CN106417341A - Indoxacarb-containing cockroach killing preparation - Google Patents
Indoxacarb-containing cockroach killing preparation Download PDFInfo
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- CN106417341A CN106417341A CN201610773003.8A CN201610773003A CN106417341A CN 106417341 A CN106417341 A CN 106417341A CN 201610773003 A CN201610773003 A CN 201610773003A CN 106417341 A CN106417341 A CN 106417341A
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- indoxacarb
- cockroach
- preparation containing
- killing
- kills
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to an indoxacarb-containing cockroach killing preparation. The effective component is a single effective indoxacarb component or a composition of the effective indoxacarb component and one or more insecticidal effective component. Indoxacarb as a new generation of carbamates pesticide has excellent killing effect on cockroaches, the killing effect on the cockroaches is as excellent as the killing effect on fipronils. The effective component can be transmitted among the dead bodies and the faeces of the cockroaches, and the secondary killing effect is achieved; the toxicities of indoxacarb to bees and aquatic organisms are much lower than the toxicity of indoxacarb to the fipronils so that indoxacarb is one of most ideal chemical agents for killing cockroaches at present.
Description
Technical field
The present invention relates to a kind of indoxacarb that contains and kill cockroach preparation, belong to technical field of pesticide.
Background technology
Indoxacarb：Chemical name：The chloro-2,3,4a of 7-, 5-tetrahydrochysene-2-[methoxycarbonyl（4-Trifluoromethoxyphen-l）Ammonia
Base formoxyl] indeno [1,2-e] [1,3,4-] oxadiazines-4a-carboxylate methyl ester；English name：Indoxacarb CAS：
173584-44-6 empirical formula：C22H17ClF3N3O7 relative molecular mass：527.83 fusing point：88.1℃；Vapour pressure：<
1.010^-5Pa（20-25℃）；Density：1.03（20℃）；Solubility in water（20℃）：<0.5mg/L；Other solvents dissolve
Degree（g/L）：Methyl alcohol the 0.39th, acetonitrile the 76th, acetone 140.Aqueous stability DT50:>30 days（pH=5）；30 days（pH=7）, about 2
My god（pH=9）.The former medicine of indoxacarb is normally controlled in more than 95%, moisture requirement below 1.0%, pH value be divided into control 4.0 ~
7.0, acetone insoluble matter requires below 0.5%.Meanwhile, FAO require indoxacarb former medicine R body burden will 1/3rd of S body with
Under.Mechanism of action indoxacarb has the mechanism of action of uniqueness, and it is quickly converted to DCJW in insect bodies（N.2 methoxy carbonyl is removed
Base metabolin）, DCJW is acted on insect nerve cell inactivation state Voltage-gated sodium channels, in irreversible blocking-up insect bodies
Nerve impulse transmission, destroy nerve impulse transmission, cause pest movements lack of proper care, can not take food, benumb and finally death.
Groton bug（Formal name used at school：Blattella germanica）Though, run after fame with Germany, but actually its original producton location be
Africa.Because of international trade contacts, during commodity circulation, input China.Due to its figure and other common cockroaches
Similar, individual size as cockroach adult 1/4th, a kind of genus cockroach.People are caused by Groton bug
Endangering similar with other cockroaches, mainly many harmful substance and germs etc. are traveled to the food of people therebetween by them in activity
And in apparatus, the life and health of people is worked the mischief.It can propagate tens of kinds of diseases.According to expert statistics, family common 7
Plant in cockroach, so that Groton bug build minimum, breeding are the fastest and adaptation ability is the strongest.Groton bug spreads disease germs ability not
Be inferior to fly, it can the thirty or forty kind disease such as spreading germs property dysentery, typhoid fever, hepatitis, its corpse can also cause human body mistake
Quick, induce the diseases such as asthma.In spring and summer season, the food that little Lian gets over is also possible to cause food posioning.Groton bug
Except stealing food food, infringement clothing, books etc. cause outside economic loss, and main harm is to spread disease.They are gnawed
During article, tell while eat Bian Labian, in addition to Pseudomonas aeruginosa, Escherichia coli etc., also can propagate hepatitis viruse.There are some researches show, moral
The little Lian of state or the main predisposing factors of human asthma and allergy.Harm for household electrical appliances：Owing to the build of Groton bug is less,
Can be come in and gone out very narrow and small gap, and often the surface-mounted integrated circuit from the heat dissipation channel entrance electrical equipment of household electrical appliances is lived in groups, and is easily caused house
Electrical short or burn out.Temperature higher applicable Groton bug existence in reason electrical equipment.During Groton bug is formally entered on a large scale
The time of state-owned nearly 20 years, the even little market town in almost small and medium-sized cities and rural area ground are spread to from the minority big city starting
District, shows according to Disease Control and Prevention Center of country related data, a female Groton bug at most can breed 1,000,000 offsprings in 1 year.
