CN106380584A - Unsaturated polyester resin composite material for anchoring agents - Google Patents
Unsaturated polyester resin composite material for anchoring agents Download PDFInfo
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- CN106380584A CN106380584A CN201610735894.8A CN201610735894A CN106380584A CN 106380584 A CN106380584 A CN 106380584A CN 201610735894 A CN201610735894 A CN 201610735894A CN 106380584 A CN106380584 A CN 106380584A
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- Prior art keywords
- parts
- pretreatment
- bentonite
- polyester resin
- composite material
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- 229920006337 unsaturated polyester resin Polymers 0.000 title claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 21
- 239000002131 composite material Substances 0.000 title claims abstract description 18
- 238000004873 anchoring Methods 0.000 title abstract 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 45
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 44
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 39
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical class O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 33
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims abstract description 22
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920002101 Chitin Polymers 0.000 claims abstract description 12
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000835 fiber Substances 0.000 claims abstract description 12
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001530 fumaric acid Substances 0.000 claims abstract description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 9
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims description 42
- 108010022355 Fibroins Proteins 0.000 claims description 35
- 239000000440 bentonite Substances 0.000 claims description 32
- 229910000278 bentonite Inorganic materials 0.000 claims description 32
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 22
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 22
- 229910001868 water Inorganic materials 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 20
- 238000002156 mixing Methods 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 229960003600 silver sulfadiazine Drugs 0.000 claims description 13
- UEJSSZHHYBHCEL-UHFFFAOYSA-N silver(1+) sulfadiazinate Chemical compound [Ag+].C1=CC(N)=CC=C1S(=O)(=O)[N-]C1=NC=CC=N1 UEJSSZHHYBHCEL-UHFFFAOYSA-N 0.000 claims description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 229910002012 Aerosil® Inorganic materials 0.000 claims description 11
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 10
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims description 10
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 10
- 235000019394 potassium persulphate Nutrition 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 238000001291 vacuum drying Methods 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 claims description 9
- 238000004108 freeze drying Methods 0.000 claims description 9
- 229940083466 soybean lecithin Drugs 0.000 claims description 9
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 8
- 238000010792 warming Methods 0.000 claims description 7
- VLCAYQIMSMPEBW-UHFFFAOYSA-N methyl 3-hydroxy-2-methylidenebutanoate Chemical compound COC(=O)C(=C)C(C)O VLCAYQIMSMPEBW-UHFFFAOYSA-N 0.000 claims description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 4
- 238000009413 insulation Methods 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- 238000009960 carding Methods 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 235000010265 sodium sulphite Nutrition 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims 3
- 230000004048 modification Effects 0.000 claims 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims 1
- 150000008064 anhydrides Chemical class 0.000 claims 1
- SYWDWCWQXBUCOP-UHFFFAOYSA-N benzene;ethene Chemical group C=C.C1=CC=CC=C1 SYWDWCWQXBUCOP-UHFFFAOYSA-N 0.000 claims 1
- 239000007789 gas Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- VDGJOQCBCPGFFD-UHFFFAOYSA-N oxygen(2-) silicon(4+) titanium(4+) Chemical compound [Si+4].[O-2].[O-2].[Ti+4] VDGJOQCBCPGFFD-UHFFFAOYSA-N 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract 1
- 229910021485 fumed silica Inorganic materials 0.000 abstract 1
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 abstract 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract 1
- 241000255789 Bombyx mori Species 0.000 description 6
