CN106404694B - Device for dynamically monitoring smoke component concentration in cigarette smoking process - Google Patents

Device for dynamically monitoring smoke component concentration in cigarette smoking process Download PDF

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CN106404694B
CN106404694B CN201610998074.8A CN201610998074A CN106404694B CN 106404694 B CN106404694 B CN 106404694B CN 201610998074 A CN201610998074 A CN 201610998074A CN 106404694 B CN106404694 B CN 106404694B
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gas absorption
adjusting seat
end flange
smoke
reflection gas
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CN106404694A (en
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计敏
邓楠
李志刚
张龙
李斌
张明建
张柯
刘勇
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Hefei Zwotech Instrument Technology Co ltd
Hefei Institutes of Physical Science of CAS
Zhengzhou Tobacco Research Institute of CNTC
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Hefei Zwotech Instrument Technology Co ltd
Hefei Institutes of Physical Science of CAS
Zhengzhou Tobacco Research Institute of CNTC
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    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
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    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
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Abstract

A device for dynamically monitoring smoke component concentration in a cigarette smoking process is characterized in that: the smoke sucking machine comprises a smoke sucking machine, a two-way valve of the smoke sucking machine, a multi-reflection gas absorption pool, a filter disc, a three-way valve and a cigarette holder which are sequentially communicated according to the smoke sucking flow direction, wherein a light incidence end of the multi-reflection gas absorption pool is connected with an optical fiber collimator, a laser current controller and a laser temperature controller, a light receiving end of the multi-reflection gas absorption pool is connected with a photoelectric detector, the laser current controller and the laser temperature controller are connected with a computer, the photoelectric detector is connected with the computer through a data acquisition card, and a vacuum pump is connected on a gas path between the two-way valve of the smoke sucking machine and the multi-reflection gas absorption pool through the two-way valve. The method overcomes the defects that the pretreatment process is time-consuming, the detection steps are complicated, and the dynamic change of the smoke components cannot be accurately reflected in the prior art, and has important significance for deeply exploring the cigarette combustion pyrolysis mechanism and evaluating the real-time toxicity of the smoke.

Description

一种用于动态监测卷烟抽吸过程中烟气组分浓度的装置A device for dynamically monitoring the concentration of smoke components during cigarette smoking

技术领域technical field

本发明涉及气体浓度检测装置,具体是一种动态监测卷烟抽吸过程中烟气组分浓度的装置。The invention relates to a gas concentration detection device, in particular to a device for dynamically monitoring the concentration of smoke components during cigarette smoking.

背景技术Background technique

卷烟在抽吸过程中,在高温燃烧区、蒸馏裂解区或是低温冷凝区,均包含一系列复杂的物理、化学变化。卷烟烟气是卷烟燃烧过程中产生的一种气溶胶,是已知组成最为复杂的体系之一。其中主流烟气是抽吸时从卷烟的滤嘴端通过的烟气,其有害成分可直接作用于人体器官,有害成分的类别和含量一起被用来判断烟气毒性,相关烟气组分的释放量可以用来反应烟支燃烧状态。但是,卷烟烟气组分与浓度随着抽吸过程的进行,一直处于动态变化的过程之中。卷烟燃烧状态又与烟气化学具有密切的相关性。因此,检测卷烟在抽吸过程中主流烟气内有害烟气成分的实时动态变化,对深入探索烟支燃烧热解机理、评估烟气毒性具有非常重要的意义。设计一种用于实时在线监测抽吸过程中烟气组分浓度的装置很有必要。During the smoking process of cigarettes, there are a series of complex physical and chemical changes in the high-temperature combustion zone, distillation cracking zone or low-temperature condensation zone. Cigarette smoke is an aerosol produced during the burning of cigarettes and is one of the most complex systems known. Among them, mainstream smoke is the smoke that passes through the filter tip of cigarettes during smoking. Its harmful components can directly act on human organs. The type and content of harmful components are used together to judge the toxicity of smoke. The release amount can be used to reflect the combustion state of the cigarette. However, the composition and concentration of cigarette smoke have been in a process of dynamic change along with the smoking process. The combustion state of cigarettes is closely related to the chemistry of smoke. Therefore, detecting the real-time dynamic changes of harmful smoke components in mainstream smoke during cigarette smoking is of great significance for in-depth exploration of the pyrolysis mechanism of cigarette combustion and evaluation of smoke toxicity. It is necessary to design a device for real-time online monitoring of the concentration of smoke components during the smoking process.

发明内容Contents of the invention

本发明主要解决的技术问题在于,针对现有技术中样品前处理耗时,检测步骤繁琐,且未能准确反映烟气组分动态变化的缺点,提供一种便捷、快速,用于表征烟气组分动态浓度的装置。The technical problem mainly solved by the present invention is to provide a convenient and fast method for characterizing flue gas in view of the disadvantages of time-consuming sample pretreatment, cumbersome detection steps and failure to accurately reflect the dynamic changes of flue gas components in the prior art. Device for dynamic concentration of components.

