CN105734955A - Inkjet printing coating of textile - Google Patents
Inkjet printing coating of textile Download PDFInfo
- Publication number
- CN105734955A CN105734955A CN201610281620.6A CN201610281620A CN105734955A CN 105734955 A CN105734955 A CN 105734955A CN 201610281620 A CN201610281620 A CN 201610281620A CN 105734955 A CN105734955 A CN 105734955A
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- China
- Prior art keywords
- inkjet printing
- printing coating
- parts
- textile
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/73—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
- D06M11/76—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/35—Heterocyclic compounds
- D06M13/352—Heterocyclic compounds having five-membered heterocyclic rings
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Abstract
The invention discloses an inkjet printing coating of a textile. The printing coating is prepared from the following components in parts by weight: 1-10 parts of aqueous silicon dioxide, 1-5 parts of a softening agent, 0.1-5 parts of a fungicide, 0.1-5 parts of an inhibitor, 1-5 parts of a wetting agent, 70-90 parts of water, 5-15 parts of aqueous polyurethane, 1-10 parts of a cross-linking agent and 1-10 parts of a solvent. The inkjet printing coating of the textile is prepared by the following steps: adding components except the aqueous polyurethane and the cross-linking agent into a material machine in sequence, and stirring at the speed of 500r/min for 20min until the components are uniformly mixed; adding the aqueous polyurethane and the cross-linking agent and stirring at the speed of 500r/min for 20min; and finally, filtering with a filter membrane with the size of 5 microns. The coating has firm bonding firmness with base cloth; the color fastness and the color brightness of dyeing ink on the base cloth are improved; and the textile printed by the coating has a soft hand feeling and strong air permeability, is environmentally friendly and has no harms to human bodies.
Description
Technical field
The present invention relates to auxiliaries for textile dyeing and printing technical field, be specifically related to a kind of textile inkjet printing coating.
Background technology
In recent years, the application of digital printing technologies is more and more extensive, and printing in textiles also faces opportunities and challenges,
Digital ink-jet fabric stamp is exactly the dyeing and finishing technology of a kind of innovation, it have precision high, fast, the most
The features such as change, rich personalization, and not desizing, environmental protection.The realization of this technique be unable to do without textile and is coated with
The provided good stamp medium of layer.Along with the environmental consciousness with people of improving of environmental regulation constantly strengthens,
High-performance, aqueous pigment ink nuisanceless, province's energy are increasingly subject to people's attention, aqueous pigment ink
Water is widely used in cotton, fiber crops, silk, hair and synthesis.Similarly, along with aqueous pigment ink
Extensive application, people are more and more higher to the requirement of fabric coating.But current existing fabric coating
The feature of environmental protection of obtained textile is poor, feel is poor, poor air permeability.
Summary of the invention
In order to overcome the deficiencies in the prior art, it is an object of the invention to provide a kind of textile inkjet printing and be coated with
Layer, this coating and base fabric have good binding strength, raising dye ink bright in color fastness and the color of base fabric
Degree, the textile touch using this coating stamp is soft, breathability strong, environmental protection, harmless.
For solving the problems referred to above, the technical solution adopted in the present invention is as follows:
A kind of textile inkjet printing coating, including following component based on quality hundred number:
As the preferred embodiment of the present invention, described textile inkjet printing coating includes following by quality hundred
The component of number meter:
As further preferred embodiment of the present invention, described textile inkjet printing coating include following by
The component of quality hundred number meter:
Preferably, the surface tension of described coating be 26-34dyn/cm, viscosity be 6-20 centipoise.
Preferably, described softening agent is the nonionic softening agent containing organosilicon, preferably BASF Lu Pingmoyin
Flower softener B ASF Luprintol Solf VSN.
Preferably, described antibacterial is isothiazolinone biocide agent.
Preferably, a kind of or the most two or more in acetic acid, carbonic acid, the citric acid of described inhibitor
Mixing.
Preferably, described wetting agent is weak cation type wetting agent or non-ionic wetting agent, preferably is selected from straight
One in chain polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, isomeric alcohol polyethenoxy ether or any two kinds with
On mixing.
