CN106387299A - Method for synchronously reducing contents of arsenic and copper in walnut protein - Google Patents
Method for synchronously reducing contents of arsenic and copper in walnut protein Download PDFInfo
- Publication number
- CN106387299A CN106387299A CN201610803961.5A CN201610803961A CN106387299A CN 106387299 A CN106387299 A CN 106387299A CN 201610803961 A CN201610803961 A CN 201610803961A CN 106387299 A CN106387299 A CN 106387299A
- Authority
- CN
- China
- Prior art keywords
- walnut protein
- serosity
- arsenic
- add
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 108090000623 proteins and genes Proteins 0.000 title claims abstract description 28
- 102000004169 proteins and genes Human genes 0.000 title claims abstract description 28
- 235000009496 Juglans regia Nutrition 0.000 title claims abstract description 27
- 235000020234 walnut Nutrition 0.000 title claims abstract description 27
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 17
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 17
- 239000010949 copper Substances 0.000 title claims abstract description 17
- 229910052785 arsenic Inorganic materials 0.000 title claims abstract description 16
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 title claims abstract description 15
- 238000000034 method Methods 0.000 title claims abstract description 12
- 240000007049 Juglans regia Species 0.000 title 1
- 241000758789 Juglans Species 0.000 claims abstract description 26
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- 238000000926 separation method Methods 0.000 claims abstract description 6
- 238000001179 sorption measurement Methods 0.000 claims abstract description 6
- 230000001954 sterilising effect Effects 0.000 claims abstract description 6
- 238000004659 sterilization and disinfection Methods 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 8
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims description 7
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims description 7
- 239000001630 malic acid Substances 0.000 claims description 7
- 235000011090 malic acid Nutrition 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- 235000010980 cellulose Nutrition 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 6
- 239000003651 drinking water Substances 0.000 claims description 5
- 235000020188 drinking water Nutrition 0.000 claims description 5
- 230000001360 synchronised effect Effects 0.000 claims description 5
- 229920000168 Microcrystalline cellulose Polymers 0.000 claims description 4
- 235000019813 microcrystalline cellulose Nutrition 0.000 claims description 4
- 239000008108 microcrystalline cellulose Substances 0.000 claims description 4
- 229940016286 microcrystalline cellulose Drugs 0.000 claims description 4
- 239000011592 zinc chloride Substances 0.000 claims description 4
- 235000005074 zinc chloride Nutrition 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims 1
- 230000003750 conditioning effect Effects 0.000 abstract 1
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000001035 drying Methods 0.000 abstract 1
- 235000015097 nutrients Nutrition 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 abstract 1
- 235000018102 proteins Nutrition 0.000 description 19
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- IKWTVSLWAPBBKU-UHFFFAOYSA-N a1010_sial Chemical compound O=[As]O[As]=O IKWTVSLWAPBBKU-UHFFFAOYSA-N 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229960002594 arsenic trioxide Drugs 0.000 description 1
- GOLCXWYRSKYTSP-UHFFFAOYSA-N arsenic trioxide Inorganic materials O1[As]2O[As]1O2 GOLCXWYRSKYTSP-UHFFFAOYSA-N 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 230000009920 chelation Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000019621 digestibility Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 230000001965 increasing effect Effects 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- -1 malic acid-hydrochloric acid compound Chemical class 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/14—Vegetable proteins
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
Abstract
The invention relates to a method for synchronously reducing the contents of arsenic and copper in walnut protein. The method disclosed by the invention comprises the following steps of taking walnut protein powder, performing pulp blending, performing substitution and chelating, performing an adsorption reaction, performing solid-liquid separation, performing conditioning, performing sterilization, performing dehydration, performing drying and the like. According to the method disclosed by the invention, the contents of the arsenic and the copper in the walnut protein can be effectively and synchronously reduced, and besides, the feeling quality and the nutrient value of the walnut protein cannot be influenced.
Description
Technical field
The present invention relates to a kind of synchronization reduces arsenic, the method for copper content in walnut protein, belong to processing of farm products field.
Background technology
Walnut protein has good aminoacid composition and ratio, and digestibility is high, is a kind of excellent vegetable protein, has
Important value.Recently as the development of industry, mining industry, heavy metal pollution problem progressively exposes.Arsenic, copper are attached to
Walnut protein, leads to the edible safety of walnut protein to be affected.After enrichment arsenic, the protein of copper are eaten, can give birth to
Enrichment, serious harm health in object.
Content of the invention
The present invention is intended to provide a kind of method is easy, the rational method of cost reduces arsenic in walnut protein, copper content, carry
High edible safety.