- 230000000845 anti-microbial effect Effects 0.000 description 5
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000787 lecithin Substances 0.000 description 3
- 235000010445 lecithin Nutrition 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 2
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 244000068988 Glycine max Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- QBUKAFSEUHGMMX-MTJSOVHGSA-N (5z)-5-[[3-(1-hydroxyethyl)thiophen-2-yl]methylidene]-10-methoxy-2,2,4-trimethyl-1h-chromeno[3,4-f]quinolin-9-ol Chemical group C1=CC=2NC(C)(C)C=C(C)C=2C2=C1C=1C(OC)=C(O)C=CC=1O\C2=C/C=1SC=CC=1C(C)O QBUKAFSEUHGMMX-MTJSOVHGSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000009830 intercalation Methods 0.000 description 1
- 230000002687 intercalation Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
- PSGGLQPNTOVNKU-UHFFFAOYSA-N tetrakis(pyridine)silver(ii) peroxydisulfate Chemical compound [Ag].C1=CC=NC=C1.C1=CC=NC=C1.C1=CC=NC=C1.C1=CC=NC=C1 PSGGLQPNTOVNKU-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/43—Compounds containing sulfur bound to nitrogen
- C08K5/435—Sulfonamides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D20/00—Setting anchoring-bolts
- E21D20/02—Setting anchoring-bolts with provisions for grouting
- E21D20/025—Grouting with organic components, e.g. resin
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/04—Polymer mixtures characterised by other features containing interpenetrating networks
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Biological Depolymerization Polymers (AREA)
Abstract
The invention discloses an unsaturated polyester resin composite material for anchoring agents. The composite material comprises the following raw materials by weight: 4-8 parts of silk fiber, 3-7 parts of chitin, 1.5-2.5 parts of methyl trimethoxy silane, 6-14 parts of fumed silica, 5-9 parts of modified bentonite, 15-23 parts of cis-methyl butenedioic acid, 10-20 parts of phthalic acid, 10-20 parts of tetrahydro cis-methyl butenedioic acid, 25-45 parts of maleic anhydride, 8-16 parts of diethylene glycol, 15-25 parts of ethylene glycol, 35-55 parts of propylene glycol, 35-60 parts of styrene, 4-10 parts of rosin, and 35-55 parts of fumaric acid. The unsaturated polyester resin composite material for anchoring agents provided by the invention has the advantages of excellent antibacterial properties, good rigidity and excellent thermal stability.
Description
Technical field
The present invention relates to unsaturated polyester resin technical field, more particularly, to a kind of Anchor Agent unsaturated polyester resin is again
Condensation material.
Background technology
Unsaturated polyester resin relative density is little, tensile strength big, rigidity is good, be rich in resilience, flexible, excellent weather resistance and hard
Good the advantages of；It both can be used alone, and can fill reinforcing agent again or filler is processed into various products, also can shades of colour, both
Can use at normal temperatures, can use at high temperature again.Unsaturated polyester resin is that high comprehensive performance obtains in Anchor Agent field
Extensively apply.But the anti-microbial property of current Anchor Agent unsaturated polyester resin is poor, and rigidity and heat stability are still full
Foot not demand it would be highly desirable to solve.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of Anchor Agent unsaturated polyester resin and is combined
Material, anti-microbial property is excellent, and rigidity is fabulous, and thermal stability is outstanding.
A kind of Anchor Agent unsaturated polyester resin composite material proposed by the present invention, its raw material includes by weight：Silkworm
Silk fiber 4-8 part, chitin 3-7 part, MTMS 1.5-2.5 part, aerosil 6-14 part, bentone
Native 5-9 part, cis-methyl-butene diacid 15-23 part, phthalic acid 10-20 part, tetrahydrochysene cis-methyl-butene diacid 10-20
Part, maleic anhydride 25-45 part, diethylene glycol 8-16 part, ethylene glycol 15-25 part, propylene glycol 35-55 part, styrene 35-60
Part, Colophonium 4-10 part, fumaric acid 35-55 part.
Preferably, the weight of silk fiber, chitin, MTMS, aerosil, modified alta-mud
Than for 5-7：4-6：1.8-2.2：8-12：6-8.
Preferably, cis-methyl-butene diacid, phthalic acid, tetrahydrochysene cis-methyl-butene diacid, maleic anhydride,
Diethylene glycol, ethylene glycol, propylene glycol, styrene, Colophonium, fumaric weight are than for 17-21：12-18：13-17：30-40：
10-14：18-22：40-50：45-50：6-8：40-50.
