CN106380933A - Printable waterborne polyurethane 3D golden oil or 3D ink - Google Patents
Printable waterborne polyurethane 3D golden oil or 3D ink Download PDFInfo
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- CN106380933A CN106380933A CN201610724782.2A CN201610724782A CN106380933A CN 106380933 A CN106380933 A CN 106380933A CN 201610724782 A CN201610724782 A CN 201610724782A CN 106380933 A CN106380933 A CN 106380933A
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- ink
- aqueous polyurethane
- printable
- polishes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses a printable waterborne polyurethane 3D golden oil or 3D ink. The 3D golden oil or 3D ink mainly includes the following components by mass percentage: waterborne polyurethane with film hardness of 65A-75A, a wetting agent, a slow drying agent, an anti-permeability agent, a leveling agent, a defoaming agent, a coupling agent, a pH regulator, a bactericide, deionized water, a color paste, and a thickening agent, etc. The golden oil or ink can be prepared into a coating on a textile surface directly through printing, the prepared coating has the advantages of strong stereo feel, good glossiness, easy stacking, no subsidence, soft handfeel, low temperature resistance, and good firmness, etc., and solves the problems of ink spreading, no blotting, cracking and other problems in existing printing ink.
Description
Technical field
The present invention relates to a kind of water color ink, particularly to a kind of printable aqueous polyurethane 3D polishes or 3D ink,
Belong to pad-ink technical field.
Background technology
Water color ink is made up of aqueous high molecular resin, pigment, water and cosolvent etc., and wherein water-based polyurethane ink is with it
The advantages of good wearability, adhesive force, solvent resistant, flexibility, heat resistance, simultaneously water color ink have safe and nontoxic harmless,
Do not fire not quick-fried, produce almost without VOC, improve the security of operating environment.Just constantly improve and open
Open up the field that is increasingly widely applied, the development and application of particularly suitable weaving and footwear material industry.The aqueous three-dimensional employing of tradition
Slab printing processing, needs the half tone of cooperation specialty, printing ink color matching is complicated, operation technological requirement is high, time-consuming；In the face of fierce city
Competition, social environment consciousness constantly strengthens, high cost, high energy consumption, pollution environment, or even the exceeded product of venomous injurant is
Do not adapt to the needs of social development, be eliminated out market the most at last.
Aqueous polyurethane 3D ink is generally divided into colored ink and 3D polishes, and 3D polishes is transparent no any covering
Power, its firmness is good, for bottoming.Colored ink passes through computerized color matching, is printed upon 3D polishes, is not required to make half tone, by adjusting
Whole printing device can be with different pattern and effect.Versatility is wide, bright in luster have flexibility, color of can arbitrarily mixing colours, vision is imitated
Really good, there is no restricted performance characteristic effect.Can follow one's bent what design was wanted oneself.Produce aqueous vertical slab rubber cement at present
Based on acrylic emulsion and polyvinyl acetate (VAE) emulsion, because technical requirements threshold height is different, production technology is simplified and traditional
Differ, the quality causing a lot of rubber cements on the market is uneven, aqueous slab rubber cement generally existing Boardy Feeling, poor flexibility, easily
After-tacking, poor heat resistance, cold short hot sticky, resist bending is bad, resistance to water wash water firmness is poor simultaneously, gambling the shortcomings of net, thus limiting
Range of application starched by slab, brings technical barrier to numerous footwear materials and textile industry producer.In sum, current water color ink
It is all serigraphy, before printing, half tone complex manufacturing technology, take, need to put into a large amount of man power and materials；Meanwhile, at present
Aqueous can be with water-borne acrylic resin as carrier with pad-ink, brittle cracking, poor adhesive force, not wear-resisting, fade, intolerant to
Washing.
Content of the invention
The defect existing for existing pad-ink, the purpose of the present invention is to be to provide one kind can directly pass through to beat
In the aqueous polyurethane 3D polishes of textile surface prepares coating or 3D ink, it is strong that the coating of preparation has a third dimension to India side formula,
Glossiness is good, easily stacking, do not sink, soft, low temperature resistant, the advantages of firmness is good, solves existing pad-ink and exist
Ink diffusion, not blotting, problems of crack.