Preferably, described cross-linking agent be Open loop temperature be the aliphatic blocked isocyanate curing agent of 90-130 DEG C.
Preferably, described aqueous polyurethane is aqueous aliphatic polyurethane dispersion emulsion, and its molecular weight is less than
20000。
Preferably, the one during described solvent is diethylene glycol, carbamide, glycerol, peg400-20000.
In the formula of the present invention, wherein:
There is substantial amounts of microcellular structure in the surface of aqueous silicon dioxide, owing to the existence of these microcellular structures makes
The surface area of silicon dioxide slight diarrhea is greatly increased.The surface area of silicon dioxide microparticle is the biggest, the absorption to ink
Ability is the strongest.When the concentration of aqueous silicon dioxide be enough to make the distance between microgranule narrow down to composition network, shape
Become a series of micropore, then due to capillarity, further increase ink capacity, therefore aqueous titanium dioxide
Silicon can improve ink or the coating colour fixation in base fabric.
The addition of softening agent makes the elasticity of fabric coating significantly improve so that the combination of coating and fiber is very
Firmly, there is good washable effect so that it is there is softness, smooth feel plentiful, whippy.
Antibacterial can improve the shelf-life of coating, prevents coating from going mouldy.Currently preferred isothiazolone
Microorganism is killed livestock by series bactericidal agent, and efficiency is high, degradability is good, has and does not produces residual, operation safety, compatibility
The advantage such as property is good, stability is strong, use cost is low.
Inhibitor is preferably the weak acid such as acetic acid, carbonic acid, citric acid, and it reacts with weakly alkaline ink,
It is beneficial to improve the readability of ink border, controls coating pH value between 5-7.
The good water solubility of wetting agent, is favorably improved the seepage velocity of coating, improves coating oozing in base fabric
Property thoroughly.
In the present invention, water is as solvent and the carrier of auxiliary agent, preferably deionized water.
Aqueous polyurethane can make coating form tough and tensile softness and moisture-penetrable ventilated thin film in base fabric, it is possible to increase
Ink adhesive force in base fabric.
Cross-linking agent coordinates water-based aliphaic polyurethane dispersion emulsion to use, and makes aqueous polyurethane strand be formed and props up
Chain structure, significantly improves water pressure resistance and resistance to water performance, and can improve ink adhesive force in base fabric.
Solvent is for regulating the viscosity of coating.
Compared to existing technology, the beneficial effects of the present invention is:
Textile inkjet printing coating of the present invention and base fabric have good binding strength, it is possible to be applicable to
In multiple different base fabric, especially textile；Improve dye ink in the color fastness of base fabric and colour brightness,
The textile touch using this coating stamp is soft, breathability strong, environmental protection, harmless.
Detailed description of the invention
The present invention is described in further detail by embodiment in detail below.
A kind of textile inkjet printing coating, it includes following component based on quality hundred number: aqueous dioxy
SiClx 1-10 part, softening agent 1-5 part, antibacterial 0.1-5 part, inhibitor 0.1-5 part, wetting agent 1-5 part,
Water 70-90 part, aqueous polyurethane 5-15 part, cross-linking agent 1-10 part, solvent 1-10 part.Wherein, described soft
Soft dose is the nonionic softening agent containing organosilicon, preferably BASF Lu Pingmo stamp softener B ASF
Luprintol Solf VSN.Described antibacterial is isothiazolinone biocide agent.Described inhibitor selected from acetic acid,
A kind of or the most two or more mixing in carbonic acid, citric acid.Described wetting agent is selected from as weak cation type
Wetting agent or non-ionic wetting agent, preferably straight chain polyoxyethylene ether, fatty alcohol-polyoxyethylene ether, isomery
A kind of or the most two or more mixing in polyoxyethylenated alcohol.Preferably, described cross-linking agent is selected from for opening
Ring temperature is the aliphatic blocked isocyanate curing agent of 90-130 DEG C.Described aqueous polyurethane is aqueous fat
Adoption urethane dispersion emulsion, its molecular weight is less than 20000.Described solvent be diethylene glycol, carbamide, glycerol,
One in peg400-20000.The surface tension of described coating is 26-34dyn/cm, viscosity is 6-20 li
Pool.