Preferably, its raw material includes by weight：Silk fiber 5-7 part, chitin 4-6 part, MTMS
1.8-2.2 part, aerosil 8-12 part, modified alta-mud 6-8 part, cis-methyl-butene diacid 17-21 part, O-phthalic
Sour 12-18 part, tetrahydrochysene cis-methyl-butene diacid 13-17 part, maleic anhydride 30-40 part, diethylene glycol 10-14 part, second two
Alcohol 18-22 part, propylene glycol 40-50 part, styrene 45-50 part, Colophonium 6-8 part, fumaric acid 40-50 part.
Preferably, modified alta-mud adopts following technique preparation：Under nitrogen protection, by acrylic acid, hydroxyethyl methacrylate
Ethyl ester, fibroin albumen, N, N '-methylene-bisacrylamide, potassium peroxydisulfate, sodium hydroxide, water mix and blend, standing and defoaming, rise
Temperature, insulation obtains pretreatment fibroin albumen；By bentonite, water mix and blend, add soybean lecithin, silver sulfadiazine stirring,
Microwave treatment, filters, washing, and vacuum drying is pulverized and obtained pretreatment bentonite；By pretreatment fibroin albumen, pretreatment swelling
Soil adds stirring in aqueous solution of sodium bisulfite, lyophilization, pulverizes and obtains modified alta-mud.
Preferably, modified alta-mud adopts following technique preparation：Under nitrogen protection, by acrylic acid, hydroxyethyl methacrylate
Ethyl ester, fibroin albumen, N, N '-methylene-bisacrylamide, potassium peroxydisulfate, sodium hydroxide, water mix and blend 120-160min, stir
Mix temperature and be 60-70 DEG C, standing and defoaming, it is warming up to 70-75 DEG C, be incubated 80-140min, obtain pretreatment fibroin albumen；Will be swollen
Profit soil, water mix and blend 25-55min, mixing speed is 2500-3500r/min, adds soybean lecithin, silver sulfadiazine to stir
Mix 70-130min, whipping temp is 80-90 DEG C, mixing speed is 800-1600r/min, microwave treatment 15-25min, microwave work(
Rate is 600-700W, filters, washing, and vacuum drying is pulverized and obtained pretreatment bentonite；By pretreatment fibroin albumen, pretreatment
Bentonite adds stirring 10-15h in aqueous solution of sodium bisulfite, lyophilization, pulverizes and obtains modified alta-mud.
Preferably, modified alta-mud adopts following technique preparation：Under nitrogen protection, by weight by 10-20 part propylene
Acid, 10-20 part hydroxyethyl methylacrylate, 6-10 part fibroin albumen, 1.5-2.5 part N, N '-methylene-bisacrylamide,
0.04-0.1 part potassium peroxydisulfate, 1-2 part sodium hydroxide, 80-120 part water mix and blend 120-160min, whipping temp is 60-70
DEG C, standing and defoaming, it is warming up to 70-75 DEG C, be incubated 80-140min, obtain pretreatment fibroin albumen；By weight will be swollen for 4-12 part
Profit soil, 70-90 part water mix and blend 25-55min, mixing speed is 2500-3500r/min, adds 1.5-2.5 part Semen sojae atricolor lecithin
Fat, 0.2-0.6 part silver sulfadiazine stirring 70-130min, whipping temp is 80-90 DEG C, and mixing speed is 800-1600r/
Min, microwave treatment 15-25min, microwave power is 600-700W, filters, washing, and vacuum drying is pulverized and obtained pretreatment swelling
Soil；By weight 25-65 part pretreatment fibroin albumen, 6-12 part pretreatment bentonite are added 220-420 part concentration for 0.4-
Stir 10-15h, lyophilization in the aqueous solution of sodium bisulfite of 1wt%, pulverize and obtain modified alta-mud.
The present invention adopts conventional fabrication process to be obtained.