本发明的目的是通过以下技术方案来实现的:The purpose of the present invention is achieved through the following technical solutions:

一种动态监测卷烟抽吸过程中烟气组分浓度的装置,按烟气抽吸流向包括依次连通的吸烟机、吸烟机两通阀、多次反射气体吸收池、滤片、三通阀及烟支夹持器,在多次反射气体吸收池的光线入射端连接有光纤准直器、激光器以及激光电流控制器和激光温度控制器,在多次反射气体吸收池的光线接收端连接有光电探测器,所述激光电流控制器、激光温度控制器均与计算机相连接,所述光电探测器通过数据采集卡与计算机相连接,在吸烟机两通阀与多次反射气体吸收池之间的气路上通过真空泵两通阀连接有真空泵。A device for dynamically monitoring the concentration of smoke components during cigarette smoking, comprising a smoking machine, a two-way valve for the smoking machine, a multi-reflection gas absorption pool, a filter, a three-way valve and The cigarette support holder is connected with a fiber collimator, laser, laser current controller and laser temperature controller at the light incident end of the multiple reflection gas absorption cell, and is connected with a photoelectric sensor at the light receiving end of the multiple reflection gas absorption cell. detector, the laser current controller and the laser temperature controller are all connected to the computer, the photoelectric detector is connected to the computer through the data acquisition card, and the gas between the two-way valve of the smoking machine and the multiple reflection gas absorption pool A vacuum pump is connected to the road through a two-way valve of the vacuum pump.

所述吸烟机为直线式吸烟机或转盘式吸烟机,吸烟机可为单通道或多通道。所述吸烟机的抽吸动力源为步进电机。The smoking machine is a linear smoking machine or a rotary table smoking machine, and the smoking machine can be single-channel or multi-channel. The suction power source of the smoking machine is a stepping motor.

所述滤片为聚四氟乙烯(PTFE)薄膜滤片或剑桥滤片。The filter is a polytetrafluoroethylene (PTFE) membrane filter or a Cambridge filter.

所述光纤准直器与多次反射气体吸收池之间通过一准直器端法兰固定调节座相连接,在该准直器端法兰固定调节座圆周方向上均布有三个腰型孔,多次反射气体吸收池端面上相应加工有三个螺纹孔;同时,准直器端法兰固定调节座一个端面设计成斜面,此斜面用于贴合多次反射气体吸收池的一个端面;三个螺钉分别装入准直器端法兰固定调节座在圆周上三个均布的腰型孔中,同时使准直器端法兰固定调节座斜面与多次反射气体吸收池端面贴合,并通过三个螺钉连接;当光线从光纤准直器中心线入射,沿着准直器端法兰固定调节座上中心孔的中心线传播。由于准直器端法兰固定调节座的贴合面是个斜面,如果此时调松准直器端法兰固定调节座上的螺钉,把准直器端法兰固定调节座旋转一定的角度,则入射光线就会在一个更小的弧度上旋转相应的角度,与此同时入射光线的入射点的位置也发生了变化。The optical fiber collimator is connected to the multi-reflection gas absorption cell through a collimator end flange fixed adjustment seat, and there are three waist-shaped holes evenly distributed in the circumferential direction of the collimator end flange fixed adjustment seat, Three threaded holes are correspondingly processed on the end surface of the multiple reflection gas absorption cell; at the same time, one end surface of the flange fixing adjustment seat at the end of the collimator is designed as an inclined plane, which is used to fit one end surface of the multiple reflection gas absorption cell; three The screws are respectively installed in the three waist-shaped holes uniformly distributed on the circumference of the collimator end flange fixed adjustment seat, and at the same time, the inclined surface of the collimator end flange fixed adjustment seat is attached to the end surface of the multiple reflection gas absorption cell, and It is connected by three screws; when the light is incident from the centerline of the fiber collimator, it propagates along the centerline of the center hole on the flange of the collimator to fix the adjustment seat. Since the fitting surface of the collimator end flange fixed adjustment seat is an inclined surface, if the screw on the collimator end flange fixed adjustment seat is loosened at this time, and the collimator end flange fixed adjustment seat is rotated by a certain angle, Then the incident light will be rotated by a corresponding angle in a smaller arc, and at the same time, the position of the incident point of the incident light will also change.

所述光电探测器与多次反射气体吸收池之间通过一探测器端法兰固定调节座相连接,在该探测器端法兰固定调节座圆周方向上均布有三个腰型孔,多次反射气体吸收池端面上相应加工有三个螺纹孔;同时,探测器端法兰固定调节座一端面设计成斜面,此斜面用于贴合多次反射气体吸收池的一个端面;三个螺钉分别装入探测器端法兰固定调节座在圆周上三个均布的腰型孔中,同时使探测器端法兰固定调节座斜面与多次反射气体吸收池端面贴合,并通过三个螺钉连接;当光线从吸收池中出射时,沿着准探测端法兰固定调节座上中心孔的中心线传播,由于探测器端法兰固定调节座的贴合面是个斜面,如果此时调松探测器端法兰固定调节座上的螺钉,把探测器端法兰固定调节座旋转一定的角度,则出射光线就会在一个更小的弧度上旋转相应的角度,与此同时出射光线的出射点的位置也发生了变化。The photoelectric detector is connected to the multi-reflection gas absorption cell through a detector end flange fixed adjustment seat, and there are three waist-shaped holes evenly distributed on the circumference of the detector end flange fixed adjustment seat, and the multiple reflection Three threaded holes are correspondingly processed on the end face of the gas absorption cell; at the same time, the end face of the fixed adjustment seat of the detector end flange is designed as an inclined plane, which is used to fit one end face of the multiple reflection gas absorption cell; the three screws are respectively installed The flange fixing and adjusting seat at the detector end is in three evenly distributed waist-shaped holes on the circumference, and at the same time, the inclined surface of the flange fixing and adjusting seat at the detector end is attached to the end surface of the multiple reflection gas absorption cell, and connected by three screws; When the light exits from the absorption cell, it propagates along the centerline of the center hole on the flange fixed adjustment seat at the quasi-detection end. Since the fitting surface of the detector end flange fixed adjustment seat is an inclined plane, if the detector is loosened at this time The screw on the adjusting seat fixed by the end flange, and the fixed adjusting seat on the detector end flange is rotated by a certain angle, then the outgoing light will be rotated by a corresponding angle in a smaller arc, and at the same time the exit point of the outgoing light will be The location has also changed.