Embodiment 1:
A kind of textile inkjet printing coating, including following component based on quality hundred number:
Said components in addition to aqueous polyurethane and cross-linking agent is put in order material machine at 500r/min
After lower stirring 20min makes its mix homogeneously, add aqueous polyurethane and cross-linking agent stirs under 500r/min
20min, finally uses the membrane filtration of 5 μm i.e. to obtain textile inkjet printing coating.
Embodiment 2:
A kind of textile inkjet printing coating, including following component based on quality hundred number:
Said components in addition to aqueous polyurethane and cross-linking agent is put in order material machine at 500r/min
After lower stirring 20min makes its mix homogeneously, add aqueous polyurethane and cross-linking agent stirs under 500r/min
20min, finally uses the membrane filtration of 5 μm i.e. to obtain textile inkjet printing coating.
Embodiment 3:
A kind of textile inkjet printing coating, including following component based on quality hundred number:
Said components in addition to aqueous polyurethane and cross-linking agent is put in order material machine at 500r/min
After lower stirring 20min makes its mix homogeneously, add aqueous polyurethane and cross-linking agent stirs under 500r/min
20min, finally uses the membrane filtration of 5 μm i.e. to obtain textile inkjet printing coating.
Embodiment 4:
A kind of textile inkjet printing coating, including following component based on quality hundred number:
Said components in addition to aqueous polyurethane and cross-linking agent is put in order material machine at 500r/min
After lower stirring 20min makes its mix homogeneously, add aqueous polyurethane and cross-linking agent stirs under 500r/min
20min, finally uses the membrane filtration of 5 μm i.e. to obtain textile inkjet printing coating.
Embodiment 5:
A kind of textile inkjet printing coating, including following component based on quality hundred number:
Said components in addition to aqueous polyurethane and cross-linking agent is put in order material machine at 500r/min
After lower stirring 20min makes its mix homogeneously, add aqueous polyurethane and cross-linking agent stirs under 500r/min
20min, finally uses the membrane filtration of 5 μm i.e. to obtain textile inkjet printing coating.
Properties of product detect:
Use Epson DX5 printhead on rule the coating obtained by above-described embodiment 1～5 and certain coating domestic
Lattice be print on the textile block of 1440*720 after, textile block is carried out following performance test:
1, the degree of resistance to xerotripsis test: carry out textile color stability experimental test according to GB/T3921.1-1997 resistance to dry
Wiping degree, standard is set to >=and 3.0 grades for qualified；
2, the degree of resistance to wet rubbing test: carry out the degree of the resistance to wet rubbing experimental test degree of resistance to wet rubbing according to GB/T3921.1-1997,
Standard is set to >=and 3.0 grades for qualified；
3, bright-colored degree: under d 65 illuminant, map file becomes 45 degree of angles with light source, and color is from the freshest
Gorgeous, the most bright-coloured, color is common, color is slightly dark, be respectively 5-1 level to the obscure tarnish of color；
4, sharpness of border degree test: coating spraying amount 30ml/ square metre, sprays latter 30 seconds and prints composite black
Color 50mm*50mm color lump, to be dried after in the outside infiltration situation of coating top edge, standard is set to≤
1.0mm level is qualified；
Testing result is as shown in table 1.
Table 1 properties of product testing result table
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Certain coating domestic | |
| Bright-colored degree | 5 | 4 | 5 | 5 | 4 | 4 |
| Xerotripsis fastness | 4 | 5 | 3 | 4 | 4 | 3 |
| Wet rubbing fastness | 4 | 3 | 4 | 4 | 5 | 4 |
| Pliability | Without feel | Without feel | Without feel | Without feel | Without feel | Slightly feel |
| Coating color | Nothing | Nothing | Nothing | Nothing | Nothing | Nothing |
| Sharpness of border degree | 0.6mm | 0.7mm | 0.6mm | 0.8mm | 0.8mm | 1.1mm |
As shown in Table 1, textile inkjet printing coating of the present invention is compared with certain coating domestic, to base
Cloth has good binding strength, resistance to xerotripsis, wet rubbing fastness excellence, it is possible to be applicable to multiple different base fabric
On, especially textile；Improve dye ink in the color fastness of base fabric and colour brightness, and it is clear to print border
Clear degree height, the textile touch using this coating stamp is soft, breathability strong, environmental protection, harmless.
