CN107505286A - Oxygen consumption amount detecting device and detection method during a kind of cigarette is burnt and sucked - Google Patents

Oxygen consumption amount detecting device and detection method during a kind of cigarette is burnt and sucked Download PDF

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Publication number
CN107505286A
CN107505286A CN201710867881.0A CN201710867881A CN107505286A CN 107505286 A CN107505286 A CN 107505286A CN 201710867881 A CN201710867881 A CN 201710867881A CN 107505286 A CN107505286 A CN 107505286A
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cigarette
gas
suction
absorption cell
triple valve
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Inventor
邓楠
邢昆明
张柯
计敏
张明建
王乐
李志刚
王金棒
王安
刘勇
李斌
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Hefei Institutes of Physical Science of CAS
Zhengzhou Tobacco Research Institute of CNTC
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Hefei Institutes of Physical Science of CAS
Zhengzhou Tobacco Research Institute of CNTC
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/39Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/39Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using tunable lasers
    • G01N2021/396Type of laser source
    • G01N2021/399Diode laser
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N2201/00Features of devices classified in G01N21/00
    • G01N2201/06Illumination; Optics
    • G01N2201/061Sources
    • G01N2201/06113Coherent sources; lasers
    • G01N2201/0612Laser diodes

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Analytical Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Optics & Photonics (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)
  • Manufacturing Of Cigar And Cigarette Tobacco (AREA)

Abstract

Oxygen consumption amount detecting device and detection method during being burnt and sucked the present invention relates to a kind of cigarette, the device include integrated gases absorption cell and connected flue gas suction trapping system, nitrogen purge system, pumped vacuum systems and photodetector system.Its method is that first system gas circuit is thoroughly purged with nitrogen, gas absorption cell is evacuated with vavuum pump again, pump unit carries out the suction of international standard pattern to cigarette afterwards, after suction terminates, the flue gas collected enters the gas absorption cell being evacuated, by photodetector system to being detected by the flue gas to be measured of absorption cell.Measurement cigarette is unignited respectively and lights the concentration of under test gas after suction, remakes difference, you can obtain the oxygen demand that cigarette burns and sucks a bite.Carry out multiple continuous sucking, you can reach that cigarette burns and sucks by mouth oxygen demand.Detected by the device and side of the present invention, simple to operate, pollution-free, strong antijamming capability, non-contact, real-time is good.