In order to realize above-mentioned technical purpose, the invention provides a kind of printable aqueous polyurethane 3D polishes or 3D ink,
This 3D ink includes following mass percent component：Become the aqueous polyurethane 60%～94% that film hardness is 65A～75A；Moistening
Agent 0.2%～1%；Drying retardant 3%～5%；Impermeable dose 0.6%～2%；Levelling agent 0.2%～1%；Defoamer 0.5%～
2%；Coupling agent 1%～2%；PH adjusting agent≤0.5% (0～0.5%)；Bactericide≤0.5% (0～0.5%)；Deionized water
≤ 15% (0～15%)；Mill base≤30% (0～30%)；Thickener 0.5%～3%；Each component gross mass is 100%.
Preferably scheme, aqueous polyurethane includes Bayer DLS, Bayer DLU, ten thousand China 7396, this A539 of river, Opel enlightening
4101st, at least one in Ning Baidi PU470.
Preferably scheme, wetting agent includes cyanogen spy OT75, at least one in enlightening high WT500, BYK346, preferably moistening
Agent is passed through to balance dynamic and static surface tension, not only can strengthen wetting power but also can prevent excessive moistening from causing diffusion to dissipate
Oil.
Preferably scheme, drying retardant includes propane diols, Tao Shi PEG600, at least one in diethylene glycol (DEG).Preferably slow curing
Agent can effectively prevent drying from too fast blocking nozzle.
Preferably scheme, levelling agent includes BYKETOL-AQ and/or OMGLA50.
Preferably scheme, defoamer includes the composition of enlightening high 825 and aerochemistry DF-37.Preferably defoamer adopts
Suds effect and effect of breaking bubble combination, reach defoaming effect optimal, it is to avoid bubble, pit, lockhole produce.
Preferably scheme, impermeable dose includes DE Degussa A200, in day Bender mountain chemistry DM-10, black cat HM-200
At least one.Preferably impermeable dose, prevent pressure excessive, infiltration occurs.
Preferably scheme, coupling agent includes DOW CORNING 6040 and/or Japanese SHIN-ETSU HANTOTAI A-187.Preferably coupling agent increase is right
The adhesive force of base material, anti-delamination.
Preferably scheme, pH adjusting agent includes Tao Shi AMP-95.
Preferably scheme, bactericide includes Korea S SK PG521.
Preferably scheme, thickener includes the graceful PTF of Hensel, extra large river 3800, at least one in Ning Baidi PS166.Optimum
Choosing is using PTF and PU thickener (extra large river 3800) collocation using it is ensured that thickening effect and Self-leveling effect.PU thickener phase simultaneously
Capacitive is good.
Preferably scheme, mill base is Clariant aqueous color paste.
The concrete preparation technology of printable aqueous polyurethane 3D ink of the present invention comprises the following steps：
1st, after waterborne polyurethane resin being filtered, it is placed in high-speed stirred dispersion machine and is stirred, rotating speed is 300r/min,
Dispersion stirring 5min；
2nd, it is kept stirring for dispersion machine continuously stirred with 300r/min speed, add pH adjusting agent, deionized water and defoamer,
High-speed stirred dispersing speed is increased to 500～700r/min, dispersion stirring 5min；
3rd, maintain rotating speed constant, sequentially add wetting agent, drying retardant, levelling agent and coupling agent, after dispersion stirring 5min, slowly
Slowly add impermeable dose；
4th, after adding, high-speed stirred dispersing speed is increased to 800～1000r/min, adds bactericide, dispersion stirring
10min；
5th, after confirming to be uniformly dispersed, it is slowly added to thickener, after adding, dispersed with stirring rotating speed is increased to 1200～
1500r/min, disperses stirring 10～15min；
6th, after material dispersion is uniform, if making colored ink, high-speed stirred dispersing speed is reduced to 1000r/
Min, adds aqueous color paste, dispersion stirring 10min；
7th, after all materials are uniformly dispersed, drop to the slow-speed of revolution, stop stirring, filter, packaging, (if preparation 3D polishes, no
Operated with the 6th step).
