CN109925983A - The method of bilayered microcapsule and its arrangement into textile fabric based on shea butter - Google Patents
The method of bilayered microcapsule and its arrangement into textile fabric based on shea butter Download PDFInfo
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- CN109925983A CN109925983A CN201910176248.6A CN201910176248A CN109925983A CN 109925983 A CN109925983 A CN 109925983A CN 201910176248 A CN201910176248 A CN 201910176248A CN 109925983 A CN109925983 A CN 109925983A
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- shea butter
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Abstract
The present invention relates to a kind of preparation methods of bilayered microcapsule based on shea butter, comprising the following steps: is uniformly mixed shea butter, unsaturated fatty acid and emulsifier and oily phase is made；Water, polyalcohol and metal salt are uniformly mixed obtained water phase；Then the water phase is added in oily phase, then homogeneous 2-3 times, obtains emulsification nanoemulsions；Nanoemulsions will be emulsified to be added in the acid solution of chitosan, obtain the shea butter microcapsule solution of chitosan package；It is added into the aqueous solution of beta-cyclodextrin, after mixing, reacts 2-4h at 40-60 DEG C.The bilayered microcapsule based on shea butter is arranged into the method into textile fabric the invention also discloses a kind of: the bilayered microcapsule based on shea butter being mixed with adhesive, obtains microcapsule dressing agent；Then microcapsule dressing agent is evenly applied on fabric, preliminary drying 1-3min bakes 1-2min, the fabric after being arranged.
Description
Technical field
The present invention relates to textile fabric finishing technique field more particularly to a kind of bilayered microcapsule based on shea butter and
It arranges the method into textile fabric.
Background technique
As the improvement of people's living standards, people are also higher and higher to the functional requirement of fabric.It is dry when autumn and winter
When, it is desirable to fabrics to have certain moisture-keeping functions, and high-efficient and lasting.Traditional fabric finishing agent cannot expire
The demand of sufficient people.
At present had it is more about by essential oil weaving face fabric finishing field application, as CN201310410614 is disclosed
A kind of real silk fabric natural essential oil Aroma finishing agent and preparation method thereof, CN201310401166 discloses a kind of pure cotton fabric
Top finish method, CN201610031889 discloses a kind of side using tea tree ethereal oil microcapsules flavoring on the textile
Method, CN201610102031 disclose a kind of preparation method and applications of composite essential oil microcapsule dressing agent.In the above patent
Disclosed finishing agent is the microcapsules of single layer, and release speed of essential oil therein is too fast, affects the use value of fabric.
Summary of the invention
In order to solve the above technical problems, the object of the present invention is to provide a kind of bilayered microcapsule based on shea butter and its
The method in textile fabric is arranged, the shea butter embedded in the bilayered microcapsule of the invention based on shea butter can be one
Determine to release under the compressing and rubbing against of intensity, be absorbed through skin, achievees the effect that moisturizing moisturizing, prevents skin aging.
The first purpose of the invention is to provide a kind of preparation methods of bilayered microcapsule based on shea butter, including with
Lower step:
(1) in mass, by 5-10 parts of shea butters, 3-5 parts of unsaturated fatty acids and 2-4 parts of emulsifiers at 60-70 DEG C
Oily phase is made in lower be uniformly mixed；In mass, 1000-5000 parts of water, 2-3 parts of polyalcohols and 2-4 parts of metal salts are uniformly mixed
Water phase is made；Then the water phase of 100-150 parts of quality is added in the oily phase of 1 part of quality, then homogeneous 2-3 times, obtains emulsification and receives
Rice milk liquid；
(2) nanoemulsions will be emulsified to be added in the acid solution of chitosan, obtains the shea butter microcapsules of chitosan package
Solution；
(3) the shea butter microcapsule solution of chitosan package is added in the aqueous solution of beta-cyclodextrin, after mixing,
2-4h is reacted at 40-60 DEG C, after fully reacting, obtains the bilayered microcapsule based on shea butter.
Further, in step (1), unsaturated fatty acid is one or more of oleic acid, linoleic acid plus linolenic acid；Institute
Stating emulsifier is Span 80 (Span80) or soybean lecithin.Preferably, unsaturated fatty acid is oleic acid.