The present invention adopts maleic anhydride, tetrahydrochysene cis-methyl-butene diacid, phthalic acid, citraconic two
Acid is synthesized in the presence of modified alta-mud with propylene glycol, ethylene glycol, diethylene glycol, and not only anti-microbial property is good, and rigidity
Excellent with thermal stability；In the pretreatment fibroin albumen of modified alta-mud of the present invention, acrylic acid, hydroxyethyl methylacrylate,
Fibroin albumen synergism, sequentially passes through N, and N '-methylene-bisacrylamide, sodium sulfite are processed, and can cancel out each other each
Shortcoming, not only absorbability is good, and excellent in mechanical performance；And in pretreatment bentonite, bentonite and water are in glue through high speed processing
Body state, with soybean lecithin, silver sulfadiazine after high-speed stirred and microwave action, ion exchangeable insertion bentonite bed
Between, carry out intercalation further with pretreatment fibroin albumen, crosslinked IPN forms network structure, and adsorptivity is strong, divides each other simultaneously
Uniformly, silver sulfadiazine cannot directly spread thus improve sustained release performance cloth, and anti-microbial property is excellent, and when surface, sulfanilamide is phonetic
When pyridine silver concentration reduces, in the presence of soybean lecithin, internal silver sulfadiazine can pass through polymeric matrix interior
Migration, sustained anti-microbial effect is strong；The bentonitic emulsifying of pretreatment is good with solubilizing effect, promotes pretreatment fibroin albumen, methyl three
Methoxy silane cooperates, stronger with the adhesion of aerosil, silk fiber and chitin, and not only antibacterial effect enters
One step strengthens, and rigidity is fabulous, and thermal stability is outstanding.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of Anchor Agent unsaturated polyester resin composite material proposed by the present invention, its raw material includes by weight：Silkworm
4 parts of silk fiber, 7 parts of chitin, 1.5 parts of MTMS, 14 parts of aerosil, 5 parts of modified alta-mud, cis
23 parts of methylmaleic acid, 10 parts of phthalic acid, 20 parts of tetrahydrochysene cis-methyl-butene diacid, 25 parts of maleic anhydride, two
16 parts of glycol, 15 parts of ethylene glycol, 55 parts of propylene glycol, 35 parts of styrene, 10 parts of Colophonium, 35 parts of fumaric acid.
Embodiment 2
A kind of Anchor Agent unsaturated polyester resin composite material proposed by the present invention, its raw material includes by weight：Silkworm
8 parts of silk fiber, 3 parts of chitin, 2.5 parts of MTMS, 6 parts of aerosil, 9 parts of modified alta-mud, cis
15 parts of methylmaleic acid, 20 parts of phthalic acid, 10 parts of tetrahydrochysene cis-methyl-butene diacid, 45 parts of maleic anhydride, two
8 parts of glycol, 25 parts of ethylene glycol, 35 parts of propylene glycol, 60 parts of styrene, 4 parts of Colophonium, 55 parts of fumaric acid.
Modified alta-mud adopts following technique preparation：Under nitrogen protection, by acrylic acid, hydroxyethyl methylacrylate, silk
Fibroin, N, N '-methylene-bisacrylamide, potassium peroxydisulfate, sodium hydroxide, water mix and blend, standing and defoaming, heat up, insulation
Obtain pretreatment fibroin albumen；By bentonite, water mix and blend, add soybean lecithin, silver sulfadiazine stirring, at microwave
Reason, filters, washing, and vacuum drying is pulverized and obtained pretreatment bentonite；Pretreatment fibroin albumen, pretreatment bentonite are added
Stir in aqueous solution of sodium bisulfite, lyophilization, pulverize and obtain modified alta-mud.
Embodiment 3
A kind of Anchor Agent unsaturated polyester resin composite material proposed by the present invention, its raw material includes by weight：Silkworm
5 parts of silk fiber, 6 parts of chitin, 1.8 parts of MTMS, 12 parts of aerosil, 6 parts of modified alta-mud, cis
21 parts of methylmaleic acid, 12 parts of phthalic acid, 17 parts of tetrahydrochysene cis-methyl-butene diacid, 30 parts of maleic anhydride, two
14 parts of glycol, 18 parts of ethylene glycol, 50 parts of propylene glycol, 45 parts of styrene, 8 parts of Colophonium, 40 parts of fumaric acid.
