | A kind of wear-resisting paper product water lustering oil and preparation method thereof |
| CN111548698A (en) * | 2020-06-19 | 2020-08-18 | 佛山市南海双维水性材料有限公司 | Water-based emulsion for high-PVC (polyvinyl chloride) interior wall coating |
| CN112592650A (en) * | 2020-12-11 | 2021-04-02 | 美盈森集团股份有限公司 | Folding-resistant wear-resistant water-based anti-scraping matt oil and preparation method thereof |
| CN113667336A (en) * | 2021-08-18 | 2021-11-19 | 朗升柯式印刷(深圳)有限公司 | UV gloss oil for printing and preparation method thereof |
| CN115466347A (en) * | 2022-10-13 | 2022-12-13 | 上海扬盛印务有限公司 | Water-based blocking yellowing type glazing oil and preparation method thereof |
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| CN107384088A (en) * | 2017-09-26 | 2017-11-24 | 广东兴艺数字印刷股份有限公司 | One kind printing environment-friendly water-based buffing oil anti-scratching wearproof coating and preparation method thereof |
| CN108385435A (en) * | 2018-02-05 | 2018-08-10 | 力嘉包装（东莞）有限公司 | Water-based gloss oil and its preparation method and application |
| CN108330734A (en) * | 2018-03-14 | 2018-07-27 | 东莞嘉颐实业有限公司 | A kind of highly resistance is adhered, high temperature resistant environment-protective waterborne preprinting gloss oil and preparation method thereof |
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| CN108774914B (en) * | 2018-06-30 | 2021-03-16 | 福建长信纸业包装有限公司 | Wear-resistant paper water-based polishing oil and preparation method thereof |
| CN111548698A (en) * | 2020-06-19 | 2020-08-18 | 佛山市南海双维水性材料有限公司 | Water-based emulsion for high-PVC (polyvinyl chloride) interior wall coating |
| CN112592650A (en) * | 2020-12-11 | 2021-04-02 | 美盈森集团股份有限公司 | Folding-resistant wear-resistant water-based anti-scraping matt oil and preparation method thereof |
| CN113667336A (en) * | 2021-08-18 | 2021-11-19 | 朗升柯式印刷(深圳)有限公司 | UV gloss oil for printing and preparation method thereof |
| CN115466347A (en) * | 2022-10-13 | 2022-12-13 | 上海扬盛印务有限公司 | Water-based blocking yellowing type glazing oil and preparation method thereof |
| CN116855135A (en) * | 2023-06-13 | 2023-10-10 | 东莞市美盈森环保科技有限公司 | Preparation process of friction-resistant varnish for self-adhesive labels |
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