CN101696549A - Flame retardant glass fiber mesh - Google Patents
Flame retardant glass fiber mesh Download PDFInfo
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- CN101696549A CN101696549A CN200910178363A CN200910178363A CN101696549A CN 101696549 A CN101696549 A CN 101696549A CN 200910178363 A CN200910178363 A CN 200910178363A CN 200910178363 A CN200910178363 A CN 200910178363A CN 101696549 A CN101696549 A CN 101696549A
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- flame retardant
- glass fiber
- emulsion
- fiber mesh
- retardant glass
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Abstract
The invention discloses a frame retardant glass fiber mesh, which is formed by submerging a mesh in a flame retardant adhesive, and is characterized in that: the flame retardant adhesive comprises a PVDC latex, a strengthened positioning emulsion, an inorganic nano filler, an assistant flame retardant and a dispersant of which a dry matter ratio is 2:(0.5-1.5):(0.05-0.35):(0.05-0.25):(0.001-0.1). The flame retardant glass fiber mesh has the advantages that: the technological process is simple and convenient to operate and control, raw materials have low cost, and the production process has no pollution; the obtained glass fiber mesh product has good flame retardancy; and the indexes, such as hand feeling, elasticity, positioning effect, strength and the like all meet related requirements. The mesh prepared by the invention can be used in the industrial and civil buildings and places without limitation to halogenated flame retardancy.
Description
Technical field
The present invention relates to a kind of flame retardant glass fiber mesh, be specifically related to a kind of preparation process condition of flame retardant glass fiber mesh and the selection and the preparation method of fire retardant glue thereof.
Background technology
All will use flame retardant glass fiber mesh in many industry and civil buildings, this screen cloth is to apply the glue oven dry of fire-retardant location to form on glass grid grey cloth.Common fire retardant glue is that polyvinyl chloride resin is stuck with paste glue or halogen free polymer emulsion and composite the forming of a large amount of expensive fire retardants that becomes good fluidity relatively to apply with a large amount of organic solvent dilutings, these two kinds of glues are not to discharge the large amount of organic contaminated environment in process in environment, be exactly that cost is high especially, can not satisfy the needs of market competition.
Summary of the invention
The process conditions that the purpose of this invention is to provide in a kind of inexpensive and process not the preparation method of the fire retardant glue that can pollute environment and must control during with its preparation fiberglass gridding cloth.
For solving the problems of the technologies described above, a kind of flame retardant glass fiber mesh of the present invention by forming in the screen cloth infuse fire retardant glue, is characterized in that: described fire retardant glue is for comprising chlorine partial emulsion, strengthening location emulsion, nanometer inorganic filler, synergistic flame retardant, dispersant; Dry is than being chlorine partial emulsion between component: strengthen the location emulsion: nanometer inorganic filler: synergistic flame retardant: dispersant=2: (0.5-1.5): (0.05-0.35): (0.05-0.25): (0.001-0.01).
Further, described reinforcement is located emulsion and be can be pure-acrylic emulsion, benzene emulsion, acrylate and vinyl acetate emulsion, styrene-butadiene emulsion or several mixtures.
Further, described nanometer inorganic filler is nano silicon, nanoclay or several mixtures.
Further, described synergistic flame retardant is an antimonous oxide.
Further, described dispersant is Sodium Polyacrylate, Negel, sulfosuccinic acid double tridecyl ester sodium or several mixtures.
Further, the bake out temperature of stating the fire retardant glue screen cloth is 80-122 ℃, and the time of staying of screen cloth in baking oven was less than 150 seconds.
The invention has the advantages that: technical process of the present invention is simple, convenient operation and control, and cost of material is low, and production process is pollution-free, and index such as the glass fiber net cloth products fire resistance of acquisition is good, feel, elasticity, locating effect and intensity all meets relevant requirements.The screen cloth that makes according to the present invention can be used for fire-retardant hard-core industry of Halogen and civil buildings place.
The specific embodiment
Embodiment 1
70 parts of vinylidene chloride polymer emulsions, 28 parts of pure-acrylic emulsions, 1.8 parts of nano silicons, 2 parts of antimonous oxides, 0.04 part of Sodium Polyacrylate dispersant, in the presence of suitable quantity of water, mix, parch fully to glue about in 105 ℃ of baking ovens, drying by the fire the glass cloth that scribbles this mixture liquid in 90 seconds, shift out baking oven.The screen cloth that obtains is being put not with fire, and the location of warp and parallel is good, and feel is not stained with certain elasticity, close with common glass fiber reticular cloth, the no xanthochromia of outward appearance.
Embodiment 2
70 parts of vinylidene chloride polymer emulsions, 37 parts of benzene emulsions, 2.2 parts of nanoclays, 2.3 parts of antimonous oxides, 0.075 part of Sodium Polyacrylate dispersant, in the presence of suitable quantity of water, mix, parch fully to glue about in 115 ℃ of baking ovens, drying by the fire the glass cloth that scribbles this mixture liquid in 90 seconds, shift out baking oven.The screen cloth that obtains is being put not with fire, and the location of warp and parallel is good, and feel is not stained with certain elasticity, close with common glass fiber reticular cloth, the no xanthochromia of outward appearance.