Modified alta-mud adopts following technique preparation：Under nitrogen protection, by weight by 20 parts of acrylic acid, 10 parts of methyl
2-(Acryloyloxy)ethanol, 10 parts of fibroin albumens, 1.5 parts of N, N '-methylene-bisacrylamide, 0.1 part of potassium peroxydisulfate, 1 part of hydroxide
Sodium, 120 parts of water mix and blend 120min, whipping temp is 70 DEG C, and standing and defoaming is warming up to 70 DEG C, is incubated 140min, obtains pre-
Process fibroin albumen；By weight by 4 parts of bentonite, 90 parts of water mix and blend 25min, mixing speed is 3500r/min, adds
1.5 parts of soybean lecithins, 0.6 part of silver sulfadiazine stir 70min, and whipping temp is 90 DEG C, and mixing speed is 800r/min, micro-
Ripple processes 25min, and microwave power is 600W, filters, washing, and vacuum drying is pulverized and obtained pretreatment bentonite；By weight will
65 parts of pretreatment fibroin albumens, 6 parts of pretreatment bentonite add in the aqueous solution of sodium bisulfite that 420 parts of concentration are 0.4wt%
Stirring 15h, lyophilization, pulverize and obtain modified alta-mud.
Embodiment 4
A kind of Anchor Agent unsaturated polyester resin composite material proposed by the present invention, its raw material includes by weight：Silkworm
7 parts of silk fiber, 4 parts of chitin, 2.2 parts of MTMS, 8 parts of aerosil, 8 parts of modified alta-mud, cis
17 parts of methylmaleic acid, 18 parts of phthalic acid, 13 parts of tetrahydrochysene cis-methyl-butene diacid, 40 parts of maleic anhydride, two
10 parts of glycol, 22 parts of ethylene glycol, 40 parts of propylene glycol, 50 parts of styrene, 6 parts of Colophonium, 50 parts of fumaric acid.
Modified alta-mud adopts following technique preparation：Under nitrogen protection, by weight by 10 parts of acrylic acid, 20 parts of methyl
2-(Acryloyloxy)ethanol, 6 parts of fibroin albumens, 2.5 parts of N, N '-methylene-bisacrylamide, 0.04 part of potassium peroxydisulfate, 2 parts of hydroxides
Sodium, 80 parts of water mix and blend 160min, whipping temp is 60 DEG C, and standing and defoaming is warming up to 75 DEG C, is incubated 80min, obtains pre- place
Filament carding fibroin；By weight by 12 parts of bentonite, 70 parts of water mix and blend 55min, mixing speed is 2500r/min, adds
2.5 parts of soybean lecithins, 0.2 part of silver sulfadiazine stir 130min, and whipping temp is 80 DEG C, and mixing speed is 1600r/min,
Microwave treatment 15min, microwave power is 700W, filters, washing, and vacuum drying is pulverized and obtained pretreatment bentonite；By weight
25 parts of pretreatment fibroin albumens, 12 parts of pretreatment bentonite are added in the aqueous solution of sodium bisulfite that 220 parts of concentration are 1wt%
Stirring 10h, lyophilization, pulverize and obtain modified alta-mud.
Embodiment 5
A kind of Anchor Agent unsaturated polyester resin composite material proposed by the present invention, its raw material includes by weight：Silkworm
6 parts of silk fiber, 5 parts of chitin, 2 parts of MTMS, 10 parts of aerosil, 7 parts of modified alta-mud, cis first
19 parts of base butene dioic acid, 15 parts of phthalic acid, 15 parts of tetrahydrochysene cis-methyl-butene diacid, 35 parts of maleic anhydride, two is sweet
12 parts of alcohol, 20 parts of ethylene glycol, 45 parts of propylene glycol, 48 parts of styrene, 7 parts of Colophonium, 45 parts of fumaric acid.
