CN106400461A - Method for improving illumination fastness of THPC flame-retardant fabric - Google Patents

Method for improving illumination fastness of THPC flame-retardant fabric Download PDF

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Publication number
CN106400461A
CN106400461A CN201610898057.7A CN201610898057A CN106400461A CN 106400461 A CN106400461 A CN 106400461A CN 201610898057 A CN201610898057 A CN 201610898057A CN 106400461 A CN106400461 A CN 106400461A
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CN
China
Prior art keywords
thpc
flame
retardant
ammonia
fire
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Granted
Application number
CN201610898057.7A
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Chinese (zh)
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CN106400461B (en
Inventor
段净尘
尚军
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Xinxiang Xinke Protection Technology Co Ltd
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Xinxiang Xinke Protection Technology Co Ltd
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Priority to CN201610898057.7A priority Critical patent/CN106400461B/en
Publication of CN106400461A publication Critical patent/CN106400461A/en
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Publication of CN106400461B publication Critical patent/CN106400461B/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06Inorganic compounds or elements
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/14De-sizing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/60Ammonia as a gas or in solution
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus

Abstract

The invention discloses a method for improving illumination fastness of a THPC flame-retardant fabric. The method comprises the following specific technological processes: turning and sewing of gray cloth; desizing, boiling-off and mercerizing; stentering; flame-retarding; oxygen low-temperature plasma treatment; dyeing; washing and drying; stentering; preshrinking; and checking and packing. The desizing, boiling-off and mercerizing process is implemented fully until pH of eluant of the grey cloth is smaller than or equal to 7, a flame-retarding process successively comprises padding of THPC flame retardant working liquid, ammonia fuming, oxidation washing and drying and stentering, the concentration of THPC flame retardant in the THPC flame retardant working liquid is higher than a normal value by 8-10%, in an ammonia fuming process, the flow velocity of ammonia is 500-700 mL/s, and ammonia fuming time is not less than 5 seconds. The wicking capability of the treated THPC flame-retardant fabric is improved by 5-6 times, surface polar groups (-OOH, -OH, and -C=O) are remarkably increased, the dyeing percentage of dyestuff is multiplied, and demands of customers to the color are met well.

Description

A kind of method of lifting THPC inflaming retarding fabric light shine fastness
Technical field
The invention belongs to light shine THPC inflaming retarding fabric technical field is and in particular to a kind of lifting THPC inflaming retarding fabric is fast light Method according to fastness.
Background technology
Some gorgeous degree are very high(As bright red, Exocarpium Citri Rubrum, fluorescein)Pure cotton cloth, is all using reactive dyeing, if The cotton of this color needs to be that THPC is fire-retardant, and THPC fire retardant has very strong reproducibility it is easy to destroy activity dye The molecular structure of material, causes bright red, such cotton fire retardant such as Exocarpium Citri Rubrum, fluorescein, light only has 1-2 level, in some illumination Such fabric is worn, such as the area such as offshore drilling platform, oil field prospecting and Southeast Asia, as long as may under the strong environment of condition Several days, the color of more than ten days such clothes will fade seriously, very unsightly.Annoying textile printing and dyeing for many years always It is well known that high brightness fire retardant protective clothing is constantly subjected to the favor of a lot of industries, light difference usually enables a wearer to very awkward on boundary A word used for translation, often occurs that back is different with shirtfront color, it has to the clothes more renewing in the case that clothes is also intact, causes Great waste.
Content of the invention
Present invention solves the technical problem that there is provided a kind of method of lifting THPC inflaming retarding fabric light shine fastness.
The present invention is to solve above-mentioned technical problem to adopt the following technical scheme that, a kind of lifting THPC inflaming retarding fabric light shine jail The method of degree is it is characterised in that concrete technology flow process is:Fabric turns over seam → desizing, kiering, mercerising → tentering → fire-retardant → oxygen Low Temperature Plasma Treating → dyeing → washing drying → tentering → preshrunk → test package, wherein desizing, kiering, mercerising process Fully until pH≤7 of fabric eluent, fire-retardant process be followed successively by pad THPC fire retardant working solution, ammonia cure, oxidation washing and Dry tentering, in THPC fire retardant working solution, the concentration of THPC fire retardant improves 8%-10% compared with normal value, ammonia cure process ammonia Flow velocity is 500-700mL/s, and the time of ammonia cure is no less than 5s.
The wicking capacity of the THPC inflaming retarding fabric after present invention process lifts 5-6 times, surface polar groups(-OOH、-OH、- C=O)Dramatically increase, dyestuff dye uptake is also multiplied, can preferably meet the demand to color for the client.
Specific embodiment
Describe the particular content of the present invention in detail in conjunction with the embodiments.
Embodiment
Under normal circumstances, cotton is all to first pass through dyeing, is then THPC more fire-retardant.It is contemplated that changing order, I.e. cotton be first THPC fire-retardant again go dye, thus overcome the destruction to reactive dye for the fire retardant, simultaneously because THPC is fire-retardant to have very strong washability in itself, its fire resistance will be made to decay because of the dyeing of rear road, washing.But, THPC Fire retardant base closed cotton fiber can reactive group, then if going dyeing, basic color yield is very low, that is, dye level Not, still can not meet and use needs.How finish THPC fire-retardant after increase cotton fiber can reactive group(As-OOH ,- OH、-C=O), the present invention solved using the method for oxygen Low Temperature Plasma Treating.Through experimental test:Wicking after process Ability has 5-6 times of lifting, surface polar groups(-OOH、-OH、-C=O)Dramatically increase, dyestuff dye uptake is also at double Increase, the demand to color for the client can be met.
Concrete technology flow process is:Fabric turns over seam → desizing, kiering, mercerising → tentering → fire-retardant(Pad THPC fire retardant work Make liquid → ammonia cure → oxidation washing → drying tentering)→ oxygen plasma process → dyeing → washing drying → tentering → preshrunk → Test package, description of the process:1st, fire-retardant front desizing, kiering and mercerising must fully, and cloth cover can not contain alkalescence;2nd, when fire-retardant, The flow of the concentration of THPC fire retardant and ammonia cure improves 8%-10% than normal, and the time of ammonia cure can not be less than 5 seconds, otherwise, dye After color, fire resistance can decline;3rd, Low Temperature Plasma Treating:The ripe equipment based on glow discharge on market to be adopted; 4th, dye:In principle as common dyeing technique, the usage amount of dyestuff and auxiliary agent, first pass through sample and determine.
The present invention solves the problems, such as that the fire-retardant rear light of the cotton THPC of vital staining is too low, also improves this simultaneously The bright-colored degree of class inflaming retarding fabric, wide market.
The ultimate principle of the present invention, principal character and advantage have been shown and described above, without departing from the present invention spirit and On the premise of scope, the present invention also has various changes and modifications, and these changes and improvements both fall within claimed invention Scope.