Embodiment 3
70 parts of vinylidene chloride polymer emulsions; 32 parts of styrene-butadiene emulsions; 4.6 parts of nanoclays; 2.3 parts of antimonous oxides; 0.045 part of Negel dispersant; mix in the presence of suitable quantity of water parch fully to glue about drying by the fire the glass cloth that scribbles this mixture liquid in 85 seconds in 110 ℃ of baking ovens, shift out baking oven.The screen cloth that obtains is being put not with fire, and the location of warp and parallel is good, and feel is not stained with certain elasticity, close with common glass fiber reticular cloth, the no xanthochromia of outward appearance.
Claims (6)
1. flame retardant glass fiber mesh by forming in the screen cloth infuse fire retardant glue, is characterized in that: described fire retardant glue is for comprising chlorine partial emulsion, strengthening location emulsion, nanometer inorganic filler, synergistic flame retardant, dispersant; Dry is than being chlorine partial emulsion between component: strengthen the location emulsion: nanometer inorganic filler: synergistic flame retardant: dispersant=2: (0.5-1.5): (0.05-0.35): (0.05-0.25): (0.001-0.01).
2. a kind of flame retardant glass fiber mesh according to claim 1 is characterized in that: described reinforcement location emulsion can be pure-acrylic emulsion, benzene emulsion, acrylate and vinyl acetate emulsion, styrene-butadiene emulsion or several mixtures.
3. a kind of flame retardant glass fiber mesh according to claim 1 is characterized in that: described nanometer inorganic filler is nano silicon, nanoclay or several mixtures.
4. a kind of flame retardant glass fiber mesh according to claim 1 is characterized in that: described synergistic flame retardant is an antimonous oxide.
5. a kind of flame retardant glass fiber mesh according to claim 1 is characterized in that: described dispersant is Sodium Polyacrylate, Negel, sulfosuccinic acid double tridecyl ester sodium or several mixtures.
6. a kind of flame retardant glass fiber mesh according to claim 1 is characterized in that: the bake out temperature of described fire retardant glue screen cloth is 80-122 ℃, and the time of staying of screen cloth in baking oven was less than 150 seconds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101783633A CN101696549B (en) | 2009-11-12 | 2009-11-12 | Flame retardant glass fiber mesh |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101783633A CN101696549B (en) | 2009-11-12 | 2009-11-12 | Flame retardant glass fiber mesh |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101696549A true CN101696549A (en) | 2010-04-21 |
| CN101696549B CN101696549B (en) | 2011-10-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101783633A Active CN101696549B (en) | 2009-11-12 | 2009-11-12 | Flame retardant glass fiber mesh |
Country Status (1)
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| CN (1) | CN101696549B (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102392356A (en) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
| CN102603959A (en) * | 2012-02-17 | 2012-07-25 | 河北华强科技开发有限公司 | Preparation method of modified coating agent for glass fiber mesh cloth |
| CN103669005A (en) * | 2013-11-30 | 2014-03-26 | 山东永泰化工有限公司 | Alkali-resistant glass fiber gridding cloth coating and preparation method thereof |
| CN104328579A (en) * | 2014-08-27 | 2015-02-04 | 安徽丹凤电子材料股份有限公司 | Preparation process of glass fiber cloth |
| CN104388017A (en) * | 2014-12-12 | 2015-03-04 | 江苏天宇纤维有限公司 | Novel glass fiber net grid and shaping glue thereof |
| CN104404767A (en) * | 2014-12-12 | 2015-03-11 | 江苏天宇纤维有限公司 | Flame-retardant fiberglass mesh grid and sizing adhesive thereof |
| CN104404768A (en) * | 2014-12-12 | 2015-03-11 | 江苏天宇纤维有限公司 | Flame-retardant fiberglass mesh grid and sizing adhesive thereof |
| CN104499285A (en) * | 2014-12-12 | 2015-04-08 | 江苏天宇纤维有限公司 | Environmental-friendly flame-retardant glass fiber mesh grid and sizing glue thereof |
| CN104603342A (en) * | 2013-08-30 | 2015-05-06 | 耀亿工业股份有限公司 | Fire-retardant flexible mesh structure and manufacturing method thereof |
| CN105734995A (en) * | 2016-04-05 | 2016-07-06 | 常熟江南玻璃纤维有限公司 | Preparation method of high-performance fire blanket |
| CN106381718A (en) * | 2016-08-30 | 2017-02-08 | 海宁杰特玻纤布业有限公司 | Preparation method of eco-friendly glass fiber wall cloth |
| CN106757503A (en) * | 2016-12-10 | 2017-05-31 | 钦州学院 | A kind of fire resistance fibre new material and preparation method thereof |