Arsenic, the method for copper in a kind of synchronous reduction walnut protein, comprise the following steps:
(1) take Walnut protein powder double centner, add 940-960 kilogram of drinking water, mix;
(2) replace chelating:Add 3.4-3.6 kilogram of malic acid, then use the hydrochloric acid of 2.8-3.0mol/L to adjust serosity pH
To 3.2-3.4, add 300-320 gram of zinc chloride, mix, at 50-52 DEG C, keep 3.2-3.4 hour, period is stirred continuously, stirring
Speed is 4200-4400 rev/min;
(3) adsorption reaction:Add 3.4-3.6 kilogram of cellulose toward in walnut protein serosity, at 52-54 DEG C, stir 50-52
Minute, mixing speed is 4600-4800 rev/min;
(4) solid-liquid separation:Carry out solid-liquid separation, remove insoluble solid;
(5) quenched:The pH to 6.4-6.6 of walnut protein serosity is adjusted in 15 minutes;
(6) sterilize, be dehydrated and be dried:Serosity carries out sterilization treatment, is then dehydrated, is dried, obtains product.
Wherein, cellulose is Microcrystalline Cellulose, and mean diameter is 320-340 mesh.
The present invention adopts malic acid-hydrochloric acid compound system, that is, add salt acid for adjusting pH to ensure malic acid chelating heavy metal institute
The specific acid condition needing, avoids excessively adding the impact to walnut protein finished product local flavor for the malic acid simultaneously.Under specific pH, no
Disconnected stirring ensure that malic acid and walnut protein are fully contacted reaction, and zinc ion is chelated with the competition of arsenic, copper.In this shape
Under state, add the Microcrystalline Cellulose of particular fineness, can efficiently target heavy metal and unnecessary zinc ion be adsorbed, from
And reach synchronous reduction arsenic, the effect of copper content.
The present invention utilizes zinc ion under specific environment to replace chelation to arsenic, the competitive of copper, and specified particle diameter is micro-
The adsorption of crystalline cellulose;By both synergistic functions, the synchronous arsenic reducing in solution, copper content.The method is grasped
Make mild condition, can operate continuously, and do not affect products taste and nutritional labeling.
Specific embodiment
Describe in more detail the present invention below by specific embodiment.
Embodiment 1
(1) take Walnut protein powder double centner, add 960 kilograms of drinking waters, mix;(2) replace chelating:Add 3.6 kilograms
Malic acid, then uses the hydrochloric acid of 3.0mol/L to adjust serosity pH to 3.4, adds 320 grams of zinc chloride, mix, keep 3.4 at 52 DEG C
Hour, period is stirred continuously, and mixing speed is 4400 revs/min;(3) adsorption reaction:3.6 thousand are added toward in walnut protein serosity
Gram Microcrystalline Cellulose (mean diameter is 340 mesh), stirs 50 minutes at 52 DEG C, mixing speed is 4800 revs/min;(4) solid-liquid
Separate:Carry out solid-liquid separation, remove insoluble solid;(5) quenched:The pH to 6.5 of walnut protein serosity is adjusted in 15 minutes;
(6) sterilize, be dehydrated and be dried:Serosity carries out sterilization treatment, is then dehydrated, is dried, obtains product.
Embodiment 2
(1) take Walnut protein powder double centner, add 960 kilograms of drinking waters, mix;(2) replace chelating:Add 3.6 kilograms
Malic acid, then uses the hydrochloric acid of 3.0mol/L to adjust serosity pH to 3.4, adds 320 grams of zinc chloride, mix, keep 3.4 at 52 DEG C
Hour, period is stirred continuously, and mixing speed is 4400 revs/min;(3) quenched:Walnut protein serosity is adjusted in 15 minutes
PH to 6.5;(4) sterilize, be dehydrated and be dried:Serosity carries out sterilization treatment, is then dehydrated, is dried, obtains product.
Embodiment 3
(1) take Walnut protein powder double centner, add 960 kilograms of drinking waters, mix;(2) chelate:Add 3.6 kilograms of Fructus Mali pumilaes
Acid, then uses the hydrochloric acid of 3.0mol/L to adjust serosity pH to 3.4, keeps 3.4 hours, period is stirred continuously at 52 DEG C, stirring speed
Spend for 4400 revs/min;(3) quenched:The pH to 6.5 of walnut protein serosity is adjusted in 15 minutes;(4) sterilize, be dehydrated and dry
Dry:Serosity carries out sterilization treatment, is then dehydrated, is dried, obtains product.
The effect analyses of different embodiments:
Note:The score value of organoleptic quality is higher, represents that taste is better
Compared with embodiment 2,3, using the embodiment 1 of present invention process, its arsenic, copper content are down to 0.028mg/ respectively
kg、0.071mg/kg;And the organoleptic quality of embodiment 1 product is basically identical with embodiment 2,3.
