CN204422414U - A kind of ultra-high sensitive gas absorption spectra measuring system based on MEMS - Google Patents
A kind of ultra-high sensitive gas absorption spectra measuring system based on MEMS Download PDFInfo
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- CN204422414U CN204422414U CN201520106415.7U CN201520106415U CN204422414U CN 204422414 U CN204422414 U CN 204422414U CN 201520106415 U CN201520106415 U CN 201520106415U CN 204422414 U CN204422414 U CN 204422414U
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Abstract
The utility model provides a kind of ultra-high sensitive gas absorption spectra measuring system based on MEMS, comprise pump laser, beam modulation device, optical path pool, reflect focalization device, MEMS micro-cantilever, detecting laser, Position-Sensitive Detector, lock-in amplifier and central processing unit, described optical path pool is for holding tested gaseous sample, described MEMS micro-cantilever is made up of pedestal and the double-decker be fixed on pedestal, the metal material layer that described double-decker comprises black silicon material layer and is formed on black silicon material layer.The utility model adopts MEMS technology to greatly improve measurement sensistivity, extends spectral measurement ranges, simultaneously to neighbourhood noise and vibration insensitive, and significantly reduce the volume and weight of measuring system, make that measuring system is portable or hand-held becomes possibility.
Description
Technical field
The utility model relates to gas absorption spectra field of measuring technique, specifically a kind of ultra-high sensitive gas absorption spectra measuring system based on MEMS.
Background technology
Along with economic development, a large amount of flue gases that traffic on the one hand, industry produce enter in air, make atmospheric pollution day by day serious, the harmful gas such as gas, formaldehyde is flooded with the various aspects of people's life on the other hand, moment endangers the life and health of people, is therefore even more important to the analysis to measure of harmful gas.
At present, the major technique of analysis to measure gas has: thermal conductivity method, electrochemical process, vapor-phase chromatography and infrared absorption.
Thermal conductivity method has the principle of different thermal conduction capability according to gas with various, calculates the content of wherein some component by measuring mixed gas coefficient of heat conductivity.Thermal conductivity method range of application is comparatively wide, can be used for analyzing hydrogen, ammonia, carbon dioxide, sulphuric dioxide and low concentration inflammable gas etc.But thermal conductivity method is very responsive to the pressure surge of gas, flow rate fluctuation, in medium, the impurity such as steam, particle is comparatively large on measurement result impact, so must install complicated sampling.
Change or the curent change of the ionic weight of electrochemical process caused by chemical reaction carry out measurement gas composition, have that volume is little, detection speed is fast, portable, can the advantage such as Site Detection and continuous detecting.But electrochemical process use cost is comparatively large, in reality detects, also can there is the problems such as sample flow, gas cross interference and pre-service.
Vapor-phase chromatography is injected in chromatographic column by a certain amount of analyte gas, and the various different components analyzed in thing at the end of arrival of different time post, thus will be separated because molecule type is different.Detecting device is by detecting the outflow stream of chromatographic column thus determining the content of each component.Vapor-phase chromatography separation efficiency is high, highly sensitive, applied range, but when directly carrying out qualitative analysis to component, must contrast with known substance or given data and corresponding chromatographic peak, or with other method (as mass spectrum, spectrum) coupling, the result of directly affirmative could be obtained, when quantitative test, the pure sample product of Chang Yaoyong known substance correct detecting the rear signal exported.
Infrared absorption has the characteristic of selective absorbing according to the infrared ray of different component gas to different wave length and carries out analysis to measure.Measure the kind that this absorption spectrum can determine gas; Measure the concentration that absorption intensity can determine tested gas.The usable range of infrared absorption is wide, not only can analytical gas composition, also can analytical solution composition, and sensitivity is higher, be swift in response, can on-line continuous indicate, also can form regulating system, therefore the method is all one of most important developing direction of gas analysis detection technique all the time.
According to this principle, it is the high sensitivity absorption measurement techniques of representative that people have established with optoacoustic spectroscopy.It is on the sample be sealed in photoacoustic cell with the monochromatic light exposure of a beam intensity periodic modulation that optoacoustic spectroscopy detects, absorption of sample luminous energy, and to discharge the mode de excitation of heat energy, the heat energy of release makes sample and surrounding medium produce periodic heat, medium is caused to produce periodic pressure fluctuation, this pressure surge can detect with sensitive microphone or piezoelectric ceramic microphone, optoacoustic effect that Here it is.The optoacoustic spectroscopy become with wavelength then can be measured by changing lambda1-wavelength.But optoacoustic spectroscopy is subject to the impact of ambient noise and vibration and is limited to the application of various complex environment.
