CN106381117A - Double-ingredient epoxy seam beautifying glue - Google Patents

Double-ingredient epoxy seam beautifying glue Download PDF

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Publication number
CN106381117A
CN106381117A CN201610947810.7A CN201610947810A CN106381117A CN 106381117 A CN106381117 A CN 106381117A CN 201610947810 A CN201610947810 A CN 201610947810A CN 106381117 A CN106381117 A CN 106381117A
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CN
China
Prior art keywords
component
percent
epoxy
ingredient
seam glue
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201610947810.7A
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Chinese (zh)
Inventor
吴玉昆
李程
吴子刚
闫静
王晓彤
段亚冲
赵苗
邵凯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanyou Tianjin Macromolecular Techonoloy Co Ltd
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Sanyou Tianjin Macromolecular Techonoloy Co Ltd
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Priority to CN201610947810.7A priority Critical patent/CN106381117A/en
Publication of CN106381117A publication Critical patent/CN106381117A/en
Withdrawn legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J163/00—Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02—Organic and inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/05—Alcohols; Metal alcoholates
    • C08K5/053—Polyhydroxylic alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08—Macromolecular additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K

Abstract

The invention relates to seam beautifying glue, in particular to double-ingredient epoxy seam beautifying glue. An ingredient A is prepared from the following ingredients in percentage by weight: 60 to 90 percent of epoxy resin, 0 to 30 percent of plasticizers, 0 to 3 percent of anti-freezing agents, 0 to 15 percent of glitter powder, 1 to 10 percent of thixotropic agents, 0.01 to 1 percent of antifoaming agents and 0 to 20 percent of filling materials; an ingredient B is prepared from the following ingredients in percentage by mass: 65 to 95 percent of curing agents, 1 to 20 percent of thixotropic agents, 0 to 30 percent of plasticizers and 0 to 15 percent of glitter powder. The ingredient A and the ingreeinet B are respectively packaged after the preparation; the ingredient A and the ingredient B can be used after being uniformly mixed according to the weight ratio of 1:1. The construction operation is convenient; the advantages of safety, non-toxicity, wear resistance, waterproof performance, mildewproof performance, stain prevention, chemical medicine resistance, anti-cracking performance, fine crack resistance, yellowing resistance, rich color and the like are realized; the seam beautifying glue can be used as the seam beautifying glue by replacing the existing cement and can be used for performing color matching on ceramic tiles in different colors so as to achieve the decoration effect.