Above-mentioned embodiment is only the preferred embodiment of the present invention, it is impossible to limit present invention protection with this
Scope, the change of any unsubstantiality that those skilled in the art is done on the basis of this and replacement are all
Belong to scope of the present invention.
Claims (10)
1. a textile inkjet printing coating, it is characterised in that: include following group based on quality hundred number
Point:
Textile inkjet printing coating the most according to claim 1, it is characterised in that: include following by
The component of quality hundred number meter:
Textile inkjet printing coating the most according to claim 1, it is characterised in that: include following by
The component of quality hundred number meter:
4. according to the textile inkjet printing coating according to any one of claims 1 to 3, it is characterised in that:
The surface tension of described coating is 26-34dyn/cm, viscosity is 6-20 centipoise.
5. according to the textile inkjet printing coating according to any one of claims 1 to 3, it is characterised in that:
Described antibacterial is isothiazolinone biocide agent.
6. according to the textile inkjet printing coating according to any one of claims 1 to 3, it is characterised in that:
A kind of or the most two or more mixing in acetic acid, carbonic acid, citric acid of the described inhibitor.
7. according to the textile inkjet printing coating according to any one of claims 1 to 3, it is characterised in that:
Described wetting agent is weak cation type wetting agent or non-ionic wetting agent, preferably be selected from straight chain polyoxyethylene ether,
A kind of or the most two or more mixing in fatty alcohol-polyoxyethylene ether, isomeric alcohol polyethenoxy ether.
8. according to the textile inkjet printing coating according to any one of claims 1 to 3, it is characterised in that:
Described cross-linking agent be Open loop temperature be the aliphatic blocked isocyanate curing agent of 90-130 DEG C.
9. according to the textile inkjet printing coating according to any one of claims 1 to 3, it is characterised in that:
Described aqueous polyurethane is aqueous aliphatic polyurethane dispersion emulsion, and its molecular weight is less than 20000.
10. according to the textile inkjet printing coating according to any one of claims 1 to 3, it is characterised in that:
Described solvent is the one in diethylene glycol, carbamide, glycerol, peg400-20000.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610281620.6A CN105734955B (en) | 2016-04-28 | 2016-04-28 | A kind of textile inkjet printing coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610281620.6A CN105734955B (en) | 2016-04-28 | 2016-04-28 | A kind of textile inkjet printing coating |
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| Publication Number | Publication Date |
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| CN105734955A true CN105734955A (en) | 2016-07-06 |
| CN105734955B CN105734955B (en) | 2018-11-20 |
Family
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| CN201610281620.6A Active CN105734955B (en) | 2016-04-28 | 2016-04-28 | A kind of textile inkjet printing coating |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106380933A (en) * | 2016-08-25 | 2017-02-08 | 湖南新力华纳米科技有限公司 | Printable waterborne polyurethane 3D golden oil or 3D ink |
| WO2021134166A1 (en) * | 2019-12-30 | 2021-07-08 | 湖州新利商标制带有限公司 | Method of manufacturing novel textile label |
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|---|---|---|---|---|
| CN106380933A (en) * | 2016-08-25 | 2017-02-08 | 湖南新力华纳米科技有限公司 | Printable waterborne polyurethane 3D golden oil or 3D ink |
| CN108384318A (en) * | 2016-08-25 | 2018-08-10 | 湖南新力华纳米科技有限公司 | A kind of printable aqueous polyurethane 3D polishes |
| CN108384318B (en) * | 2016-08-25 | 2021-02-02 | 广东神彩创新科技有限公司 | Printable waterborne polyurethane 3D gold oil |
| WO2021134166A1 (en) * | 2019-12-30 | 2021-07-08 | 湖州新利商标制带有限公司 | Method of manufacturing novel textile label |
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| Publication number | Publication date |
|---|---|
| CN105734955B (en) | 2018-11-20 |
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