上述准直器端法兰固定调节座与探测器端法兰固定调节座的不同之处是,准直器端法兰固定调节座中间设计的尺寸孔为光孔,而光电探测器端法兰固定调节座孔为螺纹孔,因为光电探测器上有相应的外螺纹,所以螺纹孔用于连接探测器。The difference between the flange fixed adjustment seat at the collimator end and the flange fixed adjustment seat at the detector end is that the size hole designed in the middle of the flange fixed adjustment seat at the collimator end is a light hole, while the flange fixed adjustment seat at the photodetector end The seat hole is a threaded hole, because there is a corresponding external thread on the photodetector, so the threaded hole is used to connect the detector.

所述多次反射气体吸收池的型号为集成式多次反射气体吸收池,其由探测器、光纤准直器和多次反射气体吸收池集成为一体。光纤准直器、光电探测器分别通过相应的准直器端法兰固定调节座、光电探测器端法兰固定调节座与多次反射气体吸收池集成为一体。The model of the multiple reflection gas absorption cell is an integrated multiple reflection gas absorption cell, which is integrated by a detector, an optical fiber collimator and a multiple reflection gas absorption cell. The fiber collimator and the photodetector are integrated with the multi-reflection gas absorption cell through the corresponding collimator end flange fixing adjustment seat and the photodetector end flange fixing adjustment seat respectively.

多次反射气体吸收池可以为赫里奥特气体吸收池以及怀特池其中的一种,体积在50-1000mL之间。The multiple reflection gas absorption cell can be one of the Heriott gas absorption cell and the White cell, and the volume is between 50-1000mL.

所述数据采集卡,数据采集卡内部设置有锁相放大器、A/D转换器。通过信号放大、二倍频谐波解调得到的二次谐波吸收信号,再经过模数转换后输送至计算机,以完成处理和显示 The data acquisition card is provided with a lock-in amplifier and an A/D converter inside the data acquisition card. The second harmonic absorption signal obtained through signal amplification and double frequency harmonic demodulation is sent to the computer after analog-to-digital conversion for processing and display .

本装置的工作机理及过程如下:吸烟机对卷烟进行抽吸,卷烟主流烟气经滤片过滤后进入多次反射气体吸收池。同时,经光纤准直器准直后的光束从多次反射气体吸收池入光孔入射,在吸收池内经多次反射后从出光孔出射,进而被光电探测器接收。光电探测器把光信号转化为电信号,电信号送入数据采集卡,信号经过锁相放大器进行放大、二倍频解调处理、前置放大器放大和数模转化后进入计算机进行数据处理和显示。动态抽吸检测完成后,通过协调控制真空泵、两通阀和三通阀,并且利用氮气对多次反射气体吸收池中的待测气体和抽吸管道中残留气体进行清洗。The working mechanism and process of the device are as follows: the cigarette is sucked by the smoking machine, and the mainstream smoke of the cigarette enters the multi-reflection gas absorption pool after being filtered by the filter. At the same time, the light beam collimated by the fiber collimator is incident from the light entrance hole of the multiple reflection gas absorption cell, and after multiple reflections in the absorption cell, it exits the light exit hole and is then received by the photodetector. The photoelectric detector converts the optical signal into an electrical signal, and the electrical signal is sent to the data acquisition card. The signal is amplified by the lock-in amplifier, demodulated by double frequency, amplified by the preamplifier and digital-to-analog converted, and then enters the computer for data processing and display. . After the dynamic suction test is completed, the vacuum pump, two-way valve and three-way valve are coordinated and controlled, and nitrogen is used to clean the gas to be tested in the multiple reflection gas absorption cell and the residual gas in the suction pipeline.

所述激光器控制过程及原理如下,激光器由激光电流控制器和激光温度控制器控制。激光温度控制器在设定所需要的温度后,激光器产生特定波长的激光光束。激光电流控制器产生数十Hz的锯齿波信号,锯齿波信号控制一个慢的扫描电流,完成对特定中心波长待测气体吸收峰的扫描。扫描的范围由控制界面设置不同的起始电流和终止电流来进行控制。调制信号发生器产生数十kHz正弦波信号进行调制。The laser control process and principle are as follows, the laser is controlled by a laser current controller and a laser temperature controller. After the laser temperature controller sets the required temperature, the laser generates a laser beam with a specific wavelength. The laser current controller generates a sawtooth wave signal of tens of Hz, and the sawtooth wave signal controls a slow scanning current to complete the scanning of the absorption peak of the gas to be measured at a specific central wavelength. The scanning range is controlled by setting different starting current and ending current on the control interface. Modulation signal generator generates tens of kHz sine wave signal for modulation.