Hinge structure, the Advantageous Effects that technical scheme is brought：The aqueous polyurethane 3D of the present invention
Polishes or 3D ink formulations it is critical only that employing a kind of special aqueous polyurethane is carrier, and this aqueous polyurethane film forming is hard
Spend relatively low (65A～75A), many experiments show into film hardness be higher than 75A or less than 65A aqueous polyurethane cannot meet will
Ask, using becoming aqueous polyurethane in the range of 65A～75A for the film hardness, have that flexibility is good, wear-resisting, adhesive force is good, water-fast
Wash, compatibility is good and other component between.On this basis, allocated suitable auxiliary agent into, such as wetting agent, drying retardant, impermeable
Agent, levelling agent, defoamer, thickener etc., each component synergy substantially, does not block up spray during making 3D polishes or 3D ink print
Mouth, and polishes or ink be difficult diffusion, absorbency good, do not ftracture.The coating third dimension of preparation is strong, and glossiness is good, easily stacks, no
It sink, soft, tortuous more than 150,000 times of normal temperature, low temperature resistant, subzero 15 DEG C of complications more than 80,000 times, dry and wet wipes color firmly 4
More than level, 60 DEG C of 5% buck washing 6h does not fall off, and does not fade, non-degradable.The ink of the present invention or polishes are adapted to various weavings
After product, the printing of footwear material requires.Additionally, the 3D polishes of the present invention or ink raw materials low cost, preparation method simple it is easy to industry
Metaplasia is produced.
Specific embodiment
Following examples are intended to further illustrate present invention, rather than the protection model limiting the claims in the present invention
Enclose.
Embodiment 1
Formula 1：Bayer DLS 45% and Wan Hua 7,396 40%；Tao Shi AMP95 0.2%；Deionized water 3.5%；Enlightening is high
825 0.3% and aerochemistry DF-37 0.5%；Cyanogen spy OT75 0.2% and Di Gao WET500 0.5%；Tao Shi PEG600
5%；OMGLA50 0.3%；DOW CORNING 6,040 1%；Day Bender mountain chemistry DM-10 1.5%；Korea S SK PG521 0.3%；
Extra large river 3,800 1.4% and the graceful PTF of Hensel 0.3%.
1st, after waterborne polyurethane resin Bayer DLS and Wan Hua 7396 being filtered, it is placed in high-speed stirred dispersion machine and is stirred
Mix, rotating speed is 300r/min, dispersion stirring 5min；
2nd, it is kept stirring for dispersion machine continuously stirred with 300r/min speed, add Tao Shi AMP95, deionized water, enlightening high by 825
With aerochemistry DF-37, high-speed stirred dispersing speed is increased to 600r/min, dispersion stirring 5min；
3rd, maintain rotating speed constant, sequentially add cyanogen spy OT75 and enlightening high WET500, Tao Shi PEG600, OMGLA50 and Dao Kang
Peaceful 6040, after dispersion stirring 5min, it is slowly added into a day Bender mountain chemistry DM-10；
4th, after adding, high-speed stirred dispersing speed is increased to 900r/min, adds Korea S SK PG521, dispersion stirring
10min；
5th, after confirming to be uniformly dispersed, it is slowly added to the graceful PTF of Hensel and extra large river 3800, after adding, by dispersed with stirring rotating speed liter
Up to 1300r/min, disperses stirring 10～15min；
6th, after all materials are uniformly dispersed, drop to the slow-speed of revolution, stop stirring, filter, packaging.
Embodiment 2
Formula 2：Bayer DLU 50% and Opel enlightening 4,101 38%；Tao Shi AMP95 0.2%；Deionized water 1.5%；Enlightening
High 825 0.5% and aerochemistry DF-37 0.5%；BYK346 0.6%；Propane diols 3.5%；OMGLA50 0.3%；Japan
SHIN-ETSU HANTOTAI A187 1.5%；DE Degussa A200 2%；Korea S SK PG5210.3%；Extra large river 3,800 0.6% and the graceful PTF of Hensel
0.5%.
Preparation process presses embodiment 1.
Embodiment 3
Formula 3：Bayer DLU 41% and this A539 of river 45%；Tao Shi AMP95 0.2%；Deionized water 2.5%；Enlightening is high
825 0.2% and aerochemistry DF-37 0.8%；Cyanogen spy OT75 0.2% and Di Gao WT500 0.5%；Tao Shi PEG600 3%
With diethylene glycol (DEG) 1%；BYKETOL-AQ 0.5%；DOW CORNING 6,040 2%；Day Bender mountain chemistry DM-10 1%；Korea S SK
PG521 0.3%；Extra large river 3,800 1.5% and the graceful PTF of Hensel 0.3%.
Preparation process presses embodiment 1.
Embodiment 4
Formula 4：Ning Baidi PU470 72%；Tao Shi AMP95 0.1%；Deionized water 0.5%；Enlightening is high 8250.2% gentle
Body chemistry DF-37 0.5%；BYK 0.3%；Diethylene glycol (DEG) 3%；OMGLA50 0.3%；Japanese SHIN-ETSU HANTOTAI A187 1.5%；Black cat
HM-200 1.2%；Korea S SK PG521 0.3%；Extra large river 3,800 1.5% and Ning Baidi PS166 0.6%；Red nano color
Slurry 18%.
