CN106381718A - Preparation method of eco-friendly glass fiber wall cloth - Google Patents

Preparation method of eco-friendly glass fiber wall cloth Download PDF

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Publication number
CN106381718A
CN106381718A CN201610763153.0A CN201610763153A CN106381718A CN 106381718 A CN106381718 A CN 106381718A CN 201610763153 A CN201610763153 A CN 201610763153A CN 106381718 A CN106381718 A CN 106381718A
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solution
glass
stir
preparation
coating
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CN106381718B (en
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沈海平
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Jiaxing Jiete New Material Co.,Ltd.
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Haining Jiete Glass Fabric Industry Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/042—Acrylic polymers
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00—Formation of filaments, threads, or the like
    • D01D5/0007—Electro-spinning
    • D01D5/0015—Electro-spinning characterised by the initial state of the material
    • D01D5/003—Electro-spinning characterised by the initial state of the material the material being a polymer solution or dispersion
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/52—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated carboxylic acids or unsaturated esters
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0013—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using multilayer webs
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
    • D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
    • D06N3/0022—Glass fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0061—Organic fillers or organic fibrous fillers, e.g. ground leather waste, wood bark, cork powder, vegetable flour; Other organic compounding ingredients; Post-treatment with organic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
    • D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1671—Resistance to bacteria, mildew, mould, fungi
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/16—Properties of the materials having other properties
    • D06N2209/1678—Resistive to light or to UV
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00—Specially adapted uses
    • D06N2211/06—Building materials
    • D06N2211/063—Wall coverings

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dispersion Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention provides a preparation method of an eco-friendly glass fiber wall cloth. Glass fibers are modified and combined with a specially-produced coating. After glass fiber modification, an aluminum-magnesium layer is arranged on the surfaces of the fibers so that combination performances of the fibers and the coating are improved and flame resistance is substantially improved. Through use of silane-modified beta cyclodextrin and a silane coupling agent, bonding properties of the coating and the glass fibers are improved. Through use of micron-order magnesium-aluminum hydrotalcite, flame retardation performances and UV resistance are improved. Through use of titanium dioxide, antibacterial effects are obtained and UV-resistant and shielding agent effects are obtained.