本发明的特点在于:集成式多次反射气体吸收池能节省调整光路的时间,同时由于光路在实验过程中固定,不易受到机械振动等因素干扰,让光电探测器探测到的输出光束非常稳定,不至于失去数据实时检测的准确性和可比性。这对动态检测尤为重要。准直器端法兰固定调节座、光电探测器端法兰固定调节座可以在一定角度旋转,进行角度的微调,这使得在微调光路更加便捷。激光扫描范围可调。通过设置不同的扫描频率,可以实现高时间分辨率的气体浓度检测,也就是在可检测卷烟在抽吸过程中实时动态分析主流烟气内有害烟气成分的变化状况。本发明装置操作简便,检测步骤简单,能实现准确地动态监测,监测的结果对深入探索烟支燃烧热解机理、评估烟气毒性具有非常重要的意义。The feature of the present invention is that the integrated multi-reflection gas absorption cell can save the time for adjusting the optical path, and at the same time, because the optical path is fixed during the experiment, it is not easily disturbed by factors such as mechanical vibration, so that the output beam detected by the photoelectric detector is very stable. The accuracy and comparability of real-time detection of data will not be lost. This is especially important for dynamic detection. The flange fixed adjustment seat at the collimator end and the flange fixed adjustment seat at the photodetector end can be rotated at a certain angle for fine adjustment of the angle, which makes it more convenient to fine-tune the optical path. The laser scanning range is adjustable. By setting different scanning frequencies, gas concentration detection with high time resolution can be realized, that is, the changes of harmful smoke components in mainstream smoke can be dynamically analyzed in real time during the smoking process of detectable cigarettes. The device of the invention is easy to operate, has simple detection steps, can realize accurate dynamic monitoring, and the monitoring result has very important significance for in-depth exploration of the pyrolysis mechanism of cigarette combustion and evaluation of smoke toxicity.

附图说明Description of drawings

图1是卷烟抽吸中烟气组分浓度在线检测装置示意图;Figure 1 is a schematic diagram of an online detection device for the concentration of smoke components in cigarette smoking;

图1中:1.步进电机,2.吸烟机,3.真空泵两通阀,4.真空泵,5.光电探测器,6.多次反射气体吸收池,7.计算机,8.激光电流控制器,9.激光器,10.温度控制器,11.光纤,12.光纤准直器,13.三通阀,14.烟支夹持器,15.烟支,16.滤片,17.吸烟机两通阀,18.数据采集卡。In Figure 1: 1. Stepping motor, 2. Smoking machine, 3. Vacuum pump two-way valve, 4. Vacuum pump, 5. Photoelectric detector, 6. Multiple reflection gas absorption cell, 7. Computer, 8. Laser current control Device, 9. Laser, 10. Temperature controller, 11. Optical fiber, 12. Optical fiber collimator, 13. Three-way valve, 14. Cigarette holder, 15. Cigarette, 16. Filter, 17. Smoking Machine two-way valve, 18. Data acquisition card.

图2是集成吸收池光电探测器连接端示意图,Figure 2 is a schematic diagram of the connection end of the integrated absorption cell photodetector,

图2中:19.出气孔,20.光电探测器端法兰固定调节座,20-1.螺纹孔,20-2.腰型孔。Among Fig. 2: 19. air outlet, 20. photodetector end flange fixed adjustment seat, 20-1. threaded hole, 20-2. waist-shaped hole.

图3是集成吸收池光纤准直器连接端示意图,Figure 3 is a schematic diagram of the connection end of the fiber collimator of the integrated absorption cell,

图3中:21.进气孔,22. 光纤准直器端法兰固定调节座,22-1.光孔,22-2.腰型孔。Among Fig. 3: 21. air inlet, 22. fiber collimator end flange fixed adjustment seat, 22-1. light hole, 22-2. waist hole.

图4是为光电探测器端法兰固定调节座结构示意图,c,d,e分别为其全剖视图、主视图和左视图。Fig. 4 is a schematic diagram of the structure of the flange fixing adjustment seat at the photodetector end, c, d, and e are the full sectional view, the front view and the left view, respectively.

图5为光纤准直器端法兰固定调节座结构示意图,f,g,h分别为其全剖视图、主视图和左视图。Fig. 5 is a schematic diagram of the structure of the flange fixing adjustment seat at the end of the fiber collimator, f, g, and h are the full sectional view, the front view and the left view, respectively.

图6 是二次谐波调谐原理图。Figure 6 is a schematic diagram of the second harmonic tuning.

图7 是TDLAS(Tunable Diode Laser Absorption Spectroscopy)计算机控制面板界面。Figure 7 is the TDLAS (Tunable Diode Laser Absorption Spectroscopy) computer control panel interface.

图8 是卷烟抽吸过程中烟气组分浓度的动态检测曲线。Figure 8 is the dynamic detection curve of the concentration of smoke components during cigarette smoking.

图9 是卷烟抽吸过程中烟气组分浓度的动态检测曲线的差分曲线。Figure 9 is the difference curve of the dynamic detection curve of the smoke component concentration during cigarette smoking.

具体实施方式Detailed ways

本发明以下结合附图做进一步描述:The present invention is further described below in conjunction with accompanying drawing:

如图1所示:一种动态监测卷烟抽吸过程中烟气组分浓度的装置,按烟气抽吸流向包括依次连通的吸烟机2、吸烟机两通阀17、多次反射气体吸收池6、滤片16、三通阀13及烟支夹持器14,在多次反射气体吸收池6的光线入射端连接有光纤准直器12、激光器9以及激光电流控制器8和激光温度控制器10,在多次反射气体吸收池的光线接收端连接有光电探测器5,所述激光电流控制器8、激光温度控制器10均与计算机7相连接,所述光电探测器5通过数据采集卡18与计算机7相连接,在吸烟机两通阀17与多次反射气体吸收池6之间的气路上通过两通阀3连接有真空泵4。As shown in Figure 1: a device for dynamically monitoring the concentration of smoke components in the process of cigarette smoking, which includes a smoking machine 2, a two-way valve 17 for the smoking machine, and a multi-reflection gas absorption pool connected in sequence according to the flow direction of the smoke suction 6. A filter 16, a three-way valve 13 and a cigarette holder 14 are connected to the light incident end of the multiple reflection gas absorption pool 6 with a fiber collimator 12, a laser 9, a laser current controller 8 and a laser temperature controller. A device 10, a photodetector 5 is connected to the light receiving end of the multiple reflection gas absorption cell, and the laser current controller 8 and the laser temperature controller 10 are all connected to the computer 7, and the photodetector 5 is connected to the computer 7 through data acquisition. The card 18 is connected with the computer 7, and the vacuum pump 4 is connected through the two-way valve 3 on the air path between the two-way valve 17 of the smoking machine and the multiple reflection gas absorption pool 6.