Utility model content
The purpose of this utility model is to provide a kind of ultra-high sensitive gas absorption spectra measuring system based on MEMS, the environmental monitoring fields such as the gaseous contamination of indoor and outdoor can be widely used in, there is the advantages such as high sensitivity, wide spectral, antinoise, volume be little, lightweight.
The technical solution of the utility model is:
A kind of ultra-high sensitive gas absorption spectra measuring system based on MEMS, this system comprises pump laser, beam modulation device, optical path pool, reflect focalization device, MEMS micro-cantilever, detecting laser, Position-Sensitive Detector, lock-in amplifier and central processing unit, described optical path pool is for holding tested gaseous sample, described MEMS micro-cantilever is made up of pedestal and the double-decker be fixed on pedestal, the metal material layer that described double-decker comprises black silicon material layer and is formed on black silicon material layer, the output terminal of described pump laser is connected with the light inlet light path of optical path pool by beam modulation device, the light-emitting window of described optical path pool is connected with the black silicon material layer light path of MEMS micro-cantilever by reflect focalization device, the output terminal of described detecting laser is connected with the metal material layer light path of MEMS micro-cantilever, described Position-Sensitive Detector is arranged on the reflected light path of metal material layer, described beam modulation device is connected with the input end of lock-in amplifier with the output terminal of Position-Sensitive Detector, the output terminal of described lock-in amplifier is connected with the input end of central processing unit.
The described ultra-high sensitive gas absorption spectra measuring system based on MEMS, this system also comprises light-beam forming unit, and described light-beam forming unit is arranged in the light path between pump laser and beam modulation device.
The described ultra-high sensitive gas absorption spectra measuring system based on MEMS, this system also comprises advance signal pretreatment unit, and its input end is connected with the output terminal of Position-Sensitive Detector, and its output terminal is connected with the input end of lock-in amplifier; Described advance signal pretreatment unit comprises prime amplifier and wave filter.
The described ultra-high sensitive gas absorption spectra measuring system based on MEMS, this system also comprises pump laser control device, and the described output terminal of pump laser control device is connected with the input end of pump laser.
The described ultra-high sensitive gas absorption spectra measuring system based on MEMS, described pump laser selects tunable laser or super continuous wave laser.
The described ultra-high sensitive gas absorption spectra measuring system based on MEMS, is provided with the first catoptron and the second catoptron in described optical path pool.
The described ultra-high sensitive gas absorption spectra measuring system based on MEMS, described reflect focalization device is made up of the first concave mirror and the second concave mirror.
The described ultra-high sensitive gas absorption spectra measuring system based on MEMS, described black silicon material layer is made up of several micro-cone structural arrangement.
The utility model adopts MEMS technology to greatly improve measurement sensistivity, extends spectral measurement ranges, simultaneously to neighbourhood noise and vibration insensitive, and significantly reduce the volume and weight of measuring system, make that measuring system is portable or hand-held becomes possibility:
(1) the utility model adopts tunable laser or super continuous wave laser as pump laser, can measure continuous print absorption spectrum in certain broad spectral range.
(2) the utility model adopts optical path pool as tested gas sample cell, when ensureing system bulk miniaturization, substantially increasing effective light path of gas absorption, improve the measurement sensistivity of system.
(3) the utility model adopts the MEMS micro cantilever structure prepared based on MEMS technology as the photothermal deformation core devices of light absorption, avoid the problem needing the photodetector changing corresponding spectral response when changing pump laser wavelength on the one hand, on the other hand reduce system bulk, such that instrument is portable or hand-held becomes possibility.
(4) the utility model adopts black silicon material as the optical-thermal conversion material of MEMS micro-cantilever, achieve on the one hand to wide spectral without Selective absorber, meet the conformance requirement that wide range is measured, the reflectivity that black silicon material is extremely low on the other hand, improve photothermal deformation coefficient, enlarge markedly at the vibration amplitude of equal pump energy Analysis of A Cantilever Beam Under structure, improve the detection sensitivity of system.