Description

A kind of preparation method of environmental-friendly glass fiber wall paper
Technical field
The present invention relates to glass fiber compound material field, especially, it is related to a kind of system of environmental-friendly glass fiber wall paper Preparation Method.
Background technology
Glass fibre wall paper is Hai Jibu again, is with the woven fabric of glass staple yarn or texturized glass yarn as base Material, processes through surface-coated and forms, be a kind of natural environmental-protective type green building material, for inner wall of building decorations.Have moisture resistance Mould proof, impact resistance, corrosion-resistant, water-fastness, nontoxic do not fire, waterproof and breathable the advantages of, effectively can also reinforce metope, play and prevent The effect of metope cracking.Protean weaving maneuver derives thousands of floral designs being rich in texture simultaneously, also can root Arbitrarily change appearance colour according to personal like, realize unexpected decorative effect, meet today's society pursue health, environmental protection, Safety, comfortable trend, are the desired decoration dresses in the places such as star hotel, high-grade office building, airport, dining room, cinema, subway Repair material.
Fiberglass woven fabric carries out surface-coated primarily to reducing the filoplume of fabric face, makes wall paper well-pressed fixed Type, is easy to construct, and gives wall paper the affinity good with metope, coating simultaneously.The master of domestic glass fibre wall paper coating at present Composition is wanted to include：Hot water gelatinized starch, acrylic acid ester emulsion, defoamer, antibacterial etc..Typical technique is as follows：By pre-gelatinized Starch stirs gelatinizing in the hot water, and adds the auxiliary agents such as phosphoric acid adjustment slurry viscosity, is subsequently adding acrylate after adjustment pH value Emulsion, is stirring evenly and then adding into filtering and discharging after the auxiliary agents such as antibacterial, defoamer；The coated machine of coating is coated in glass fibre fabric On, then through 200 DEG C about drying and shaping.Glass fibre wall paper when using will first overleaf gluing, then smooth stick to On wall, this is very high to the resistance to water of coating and softness requirements.Above-mentioned technique can be by adjusting the Tg of acrylic acid ester emulsion To adjust flexibility, Tg is lower, the flexibility of wall paper is better.
But glass fibre wall paper when running into fire although the glass fibre of internal layer has good fire resistance, but The organic components on surface can occur due to imperfect combustion, leads to distribute the toxic gas such as carbon monoxide, therefore is necessary to research and develop A kind of more environmentally-friendly fire-retardant glass fibre wall paper.
Content of the invention
Present invention aim at providing a kind of preparation method of environmental-friendly glass fiber wall paper, to solve technical problem.
A kind of preparation method of environmental-friendly glass fiber wall paper, comprises the following steps：
A, aluminum ethylate. and Diethoxymagnesium are added in ethanol, add acetone, stir；
B, be slowly added to mass fraction be 50-60% ethanol solution, stir 6-8 hour, obtain solution glue；
C, solution glue is slowly added into mass fraction be 15-20% vinyl acetate resin solution in, stir 4-6 hour；
D, using above solution as spinning solution, using electrostatic spinning process, loaded on the glass fibers；
E, 500-650 DEG C of high-temperature calcination 2-3 hour, obtains modified glass-fiber fabric；
F, coated for coating machine is coated on modified glass-fiber fabric, then through 200-220 DEG C of drying and shaping, you can.
Preferably, in described step A, the mol ratio of aluminum ethylate. and Diethoxymagnesium is（2-3）：1.
Preferably, the coating of described step F, including the main component of following percentage by weight：
Acrylic acid ester emulsion 5-8%
Silane-modified beta cyclodextrin 8-12%
Carboxymethyl cellulose 2-5%
Silane coupler 0.5-1%
Micro-scale titanium dioxide 1-3%
Micron order magnesium aluminum-hydrotalcite 0.3-0.5%
Water surplus.
Increased magnalium layer in fiber surface after glass fibre being modified in the present invention, not only increase fiber and painting The binding ability of layer, and its fire resistance also significantly improves.
Add silane-modified beta cyclodextrin and silane coupler to cooperate in the coating, enhance coating and glass fibre Adhesive property；Add micron order magnesium aluminum-hydrotalcite to have good fire resistance, be quickly generated high temperature resistant reaching at high temperature More than 1600 DEG C of aluminum-spinel structure, blocks burning things which may cause a fire disaster, prevents Organic substance from burning further, will not play toxic smoke, significantly mitigate Injury to people；Micron order magnesium aluminum-hydrotalcite and micro-scale titanium dioxide cooperate simultaneously, and uvioresistant effect is more preferable.
Under the high humidity environments such as basement, bathroom, acrylate coatings can occur xanthochromia after three to five years, if temperature Higher, after 1 year, xanthochromia may will occur, the present invention adds titanium dioxide in the coating, not only has the effect of antibacterial, but also There are uvioresistant and the effect of screening agent, elegant in appearance.