在本发明中,光纤准直器12与多次反射气体吸收池6之间通过一光纤准直器法兰固定调节座22相连接,光电探测器5与多次反射气体吸收池6之间通过一光电探测器法兰固定调节座20相连接,在光纤准直器法兰固定调节座22和光电探测器法兰固定调节座20上均对称加工有三个弧状腰型孔,以增加法兰盘安装时的转动角度。准直器端法兰固定调节座22在圆周上均布有三个腰型孔22-2,多次反射气体吸收池端面上相应的加工有三个螺纹孔,同时准直器端法兰固定调节座一端设计成斜面,此斜面用于贴合多次反射气体吸收池的一个端面。三个螺钉分别装入准直器端法兰固定调节座在圆周上三个均布的腰型孔中,同时使准直器端法兰固定调节座斜面与多次反射气体吸收池端面贴合,此时紧固三个螺钉以两个端面的连接。光线从光纤准直器中心线入射,沿着准直器端法兰固定调节座上中心孔的中心线传播。由于准直器端法兰固定调节座的贴合面是个斜面,如果此时调松准直器端法兰固定调节座上的螺钉,把准直器端法兰固定调节座旋转一定的角度,则入射光线就会在一个更小的弧度上旋转相应的角度,与此同时入射光线的入射点的位置也发生了变化。光电探测器端法兰固定调节座与准直器端法兰固定调节座除去一处不同,其他细节完全相同。不同之处是,准直器端法兰固定调节座22中间设计的尺寸孔为光孔22-1,而光电探测器端法兰固定调节座20孔为螺纹孔20-1,因为光电探测器5上有相应的外螺纹,所以螺纹孔用于连接探测器。从图4中的全剖视图c和图5中的全剖视图f可以清晰地看出结构的差异,全剖视图c中的孔为螺纹孔,全剖视图f中的孔为光孔。光电探测器端法兰固定调节座的螺纹孔可以直接和具有外螺纹的光电探测器连接,而光孔是用来穿过光纤准直器,之后由光纤准直器上的螺纹孔与光纤准直器法兰固定调节座连接。In the present invention, the optical fiber collimator 12 and the multiple reflection gas absorption cell 6 are connected through a fiber collimator flange fixing adjustment seat 22, and the photodetector 5 and the multiple reflection gas absorption cell 6 are connected by a A photodetector flange fixed adjustment seat 20 is connected, and three arc-shaped waist-shaped holes are symmetrically processed on the fiber collimator flange fixed adjustment seat 22 and the photodetector flange fixed adjustment seat 20 to increase the flange Angle of rotation during installation. There are three waist-shaped holes 22-2 evenly distributed on the circumference of the collimator end flange fixed adjustment seat 22, and three threaded holes are correspondingly processed on the end surface of the multiple reflection gas absorption cell, and the collimator end flange fixed adjustment seat One end is designed as an inclined plane, and the inclined plane is used to fit one end face of the multiple reflection gas absorption cell. The three screws are respectively installed in the three uniformly distributed waist-shaped holes on the circumference of the collimator end flange fixing adjustment seat, and at the same time, the slope of the collimator end flange fixing adjustment seat is attached to the end surface of the multiple reflection gas absorption cell , at this time tighten the three screws to connect the two end faces. The light is incident from the centerline of the fiber collimator, and propagates along the centerline of the center hole on the fixed adjustment base of the flange at the end of the collimator. Since the fitting surface of the collimator end flange fixed adjustment seat is an inclined surface, if the screw on the collimator end flange fixed adjustment seat is loosened at this time, and the collimator end flange fixed adjustment seat is rotated by a certain angle, Then the incident light will be rotated by a corresponding angle in a smaller arc, and at the same time, the position of the incident point of the incident light will also change. The flange fixed adjustment seat at the photodetector end is different from the flange fixed adjustment seat at the collimator end, and the other details are identical. The difference is that the size hole designed in the middle of the collimator end flange fixing adjustment seat 22 is the light hole 22-1, while the photodetector end flange fixing adjustment seat 20 hole is a threaded hole 20-1, because the photodetector 5 There is a corresponding external thread, so the threaded hole is used to connect the detector. From the full sectional view c in Figure 4 and the full sectional view f in Figure 5, the difference in structure can be clearly seen. The hole in the full sectional view c is a threaded hole, and the hole in the full sectional view f is a light hole. The threaded hole of the flange fixing adjustment seat at the photodetector end can be directly connected with the photodetector with external thread, and the light hole is used to pass through the fiber collimator, and then the threaded hole on the fiber collimator and the fiber collimator Straightener flange fixed adjustment seat connection.