1st, by after waterborne polyurethane resin Ning Baidi PU470 filtration, it is placed in high-speed stirred dispersion machine and is stirred, rotating speed
For 300r/min, dispersion stirring 5min；
2nd, it is kept stirring for dispersion machine continuously stirred with 300r/min speed, add Tao Shi AMP95, deionized water and enlightening high
825 and aerochemistry DF-37, high-speed stirred dispersing speed is increased to 600r/min, dispersion stirring 5min；
3rd, maintain rotating speed constant, sequentially add BYK, diethylene glycol (DEG), OMGLA50 and Japanese SHIN-ETSU HANTOTAI A187, dispersion stirring 5min
Afterwards, it is slowly added into black cat HM-200；
4th, after adding, high-speed stirred dispersing speed is increased to 900r/min, adds Korea S SK PG521, dispersion stirring
10min；
5th, after confirming to be uniformly dispersed, it is slowly added to extra large river 3800 and Ning Baidi PS166, after adding, by dispersed with stirring rotating speed
It is increased to 1200～1500r/min, disperse stirring 10～15min；
6th, after material dispersion is uniform, high-speed stirred dispersing speed is reduced to 1000r/min, adds red nano color
Slurry, dispersion stirring 10min；
7th, after all materials are uniformly dispersed, drop to the slow-speed of revolution, stop stirring, filter, packaging.
Embodiment 1～3 be obtained the white thick liquid of 3D polishes, embodiment 4 preparation colored ink take on a red color, outward appearance with
Mill base is homochromy, and the pH value of each product is 7.0～9.0, without formaldehyde and APEO.Through lot of experiment validation：For footwear material and spinning
Nozzle is not blocked up in the processing of fabric coating, and ink is difficult to disperse, and absorbency is good；On fabric, the coating third dimension of preparation is strong, glossiness
Good, easily stacking, do not sink, soft, tortuous more than 150,000 times of normal temperature, low temperature resistant, subzero 15 DEG C of complications more than 80,000 times, do
Firmly more than 4 grades, 60 DEG C of 5% buck washing 6h does not fall off wet rubbing color, does not fade, non-degradable.
Claims (9)
1. a kind of printable aqueous polyurethane 3D polishes or 3D ink it is characterised in that：Including following mass percent component：
Each component gross mass is 100%.
2. printable aqueous polyurethane 3D polishes according to claim 1 or 3D ink it is characterised in that：
Described aqueous polyurethane includes Bayer DLS, Bayer DLU, ten thousand China 7396, this A539 of river, Opel enlightening 4101, Ning Baidi
At least one in PU470.
3. printable aqueous polyurethane 3D polishes according to claim 1 or 3D ink it is characterised in that：
Described wetting agent includes cyanogen spy OT75, at least one in enlightening high WT500, BYK346.
4. printable aqueous polyurethane 3D polishes according to claim 1 or 3D ink it is characterised in that：
Described drying retardant includes propane diols, Tao Shi PEG600, at least one in diethylene glycol (DEG).
5. printable aqueous polyurethane 3D polishes according to claim 1 or 3D ink it is characterised in that：
Described levelling agent includes BYKETOL-AQ and/or OMGLA50.
6. printable aqueous polyurethane 3D polishes according to claim 1 or 3D ink it is characterised in that：
Described defoamer includes the composition of enlightening high 825 and aerochemistry DF-37.
7. printable aqueous polyurethane 3D polishes according to claim 1 or 3D ink it is characterised in that：
At least one in described impermeable dose of inclusion DE Degussa A200, day Bender mountain chemistry DM-10, black cat HM-200.
8. printable aqueous polyurethane 3D polishes according to claim 1 or 3D ink it is characterised in that：
Described coupling agent includes DOW CORNING 6040 and/or Japanese SHIN-ETSU HANTOTAI A-187.