Description

A kind of two component epoxy U.S. seam glue
Technical field
The invention belongs to the technical field of building chemical material, it is related to a kind of U.S. seam glue, more particularly to a kind of double-component Epoxy U.S. seam glue is it is adaptable to the joint fillings such as mosaic or ceramic tile and decoration.
Background technology
With social development, various New Building Materials emerge in an endless stream, and ceramic tile has become China ground and wall decoration One of principal item of material, range of application is more and more wider.At present, between ceramic tile and ceramic tile, the most frequently used packing material in gap is water Mud base ceramic tile U.S. seam glue.But, the ceramic tile U.S. seam easy moisture absorption of glue of cement base, infiltration, accumulate dust and dirt, stain resistance is not Well, substantially all there is accumulation of salt in the surface soil phenomenon, it is attractive in appearance that impact is decorated in easy breed bacteria and mould.U.S. seam glue based on epoxy resin Problem above can thoroughly be solved, do not have accumulation of salt in the surface soil phenomenon, easy construction, cold curing, resistant, scrubbing resistance.
Chinese patent CN 102674751 A and CN 102992715 B describe two kinds of bi-component epoxies U.S. seam glue and its Preparation method, safe efficient, have no side effect, but U.S. component A of seam glue and the weight of component B are than being all not reaching to 1:1, apply Work is not convenient.
Content of the invention
In order to solve the above-mentioned problems in the prior art, the invention provides a kind of bi-component epoxy U.S. seam glue, make Substitute the material of cement for the joint filling between mosaic or ceramic tile, there is A, B component by weight 1:1 mixes and can use Feature, safe efficient, have no side effect, easy construction.
The present invention for achieving the above object, be employed technical scheme comprise that：A kind of bi-component epoxy U.S. seam glue, including A group Point and B component it is characterised in that wherein component A, consist of the following composition by weight percentage：
Epoxy resin 60-90%,
Plasticizer 0-30%,
Antifreezing agent 0-3%,
Glitter powder 0-15%,
Thixotropic agent 1-10%,
Defoamer 0.01-1%,
Filler 0-20%；
B component, consists of the following composition by mass percentage：
Curing agent 65-95%,
Thixotropic agent 1-20%,
Plasticizer 0-30%,
Glitter powder 0-15%.
Beneficial effects of the present invention are：After a kind of bi-component epoxy of the present invention U.S. seam glue, component A and B component preparation and Pack respectively.By A, B component by weight 1:1 mixes and can use, and constructing operation is convenient.And there is safety non-toxic, resistance to The advantages of mill, waterproof, mould proof, antifouling, anti-chemical medicine, crack resistence, anti-microgroove, color inhibition, various colors, both can replace existing Some cement, with helping seam glue, can be matched colors to the ceramic tile of different colours again, realizes the effect of decoration.
Specific embodiment
A kind of bi-component epoxy U.S. seam glue of the present invention and preparation method thereof is given by below example, but is not limited to This embodiment.
A kind of bi-component epoxy U.S. seam glue, including component A and B component, wherein component A, by weight percentage by following one-tenth It is grouped into：
Epoxy resin 60-90%,
Plasticizer 0-30%,
Antifreezing agent 0-3%,
Glitter powder 0-15%,
Thixotropic agent 1-10%,
Defoamer 0.01-1%,
Filler 0-20%.
B component, consists of the following composition by mass percentage：
Curing agent 65-95%,
Thixotropic agent 1-20%,
Plasticizer 0-30%,
Glitter powder 0-15%.
Pack after component A and B component preparation and respectively.
Preferably, epoxy resin be bisphenol A type epoxy resin, bisphenol f type epoxy resin, in modified epoxy at least A kind of.
Preferably, plasticizer be dioctyl phthalate, at least one in dibutyl phthalate.
Preferably, antifreezing agent be ethylene glycol, at least one in propane diols.
Preferably, defoamer be mineral oil defoaming agent, at least one in silicone defoamer.
Preferably, filler be powdered whiting, precipitated calcium carbonate, nano-calcium carbonate, silica flour, talcum powder, titanium dioxide, heavy At least one in the barium sulfate of shallow lake.
Preferably, curing agent be modified polysulfide alcohol, at least one in modified aliphatic cyclic amine, modified fatty amine.
Preferably, thixotropic agent is at least in aerosil, organobentonite, polyamide wax or rilanit special Kind.
During use, by A, B component by weight 1:1 mixes and can use.
Embodiment 1：
Glue component A is stitched by U.S.：59.95% bisphenol A epoxide resin E44,30% dioctyl phthalate, 1% second two Alcohol, 9% aerosil, 0.05% defoamer.
Glue B component is stitched by U.S.：The glitter powder of 65% curing agent, 20% aerosil and 15%.
Embodiment 2：
Glue component A is stitched by U.S.：84.99% bisphenol A epoxide resin E44,4% dibutyl phthalate, 1% glycerine, 10% aerosil, 0.01% defoamer.Glue B component is stitched by U.S.：85% curing agent, 5% aerosil With 10% glitter powder.
Embodiment 3：
Glue component A is stitched by U.S.：84.99% bisphenol A epoxide resin E44,4% dioctyl phthalate, 1% ethylene glycol, 10% aerosil, 0.01% defoamer.Glue B component is stitched by U.S.：85% curing agent, 5% aerosil With 10% glitter powder.
Embodiment 4:
Glue component A is stitched by U.S.：77% bisphenol A epoxide resin E44,9% dioctyl phthalate, 3% glycerine, 5% Glitter powder, 5% aerosil, 1% defoamer.
Glue B component is stitched by U.S.：The dioctyl phthalate of 77% curing agent, 10% aerosil and 13%.
Embodiment 5:
Glue component A is stitched by U.S.：61.95% bisphenol A epoxide resin E51,15% dioctyl phthalate, 1% second two Alcohol, 10% glitter powder, 2% aerosil, 0.05% defoamer, 10% nano-calcium carbonate.
Glue B component is stitched by U.S.：The dioctyl phthalate of 62% curing agent, 18% aerosil and 20%.
Embodiment 6:
Glue component A is stitched by U.S.：60% bisphenol A epoxide resin E51,1% ethylene glycol, 13% glitter powder, 5% gas phase dioxy SiClx, 1% defoamer, 20% nano-calcium carbonate.
Glue B component is stitched by U.S.：The dioctyl phthalate of 60% curing agent, 10% aerosil and 30%.