Further, in step (1), polyalcohol is glycerol, propylene glycol or 1,3 butanediols；The metal salt is chlorination
Sodium.Preferably, polyalcohol is glycerol.
Further, in step (1), homogenization pressure 60-120MPa.
Further, in step (2), the mass ratio of the acid in chitosan and acid solution is 1:1-2.
Further, in step (2), the acid in acid solution is in citric acid, acetic acid, acetic acid, lactic acid and acrylic acid
It is one or more of.
Further, in step (3), the shea butter microcapsules of chitosan package and the mass ratio of beta-cyclodextrin are 1:
1-3。
Second object of the present invention is to disclose a kind of pair using prepared by above-mentioned preparation method based on shea butter
Microcapsule.
Third object of the present invention is to disclose a kind of microcapsule dressing agent, including using prepared by above-mentioned preparation method
Bilayered microcapsule and adhesive based on shea butter；The bilayered microcapsule of shea butter and the mass ratio of adhesive are 1:4-7.
Further, adhesive is one in aqueous polyurethane, amino silicone micro emulsion and polyethylene glycol oxide (PEO) nanoparticle
Kind is several.
Fourth object of the present invention is to disclose a kind of bilayered microcapsule by based on shea butter to arrange to textile fabric
In method, comprising the following steps:
(S1) the above-mentioned bilayered microcapsule based on shea butter of the invention is mixed with adhesive, obtains microcapsules arrangement
Agent；The mass ratio of the bilayered microcapsule and adhesive based on shea butter is 1:4-7；
(S2) then microcapsule dressing agent is evenly applied on fabric, preliminary drying 1-3min, then exists at 50-70 DEG C
1-2min is baked at 100-120 DEG C, the fabric after being arranged.
The present invention emulsifies shea butter in the preparation of the bilayered microcapsule based on shea butter, passes through chitosan oil
The outer layer that the positive and negative charge active force of acid is gathered in shea butter forms first layer micro-capsule wall, then is gathered shell by envelope combined techniques
The shea butter of sugar package is microcapsule embedded in beta-cyclodextrin, forms bilayered microcapsule.
Bilayered microcapsule based on shea butter of the invention obtains efficient microcapsule dressing agent after compounding with adhesive,
When being used for the arrangement of fabric, the shea butter of bilayered microcapsule embedding releases under the compressing and rubbing against of some strength
Come, is absorbed through skin, can reach moisturizing moisturizing, the effect for preventing skin aging.It is not related to harmful in whole process of the present invention
Substance is learned, the bilayered microcapsule had good sustained release effect of preparation very safe to human body, coating is soft simultaneously flexible, not shadow after arrangement
Feel, gas permeability and the penetrability of fabric are rung, and there is certain anti-microbial property and washing fastness.
According to the above aspect of the present invention, the present invention has at least the following advantages:
Harmful chemicals it are not related in the preparation process of bilayered microcapsule and finishing agent based on shea butter of the invention
Matter, bilayered microcapsule had good sustained release effect very safe to human body, prepared, coating is soft and flexible, does not influence after arrangement
Feel, gas permeability and the penetrability of fabric, and there is certain anti-microbial property and washing fastness.
The above description is only an overview of the technical scheme of the present invention, in order to better understand the technical means of the present invention,
And can be implemented in accordance with the contents of the specification, with presently preferred embodiments of the present invention and cooperation, detailed description is as follows below.
Specific embodiment
With reference to embodiment, the embodiment of the present invention is furthur described in detail.Following embodiment is used for
Illustrate the present invention, but is not intended to limit the scope of the invention.
