CN106400461B - A method of promoting THPC inflaming retarding fabric light shine fastness - Google Patents

A method of promoting THPC inflaming retarding fabric light shine fastness Download PDF

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Publication number
CN106400461B
CN106400461B CN201610898057.7A CN201610898057A CN106400461B CN 106400461 B CN106400461 B CN 106400461B CN 201610898057 A CN201610898057 A CN 201610898057A CN 106400461 B CN106400461 B CN 106400461B
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China
Prior art keywords
thpc
fire
retardant
tentering
fabric
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CN201610898057.7A
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CN106400461A (en
Inventor
段净尘
尚军
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Xinxiang Xinke Protection Technology Co Ltd
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Xinxiang Xinke Protection Technology Co Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06Inorganic compounds or elements
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06LDRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L1/00Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
    • D06L1/12Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
    • D06L1/14De-sizing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/60Ammonia as a gas or in solution
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention discloses a kind of method promoting THPC inflaming retarding fabric light shine fastness, concrete technology flow process is:Fabric turns over seam → desizing, kiering, mercerising → tentering → fire-retardant → oxygen Low Temperature Plasma Treating → dyeing → washing drying → tentering → preshrunk → test package, wherein desizing, kiering, mercerising process are fully until pH≤7 of fabric eluent, fire-retardant process, which is followed successively by, pads THPC fire retardants working solution, ammonia cure, oxidation washing and drying tentering, the concentration of THPC fire retardants improves 8% 10% compared with normal value in THPC fire retardant working solutions, the flow velocity of ammonia cure process ammonia is 500 700mL/s, and the time of ammonia cure is no less than 5s.The wicking capacity of the present invention treated THPC inflaming retarding fabrics promotes 56 times, surface polar groups(‑OOH、‑OH、‑C=O)It dramatically increases, dyestuff dye uptake is also multiplied, and can preferably meet the needs of client is to color.

Description

A method of promoting THPC inflaming retarding fabric light shine fastness
Technical field
The invention belongs to light shine THPC inflaming retarding fabric technical fields, and in particular to a kind of promotion THPC inflaming retarding fabrics are fast light According to the method for fastness.
Background technology
Some gorgeous degree are very high(Such as bright red, Exocarpium Citri Rubrum, fluorescein)Pure cotton cloth, all be use reactive dyeing, if The cotton of this color needs to be that THPC is fire-retardant, and THPC fire retardants have very strong reproducibility, it is easy to destroy activity dye The molecular structure of material causes such cotton fire retardant such as bright red, Exocarpium Citri Rubrum, fluorescein, and light only has 1-2 grades, in some illumination Such fabric, such as offshore drilling platform, oil field prospecting and Southeast Asia area are worn under the strong environment of condition, as long as may The color of clothes as several days, more than ten days will fade seriously, very unsightly.Annoying textile printing and dyeing always for many years Boundary, it is well known that high brightness fire retardant protective clothing is constantly subjected to the favor of many industries, and light difference usually enables a wearer to very awkward , often there is back in a word used for translation and shirtfront color is different, in the case where clothes is also intact, it has to which the clothes more renewed causes Great waste.
Invention content
The technical problem to be solved by the present invention is to provide a kind of methods promoting THPC inflaming retarding fabric light shine fastness.
The present invention adopts the following technical scheme that a kind of promotion THPC inflaming retarding fabrics light shine is firm to solve above-mentioned technical problem The method of degree, it is characterised in that concrete technology flow process is:Fabric turns over seam → desizing, kiering, mercerising → tentering → fire-retardant → oxygen Low Temperature Plasma Treating → dyeing → washing drying → tentering → preshrunk → test package, wherein desizing, kiering, mercerising process Fully until fabric eluent pH≤7, fire-retardant process be followed successively by pad THPC fire retardants working solution, ammonia cure, oxidation washing and Tentering is dried, the concentration of THPC fire retardants improves 8%-10% compared with normal value in THPC fire retardant working solutions, ammonia cure process ammonia Flow velocity is 500-700mL/s, and the time of ammonia cure is no less than 5s.
The wicking capacity of the present invention treated THPC inflaming retarding fabrics promotes 5-6 times, surface polar groups(-OOH、-OH、- C=O)It dramatically increases, dyestuff dye uptake is also multiplied, and can preferably meet the needs of client is to color.
Specific implementation mode
Detailed description of the present invention particular content in conjunction with the embodiments.
Embodiment
Under normal circumstances, cotton is all to first pass through dyeing, and it is fire-retardant to be then THPC again.It is contemplated that change sequence, That is cotton is first that THPC is fire-retardant to be gone to dye again, thus overcomes destruction of the fire retardant to reactive dye, simultaneously because THPC is fire-retardant itself to have very strong washability, will not be dyed because of rear road, washing makes its flame retardant property decay.But THPC Fire retardant base closed cotton fiber can reactive group, then if going dyeing, basic color yield is very low, that is, dye level Not enough, cannot still meet using needs.How finish THPC it is fire-retardant after increase cotton fiber can reactive group(Such as-OOH ,- OH、-C=O), the present invention solved using the method for oxygen Low Temperature Plasma Treating.Through experimental test:Wicking that treated Ability has 5-6 times of promotion, surface polar groups(-OOH、-OH、-C=O)It dramatically increases, dyestuff dye uptake is also at double Increase, can meet the needs of client is to color.
Concrete technology flow process is:Fabric turns over seam → desizing, kiering, mercerising → tentering → fire-retardant(Pad THPC fire retardant works Make liquid → ammonia cure → oxidation is washed → and dries tentering)→ oxygen plasma treatment → dyeing → washing drying → tentering → preshrunk → Test package, description of the process:1, fire-retardant preceding desizing, kiering and mercerising must be abundant, and cloth cover cannot contain alkalinity;2, when fire-retardant, The concentration of THPC fire retardants and the flow of ammonia cure cannot be less than 5 seconds, otherwise, dye than normally improving 8%-10%, the time of ammonia cure Flame retardant property can decline after color;3, Low Temperature Plasma Treating:To use the equipment based on glow discharge ripe in the market; 4, it dyes:In principle as common dyeing technique, the usage amount of dyestuff and auxiliary agent is determined by sample first.
The present invention solves the problems, such as that the fire-retardant rear lights of the cotton THPC of vital staining are too low, while also improving this The bright-colored degree of class inflaming retarding fabric, wide market.
Have been shown and described above the basic principle of the present invention, main feature and advantage, do not depart from spirit of that invention and Under the premise of range, the present invention also has various changes and modifications, these changes and improvements both fall within claimed invention Range.