光纤准直器12、光电探测器5分别通过相应的准直器端法兰固定调节座22、光电探测器端法兰固定调节座20与多次反射气体吸收池6集成为一体。具体结构参见图2、3、4、5。The fiber collimator 12 and the photodetector 5 are integrated with the multiple reflection gas absorption cell 6 through the corresponding collimator end flange fixing adjustment seat 22 and the photodetector end flange fixing adjustment seat 20 respectively. Refer to Figures 2, 3, 4, and 5 for specific structures.

本装置的检测过程及工作原理说明如下:The detection process and working principle of this device are described as follows:

烟气采样系统建立在商用吸烟机2的基础上。实验按照ISO要求采用限制性抽吸模式,即对每支卷烟进行逐口抽吸,每口抽吸时间为2s,抽吸体积为35mL烟气,间隔58s后进行下一口抽吸,每支卷烟固定抽吸6口。为消除点烟带来的干扰,实验中采用电子自动点烟方式。卷烟的抽吸由步进电机1驱动活塞完成。PTFE滤片可以滤除大于等于0.22um的颗粒物。剑桥滤片可以滤除大于等于0.30um DOP标准颗粒的截留率大于99.9%,它是全球香烟标准“剑桥滤片法”的专用过滤介质,方法是利用吸烟机模拟人抽烟过程,通过剑桥滤片截留卷烟抽吸过程中的颗粒物和烟碱,通过HPLC测定焦油和尼古丁含量。抽吸的烟气首先通过剑桥滤片或者聚四氟乙烯(PTFE)薄膜滤片过滤掉颗粒物,以防止污染光学系统,然后经由三通阀13进入多次反射气体吸收池6。The smoke sampling system is based on a commercial smoking machine2. The experiment adopts the restrictive smoking mode in accordance with ISO requirements, that is, each cigarette is puffed one by one, the puffing time of each puff is 2s, the puffing volume is 35mL of smoke, and the next puff is puffed after an interval of 58s. Fixed suction 6 mouthfuls. In order to eliminate the interference caused by lighting cigarettes, an electronic automatic cigarette lighting method was used in the experiment. The smoking of the cigarette is completed by the piston driven by the stepper motor 1 . The PTFE filter can filter out particles greater than or equal to 0.22um. The Cambridge filter can filter out standard particles greater than or equal to 0.30um DOP, and the retention rate is greater than 99.9%. It is a special filter medium for the global cigarette standard "Cambridge filter method". Particles and nicotine during cigarette smoking are intercepted, and tar and nicotine contents are determined by HPLC. The sucked flue gas first passes through a Cambridge filter or a polytetrafluoroethylene (PTFE) membrane filter to filter out particulate matter to prevent contamination of the optical system, and then enters the multiple reflection gas absorption cell 6 through the three-way valve 13 .

多次反射气体吸收池6同时可用于固定和开放光程气体浓度的检测。多次反射气体吸收池6可为型号为HT-3S、HT-10M、HT-15L气体吸收池或其他赫里奥特气体吸收池以及怀特池其中的一种。多次反射气体吸收池体积在50-1000mL之间。The multi-reflection gas absorption cell 6 can be used for detection of gas concentration in both fixed and open light paths. The multi-reflection gas absorption cell 6 can be a type of HT-3S, HT-10M, HT-15L gas absorption cell or one of other Heriott gas absorption cells and White cells. The volume of the multi-reflection gas absorption cell is between 50-1000mL.

激光电流控制器8和温度控制器10向激光器9提供50Hz的锯齿波扫描信号和40KHz的正弦波调制信号,激光器9输出波长在待测气体中心吸收波长附近扫描。激光光束通过多次反射气体吸收池6,经多次反射后被聚焦到光电探测器5上。光电探测器5捕捉到的微弱信号经过锁相放大器进行放大处理和二倍频谐波解调得到二次谐波吸收信号。最后经过A/D转换送至计算机7进行处理。The laser current controller 8 and the temperature controller 10 provide the laser 9 with a sawtooth wave scanning signal of 50 Hz and a sine wave modulation signal of 40 KHz, and the output wavelength of the laser 9 scans near the central absorption wavelength of the gas to be measured. The laser beam passes through the multiple reflection gas absorption cell 6 and is focused onto the photodetector 5 after multiple reflections. The weak signal captured by the photodetector 5 is amplified by a lock-in amplifier and demodulated by a double frequency harmonic to obtain a second harmonic absorption signal. Finally, it is sent to the computer 7 for processing after A/D conversion.

检测完成之后,将两通阀17关闭,两通阀3开启,三通阀13切换位置与氮气瓶连接,在真空泵4抽吸作用下完成多次反射气体吸收池6的清洗工作,为下一口烟气的检测做好准备。After the detection is completed, the two-way valve 17 is closed, the two-way valve 3 is opened, the three-way valve 13 is switched and connected to the nitrogen cylinder, and the cleaning of the multiple reflection gas absorption pool 6 is completed under the suction of the vacuum pump 4 for the next mouthful. Get ready for smoke testing.

如图2、3所示,光纤准直器通过光纤准直器法兰固定调节座连接在多次反射气体吸收池6的光线入射端,光电探测器5通过光电探测器端法兰固定调节座固定在多次反射气体吸收池6的光线出射端,这种新型设计节省调整光路的时间,同时由于光路在实验过程中固定,不易受到机械振动等因素干扰,让探测器探测到的输出光束非常稳定,不至于失去数据实时检测的准确性和可比性。As shown in Figures 2 and 3, the fiber collimator is connected to the light incident end of the multiple reflection gas absorption cell 6 through the fiber collimator flange fixing adjustment seat, and the photodetector 5 is fixed to the adjustment seat through the photodetector end flange Fixed at the light exit end of the multi-reflection gas absorption cell 6, this new design saves the time for adjusting the optical path, and at the same time, because the optical path is fixed during the experiment, it is not easily disturbed by factors such as mechanical vibration, so that the output beam detected by the detector is very Stable, so as not to lose the accuracy and comparability of real-time data detection.