The present invention carries out replacing chelating using zinc ion in certain circumstances, and arsenic, copper content decline;Continue fine using crystallite
After dimension element is adsorbed, the arsenic of product, copper content reduce further it is seen that zinc replaces chelating and cellulose adsorption has collaborative increasing
Effect acts on.
Claims (2)
1. a kind of synchronous arsenic, method of copper content of reducing in walnut protein is it is characterised in that comprise the following steps:
(1) take Walnut protein powder double centner, add 940-960 kilogram of drinking water, mix;
(2) replace chelating:Add 3.4-3.6 kilogram of malic acid, then use 2.8-3.0mol/L hydrochloric acid adjust serosity pH to
3.2-3.4, adds 300-320 gram of zinc chloride, mixes, and keeps 3.2-3.4 hour at 50-52 DEG C, and period is stirred continuously, stirring speed
Spend for 4200-4400 rev/min;
(3) adsorption reaction:Add 3.4-3.6 kilogram of cellulose toward in walnut protein serosity, at 52-54 DEG C, stir 50-52 minute,
Mixing speed is 4600-4800 rev/min;
(4) solid-liquid separation:Carry out solid-liquid separation, remove insoluble solid;
(5) quenched:The pH to 6.4-6.6 of walnut protein serosity is adjusted in 15 minutes;
(6) sterilize, be dehydrated and be dried:Serosity carries out sterilization treatment, is then dehydrated, is dried, obtains product.
2. it is characterised in that cellulose is Microcrystalline Cellulose, mean diameter is production method according to claim 1
320-340 mesh.
Priority Applications (1)
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CN201610803961.5A CN106387299A (en) | 2016-09-06 | 2016-09-06 | Method for synchronously reducing contents of arsenic and copper in walnut protein |
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CN201610803961.5A CN106387299A (en) | 2016-09-06 | 2016-09-06 | Method for synchronously reducing contents of arsenic and copper in walnut protein |
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Publication Number | Publication Date |
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CN106387299A true CN106387299A (en) | 2017-02-15 |
Family
ID=57998581
Family Applications (1)
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CN201610803961.5A Pending CN106387299A (en) | 2016-09-06 | 2016-09-06 | Method for synchronously reducing contents of arsenic and copper in walnut protein |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107236038A (en) * | 2017-06-20 | 2017-10-10 | 华兰生物工程股份有限公司 | Microcrystalline cellulose improves method of protein clarity and products thereof and application |
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CN100482597C (en) * | 2005-12-02 | 2009-04-29 | 东海生物科技股份有限公司 | Use of gamma- polyglutamic acid, gamma- polyglutamate and/ or its aqueous gel for removing heavy metal and dissolving calcium and/ or magnesium scale |
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CN103007896A (en) * | 2012-12-24 | 2013-04-03 | 漳州师范学院 | Preparation method of cellulose adsorbent for adsorbing heavy metal cations |
CN103340414A (en) * | 2013-07-12 | 2013-10-09 | 普洱永吉生物技术有限责任公司 | Method for removing cadmium in rice protein |
CN103461646A (en) * | 2013-09-29 | 2013-12-25 | 东北农业大学 | Method suitable for removing arsenic from rice bran |
CN103549234A (en) * | 2013-10-23 | 2014-02-05 | 华中农业大学 | Method of reducing heavy metals of cereals |
CN103601321A (en) * | 2013-11-27 | 2014-02-26 | 昊华宇航化工有限责任公司 | Operation and regeneration method of chelate resin tower in production of ionic membrane caustic soda |
CN103815415A (en) * | 2014-03-21 | 2014-05-28 | 许自霖 | High-quality functional alga dietary fiber |
CN105410598A (en) * | 2015-10-30 | 2016-03-23 | 江南大学 | Preparation method of rice products with low content of heavy metal |
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2016
- 2016-09-06 CN CN201610803961.5A patent/CN106387299A/en active Pending
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CN100482597C (en) * | 2005-12-02 | 2009-04-29 | 东海生物科技股份有限公司 | Use of gamma- polyglutamic acid, gamma- polyglutamate and/ or its aqueous gel for removing heavy metal and dissolving calcium and/ or magnesium scale |
CN101274268A (en) * | 2007-12-29 | 2008-10-01 | 中国科学院长春应用化学研究所 | Biological adsorbing agent with adsorption capacity of heavy metal ion, and producing method and application thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN107236038A (en) * | 2017-06-20 | 2017-10-10 | 华兰生物工程股份有限公司 | Microcrystalline cellulose improves method of protein clarity and products thereof and application |
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