With a large amount of uses of preventing and treating insecticide, Groton bug has had been provided with the extremely strong resistance to the action of a drug, and most insecticides are invalid to it.
Because of the existence of Groton bug be difficult to prevent and treat, causing cockroach to replace mouse becomes first of the four pests！
The method of current domestic preventing and treating Groton bug mainly has the medicament of following several formulation, and pulvis will kill Groton bug
Medicament be configured to can wet-milling, be then watered and be sprayed at the place that Groton bug haunts, but this effect is very undesirable because
Groton bug all perches in hidden small gaps general daytime, and powder product is difficult to be injected into perching of Groton bug
Ground, can only be sprayed at the indoor open field of cockroach out activity, and indoor open field is generally also the place of human lives,
Therefore this type of product is very big on the impact of human residential environment, has been substantially at superseded ranks at present.Fumigant will kill moral
The medicament of the little Lian of state is configured to fumigant, during use by igniting heat by way of by medicament heating evaporation in the air, the method
Advantage be that liquid steam can waft in the small gaps hidden oneself into cockroach, but shortcoming is the same with pulvis, needs to put all over the sky cigarette, medicine
The utilization rate of thing is extremely low, and environmental pollution is very big, at present only in local uses such as some uninhabited refuse landfills, indoor
The roach that goes out has not used this type of product substantially.
Granule：The medicament killing Groton bug is configured to fine granularity, after containing with box, is placed on what cockroach haunted
Proximate.This formulation can avoid the insecticide-applying way dancing in the air formula all over the sky of powder product, but to the killing effect of cockroach also
It is very undesirable.Because the food of the many liquid of cockroach eating, the requirement to the moisture in food is very high, and in granule product
Because water content is typically all controlled very low by the needs of mildew-resistant, therefore cockroach not liking takes food, thus killing effect is also very
Difference.
Cockroach killing bait：This formulation is that current chemicals kills the most advanced also ideal agent in the formulation of cockroach
This formulation of type is to be uniformly dispersed in active ingredient in the bait formulation with liquid as matrix, because containing greatly in this kind of product
The water of amount, therefore very good to the palatability of cockroach, cockroach enjoys a lot to take food, and during use, bait formulation point is coated in cockroach and haunts
Place, medicament is taken food in stomach by cockroach, and therefore killing effect is also good than other all of formulations, is in the market
Kill main force's dosage form product of cockroach.Imidacloprid is the first generation active ingredient of this cockroach killing bait, the effective agent generally using
Amount is about 2%, and roach effect of going out when product is just introduced to the market is fine, has good quick-acting, but As time goes on, adds
The extremely powerful fertility of cockroach, the product of active ingredient containing imidacloprid occurs in that the resistance to the action of a drug soon, kills roach effect anxious
Acute decline.Hydramethylnon is the second generation active ingredient of this cockroach killing bait, and this active ingredient resistance to the action of a drug is formed slowly.Hydramethylnon
Predominantly stomach poison function, i.e. has action of contace poison, it may have stomach poison function, therefore the onset time of medicine unlike imidacloprid
Also long, it usually needs the time of seven to ten days could onset, but the long drug effect performance time to needs by use bait
The application places that agent reduces rapidly cockroach density is not appropriate for, and this defect also have impact on its large-scale popularization and application.Fluorine
Worm nitrile is the third generation active ingredient of this cockroach killing bait, as the product drawing century when just releasing, achieves extraordinary effect
Really, but the former medicine of ethiprole has high toxicity to honeybee and aquatile, a lot of countries forbidden the synthesis of its former medicine with
Producing and registration, therefore its application is also greatly limited.