Embodiment 1
It present embodiments provides a kind of by method of the bilayered microcapsule arrangement into textile fabric based on shea butter, packet
Include following steps:
1) it emulsifies: being in mass ratio that 10:1:3 is uniformly mixed at 70 DEG C and is made oily with Span80 by shea butter, oleic acid
Phase；It is in mass ratio that 5400:3:1 is uniformly mixed water phase is made by deionized water and glycerol, sodium chloride.By the water phase prepared with
Thread form is slowly added in oily phase, obtains mixed emulsion, then with high pressure homogenizer to mixed emulsion homogeneous 2 times, homogenization pressure
For 120MPa, emulsification nanoemulsions are obtained；
2) preparation of chitosan microcapsules: chitosan is mixed with citric acid with mass ratio for 1:1, the acid of chitosan is obtained
The resulting emulsification nanoemulsions of step 1) are added under stirring conditions in solution thereto, form the wooden fruit of cream of chitosan package
Oil microcapsule solution；
3) embedding of beta-cyclodextrin: beta-cyclodextrin is dissolved in distilled water, by above-mentioned steps 2) resulting chitosan package
Shea butter microcapsule solution be slowly added into beta-cyclodextrin aqueous solution, constant temperature stir 2h, refrigerated overnight, filter, washing,
Bilayered microcapsule is obtained after drying；
4) preparation of microcapsule dressing agent: bilayered microcapsule solution is compounded with aqueous polyurethane with mass ratio for 1:4
To efficient microcapsule dressing agent；
5) microcapsule dressing agent: being evenly applied on fabric by top finish with scraper type coating apparatus, pre- at 50 DEG C
3min is dried, then 2min is baked at 100 DEG C, obtains finished product.
Fabric made from above-mentioned preparation step is with lasting moistening effect, performance effect that shea butter can be permanent,
Reach slow release effect.
Embodiment 2
It present embodiments provides a kind of by method of the bilayered microcapsule arrangement into textile fabric based on shea butter, packet
Include following steps:
1) it emulsifies: with soybean lecithin being in mass ratio that 10:1:4 is uniformly mixed system at 70 DEG C by shea butter, oleic acid
Obtain oily phase；It is in mass ratio that 5400:3:1 is uniformly mixed water phase is made by deionized water and glycerol, sodium chloride.The water that will be prepared
It is mutually slowly added in the form of thread in oily phase, obtains mixed emulsion, then with high pressure homogenizer to mixed emulsion homogeneous 3 times, homogeneous
Pressure is 60MPa, obtains emulsification nanoemulsions；
2) preparation of chitosan microcapsules: chitosan is mixed with acetic acid with mass ratio for 1:1, the acid for obtaining chitosan is molten
The resulting emulsification nanoemulsions of step 1) are added under stirring conditions in liquid thereto, form the shea butter of chitosan package
Microcapsule solution；
3) embedding of beta-cyclodextrin: beta-cyclodextrin is dissolved in distilled water, by above-mentioned steps 2) resulting chitosan package
Shea butter microcapsule solution be slowly added into beta-cyclodextrin aqueous solution, constant temperature stir 4h, refrigerated overnight, filter, washing,
Bilayered microcapsule is obtained after drying；
4) preparation of microcapsule dressing agent: bilayered microcapsule solution is compounded with PEO nanoparticle with mass ratio for 1:5
To efficient microcapsule dressing agent；
5) microcapsule dressing agent: being evenly applied on fabric by top finish with scraper type coating apparatus, pre- at 70 DEG C
2min is dried, then 2min is baked at 120 DEG C, obtains finished product.
Fabric made from above-mentioned preparation step is with lasting moistening effect, performance effect that shea butter can be permanent,
Reach slow release effect.
The above is only a preferred embodiment of the present invention, it is not intended to restrict the invention, it is noted that for this skill
For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is several improvement and
Modification, these improvements and modifications also should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of preparation method of the bilayered microcapsule based on shea butter, which comprises the following steps:
(1) in mass, 5-10 parts of shea butters, 3-5 parts of unsaturated fatty acids and 2-4 parts of emulsifiers are mixed at 60-70 DEG C
It closes and oily phase is uniformly made；In mass, 1000-5000 parts of water, 2-3 parts of polyalcohols and 2-4 parts of metal salts are uniformly mixed and are made
Water phase；Then it is 100-150:1 according to mass ratio, the water phase is added in oily phase, then homogeneous 2-3 times, obtains emulsification nanometer
Lotion；
(2) the emulsification nanoemulsions are added in the acid solution of chitosan, obtain the shea butter microcapsules of chitosan package
Solution；
(3) the shea butter microcapsule solution for wrapping up the chitosan is added in the aqueous solution of beta-cyclodextrin, after mixing,
2-4h is reacted at 40-60 DEG C, after fully reacting, obtains the bilayered microcapsule based on shea butter.