The invention has the advantages that：The preparation method of the environmental-friendly glass fiber wall paper of the present invention, glass fibre Increased magnalium layer in fiber surface after being modified, not only increase the binding ability of fiber and coating, and its anti-flammability Can also significantly improve；Add silane-modified beta cyclodextrin and silane coupler, enhance the adhesive property of coating and glass fibre； Micron order magnesium aluminum-hydrotalcite is added to improve fire resistance and anti-ultraviolet property, and when there is fire, rapid extinguishing, will not dissipate Toxophoric cigarette；Add titanium dioxide, not only have an effect of antibacterial, and the effect of also uvioresistant and screening agent.
In addition to objects, features and advantages described above, the present invention also has other objects, features and advantages. The present invention is further detailed explanation below.
Specific embodiment
Hereinafter embodiments of the invention are described in detail, but the present invention can limit according to claim and cover Multitude of different ways implement.
Embodiment 1
A kind of preparation method of environmental-friendly glass fiber wall paper, comprises the following steps：
A, aluminum ethylate. and Diethoxymagnesium are added in ethanol, add acetone, stir；The mol ratio of aluminum ethylate. and Diethoxymagnesium is 2.5：1；
B, it is slowly added to the ethanol solution that mass fraction is 50%, stir 7 hours, obtain solution glue；
C, solution glue is slowly added in the vinyl acetate resin solution that mass fraction is 15%, stirs 5 hours；
D, using above solution as spinning solution, using electrostatic spinning process, loaded on the glass fibers；
E, 550 DEG C of high-temperature calcinations 2.5 hours, obtain modified glass-fiber fabric；
F, coated for coating machine is coated on modified glass-fiber fabric, then through 210 DEG C of drying and shaping, you can.
Coating described in step F, is to be formed by after the composition coating of following percentage by weight：
Acrylic acid ester emulsion 7%
Silane-modified beta cyclodextrin 10%
Carboxymethyl cellulose 3%
Silane coupler 0.8%
Micro-scale titanium dioxide 2.5%
Micron order magnesium aluminum-hydrotalcite 0.4%
Water surplus.
Embodiment 2
A kind of preparation method of environmental-friendly glass fiber wall paper, comprises the following steps：
A, aluminum ethylate. and Diethoxymagnesium are added in ethanol, add acetone, stir；The mol ratio of aluminum ethylate. and Diethoxymagnesium is 2：1；
B, it is slowly added to the ethanol solution that mass fraction is 50%, stir 8 hours, obtain solution glue；
C, solution glue is slowly added in the vinyl acetate resin solution that mass fraction is 15%, stirs 4 hours；
D, using above solution as spinning solution, using electrostatic spinning process, loaded on the glass fibers；
E, 650 DEG C of high-temperature calcinations 2 hours, obtain modified glass-fiber fabric；
F, coated for coating machine is coated on modified glass-fiber fabric, then through 220 DEG C of drying and shaping, you can.
Coating described in step F, is to be formed by after the composition coating of following percentage by weight：
Acrylic acid ester emulsion 8%
Silane-modified beta cyclodextrin 8%
Carboxymethyl cellulose 5%
Silane coupler 0.5%
Micro-scale titanium dioxide 3%
Micron order magnesium aluminum-hydrotalcite 0.3%
Water surplus.
Embodiment 3
A kind of preparation method of environmental-friendly glass fiber wall paper, comprises the following steps：
A, aluminum ethylate. and Diethoxymagnesium are added in ethanol, add acetone, stir；The mol ratio of aluminum ethylate. and Diethoxymagnesium is 3：1；
B, it is slowly added to the ethanol solution that mass fraction is 60%, stir 6 hours, obtain solution glue；
C, solution glue is slowly added in the vinyl acetate resin solution that mass fraction is 20%, stirs 6 hours；
D, using above solution as spinning solution, using electrostatic spinning process, loaded on the glass fibers；
E, 500 DEG C of high-temperature calcinations 3 hours, obtain modified glass-fiber fabric；
F, coated for coating machine is coated on modified glass-fiber fabric, then through 200 DEG C of drying and shaping, you can.
Coating described in step F, is to be formed by after the composition coating of following percentage by weight：
Acrylic acid ester emulsion 5%
Silane-modified beta cyclodextrin 12%
Carboxymethyl cellulose 2%
Silane coupler 1%
Micro-scale titanium dioxide 1%
Micron order magnesium aluminum-hydrotalcite 0.5%
Water surplus.
The environmental-friendly glass fiber wall paper of embodiment of the present invention 1-3, carries out combustion testing, extinguishes rapidly in 2s, do not distribute Toxic smoke, flame retardant effect is very good.
Comparative example 1
Micro-scale titanium dioxide in embodiment 1 floating coat is removed, remaining condition is constant.
Xanthochromia test is carried out to the glass fibre wall paper of embodiment of the present invention 1-3 and comparative example 1, test condition is： Glass fibre wall paper is fitted in 70 DEG C, on the indoor cement wall surface of 95%R.H., obtains following data：
1 month 3 months 6 months
Embodiment 1 Non yellowing Non yellowing Non yellowing
Embodiment 2 Non yellowing Non yellowing Slight xanthochromia
Embodiment 3 Non yellowing Non yellowing Slight xanthochromia
Comparative example 1 Slight xanthochromia Notable xanthochromia Notable xanthochromia
By test data it is recognised that the glass fibre wall paper of the present invention, even if under extreme conditions, remain to keep extraordinary Xanthochromia performance.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for the skill of this area For art personnel, the present invention can have various modifications and variations.All within the spirit and principles in the present invention, made any repair Change, equivalent, improvement etc., should be included within the scope of the present invention.