Content of the invention
The present invention is directed to drawbacks described above, it is therefore intended that provide a kind of good one of cockroach effect of killing to kill cockroach system containing indoxacarb
Agent.
It for this technical solution used in the present invention is：Active ingredient of the present invention is single indoxacarb active ingredient or indoxacarb
Compound with other one or more insecticidal active ingredients.
Its active ingredient indoxacarb（Mass fraction）Content be 0.05 ~ 5.0%, the content more optimizing is 0.1 ~ 1%.
Containing the moisture of 20% ~ 80% in its system, the moisture more optimizing is 40% ~ 70%.
Its system contains the cockroach sex attractant composition of 0.001% ~ 1.00%.
In its system containing 5 ~ 50% glycerine, or sorbierite or glycerine and sorbitol mixture are as the guarantor of system
Humectant.
Its system formulation contains the polyacrylate polymer gel skeleton of 0.1 ~ 5.0.
Containing as wrapping up the former powder-beta-dextrin of medicinal 1.0 ~ 10.0 of indoxacarb in its system formulation.
In its system formulation containing as bag sweetener 1 ~ 30% fructose, sucrose, glucose, in maltose
Plant or multiple mixtures.
It is an advantage of the invention that：The present invention can effectively solve the first generation and kill with the cockroach bait formulation that kills based on imidacloprid
The problem of effect difference.Cockroach is after taking food imidacloprid bait formulation, and within the very short time, cockroach is just gone down, and causes part cockroach
The amount taking food bait formulation is simultaneously little, does not reaches the dosage of complete lethal, and it is not high to the fatal rate of cockroach, and down and out cockroach exists
The meeting of about 30 ~ 50% after two to three days recovers normal, and the breeding potential of cockroach is very high, causes using with pyrrole worm
Quinoline be active ingredient kill the resistance rapid increase to imidacloprid for the cockroach bait formulation cockroach after being used for a while, kill roach effect
Decline further, and imidacloprid is invalid to ovum.And use and kill cockroach bait formulation with indoxacarb as active ingredient, cockroach is taking food
After several hours in do not show higher toxicity, but after a couple of days, as long as the cockroach taking food, its death rate can be 98%
Above, and the former medicine of indoxacarb can be transmitted in ovum by parent, if what the female cockroach with ovum had taken food containing indoxacarb
After bait formulation, its entrained ovum also can be poisoned and not hatched.And indoxacarb also has transmission effect, cockroach take food companion's ight soil with
The habit of corpse.Take food the companion's ight soil containing indoxacarb composition also can be up to its death rate in two days of cockroach of corpse
More than 80%.A dispenser, the effect of the chain roach that goes out can be played.
Cockroach killing bait in the present invention is the transparent g., jelly-like gelinite of water white transparency or other colors, has certain gluing
Attached property, in that context it may be convenient to some cloth, in any desired place, puts system crystal clear after cloth, system surface just shape after one or two minute
Become a kind of neither to absorb water nor the ganoine thin film with some strength of dehydration, can firmly stick to a cloth object table face length
For bimester one, i.e. will not desiccation come off, also will not absorb water thinning trickling, and excellent cockroach can also be kept to take food
Palatability.