Claims (1)

1. a kind of method of lifting THPC inflaming retarding fabric light shine fastness is it is characterised in that concrete technology flow process is:Fabric turns over seam → desizing, kiering, mercerising → tentering → fire-retardant → oxygen Low Temperature Plasma Treating → dyeing → washing drying → tentering → pre- , fully up to pH≤7 of fabric eluent, fire-retardant process is followed successively by leaching for contracting → test package, wherein desizing, kiering, mercerising process Roll THPC fire retardant working solution, ammonia cure, oxidation washing and dry tentering, the concentration of THPC fire retardant in THPC fire retardant working solution Improve 8%-10% compared with normal value, the flow velocity of ammonia cure process ammonia is 500-700mL/s, and the time of ammonia cure is no less than 5s.
CN201610898057.7A 2016-10-17 2016-10-17 A method of promoting THPC inflaming retarding fabric light shine fastness Active CN106400461B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610898057.7A CN106400461B (en) 2016-10-17 2016-10-17 A method of promoting THPC inflaming retarding fabric light shine fastness

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Application Number Priority Date Filing Date Title
CN201610898057.7A CN106400461B (en) 2016-10-17 2016-10-17 A method of promoting THPC inflaming retarding fabric light shine fastness

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CN106400461B CN106400461B (en) 2018-09-28

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107677082A (en) * 2017-11-15 2018-02-09 新乡市新科防护科技有限公司 A kind of method for improving the fire-retardant uniformity of inflaming retarding fabric
CN108396557A (en) * 2018-02-27 2018-08-14 湖北金利源大悟纺织服装股份有限公司 A kind of preparation method of fire retardant
CN110306313A (en) * 2019-07-13 2019-10-08 新乡市新星特种织物有限公司 The method of flame retardant knitted cloth promotion light fastness

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JPH06146170A (en) * 1992-10-30 1994-05-27 Unitika Ltd Method for improving and processing flame resistance of m-based aramid textile fabric
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JPH06146170A (en) * 1992-10-30 1994-05-27 Unitika Ltd Method for improving and processing flame resistance of m-based aramid textile fabric
CN101016694A (en) * 2007-02-15 2007-08-15 欧卫国 Flame-proof treatment method for light and thin natural fiber material
CN101418516A (en) * 2008-11-19 2009-04-29 南通东升艾克特种纺织防护面料有限公司 Dyeing method after flame-retardant for all-cotton fabric
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107677082A (en) * 2017-11-15 2018-02-09 新乡市新科防护科技有限公司 A kind of method for improving the fire-retardant uniformity of inflaming retarding fabric
CN108396557A (en) * 2018-02-27 2018-08-14 湖北金利源大悟纺织服装股份有限公司 A kind of preparation method of fire retardant
CN110306313A (en) * 2019-07-13 2019-10-08 新乡市新星特种织物有限公司 The method of flame retardant knitted cloth promotion light fastness
CN110306313B (en) * 2019-07-13 2021-08-10 新乡市新星特种织物有限公司 Method for improving light fastness of flame-retardant knitted fabric

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