Description

Oxygen consumption amount detecting device and detection method during a kind of cigarette is burnt and sucked
Technical field
The present invention relates to the detection of combustion product gases, oxygen consumption amount detecting device and detection during specifically a kind of cigarette is burnt and sucked Method.
Background technology
In aspiration procedure, a series of physical and chemical reaction occurs cigarette for pipe tobacco, forms substantial amounts of product, there is 5000 It is a variety of.Wherein harmful components have 149 kinds, including tar, and CO, nitrosamine, aldehyde and nitro hydrocarbon etc., they there is harm to make human body With.Smoking is harmful to your health, although the theory of Tobacco Control is constantly being promoted, but still has many people smoking.In order to reduce cigarette smoking During harmful substance yield, factor caused by influenceing harmful substance during the cigarette smoking of studying becomes to closing weight Will.Harmful substance major part by the macromolecular compound imperfect combustion in tobacco and is cracked to form, cigarette caused by cigarette smoking Careless unique nitrosamine is by being that tobacco physical action produces, and such reaction is closely related with caused heat in aspiration procedure, again Due to the oxygen positive correlation consumed in reaction quantity of heat production and aspiration procedure.And oxygen consumption is more, quantity of heat production is bigger, reaction Ground is more abundant, and the number of cigarette burning oxygen demand can reflect in cigarette combustion process the size of the completeness reacted.Therefore, grind Study carefully the oxygen demand during cigarette smoking have to the extent of reaction for studying cigarette and the yield for reducing harmful substance it is important Researching value.
Mass spectrography has the advantages that high sensitivity, detection speed are fast, but if do not carried out pre-treatment to cigarette smoke, quantitative Easily disturbed during analysis by other materials ionization fragment in cigarette mainstream flue gas, be difficult to the quantitative detection of accurate realization.It is adjustable Humorous diode laser absorption spectrum(TDLAS)Technology can effectively exclude other due to the high-resolution characteristic using laser The absorption interference of material, has the advantages that strong antijamming capability, high sensitivity, fast response time and cost-effective, is that one kind exists The effective technology means of detection are realized under complicated gas condition.
The content of the invention
The purpose of the present invention is based on above-mentioned prior art situation, and burning and sucking oxygen consumption quantifier elimination for research cigarette provides A kind of cigarette burn and suck during oxygen consumption amount detecting device and detection method.
The purpose of the present invention is achieved through the following technical solutions:
Oxygen consumption amount detecting device during a kind of cigarette is burnt and sucked, including integrated gases absorption cell and with the integrated gases inhale Flue gas suction trapping system, nitrogen purge system, pumped vacuum systems and the photodetector system that receives pond is connected.
The flue gas suction trapping system includes passing through the cigarette holder of pipeline connection, triple valve b, filter disc, cigarette successively Gas pump unit, servomotor, pass through two-way valve a and integrated gases absorption cell on the pipeline between filter disc and pump unit Gas approach connection;
The nitrogen purge system includes nitrogen cylinder, pressure-reducing valve, and is clamped by the cigarette in triple valve a and feeding flue gas gathering system Device, triple valve b connections;
The pumped vacuum systems includes vavuum pump, and is gone out by triple valve c, two-way valve b and integrated gases absorption cell flue gas Mouth connection;
The photodetector system includes laser, laser controller, temperature controller, data acquisition unit and computer, swashs Light device is connected by laser aligner with the light incidence end of integrated gases absorption cell, and data acquisition unit passes through photodetector Be connected with the beam projecting end of integrated gases absorption cell, the laser controller, temperature controller, data acquisition unit with Computer connects, and carries out respective handling by computer software control.
In apparatus of the present invention, the piping volume between the triple valve a and triple valve b is more than 100mL.
The method of oxygen demand is as follows during being burnt and sucked using said apparatus detection cigarette:The nitrogen pair in nitrogen cylinder is used first System gas circuit is thoroughly purged, and then gas absorption cell is evacuated with vavuum pump, and pump unit is carried out to cigarette afterwards The suction of international standard pattern, after suction terminates, the flue gas collected is inhaled into the gas absorption cell being evacuated;It is same with this When, temperature controller, laser controller enter trip temperature and electric current tuning to laser, the scanned oxygen of the laser beam after tuning Absorption line, enter absorption cell by laser aligner, absorbed by under test gas, by photodetector after multiple reflections Receive, gathered and stored by data acquisition unit, finally handled through computer, the absorption signal of under test gas is by demarcation Obtain the concentration of under test gas.Detection cigarette is unignited respectively and lights the concentration of under test gas after suction, and two concentration are subtracted each other Can obtain the oxygen demand that cigarette burns and sucks a bite, carry out continuous sucking, you can obtain that cigarette burns and sucks by mouth oxygen demand.