Cockroach killing bait system in 008 present invention is added with the cockroach sex attractant of trace, can be to roach after bait formulation point cloth
Dung beetle produces strong attracting action, even if the conceived cockroach concealed in very deep gap also can be out when smelling the smell of product
Take food, the effect finished off with one blow can be played.Little blackbeetle can be killed in bud.
Indoxacarb, as carbamate chemicals for agriculture of new generation, has splendid the killing that same ethiprole is the same to cockroach
Going out effect, its active ingredient can be transmitted between the corpse of cockroach and ight soil, has a chain roach effect of going out, and indoxacarb pair
Honeybee is more much smaller than ethiprole with hydrobiological toxicity, is presently the most preferably one of chemical agent killing cockroach.
Detailed description of the invention
Preparation example one
0.2% indoxacarb cockroach killing bait：
Add 50 grams of distilled water in the beaker of 200 milliliters, be subsequently adding 30 grams of powder-beta-dextrins, after slightly stirring, add 2.1 grams of indenes
The former medicine of worm prestige and 0.2 gram of sex attractant, dispersed with stirring is uniform, forms the slurry of slightly thickness, adds this slurry in colloid mill and fills
Divide and grind more than 30 minutes, make the former medicine of indoxacarb be wrapped up by powder-beta-dextrin completely and sex attractant, add the steaming of about 50 grams
Distilled water, slightly heats up, and makes to be enclosed with the former medicine of indoxacarb and the powder-beta-dextrin of sex attractant is dissolved completely in distilled water, formed transparent
The aqueous solution.
By remaining material dissolution in remaining distilled water, in airtight container swelling more than 24 hours, formed thick
Thick slurry.Finally the powder-beta-dextrin aqueous solution being dissolved with the former medicine of indoxacarb and sex attractant is added in slurry, in colloid mill
Regrind a more than hour, make indoxacarb and sex attractant be completely dispersed uniformly in system, form gel jelly body
System.
Being thoroughly degassed in the equipment that this gel jelly body finally ties up to vacuum degasser, degassing after terminating is
Obtain transparent gel-form 0.2% indoxacarb Cockroach killing bait agent 1000 grams.
Preparation example two
0.5% indoxacarb cockroach killing bait：
Add 120 grams of distilled water in the beaker of 200 milliliters, be subsequently adding 80 grams of powder-beta-dextrins, after slightly stirring, add 5.2 grams of indenes
The former medicine of worm prestige and 0.25 gram of sex attractant, dispersed with stirring is uniform, forms the slurry of slightly thickness, adds this slurry in colloid mill and fills
Divide and grind more than 30 minutes, make the former medicine of indoxacarb be wrapped up by powder-beta-dextrin completely and sex attractant, add the steaming of about 100 grams
Distilled water, slightly heats up, and makes to be enclosed with the former medicine of indoxacarb and the powder-beta-dextrin of sex attractant is dissolved completely in distilled water, formed transparent
The aqueous solution.
By remaining material dissolution in remaining distilled water, in airtight container swelling more than 24 hours, formed thick
Thick slurry.Finally the powder-beta-dextrin aqueous solution being dissolved with the former medicine of indoxacarb and sex attractant is added in slurry, in colloid mill
Regrind a more than hour, make indoxacarb and sex attractant be completely dispersed uniformly in system, form gel jelly body
System.
Being thoroughly degassed in the equipment that this gel jelly body finally ties up to vacuum degasser, degassing after terminating is
Obtain transparent gel-form 0.5% indoxacarb Cockroach killing bait agent 1000 grams.
Preparation example three
1.0% indoxacarb cockroach killing bait：
Add 150 grams of distilled water in the beaker of 500 milliliters, be subsequently adding 150 grams of powder-beta-dextrins, after slightly stirring, add 10.3 grams
The former medicine of indoxacarb and 0.28 gram of sex attractant, dispersed with stirring is uniform, forms the slurry of slightly thickness, adds this slurry in colloid mill
It is fully ground more than 30 minutes, make the former medicine of indoxacarb be wrapped up by powder-beta-dextrin completely and sex attractant, add about 120 grams
Distilled water, slightly heats up, and makes to be enclosed with the former medicine of indoxacarb and the powder-beta-dextrin of sex attractant is dissolved completely in distilled water, formed transparent
The aqueous solution.