(5) the utility model adopts lock-in amplifier to carry out input, the resonance of MEMS micro cantilever structure generation is had to the function of narrow-band filtering, to the vibration of surrounding environment and optical noise insensitive, make instrument have very strong antijamming capability when indoor or outdoor application.
Accompanying drawing explanation
Fig. 1 is system principle diagram of the present utility model;
Fig. 2 is system architecture schematic diagram of the present utility model;
Fig. 3 is the structural representation of optical path pool of the present utility model;
Fig. 4 is the structural representation of MEMS micro-cantilever of the present utility model;
Fig. 5 is the measuring principle figure of MEMS micro-cantilever of the present utility model;
Fig. 6 is interchange photo-signal measuring principle figure of the present utility model;
Fig. 7 is Photothermal Signals of the present utility model and absorption signal measuring principle figure.
Embodiment
The utility model is further illustrated below in conjunction with the drawings and specific embodiments.
As shown in Figure 1, based on a ultra-high sensitive gas absorption spectra measuring system of MEMS, comprise pump laser 1, light-beam forming unit 2, beam modulation device 3, optical path pool 4, first concave mirror 5, second concave mirror 6, MEMS micro-cantilever 7, detecting laser 8, Position-Sensitive Detector 9, advance signal pretreatment unit 10, lock-in amplifier 11, central processing unit 12 and pump laser control device 13.Optical path pool 4, for holding tested gaseous sample, which is provided with light inlet 43, light-emitting window 44, air admission hole 45 and venthole 46, as shown in Figure 3.MEMS micro-cantilever 7 is made up of pedestal 73 and the double-decker be fixed on pedestal 73, and this double-decker comprises black silicon material layer 71 and is formed at the metal material layer 72 on black silicon material layer 71, as shown in Figure 4.
The output terminal of pump laser control device 13 is connected with the input end of pump laser 1, and the output terminal of pump laser 1 is connected with light inlet 43 light path of optical path pool 4 with beam modulation device 3 by light-beam forming unit 2 successively.The light-emitting window 44 of optical path pool 4 is connected with black silicon material layer 71 light path of MEMS micro-cantilever 7 with the second concave mirror 6 by the first concave mirror 5.The output terminal of detecting laser 8 is connected with metal material layer 72 light path of MEMS micro-cantilever 7.Position-Sensitive Detector 9 is arranged on the reflected light path of metal material layer 72, and its output terminal is connected with the input end of advance signal pretreatment unit 10.The output terminal of advance signal pretreatment unit 10 is connected with the input end of lock-in amplifier 11, and the output terminal of beam modulation device 3 is connected with the input end of lock-in amplifier 11, and the output terminal of lock-in amplifier 11 is connected with the input end of central processing unit 12.
As shown in Figure 2, in actual applications, advance signal pretreatment unit 10, lock-in amplifier 11 and central processing unit 12 can be integrated on main control chip 17, and light-beam forming unit 2, beam modulation device 3, optical path pool 4, first concave mirror 5, second concave mirror 6, MEMS micro-cantilever 7, detecting laser 8, Position-Sensitive Detector 9 and main control chip 17 form portable surveying instrument 0.The pumping laser bundle that pump laser 1 sends is coupled in optical fiber 14, be input in portable surveying instrument 0 by optic fibre switching head 15, then enter light-beam forming unit 2 and beam modulation device 3 successively by fiber output head 16, the pumping laser bundle after modulating via beam modulation device 3 enters optical path pool 4 by light inlet 43.
The pumping laser bundle reflected from optical path pool 4, after the first concave mirror 5 and the second concave mirror 6, focuses on the black silicon material layer 71 of MEMS micro-cantilever 7, produces resonance after MEMS micro-cantilever 7 absorptive pumping laser beam energy.The exploring laser light bundle that detecting laser 8 sends incides on the metal material layer 72 of MEMS micro-cantilever 7, incides on Position-Sensitive Detector 9 after reflection.The photo-signal that Position-Sensitive Detector 9 produces is input in lock-in amplifier 11 after the amplification, filtering of advance signal pretreatment unit 10, the modulation frequency signal of beam modulation device 3 is also input in lock-in amplifier 11 simultaneously, and photo-signal is demodulated into Photothermal Signals by lock-in amplifier 11.Photothermal Signals is converted to actual absorption signal by certain algorithm by central processing unit 12.
Pump laser 1 is tunable laser or super continuous wave laser etc., and its wavelength is continuously adjustabe in certain spectral range.The parameter such as wavelength, power of pump laser 1 is controlled by pump laser control device 13, thus can obtain the absorption spectrum of tested gaseous sample in a wavelength range.