Comprise the following steps that:
1. triple valve a, triple valve b, two-way valve a, two-way valve b, triple valve c electric must be interconnected simultaneously, afterwards in nitrogen cylinder Nitrogen carries out 10s cleanings to whole conducting pipeline, makes to be full of nitrogen in pipeline;
2. triple valve a cuts out system pipeline, it is set to connect air;Two-way valve a is closed;Two-way valve b is stayed open;
Triple valve c switching states make it connect vavuum pump after 3.1s, vacuum pumping 9s, gas absorption cell is evacuated shape State;
4. two-way valve b is closed;Triple valve c cuts out system pipeline after 1s, it is connected air, and triple valve b connection pump units are taken out Unit suction 2s is inhaled, completes 35ml suction;
5. switching three-way valve b, makes it connect triple valve a, the 35mL flue gases of suction enter subsequent pipeline, are stored in triple valve a Between pump unit.Two-way valve a is opened after 3s, and the under test gas in pipeline is inhaled into the integrated gases being evacuated and inhaled Receives pond, the detection of oxygen content is carried out, detection time 32s, enters next circulation after waiting 2s.
The foundation of the detection method is dexterously to be pressed by the rule that oxygen content under the conditions of constant temperature and pressure constant humidity is constant Aspirated according to international standard suction mode, detect first cigarette it is unignited before suction a bite when oxygen concentration, then detect volume The remaining concentration of oxygen after every mouth when cigarette is burnt and sucked, the difference of two concentration are the oxygen demand during every mouthful of cigarette is burnt and sucked.
In particular, described photodetector system is provided the saw of low frequency by laser controller and temperature controller respectively The sinewave modulation signal of tooth ripple modulated signal and high frequency, laser are modulated.Laser beam after modulation is through integrated gases Gas is absorbed with after opto-electronic conversion in absorption cell, and the upper computer software that computer is sent into after the demodulation of the frequency multiplication of data acquisition unit two enters Row processing, obtains the absorbed second harmonic strength signal of under test gas.The peak signal of second harmonic is demarcated through calibrating gas Afterwards, the concentration of under test gas is obtained.
The specification of pipeline in described flue gas suction trapping system between triple valve a and triple valve b needs to meet necessarily Requirement, the volume of pipeline is 50-500mL.Because cigarette is after the pump unit suction driven by servomotor, flue gas quilt Discharge into gas pipeline.Because flue gas can not be by air pollution, therefore pipeline need to be full of nitrogen, make the flue gas of suction in nitrogen atmosphere In.Flue gas can not introduce foreign gas during being sucked into the integrated gases absorption cell of vacuum pumping simultaneously.To sum up, pipeline The volume of middle nitrogen should be more than the volume and cigarette holder to integrated gases absorption cell front end of integrated gases absorption cell Between conduit volume sum.
The advantage of the invention is that:Detection means design advantages of simple, plant running are reliable and stable, cost-effective, use Convenient, easy to maintain;Detection method is simple to operate, pollution-free, strong antijamming capability, it is non-contact, without destructiveness, response speed It hurry up, accuracy of detection is high, and sensitivity is higher, and real-time is good.
Brief description of the drawings
Fig. 1 is structure of the detecting device schematic diagram of the present invention.
In figure:1. nitrogen cylinder, 2. pressure-reducing valves, 3. cigarette holders, 4. triple valve a, 5. triple valve b, 6. two-way valve a, 7. Filter disc, 8. data acquisition units, 9. pump units, 10. computers, 11. servomotors, 12. lasers, 13. temperature controllers, 14. laser controller, 15. integrated gases absorption cells, 16. two-way valve b, 17. triple valve c, 18. vavuum pumps, 19. cigarette.
Fig. 2 is integrated gases absorption cell theory of constitution figure,
In figure:15-1. laser aligners, 15-2. gas absorption cell pond bodies, 15-3. photodetectors.
Fig. 3 is cigarette by mouth oxygen demand testing result figure.
Embodiment
Embodiments of the present invention is further illustrated below in conjunction with the accompanying drawings.
As shown in Figure 1, 2:Oxygen consumption amount detecting device during a kind of cigarette is burnt and sucked, it is characterised in that:Including integrated form gas Body absorption cell and the flue gas suction trapping system, the nitrogen purge system that are connected with the integrated gases absorption cell, vacuumize System and photodetector system.
The flue gas suction trapping system is included by the cigarette holder [3] of pipeline connection, triple valve b [5], filter successively Piece [7], flue gas pump unit [9], servomotor [11] are logical by two on the pipeline between filter disc [7] and pump unit [9] Valve a [6] connects with the gas approach of integrated gases absorption cell [15];
The nitrogen purge system includes nitrogen cylinder [1], pressure-reducing valve [2], and by triple valve a [4] and feeding flue gas gathering system Cigarette holder [3], triple valve b [5] connection;