By remaining material dissolution in remaining distilled water, in airtight container swelling more than 24 hours, formed thick
Thick slurry.Finally the powder-beta-dextrin aqueous solution being dissolved with the former medicine of indoxacarb and sex attractant is added in slurry, in colloid mill
Regrind a more than hour, make indoxacarb and sex attractant be completely dispersed uniformly in system, form gel jelly body
System.
Being thoroughly degassed in the equipment that this gel jelly body finally ties up to vacuum degasser, degassing after terminating is
Obtain transparent gel-form 1.0% indoxacarb Cockroach killing bait agent 1000 grams.
Claims (8)
1. one kind is killed cockroach preparation containing indoxacarb, it is characterised in that active ingredient is single indoxacarb active ingredient or indoxacarb
Compound with other one or more insecticidal active ingredients.
2. one according to claim 1 kills cockroach preparation containing indoxacarb, it is characterised in that its active ingredient indoxacarb
（Mass fraction）Content be 0.05 ~ 5.0%, the content more optimizing is 0.1 ~ 1%.
3. one according to claim 1 kills cockroach preparation containing indoxacarb, it is characterised in that in its system containing 20% ~
The moisture of 80%, the moisture more optimizing is 40% ~ 70%.
4. one according to claim 1 kills cockroach preparation containing indoxacarb, it is characterised in that contain 0.001% in its system
The cockroach sex attractant composition of ~ 1.00%.
5. one according to claim 1 kills cockroach preparation containing indoxacarb, it is characterised in that contain 5 ~ 50% in its system
Glycerine, or sorbierite or glycerine and sorbitol mixture are as the NMF of system.
6. one according to claim 1 kills cockroach preparation containing indoxacarb, it is characterised in that contain in its system formulation
The polyacrylate polymer gel skeleton of 0.1 ~ 5.0.
7. one according to claim 1 kills cockroach preparation containing indoxacarb, it is characterised in that containing work in its system formulation
For the former powder-beta-dextrin of medicinal 1.0 ~ 10.0 of parcel indoxacarb.
8. one according to claim 1 kills cockroach preparation containing indoxacarb, it is characterised in that containing work in its system formulation
For the fructose of the 1 ~ 30% of bag sweetener, sucrose, glucose, the mixture of one or more in maltose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773003.8A CN106417341A (en) | 2016-08-31 | 2016-08-31 | Indoxacarb-containing cockroach killing preparation |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610773003.8A CN106417341A (en) | 2016-08-31 | 2016-08-31 | Indoxacarb-containing cockroach killing preparation |
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| CN106417341A true CN106417341A (en) | 2017-02-22 |
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| CN201610773003.8A Pending CN106417341A (en) | 2016-08-31 | 2016-08-31 | Indoxacarb-containing cockroach killing preparation |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109122726A (en) * | 2018-10-21 | 2019-01-04 | 江苏长青生物科技有限公司 | It is a kind of to kill cockroach gel bait formulation and preparation method thereof with chain transmission effects |
| CN109221227A (en) * | 2018-10-21 | 2019-01-18 | 江苏长青生物科技有限公司 | It is a kind of efficiently to kill cockroach gel bait formulation and preparation method thereof |
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| CN1376028A (en) * | 1999-09-22 | 2002-10-23 | 埃科莱布有限公司 | Water-based pest baits containing water sensitive insecticides |
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| CN109122726A (en) * | 2018-10-21 | 2019-01-04 | 江苏长青生物科技有限公司 | It is a kind of to kill cockroach gel bait formulation and preparation method thereof with chain transmission effects |
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Application publication date: 20170222 |
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