Modified alta-mud adopts following technique preparation：Under nitrogen protection, by acrylic acid, hydroxyethyl methylacrylate, silk
Fibroin, N, N '-methylene-bisacrylamide, potassium peroxydisulfate, sodium hydroxide, water mix and blend 140min, whipping temp is 65
DEG C, standing and defoaming, it is warming up to 72 DEG C, be incubated 110min, obtain pretreatment fibroin albumen；By bentonite, water mix and blend
40min, mixing speed is 3000r/min, adds soybean lecithin, silver sulfadiazine stirring 100min, and whipping temp is 85 DEG C,
Mixing speed is 1200r/min, microwave treatment 20min, and microwave power is 650W, filters, washing, vacuum drying, and pulverizing obtains
Pretreatment bentonite；Pretreatment fibroin albumen, pretreatment bentonite are added stirring 12h in aqueous solution of sodium bisulfite, freezing
Dry, pulverize and obtain modified alta-mud.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. a kind of Anchor Agent unsaturated polyester resin composite material is it is characterised in that its raw material includes by weight：Silk fibroin
Dimension 4-8 part, chitin 3-7 part, MTMS 1.5-2.5 part, aerosil 6-14 part, modified alta-mud 5-
9 parts, cis-methyl-butene diacid 15-23 part, phthalic acid 10-20 part, tetrahydrochysene cis-methyl-butene diacid 10-20 part is suitable
Anhydride maleique 25-45 part, diethylene glycol 8-16 part, ethylene glycol 15-25 part, propylene glycol 35-55 part, styrene 35-60 part, Colophonium
4-10 part, fumaric acid 35-55 part.
2. according to claim 1 Anchor Agent unsaturated polyester resin composite material it is characterised in that silk fiber, first
Shell element, MTMS, aerosil, the weight of modified alta-mud are than for 5-7：4-6：1.8-2.2：8-12：
6-8.
3. Anchor Agent unsaturated polyester resin composite material according to claim 1 or claim 2 is it is characterised in that cis methyl
Butene dioic acid, phthalic acid, tetrahydrochysene cis-methyl-butene diacid, maleic anhydride, diethylene glycol, ethylene glycol, propylene glycol, benzene
Ethylene, Colophonium, fumaric weight are than for 17-21：12-18：13-17：30-40：10-14：18-22：40-50：45-
50：6-8：40-50.
4. according to any one of claim 1-3 Anchor Agent unsaturated polyester resin composite material it is characterised in that it is former
Material includes by weight：Silk fiber 5-7 part, chitin 4-6 part, MTMS 1.8-2.2 part, gas phase titanium dioxide
Silicon 8-12 part, modified alta-mud 6-8 part, cis-methyl-butene diacid 17-21 part, phthalic acid 12-18 part, the cis first of tetrahydrochysene
Base butene dioic acid 13-17 part, maleic anhydride 30-40 part, diethylene glycol 10-14 part, ethylene glycol 18-22 part, propylene glycol 40-50
Part, styrene 45-50 part, Colophonium 6-8 part, fumaric acid 40-50 part.
5. according to any one of claim 1-4 Anchor Agent unsaturated polyester resin composite material it is characterised in that modification
Bentonite adopts following technique preparation：Under nitrogen protection, by acrylic acid, hydroxyethyl methylacrylate, fibroin albumen, N, N '-
Methylene-bisacrylamide, potassium peroxydisulfate, sodium hydroxide, water mix and blend, standing and defoaming, heats up, insulation obtains pretreatment silk
Fibroin；By bentonite, water mix and blend, add soybean lecithin, silver sulfadiazine stirring, microwave treatment, filter, washing,
Vacuum drying, pulverizes and obtains pretreatment bentonite；Pretreatment fibroin albumen, pretreatment bentonite are added sodium sulfite water-soluble
Stir in liquid, lyophilization, pulverize and obtain modified alta-mud.