The pumped vacuum systems includes vavuum pump [18], and is inhaled by triple valve c [17], two-way valve b [16] and integrated gases The exhanst gas outlet connection of receives pond [15];
The photodetector system includes laser [12], laser controller [14], temperature controller [13], data acquisition unit [8] and computer [10], laser [12] pass through laser aligner [15-1] and the light of integrated gases absorption cell [15] Incidence end connects, and data acquisition unit [8] passes through photodetector [15-3] and the beam projecting of integrated gases absorption cell [15] End is connected, and the laser controller [14], temperature controller [13], data acquisition unit [8] are connected with computer [10], and Respective handling is carried out by computer software control.
In apparatus of the present invention, the piping volume between the triple valve a [4] and triple valve b [5] is more than 100mL, so It can prevent air from entering in integrated gases absorption cell [15], influence testing result.Because cigarette [19] is by by servo electricity After pump unit [9] suction of machine [11] driving, flue gas is passed into gas pipeline.Because flue gas can not be by air pollution, therefore Pipeline need to be full of nitrogen, make the flue gas of suction in nitrogen atmosphere.Flue gas is sucked into the integrated gases suction of vacuum pumping simultaneously Foreign gas can not be introduced during receives pond.To sum up, the volume of nitrogen should be more than integrated gases absorption cell in pipeline [15] volume and cigarette holder [3] arrives conduit volume sum between integrated gases absorption cell [15] front end.
Integrated gases absorption cell [15] is by laser aligner [15-1], gas absorption cell pond body [15-2], photodetection Device [15-3] forms, as shown in Figure 2.
It is as follows using the above-mentioned method for stating oxygen demand during device detection cigarette is burnt and sucked:Described device detection cigarette is burnt and sucked During oxygen demand method, system gas circuit is thoroughly purged with the nitrogen in nitrogen cylinder [1] first, then uses vavuum pump [18] gas absorption cell is evacuated, pump unit [9] carries out the suction of international standard pattern to cigarette afterwards, and suction terminates Afterwards, the flue gas collected is inhaled into the gas absorption cell [15] being evacuated;At the same time, laser controller [14] is to laser Device [12] enters trip temperature and electric current tuning, the absorption line of the scanned oxygen of the laser beam after tuning, by optical fiber collimator Into absorption cell, absorbed, received after multiple reflections by photodetector [15-5], by data acquisition unit by under test gas [8] collection storage, is finally handled through computer [10], and the absorption signal of under test gas can obtain gas to be measured by demarcation The concentration of body.Detection cigarette is unignited respectively and lights the concentration of under test gas after suction, and two concentration, which are subtracted each other, can be rolled up Cigarette burns and sucks the oxygen demand of a bite, carries out continuous sucking, you can obtain that cigarette burns and sucks by mouth oxygen demand.Progress is repeatedly continuously taken out Inhale, you can reach that cigarette burns and sucks by mouth oxygen demand.
Comprise the following steps that:
(1)Triple valve a [4], triple valve b [5], two-way valve a [6], two-way valve b [16], triple valve c [17] at the same it is electric mutually be connected Logical, the nitrogen in nitrogen cylinder [1] carries out 10s cleanings to whole conducting pipeline afterwards, makes to be full of nitrogen in pipeline;
(2)Triple valve a [4] cuts out system pipeline, it is connected air;Two-way valve a [6] is closed;Two-way valve
B [16] is stayed open;
(3)Triple valve c [17] switching state makes it connect vavuum pump after 1s, vacuum pumping 9s, is pumped into gas absorption cell Vacuum state;
(4)Two-way valve b [16] is closed;Triple valve c [17] cuts out system pipeline after 1s, it is connected air, triple valve b [5] is even Pump unit [9] pump unit suction 2s is met, completes 35ml suction;
(5) switching three-way valve b [5], make it connect triple valve a [4], and the 35mL flue gases of suction enter subsequent pipeline, are stored in Between triple valve a [4] and pump unit [9].Two-way valve a [6] is opened after 3s, and the under test gas in pipeline, which is inhaled into, has been pumped into very Empty integrated gases absorption cell [15], the detection of oxygen content is carried out, detection time 32s, enters next follow after waiting 2 Ring.
Because the component in the gas permeability and main flume of cigarette first forms the thermal source that lit a cigarette (match, butane sparking Mechanical, electrical resistance heating unit etc.) form, thermal source flame color(Colourless, yellow, blueness), cigar lighter lights a cigarette away from fire end distance The factors such as whole story time are had a great influence, therefore the detection data of first are excluded from experimental result, from second mouthful of testing number Rule according to the cigarette mainstream flue gas transfer components that begin one's study is more reasonable.
Detection method is detected under above-mentioned condition first by the rule that oxygen content under the conditions of constant temperature and pressure constant humidity is constant The concentration of atmospheric oxygen, then detect the remaining concentration of oxygen during every mouthful of cigarette is burnt and sucked, it is only necessary to do difference can Obtain the oxygen demand during every mouthful of cigarette is burnt and sucked, wherein n values 2,3,4,5,6,7.