As shown in Figure 3, the multiple reflections formula structure that is made up of the first catoptron 41 and the second catoptron 42 of optical path pool 4.Tested gaseous sample enters optical path pool 4 from air admission hole 45, leaves optical path pool 4 from venthole 46.Pumping laser bundle enters optical path pool 4 from light inlet 43, by exporting from light-emitting window 44 after the multiple reflections of the first catoptron 41 and the second catoptron 42, reach the object effectively increasing light path in less space, reduce the volume and weight of system on the one hand, improve detection sensitivity on the other hand.
As shown in Figure 4, MEMS micro-cantilever 7 adopts MEMS(Micro-Electro-Mechanical System, MEMS (micro electro mechanical system)) technique makes, be divided into double-decker, upper strata is black silicon material layer 71, lower floor differs larger metal material layer 72 with black silicon material thermal expansivity, is fixed on one end by pedestal 73, forms MEMS micro cantilever structure.Black silicon material layer 71 is prepared mainly through femtosecond laser scanning method, chemical corrosion method, plasma processing method, forms multiple micro-cone structure on surface.Different according to technological level, from several microns to tens microns not etc., cone diameter is not from hundreds of nanometer to several microns etc. for cone height.The black silicon material layer 71 of this structure has extremely low reflectivity, improves photothermal deformation coefficient, and under equal pump energy, the vibration amplitude of MEMS micro cantilever structure enlarges markedly, and improves the detection sensitivity of system.In addition, black silicon material layer 71 has almost consistent absorptivity near ultraviolet to infrared band, has without Selective absorber characteristic to the wavelength of pump laser 1, can meet wide range and measure conforming requirement.Plate very thin, the ganoid metal material layer 72 of a layer thickness at black silicon material layer 71 back side, namely obtain the MEMS micro-cantilever 7 of ultrathin bendable.
The measuring principle of MEMS micro-cantilever 7 is as follows:
After on the black silicon material layer 71 that pumping laser bundle after tested gaseous sample in optical path pool 4 absorbs focuses on MEMS micro-cantilever 7, elastic hot occurs to expand, the thermal expansivity due to black silicon material layer 71 and metal material layer 72 is obviously different and produce resonance.The light intensity of Oscillation Amplitude after absorbing through gaseous sample tested in optical path pool 4 becomes monotonic relationshi.In optical path pool 4, the absorption of tested gaseous sample is larger, and the light intensity incided on MEMS micro-cantilever 7 is less, and the Oscillation Amplitude of MEMS micro-cantilever 7 is less; Otherwise the absorption of tested gaseous sample is less in optical path pool 4, the light intensity incided on MEMS micro-cantilever 7 is larger, and the Oscillation Amplitude of MEMS micro-cantilever 7 is larger.
As shown in Figure 5, in metal material layer 72 side of MEMS micro-cantilever 7, the exploring laser light bundle that detecting laser 8 sends incides on metal material layer 72, due to the resonance of MEMS micro-cantilever 7, reflected light has different reflection angle, different photocurrents can be produced by Position-Sensitive Detector 9, thus produce the photo-signal exchanging change.
For tested gaseous sample same in optical path pool 4, have different absorptions at different wavelength, thus Position-Sensitive Detector 9 can produce the interchange photo-signal of various amplitude.As shown in Figure 6, tested gaseous sample absorbs less at wavelength X 1 place, so the pump laser intensity incided on MEMS micro-cantilever 7 is comparatively large, the resonance amplitude that MEMS micro-cantilever 7 produces is comparatively large, thus it is larger to exchange photo-signal amplitude.Otherwise tested gaseous sample absorbs comparatively large at wavelength X 2 place, then the interchange photo-signal amplitude produced is less.
Exchange photo-signal after the enlarge leadingly of main control chip 17, filtering and lock-in amplify, interchange photo-signal is demodulated into Photothermal Signals.Photothermal Signals is direct current signal, proportional with the amplitude exchanging photo-signal.As shown in Figure 7, tested gaseous sample absorbs less at wavelength X 1 place, thus it is comparatively large to exchange photo-signal amplitude, and namely Photothermal Signals is larger.Otherwise tested gaseous sample absorbs comparatively large at wavelength X 2 place, thus the interchange photo-signal amplitude produced is less, and namely Photothermal Signals is less.Finally, Photothermal Signals inverting is the absorption signal of reality by certain algorithm by the central processing unit 12 in main control chip 17.