6. according to any one of claim 1-5 Anchor Agent unsaturated polyester resin composite material it is characterised in that modification
Bentonite adopts following technique preparation：Under nitrogen protection, by acrylic acid, hydroxyethyl methylacrylate, fibroin albumen, N, N '-
Methylene-bisacrylamide, potassium peroxydisulfate, sodium hydroxide, water mix and blend 120-160min, whipping temp is 60-70 DEG C, quiet
Put deaeration, be warming up to 70-75 DEG C, be incubated 80-140min, obtain pretreatment fibroin albumen；By bentonite, water mix and blend 25-
55min, mixing speed is 2500-3500r/min, adds soybean lecithin, silver sulfadiazine stirring 70-130min, stirring temperature
Spend for 80-90 DEG C, mixing speed is 800-1600r/min, microwave treatment 15-25min, microwave power is 600-700W, filters,
Washing, vacuum drying, pulverize and obtain pretreatment bentonite；Pretreatment fibroin albumen, pretreatment bentonite are added bisulfite
Stir 10-15h, lyophilization in sodium water solution, pulverize and obtain modified alta-mud.
7. according to any one of claim 1-6 Anchor Agent unsaturated polyester resin composite material it is characterised in that modification
Bentonite adopts following technique preparation：Under nitrogen protection, by weight by 10-20 part acrylic acid, 10-20 part methacrylic acid
Hydroxyl ethyl ester, 6-10 part fibroin albumen, 1.5-2.5 part N, N '-methylene-bisacrylamide, 0.04-0.1 part potassium peroxydisulfate, 1-2 part
Sodium hydroxide, 80-120 part water mix and blend 120-160min, whipping temp is 60-70 DEG C, and standing and defoaming is warming up to 70-75
DEG C, it is incubated 80-140min, obtain pretreatment fibroin albumen；By weight by 4-12 part bentonite, 70-90 part water mix and blend
25-55min, mixing speed is 2500-3500r/min, adds 1.5-2.5 part soybean lecithin, 0.2-0.6 part silver sulfadiazine
Stirring 70-130min, whipping temp is 80-90 DEG C, and mixing speed is 800-1600r/min, microwave treatment 15-25min, microwave
Power is 600-700W, filters, washing, and vacuum drying is pulverized and obtained pretreatment bentonite；By weight 25-65 part is located in advance
Filament carding fibroin, 6-12 part pretreatment bentonite add in the aqueous solution of sodium bisulfite that 220-420 part concentration is 0.4-1wt%
Stirring 10-15h, lyophilization, pulverize and obtain modified alta-mud.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610735894.8A CN106380584A (en) | 2016-08-27 | 2016-08-27 | Unsaturated polyester resin composite material for anchoring agents |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610735894.8A CN106380584A (en) | 2016-08-27 | 2016-08-27 | Unsaturated polyester resin composite material for anchoring agents |
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| Publication Number | Publication Date |
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| CN106380584A true CN106380584A (en) | 2017-02-08 |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735405A (en) * | 2009-12-29 | 2010-06-16 | 浙江天和树脂有限公司 | Imitation marble unsaturated polyester resin and preparation method thereof |
| CN102516468A (en) * | 2011-12-28 | 2012-06-27 | 浙江天和树脂有限公司 | Unsaturated polyester resin with high cohesive force and high wettability and preparation method for unsaturated polyester resin |
-
2016
- 2016-08-27 CN CN201610735894.8A patent/CN106380584A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101735405A (en) * | 2009-12-29 | 2010-06-16 | 浙江天和树脂有限公司 | Imitation marble unsaturated polyester resin and preparation method thereof |
| CN102516468A (en) * | 2011-12-28 | 2012-06-27 | 浙江天和树脂有限公司 | Unsaturated polyester resin with high cohesive force and high wettability and preparation method for unsaturated polyester resin |
Non-Patent Citations (1)
| Title |
|---|
| 高孝俊等: "卵磷脂-肝素/蒙脱土纳米中间体的制备及血液相容性的研究", 《功能材料》 * |
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Application publication date: 20170208 |