Claims (1)

1. a kind of method promoting THPC inflaming retarding fabric light shine fastness, it is characterised in that concrete technology flow process is:Fabric turns over seam → desizing, kiering, mercerising → tentering → fire-retardant → oxygen Low Temperature Plasma Treating → dyeing → washing drying → tentering → pre- Contracting → test package, wherein desizing, kiering, mercerising process are fully until pH≤7 of fabric eluent, fire-retardant process are followed successively by leaching It rolls THPC fire retardants working solution, ammonia cure, oxidation washing and dries tentering, the concentration of THPC fire retardants in THPC fire retardant working solutions 8%-10% is improved compared with normal value, the flow velocity of ammonia cure process ammonia is 500-700mL/s, and the time of ammonia cure is no less than 5s;The base The material of cloth is cotton.
CN201610898057.7A 2016-10-17 2016-10-17 A method of promoting THPC inflaming retarding fabric light shine fastness Active CN106400461B (en)

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Application Number Priority Date Filing Date Title
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CN106400461B true CN106400461B (en) 2018-09-28

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107677082A (en) * 2017-11-15 2018-02-09 新乡市新科防护科技有限公司 A kind of method for improving the fire-retardant uniformity of inflaming retarding fabric
CN108396557B (en) * 2018-02-27 2021-05-04 湖北金利源大悟纺织服装股份有限公司 Preparation method of flame-retardant cloth
CN110306313B (en) * 2019-07-13 2021-08-10 新乡市新星特种织物有限公司 Method for improving light fastness of flame-retardant knitted fabric

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016694A (en) * 2007-02-15 2007-08-15 欧卫国 Flame-proof treatment method for light and thin natural fiber material
CN101418516A (en) * 2008-11-19 2009-04-29 南通东升艾克特种纺织防护面料有限公司 Dyeing method after flame-retardant for all-cotton fabric
CN102936837A (en) * 2012-10-29 2013-02-20 中国人民解放军海军医学研究所 Water and oil-repellent flame-retardant all-cotton fabric preparation technology and application thereof
CN103233360A (en) * 2013-05-02 2013-08-07 江苏邦威服饰有限公司 Flame-retardant jean fabric
CN103603193A (en) * 2013-11-18 2014-02-26 河北名世锦簇纺织有限公司 Flame-retardant fabric
CN104831542A (en) * 2015-04-02 2015-08-12 安徽龙盛纺织科技有限公司 Processing method of flame retardation fabric

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06146170A (en) * 1992-10-30 1994-05-27 Unitika Ltd Method for improving and processing flame resistance of m-based aramid textile fabric

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101016694A (en) * 2007-02-15 2007-08-15 欧卫国 Flame-proof treatment method for light and thin natural fiber material
CN101418516A (en) * 2008-11-19 2009-04-29 南通东升艾克特种纺织防护面料有限公司 Dyeing method after flame-retardant for all-cotton fabric
CN102936837A (en) * 2012-10-29 2013-02-20 中国人民解放军海军医学研究所 Water and oil-repellent flame-retardant all-cotton fabric preparation technology and application thereof
CN103233360A (en) * 2013-05-02 2013-08-07 江苏邦威服饰有限公司 Flame-retardant jean fabric
CN103603193A (en) * 2013-11-18 2014-02-26 河北名世锦簇纺织有限公司 Flame-retardant fabric
CN104831542A (en) * 2015-04-02 2015-08-12 安徽龙盛纺织科技有限公司 Processing method of flame retardation fabric

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