The above embodiment is only be described preferred implementation of the present utility model; not scope of the present utility model is limited; under the prerequisite not departing from the utility model design spirit; the various distortion that those of ordinary skill in the art make the technical solution of the utility model and improvement, all should fall in protection domain that claims of the present utility model determine.
Claims (8)
1. the ultra-high sensitive gas absorption spectra measuring system based on MEMS, it is characterized in that: this system comprises pump laser, beam modulation device, optical path pool, reflect focalization device, MEMS micro-cantilever, detecting laser, Position-Sensitive Detector, lock-in amplifier and central processing unit, described optical path pool is for holding tested gaseous sample, described MEMS micro-cantilever is made up of pedestal and the double-decker be fixed on pedestal, the metal material layer that described double-decker comprises black silicon material layer and is formed on black silicon material layer;
The output terminal of described pump laser is connected with the light inlet light path of optical path pool by beam modulation device, the light-emitting window of described optical path pool is connected with the black silicon material layer light path of MEMS micro-cantilever by reflect focalization device, the output terminal of described detecting laser is connected with the metal material layer light path of MEMS micro-cantilever, described Position-Sensitive Detector is arranged on the reflected light path of metal material layer, described beam modulation device is connected with the input end of lock-in amplifier with the output terminal of Position-Sensitive Detector, the output terminal of described lock-in amplifier is connected with the input end of central processing unit.
2. the ultra-high sensitive gas absorption spectra measuring system based on MEMS according to claim 1, it is characterized in that: this system also comprises light-beam forming unit, described light-beam forming unit is arranged in the light path between pump laser and beam modulation device.
3. the ultra-high sensitive gas absorption spectra measuring system based on MEMS according to claim 1, it is characterized in that: this system also comprises advance signal pretreatment unit, its input end is connected with the output terminal of Position-Sensitive Detector, and its output terminal is connected with the input end of lock-in amplifier; Described advance signal pretreatment unit comprises prime amplifier and wave filter.
4. the ultra-high sensitive gas absorption spectra measuring system based on MEMS according to claim 1, it is characterized in that: this system also comprises pump laser control device, the described output terminal of pump laser control device is connected with the input end of pump laser.
5. the ultra-high sensitive gas absorption spectra measuring system based on MEMS according to claim 1, is characterized in that: described pump laser selects tunable laser or super continuous wave laser.
6. the ultra-high sensitive gas absorption spectra measuring system based on MEMS according to claim 1, is characterized in that: be provided with the first catoptron and the second catoptron in described optical path pool.
7. the ultra-high sensitive gas absorption spectra measuring system based on MEMS according to claim 1, is characterized in that: described reflect focalization device is made up of the first concave mirror and the second concave mirror.
8. the ultra-high sensitive gas absorption spectra measuring system based on MEMS according to claim 1, is characterized in that: described black silicon material layer is made up of several micro-cone structural arrangement.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104655587A (en) * | 2015-02-14 | 2015-05-27 | 合肥知常光电科技有限公司 | Extra-high sensitive gas absorption spectrum measuring system and method based on MEMS |
| CN114235711A (en) * | 2022-02-24 | 2022-03-25 | 朗思传感科技(深圳)有限公司 | Miniaturized portable high-sensitivity gas measurement system |
| CN114324225A (en) * | 2021-09-08 | 2022-04-12 | 中山大学 | Micro-nano device capable of regulating spectral response and applied to gas sensing |
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2015
- 2015-02-14 CN CN201520106415.7U patent/CN204422414U/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104655587A (en) * | 2015-02-14 | 2015-05-27 | 合肥知常光电科技有限公司 | Extra-high sensitive gas absorption spectrum measuring system and method based on MEMS |
| CN114324225A (en) * | 2021-09-08 | 2022-04-12 | 中山大学 | Micro-nano device capable of regulating spectral response and applied to gas sensing |
| CN114324225B (en) * | 2021-09-08 | 2023-06-02 | 中山大学 | Micro-nano device applied to gas sensing and capable of regulating and controlling spectral response |
| CN114235711A (en) * | 2022-02-24 | 2022-03-25 | 朗思传感科技(深圳)有限公司 | Miniaturized portable high-sensitivity gas measurement system |
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