| CN106957569A (en) * | 2017-03-29 | 2017-07-18 | 崔玉香 | A kind of negative oxygen liquid wall clothing and preparation method thereof |
| CN108997948A (en) * | 2018-06-08 | 2018-12-14 | 浙江青龙胶带有限公司 | A kind of glass cloth silica gel electric adhesive tape and its production technology |
| CN109097871A (en) * | 2018-06-21 | 2018-12-28 | 北京点域科技有限公司 | A method of fire retardant is prepared using glass fibre |
| RU191148U1 (en) * | 2017-03-22 | 2019-07-25 | Александр Владимирович Печников | GLASS FIBER NONWOVEN |
| CN111648133A (en) * | 2020-06-02 | 2020-09-11 | 北京建筑材料科学研究总院有限公司 | Alkali-resistant flame-retardant waterproof air-permeable agent and film for building with ultra-low energy consumption and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1098125A (en) * | 1993-07-30 | 1995-02-01 | 上船太仓甲板敷料厂 | Thin light deck dressing |
| CN1301766C (en) * | 2003-06-19 | 2007-02-28 | 公安部四川消防研究所 | Back-fire relief bag |
| US20060083878A1 (en) * | 2004-10-20 | 2006-04-20 | Bauman Bernard D | Fire-resistant plastic tanks and containers |
| CN101307633A (en) * | 2008-07-16 | 2008-11-19 | 王晓东 | Heat insulation decoration integrated brick and method of manufacture |
| CN101343837B (en) * | 2008-07-29 | 2013-01-02 | 邱晓健 | Environmental protection fire-resistant screen cloth |
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2009
- 2009-11-12 CN CN2009101783633A patent/CN101696549B/en active Active
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102392356B (en) * | 2011-07-07 | 2013-07-10 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
| CN102392356A (en) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
| CN102603959A (en) * | 2012-02-17 | 2012-07-25 | 河北华强科技开发有限公司 | Preparation method of modified coating agent for glass fiber mesh cloth |
| CN102603959B (en) * | 2012-02-17 | 2014-05-07 | 河北华强科技开发有限公司 | Preparation method of modified coating agent for glass fiber mesh cloth |
| CN104603342A (en) * | 2013-08-30 | 2015-05-06 | 耀亿工业股份有限公司 | Fire-retardant flexible mesh structure and manufacturing method thereof |
| CN103669005A (en) * | 2013-11-30 | 2014-03-26 | 山东永泰化工有限公司 | Alkali-resistant glass fiber gridding cloth coating and preparation method thereof |
| CN103669005B (en) * | 2013-11-30 | 2016-09-07 | 山东永泰化工有限公司 | A kind of alkali-proof glass fiber mesh coating and preparation method thereof |
| CN104328579A (en) * | 2014-08-27 | 2015-02-04 | 安徽丹凤电子材料股份有限公司 | Preparation process of glass fiber cloth |
| CN104499285A (en) * | 2014-12-12 | 2015-04-08 | 江苏天宇纤维有限公司 | Environmental-friendly flame-retardant glass fiber mesh grid and sizing glue thereof |
| CN104404767A (en) * | 2014-12-12 | 2015-03-11 | 江苏天宇纤维有限公司 | Flame-retardant fiberglass mesh grid and sizing adhesive thereof |
| CN104388017A (en) * | 2014-12-12 | 2015-03-04 | 江苏天宇纤维有限公司 | Novel glass fiber net grid and shaping glue thereof |
| CN104404768A (en) * | 2014-12-12 | 2015-03-11 | 江苏天宇纤维有限公司 | Flame-retardant fiberglass mesh grid and sizing adhesive thereof |
| CN105734995A (en) * | 2016-04-05 | 2016-07-06 | 常熟江南玻璃纤维有限公司 | Preparation method of high-performance fire blanket |
| CN106381718B (en) * | 2016-08-30 | 2018-11-06 | 海宁杰特玻纤布业有限公司 | A kind of preparation method of environmental-friendly glass fiber wall paper |
| CN106381718A (en) * | 2016-08-30 | 2017-02-08 | 海宁杰特玻纤布业有限公司 | Preparation method of eco-friendly glass fiber wall cloth |
| CN106757503A (en) * | 2016-12-10 | 2017-05-31 | 钦州学院 | A kind of fire resistance fibre new material and preparation method thereof |
| RU191148U1 (en) * | 2017-03-22 | 2019-07-25 | Александр Владимирович Печников | GLASS FIBER NONWOVEN |
| CN106957569A (en) * | 2017-03-29 | 2017-07-18 | 崔玉香 | A kind of negative oxygen liquid wall clothing and preparation method thereof |
| CN108997948A (en) * | 2018-06-08 | 2018-12-14 | 浙江青龙胶带有限公司 | A kind of glass cloth silica gel electric adhesive tape and its production technology |
| CN109097871A (en) * | 2018-06-21 | 2018-12-28 | 北京点域科技有限公司 | A method of fire retardant is prepared using glass fibre |
| CN111648133A (en) * | 2020-06-02 | 2020-09-11 | 北京建筑材料科学研究总院有限公司 | Alkali-resistant flame-retardant waterproof air-permeable agent and film for building with ultra-low energy consumption and preparation method thereof |
| CN111648133B (en) * | 2020-06-02 | 2021-06-25 | 北京建筑材料科学研究总院有限公司 | Alkali-resistant flame-retardant waterproof air-permeable agent and film for building with ultra-low energy consumption and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN101696549B (en) | 2011-10-05 |
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