当光线从光纤准直器入射时,光线就沿着图5的中心点划线传播,如果此时调节图5上的螺钉,把图5中的光纤准直器法兰固定调节座旋转一定的角度,则入射光线就会在更小的弧度上旋转相应的角度。通过改变旋转图5角度的大小,即可调节入射光线射入的角度,当然入射点的位置在调节过程中也相应的变化了。与此同时,在光线出射端,旋转图4中的光电探测器端法兰固定调节座,同样可以微调光电探测器上的方形感光面的位置和角度,进而使光电探测器感光面接收到出射光线,实现光线的接收和光电转换。When light is incident from the fiber collimator, the light propagates along the dotted line in the center of Figure 5. If the screw on Figure 5 is adjusted at this time, the fiber collimator flange fixing adjustment seat in Figure 5 is rotated by a certain amount. Angle, the incident light will be rotated by the corresponding angle in a smaller arc. By changing the angle of rotation in Figure 5, the angle of the incident light can be adjusted, and of course the position of the incident point changes accordingly during the adjustment process. At the same time, at the light exit end, rotating the photodetector end flange fixing adjustment seat in Figure 4 can also fine-tune the position and angle of the square photosensitive surface on the photodetector, so that the photosensitive surface of the photodetector receives the outgoing light. Light, to achieve light reception and photoelectric conversion.

如图6和7所示,在控制面板上设置控制器温度,从而激光器产生一定中心波长的激光光束。同时在扫描电流调节面板设置起始电流和截止电流用来实现在中心波长周围小范围的扫描。中心波长对应着待测气体的波长,扫面电流的范围按待测气体的吸收线型函数的半宽和避免其他气体的交叉干扰而定。As shown in Figures 6 and 7, set the controller temperature on the control panel so that the laser generates a laser beam with a certain center wavelength. At the same time, set the start current and cut-off current on the scan current adjustment panel to realize the scan in a small range around the center wavelength. The central wavelength corresponds to the wavelength of the gas to be measured, and the range of the sweep current is determined by the half-width of the absorption line function of the gas to be measured and the avoidance of cross-interference from other gases.

激光器由激光电流控制器和激光温度控制器控制。激光温度控制器在设定所需要的温度后,激光器产生特定波长的激光光束。激光电流控制器产生数十Hz的锯齿波信号,锯齿波信号控制一个慢的扫描电流,完成对特定中心波长待测气体吸收峰的扫描。扫描的范围由控制界面设置不同的起始电流和终止电流来进行控制。调制信号发生器产生数十kHz正弦波信号进行调制。调制信号驱动激光器产生相应的光束,在多次反射气体吸收池内经多次反射后从出光孔出射,进而被光电探测器接收。光电探测器把光信号转化为电信号,电信号送入数据采集卡,信号经过锁相放大器进行放大、二倍频解调处理、前置放大器放大和数模转化后进入计算机进行数据处理并显示。之后经过浓度标定后即可获得气体浓度。The laser is controlled by a laser current controller and a laser temperature controller. After the laser temperature controller sets the required temperature, the laser generates a laser beam with a specific wavelength. The laser current controller generates a sawtooth wave signal of tens of Hz, and the sawtooth wave signal controls a slow scanning current to complete the scanning of the absorption peak of the gas to be measured at a specific central wavelength. The scanning range is controlled by setting different starting current and ending current on the control interface. Modulation signal generator generates tens of kHz sine wave signal for modulation. The modulation signal drives the laser to generate a corresponding beam, which is reflected multiple times in the multiple reflection gas absorption cell and then emerges from the light exit hole, and then is received by the photodetector. The photoelectric detector converts the optical signal into an electrical signal, and the electrical signal is sent to the data acquisition card. The signal is amplified by the lock-in amplifier, demodulated by double frequency, amplified by the preamplifier and digital-to-analog converted, and then enters the computer for data processing and display. . After the concentration calibration, the gas concentration can be obtained.

整个监测的效果图如图8,图9所示。图8为卷烟抽吸过程中烟气组分浓度的动态检测曲线,反映在卷烟抽吸过程中烟气组分浓度的动态变化趋势。图9 是卷烟抽吸过程中烟气组分浓度的动态检测曲线的差分曲线,反应气体组分浓度的变化速率。本发明装置操作简便,检测步骤简单,能实现气体准确地动态监测,监测的结果对深入探索烟支燃烧热解机理具有重要意义,同时检测卷烟烟气中有害气体能较好地评估烟气毒性。The effect diagram of the whole monitoring is shown in Fig. 8 and Fig. 9. Fig. 8 is a dynamic detection curve of the smoke component concentration during cigarette smoking, reflecting the dynamic change trend of the smoke component concentration during cigarette smoking. Figure 9 is the difference curve of the dynamic detection curve of the smoke component concentration during cigarette smoking, which reflects the change rate of the gas component concentration. The device of the invention is easy to operate, has simple detection steps, and can realize accurate dynamic monitoring of gas. The monitoring results are of great significance for in-depth exploration of the combustion pyrolysis mechanism of cigarettes. At the same time, the detection of harmful gases in cigarette smoke can better evaluate the toxicity of smoke .