Claims (8)

1. a kind of bi-component epoxy U.S. seam glue, including component A and B component it is characterised in that wherein component A, by weight percentage Consist of the following composition：
Epoxy resin 60-90%,
Plasticizer 0-30%,
Antifreezing agent 0-3%,
Glitter powder 0-15%,
Thixotropic agent 1-10%,
Defoamer 0.01-1%,
Filler 0-20%；
B component, consists of the following composition by mass percentage：
Curing agent 65-95%,
Thixotropic agent 1-20%,
Plasticizer 0-30%,
Glitter powder 0-15%.
2. a kind of bi-component epoxy U.S. seam glue according to claim 1 is it is characterised in that described epoxy resin is bisphenol-A At least one in type epoxy resin, bisphenol f type epoxy resin, modified epoxy.
3. a kind of bi-component epoxy U.S. seam glue according to claim 1 is it is characterised in that described plasticizer is O-phthalic At least one in dioctyl phthalate, dibutyl phthalate.
4. bi-component epoxy according to claim 1 U.S. seam glue it is characterised in that described antifreezing agent be ethylene glycol, the third two At least one in alcohol.
5. a kind of bi-component epoxy U.S. seam glue according to claim 1 is it is characterised in that defoamer is mineral oils froth breaking At least one in agent, silicone defoamer.
6. a kind of bi-component epoxy U.S. seam glue according to claim 1 is it is characterised in that described thixotropic agent is gas phase dioxy At least one in SiClx, organobentonite, polyamide wax or rilanit special.
7. a kind of bi-component epoxy U.S. seam glue according to claim 1 is it is characterised in that described filler is heavy carbonic acid At least one in calcium, precipitated calcium carbonate, silica flour, talcum powder, titanium dioxide, blanc fixe.
8. a kind of bi-component epoxy U.S. seam glue according to claim 1 is it is characterised in that described curing agent is modified polysulfide At least one in alcohol, modified aliphatic cyclic amine, modified fatty amine.
CN201610947810.7A 2016-10-26 2016-10-26 Double-ingredient epoxy seam beautifying glue Withdrawn CN106381117A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109796920A (en) * 2019-01-30 2019-05-24 派丽(上海)管理有限公司 A kind of detection method of water-whitening resistance U.S. porcelain cement and its performance
CN109868103A (en) * 2019-01-30 2019-06-11 派丽(上海)管理有限公司 A kind of detection method of sag resistance U.S. porcelain cement and its performance
CN110408171A (en) * 2018-04-26 2019-11-05 江苏飞锦毅科技有限公司 A kind of two-component negative oxygen ion joint trimming agent and preparation method thereof
CN110964443A (en) * 2018-09-29 2020-04-07 山东齐辰新型建材有限公司 Low-cost system crack beautifying agent for ceramic tile crack beautifying curing agent
CN112459527A (en) * 2020-12-03 2021-03-09 安徽墨砂工程修缮技术有限公司 Brick-smashing-free toilet leakage repairing method
CN112680155A (en) * 2020-12-22 2021-04-20 孟运杰 Real porcelain glue crack beautifying agent
CN114656910A (en) * 2022-03-22 2022-06-24 湖南浩森胶业有限公司 Low-cost durable epoxy seam beautifying agent
CN114702928A (en) * 2022-03-22 2022-07-05 湖南浩森胶业有限公司 Bi-component epoxy seam beautifying agent based on automatic sealing cover
CN114736637A (en) * 2022-03-22 2022-07-12 湖南浩森胶业有限公司 Environment-friendly weather-resistant epoxy seam beautifying agent
CN114752330A (en) * 2022-03-22 2022-07-15 湖南浩森胶业有限公司 Waterproof economical double-component epoxy crack sealer

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110408171A (en) * 2018-04-26 2019-11-05 江苏飞锦毅科技有限公司 A kind of two-component negative oxygen ion joint trimming agent and preparation method thereof
CN110964443A (en) * 2018-09-29 2020-04-07 山东齐辰新型建材有限公司 Low-cost system crack beautifying agent for ceramic tile crack beautifying curing agent
CN109796920A (en) * 2019-01-30 2019-05-24 派丽(上海)管理有限公司 A kind of detection method of water-whitening resistance U.S. porcelain cement and its performance
CN109868103A (en) * 2019-01-30 2019-06-11 派丽(上海)管理有限公司 A kind of detection method of sag resistance U.S. porcelain cement and its performance
CN112459527A (en) * 2020-12-03 2021-03-09 安徽墨砂工程修缮技术有限公司 Brick-smashing-free toilet leakage repairing method
CN112680155A (en) * 2020-12-22 2021-04-20 孟运杰 Real porcelain glue crack beautifying agent
CN114656910A (en) * 2022-03-22 2022-06-24 湖南浩森胶业有限公司 Low-cost durable epoxy seam beautifying agent
CN114702928A (en) * 2022-03-22 2022-07-05 湖南浩森胶业有限公司 Bi-component epoxy seam beautifying agent based on automatic sealing cover
CN114736637A (en) * 2022-03-22 2022-07-12 湖南浩森胶业有限公司 Environment-friendly weather-resistant epoxy seam beautifying agent
CN114752330A (en) * 2022-03-22 2022-07-15 湖南浩森胶业有限公司 Waterproof economical double-component epoxy crack sealer

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