Claims (5)

  1. A kind of 1. oxygen consumption amount detecting device during cigarette is burnt and sucked, it is characterised in that:Including integrated gases absorption cell and with Flue gas suction trapping system, nitrogen purge system, pumped vacuum systems and the photoelectricity inspection that the integrated gases absorption cell is connected Examining system;
    The flue gas suction trapping system includes passing through the cigarette holder [3] of pipeline connection, triple valve b [5], filter disc successively [7], flue gas pump unit [9], servomotor [11], two-way valve is passed through on the pipeline between filter disc [7] and pump unit [9] A [6] connects with the gas approach of integrated gases absorption cell [15];
    The nitrogen purge system includes nitrogen cylinder [1], pressure-reducing valve [2], and by triple valve a [4] and feeding flue gas gathering system Cigarette holder [3], triple valve b [5] connection;
    The pumped vacuum systems includes vavuum pump [18], and is inhaled by triple valve c [17], two-way valve b [16] and integrated gases The exhanst gas outlet connection of receives pond [15];
    The photodetector system includes laser [12], laser controller [14], temperature controller [13], data acquisition unit [8] and computer [10], laser [12] pass through laser aligner [15-1] and the light of integrated gases absorption cell [15] Incidence end connects, and data acquisition unit [8] passes through photodetector [15-3] and the beam projecting of integrated gases absorption cell [15] End is connected, and the laser controller [14], temperature controller [13], data acquisition unit [8] are connected with computer [10], and Respective handling is carried out by computer software control.
  2. Oxygen consumption amount detecting device during 2. cigarette according to claim 1 is burnt and sucked, it is characterised in that:The triple valve a [4] piping volume between triple valve b [5] is more than 100ml.
  3. A kind of 3. method that oxygen demand during cigarette is burnt and sucked is detected using claim 1 described device, it is characterised in that:First System gas circuit is thoroughly purged with nitrogen, then gas absorption cell be evacuated with vavuum pump [18], suction is single afterwards First [9] carry out the suction of international standard pattern to cigarette, and after suction terminates, the flue gas collected is inhaled into the gas being evacuated Body absorption cell [15];At the same time, temperature controller [13], laser controller [14] enter trip temperature and electric current to laser [12] Tuning, the absorption line of the scanned oxygen of laser beam after tuning, enters absorption cell by laser aligner [15-1], is treated Survey gas to absorb, received after multiple reflections by photodetector [15-3], gathered and stored by data acquisition unit [8], finally Handled through computer [10], the absorption signal of under test gas can obtain the concentration of under test gas by demarcation;Examine respectively Survey cigarette is unignited and lights the concentration of under test gas after suction, surveys concentration and subtracts each other, you can obtains the consumption that cigarette burns and sucks a bite Oxygen amount, carry out continuous sucking, you can obtain that cigarette burns and sucks by mouth oxygen demand.
  4. The method of oxygen demand during 4. detection cigarette according to claim 3 is burnt and sucked, it is characterised in that:Specific steps are such as Under:
    Triple valve a [4], triple valve b [5], two-way valve a [6], two-way valve b [16], triple valve c [17] at the same it is electric interconnect, The nitrogen in nitrogen cylinder [1] carries out 10s cleanings to whole conducting pipeline afterwards, makes to be full of nitrogen in pipeline;
    Triple valve a [4] cuts out system pipeline, it is connected air;Two-way valve a [6] is closed;Two-way valve
    B [16] is stayed open;
    Triple valve c [17] switching state makes it connect vavuum pump [18] after 1s, vacuum pumping 9s, makes gas absorption cell [15] quilt Vacuum state;
    Two-way valve b [16] is closed;Triple valve c [17] cuts out system pipeline after 1s, it is connected air,
    Triple valve b [5] connection pump units [9], pump unit suction 2s, complete 35ml suction;
    Switching three-way valve b [5], makes it connect triple valve a [4], and the 35mL flue gases of suction enter subsequent pipeline, are stored in threeway Between valve a [4] and pump unit [9];Two-way valve a [6] is opened after 3s, and the under test gas in pipeline is inhaled into what is be evacuated Integrated gases absorption cell [15], the detection of oxygen content is carried out, detection time 32s, enters next circulation after waiting 2s.
  5. The method of oxygen demand during 5. the detection cigarette according to claim 3 or 4 is burnt and sucked, it is characterised in that:The detection The foundation of method is dexterously to be aspirated by the rule that oxygen content under the conditions of constant temperature and pressure constant humidity is constant according to international standard Pattern is aspirated, detect first cigarette it is unignited before suction a bite when oxygen concentration, then detect every mouth when cigarette is burnt and sucked The remaining concentration of oxygen afterwards, the difference of two concentration are the oxygen demand during every mouthful of cigarette is burnt and sucked.
CN201710867881.0A 2017-09-22 2017-09-22 Oxygen consumption amount detecting device and detection method during a kind of cigarette is burnt and sucked Pending CN107505286A (en)

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CN114113053A (en) * 2020-08-31 2022-03-01 中国烟草总公司郑州烟草研究院 Cigarette tobacco section oxygen content detection device and detection method thereof
CN114720529A (en) * 2022-04-19 2022-07-08 浙江中烟工业有限责任公司 Method and system for detecting oxygen concentration around combustion cone of burning and smoking cigarette

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