Claims (8)

1. The utility model provides a device of smoke component concentration in dynamic monitoring cigarette smoking process which characterized in that: the smoke sucking machine comprises a smoke sucking machine, a two-way valve of the smoke sucking machine, a multi-reflection gas absorption pool, a filter disc, a three-way valve and a cigarette holder which are sequentially communicated according to the smoke sucking flow direction, wherein a light incidence end of the multi-reflection gas absorption pool is connected with an optical fiber collimator, a laser current controller and a laser temperature controller, a light receiving end of the multi-reflection gas absorption pool is connected with a photoelectric detector, the laser current controller and the laser temperature controller are connected with a computer, the photoelectric detector is connected with the computer through a data acquisition card, and a vacuum pump is connected on a gas path between the two-way valve of the smoke sucking machine and the multi-reflection gas absorption pool through the two-way valve;
the optical fiber collimator is connected with the multi-reflection gas absorption pool through a collimator end flange fixing and adjusting seat, three waist-shaped holes are uniformly distributed in the circumferential direction of the collimator end flange fixing and adjusting seat, and three threaded holes are correspondingly processed on the end face of the multi-reflection gas absorption pool; meanwhile, one end face of the collimator end flange fixed adjusting seat is designed into an inclined plane, and the inclined plane is used for being attached to one end face of the multi-reflection gas absorption cell; three screws are respectively arranged in three uniformly distributed kidney-shaped holes on the circumference of the collimator end flange fixing and adjusting seat, and meanwhile, the inclined plane of the collimator end flange fixing and adjusting seat is attached to the end face of the multi-reflection gas absorption tank and is connected with the end face of the multi-reflection gas absorption tank through the three screws; when light rays are incident from the central line of the optical fiber collimator and are transmitted along the central line of the central hole in the collimator end flange fixing adjusting seat, because the binding surface of the collimator end flange fixing adjusting seat is an inclined surface, if the screw on the collimator end flange fixing adjusting seat is loosened, and the collimator end flange fixing adjusting seat is rotated for a certain angle, the incident light rays can rotate for a corresponding angle on a smaller radian, and meanwhile, the position of the incident point of the incident light rays is also changed;
the photoelectric detector is connected with the multi-reflection gas absorption pool through a detector end flange fixing and adjusting seat, three waist-shaped holes are uniformly distributed in the circumferential direction of the detector end flange fixing and adjusting seat, and three threaded holes are correspondingly processed on the end face of the multi-reflection gas absorption pool; meanwhile, one end face of the detector end flange fixed adjusting seat is designed into an inclined plane, and the inclined plane is used for being attached to one end face of the multiple reflection gas absorption cell; three screws are respectively arranged in three uniformly distributed waist-shaped holes on the circumference of the detector end flange fixing and adjusting seat, and meanwhile, the inclined plane of the detector end flange fixing and adjusting seat is attached to the end face of the multi-reflection gas absorption cell and is connected with the end face of the multi-reflection gas absorption cell through the three screws; when light rays are emitted from the absorption cell, the light rays are transmitted along the central line of the central hole in the fixed adjusting seat of the end flange of the detector, and because the binding surface of the fixed adjusting seat of the end flange of the detector is an inclined surface, if the screw on the fixed adjusting seat of the end flange of the detector is loosened, the fixed adjusting seat of the end flange of the detector is rotated for a certain angle, the emitted light rays can rotate for a corresponding angle on a smaller radian, and meanwhile, the position of an emergent point of the emitted light rays is also changed.
2. The device for dynamically monitoring the concentration of smoke constituents in the smoking process of a cigarette according to claim 1, wherein: the multi-reflection gas absorption cell is one of a white cell and a Herriott gas absorption cell, and the volume of the multi-reflection gas absorption cell is 50-1000 mL.
3. The device for dynamically monitoring the concentration of smoke constituents in the smoking process of a cigarette according to claim 1, wherein: the smoking machine is a linear smoking machine or a rotating disc type smoking machine, and can be a single channel or a multi-channel smoking machine.
4. The device for dynamically monitoring the concentration of smoke constituents in the smoking process of a cigarette according to claim 1, wherein: the filter disc is a Polytetrafluoroethylene (PTFE) film filter disc or a Cambridge filter disc.
5. The device for dynamically monitoring the concentration of smoke components in the smoking process of a cigarette according to claim 1 or 3, wherein: the power source of the smoking machine is a stepping motor.
6. The device for dynamically monitoring the concentration of smoke constituents in the smoking process of a cigarette according to claim 1, wherein: the central hole of the fixed adjusting seat of the end flange of the detector is a threaded hole which is convenient to be connected with the external thread on the photoelectric detector.
7. The device for dynamically monitoring the concentration of smoke constituents in the smoking process of a cigarette according to claim 1, wherein: the optical fiber collimator and the photoelectric detector are integrated with the multi-reflection gas absorption cell through a corresponding collimator end flange fixed adjusting seat and a corresponding photoelectric detector end flange fixed adjusting seat.
8. The device for dynamically monitoring the concentration of smoke constituents in the smoking process of a cigarette according to claim 1, wherein: a phase-locked amplifier and an A/D converter are arranged in the data acquisition card; and a second harmonic absorption signal obtained by signal amplification and double-frequency harmonic demodulation is transmitted to a computer after analog-to-digital conversion so as to complete processing and display.
CN201610998074.8A 2016-11-14 2016-11-14 Device for dynamically monitoring smoke component concentration in cigarette smoking process Active CN106404694B (en)

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