Claims (4)

1. a kind of preparation method of environmental-friendly glass fiber wall paper is it is characterised in that the method comprises the following steps：
A, aluminum ethylate. and Diethoxymagnesium are added in ethanol, add acetone, stir；
B, be slowly added to mass fraction be 50-60% ethanol solution, stir 6-8 hour, obtain solution glue；
C, solution glue is slowly added into mass fraction be 15-20% vinyl acetate resin solution in, stir 4-6 hour；
D, using above solution as spinning solution, using electrostatic spinning process, loaded on the glass fibers；
E, 500-650 DEG C of high-temperature calcination 2-3 hour, obtains modified glass-fiber fabric；
F, coated for coating machine is coated on modified glass-fiber fabric, then through 200-220 DEG C of drying and shaping, you can.
2. the preparation method of environmental-friendly glass fiber wall paper as claimed in claim 1 is it is characterised in that in described step A, The mol ratio of aluminum ethylate. and Diethoxymagnesium is（2-3）：1.
3. the preparation method of environmental-friendly glass fiber wall paper as claimed in claim 1 is it is characterised in that described step F Coating, including the main component of following percentage by weight：
Acrylic acid ester emulsion 5-8%
Silane-modified beta cyclodextrin 8-12%
Carboxymethyl cellulose 2-5%
Silane coupler 0.5-1%
Micro-scale titanium dioxide 1-3%
Micron order magnesium aluminum-hydrotalcite 0.3-0.5%
Water surplus.
4. the preparation method of environmental-friendly glass fiber wall paper as claimed in claim 1 is it is characterised in that comprise the following steps：
A, aluminum ethylate. and Diethoxymagnesium are added in ethanol, add acetone, stir；
B, be slowly added to mass fraction be 50-60% ethanol solution, stir 7 hours, obtain solution glue；
C, solution glue is slowly added into mass fraction be 15-20% vinyl acetate resin solution in, stir 5 hours；
D, using above solution as spinning solution, using electrostatic spinning process, loaded on the glass fibers；
E, 550 DEG C of high-temperature calcinations 2.5 hours, obtain modified glass-fiber fabric；
F, coated for coating machine is coated on modified glass-fiber fabric, then through 210 DEG C of drying and shaping, you can；
In described step A, the mol ratio of aluminum ethylate. and Diethoxymagnesium is 2.5：1；
The coating of described step F, including the main component of following percentage by weight：
Acrylic acid ester emulsion 7%
Silane-modified beta cyclodextrin 10%
Carboxymethyl cellulose 3%
Silane coupler 0.8%
Micro-scale titanium dioxide 2.5%
Micron order magnesium aluminum-hydrotalcite 0.4%
Water surplus.
CN201610763153.0A 2016-08-30 2016-08-30 A kind of preparation method of environmental-friendly glass fiber wall paper Active CN106381718B (en)

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
CN107641977A (en) * 2017-09-12 2018-01-30 青岛瑞利特新材料科技有限公司 A kind of graphene glass wall base cloth and preparation method thereof
CN108004798A (en) * 2017-12-16 2018-05-08 陈雨薇 Preparation method of coating wall cloth
CN108130647A (en) * 2017-11-24 2018-06-08 湖州织里创塑塑料科技有限公司 A kind of black-out cloth
CN109097871A (en) * 2018-06-21 2018-12-28 北京点域科技有限公司 A method of fire retardant is prepared using glass fibre
CN110820129A (en) * 2019-11-14 2020-02-21 莱芜耀佳玻璃纤维有限公司 Fireproof wall cloth manufacturing process
CN112322091A (en) * 2020-11-23 2021-02-05 成都市富百乐装饰材料实业有限公司 Air purification, sterilization and mildew-proof coating and preparation method thereof

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CN101696549A (en) * 2009-11-12 2010-04-21 江苏九鼎新材料股份有限公司 Flame retardant glass fiber mesh
CN201695894U (en) * 2010-08-16 2011-01-05 雷震 Foam fireproof door core plate
CN102604376A (en) * 2012-03-14 2012-07-25 济南泰星精细化工有限公司 Environment-friendly halogen-free flame retardant for glass fiber reinforced PA6 (polyamide) and preparation method thereof

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Publication number Priority date Publication date Assignee Title
EP1857267A1 (en) * 2006-05-19 2007-11-21 K+S GmbH Modell-und Formenbau Bi-component plastic part and process to obtain this part
CN101696549A (en) * 2009-11-12 2010-04-21 江苏九鼎新材料股份有限公司 Flame retardant glass fiber mesh
CN201695894U (en) * 2010-08-16 2011-01-05 雷震 Foam fireproof door core plate
CN102604376A (en) * 2012-03-14 2012-07-25 济南泰星精细化工有限公司 Environment-friendly halogen-free flame retardant for glass fiber reinforced PA6 (polyamide) and preparation method thereof

Cited By (7)

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CN107641977A (en) * 2017-09-12 2018-01-30 青岛瑞利特新材料科技有限公司 A kind of graphene glass wall base cloth and preparation method thereof
CN108130647A (en) * 2017-11-24 2018-06-08 湖州织里创塑塑料科技有限公司 A kind of black-out cloth
CN108004798A (en) * 2017-12-16 2018-05-08 陈雨薇 Preparation method of coating wall cloth
CN108004798B (en) * 2017-12-16 2020-02-14 陈雨薇 Preparation method of coating wall cloth
CN109097871A (en) * 2018-06-21 2018-12-28 北京点域科技有限公司 A method of fire retardant is prepared using glass fibre
CN110820129A (en) * 2019-11-14 2020-02-21 莱芜耀佳玻璃纤维有限公司 Fireproof wall cloth manufacturing process
CN112322091A (en) * 2020-11-23 2021-02-05 成都市富百乐装饰材料实业有限公司 Air purification, sterilization and mildew-proof coating and preparation method thereof

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