9. printable aqueous polyurethane 3D polishes according to claim 1 or 3D ink it is characterised in that：
Described pH adjusting agent includes Tao Shi AMP-95；
Described bactericide includes Korea S SK PG521；
Described thickener includes the graceful PTF of Hensel, extra large river 3800, at least one in Ning Baidi PS166.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610724782.2A CN106380933B (en) | 2016-08-25 | 2016-08-25 | A kind of printable aqueous polyurethane 3D polishes or 3D ink |
| CN201810147939.9A CN108384318B (en) | 2016-08-25 | 2016-08-25 | Printable waterborne polyurethane 3D gold oil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610724782.2A CN106380933B (en) | 2016-08-25 | 2016-08-25 | A kind of printable aqueous polyurethane 3D polishes or 3D ink |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810147939.9A Division CN108384318B (en) | 2016-08-25 | 2016-08-25 | Printable waterborne polyurethane 3D gold oil |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106380933A true CN106380933A (en) | 2017-02-08 |
| CN106380933B CN106380933B (en) | 2018-06-29 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610724782.2A Expired - Fee Related CN106380933B (en) | 2016-08-25 | 2016-08-25 | A kind of printable aqueous polyurethane 3D polishes or 3D ink |
| CN201810147939.9A Active CN108384318B (en) | 2016-08-25 | 2016-08-25 | Printable waterborne polyurethane 3D gold oil |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810147939.9A Active CN108384318B (en) | 2016-08-25 | 2016-08-25 | Printable waterborne polyurethane 3D gold oil |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107057028A (en) * | 2017-02-20 | 2017-08-18 | 深圳凯奇化工有限公司 | A kind of water nano height covers 3D printing coating and preparation method thereof |
| CN108978284A (en) * | 2018-08-01 | 2018-12-11 | 东莞市海亚印花材料有限公司 | A method of the spray printing fastness of ink in enhancing ink-jet digit printing |
| CN109266095A (en) * | 2018-09-25 | 2019-01-25 | 惠州市彩森环保涂料有限公司 | The aqueous 3D ink of Environmental protection net cloth silk-screen and its preparation process |
| CN111909567A (en) * | 2020-08-12 | 2020-11-10 | 福建华峰运动用品科技有限公司 | Water-based UV (ultraviolet) curing ink, preparation method and 3D (three-dimensional) pattern fabric using ink |
| CN114085328A (en) * | 2021-08-10 | 2022-02-25 | 珠海市三绿实业有限公司 | Washable LCD type 3D printing photosensitive resin and preparation method thereof |
| CN115678372A (en) * | 2022-10-14 | 2023-02-03 | 江西易必居新型建材有限公司 | Novel colorful stone-like paint and preparation method thereof |
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| TR201811584A2 (en) * | 2018-08-09 | 2018-08-27 | Oez Anadolu Kimya Sanayi Ve Ticaret Anonim Sirketi | INNOVATION IN 3D PRINTINGS USED IN TEXTILE |
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| CN105482549A (en) * | 2016-01-20 | 2016-04-13 | 江西统百利彩印包装股份有限公司 | Environment-friendly, sun-resistant and wear-proof water-based ink and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107057028A (en) * | 2017-02-20 | 2017-08-18 | 深圳凯奇化工有限公司 | A kind of water nano height covers 3D printing coating and preparation method thereof |
| CN108978284A (en) * | 2018-08-01 | 2018-12-11 | 东莞市海亚印花材料有限公司 | A method of the spray printing fastness of ink in enhancing ink-jet digit printing |
| CN109266095A (en) * | 2018-09-25 | 2019-01-25 | 惠州市彩森环保涂料有限公司 | The aqueous 3D ink of Environmental protection net cloth silk-screen and its preparation process |
| CN111909567A (en) * | 2020-08-12 | 2020-11-10 | 福建华峰运动用品科技有限公司 | Water-based UV (ultraviolet) curing ink, preparation method and 3D (three-dimensional) pattern fabric using ink |
| CN114085328A (en) * | 2021-08-10 | 2022-02-25 | 珠海市三绿实业有限公司 | Washable LCD type 3D printing photosensitive resin and preparation method thereof |
| CN115678372A (en) * | 2022-10-14 | 2023-02-03 | 江西易必居新型建材有限公司 | Novel colorful stone-like paint and preparation method thereof |
| CN116426159A (en) * | 2023-03-17 | 2023-07-14 | 陈伟忠 | High-elasticity printing ink for vamp and preparation and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106380933B (en) | 2018-06-29 |
| CN108384318A (en) | 2018-08-10 |
| CN108384318B (en) | 2021-02-02 |
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Effective date of registration: 20190411 Address after: 415900 Five Groups of Qizui Residential Committee of Longyang Town, Hanshou County, Hunan Province Patentee after: Xu Lixin Address before: 415000 Jinfeng Road, Huangfu Residential Committee, Hanshou Economic Development Zone, Changde City, Hunan Province (west side of Taitong Template Company) Patentee before: HUNAN XINLIHUA NANO TECHNOLOGY CO., LTD. |
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