2. preparation method according to claim 1, it is characterised in that: in step (1), the unsaturated fatty acid is oil
One or more of acid, linoleic acid plus linolenic acid；The emulsifier is Span 80 or soybean lecithin.
3. preparation method according to claim 1, it is characterised in that: in step (1), the polyalcohol is glycerol, third
Glycol or 1,3 butanediols；The metal salt is sodium chloride.
4. preparation method according to claim 1, it is characterised in that: in step (1), homogenization pressure 60-120MPa.
5. preparation method according to claim 1, it is characterised in that: in step (2), the acid in acid solution is lemon
One or more of acid, acetic acid, acetic acid, lactic acid and acrylic acid.
6. preparation method according to claim 1, it is characterised in that: in step (3), the shea butter of chitosan package
The mass ratio of microcapsules and beta-cyclodextrin is 1:1-3.
7. the bilayered microcapsule based on shea butter prepared by a kind of preparation method of any of claims 1-6.
8. a kind of microcapsule dressing agent, it is characterised in that: including the bilayered microcapsule as claimed in claim 7 based on shea butter
And adhesive；The mass ratio of the bilayered microcapsule and adhesive based on shea butter is 1:4-7.
9. microcapsule dressing agent according to claim 8, it is characterised in that: described adhesive is aqueous polyurethane, amino
One or more of silicon micro emulsion and polyethylene glycol oxide nanoparticle.
10. a kind of bilayered microcapsule by as claimed in claim 7 based on shea butter arranges the method into textile fabric,
It is characterized in that, comprising the following steps:
(S1) bilayered microcapsule based on shea butter is mixed with adhesive, obtains microcapsule dressing agent；It is described to be based on
The bilayered microcapsule of shea butter and the mass ratio of adhesive are 1:4-7；
(S2) then the microcapsule dressing agent is evenly applied on fabric, preliminary drying 1-3min, then exists at 50-70 DEG C
1-2min is baked at 100-120 DEG C, the fabric after being arranged.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201910176248.6A CN109925983B (en) | 2019-03-08 | 2019-03-08 | Shea butter-based double-layer microcapsule and method for finishing same into textile fabric |
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|---|---|---|---|
| CN201910176248.6A CN109925983B (en) | 2019-03-08 | 2019-03-08 | Shea butter-based double-layer microcapsule and method for finishing same into textile fabric |
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| CN109925983A true CN109925983A (en) | 2019-06-25 |
| CN109925983B CN109925983B (en) | 2021-12-28 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110656504A (en) * | 2019-09-03 | 2020-01-07 | 无锡德冠生物科技有限公司 | Biomass aromatic finishing agent and preparation method thereof |
| CN111088694A (en) * | 2019-12-11 | 2020-05-01 | 李慧峰 | Finishing process for home textile fabric based on shea butter |
| CN111359552A (en) * | 2020-03-02 | 2020-07-03 | 浙江理工大学 | Self-crosslinking essential oil microcapsule and preparation method thereof |
| CN112062932A (en) * | 2020-08-07 | 2020-12-11 | 宁波芬畅凝科香精香料有限公司 | Essence microcapsule and preparation method thereof |
| CN112451423A (en) * | 2020-10-28 | 2021-03-09 | 杭州乐铭科技有限公司 | Skin aging resistant microcapsule, microcapsule fiber and preparation method thereof |
| CN112553908A (en) * | 2020-12-28 | 2021-03-26 | 江苏全球康功能纺织品有限公司 | Manufacturing method of sleep-aiding fabric based on plant essential oil |
| KR20210051807A (en) * | 2019-10-31 | 2021-05-10 | 박순영 | Capsule-type moisturizing processing agent, moisturizing fiber fabric to which the same is applied, and respective manufacturing methods |
| CN114225086A (en) * | 2021-12-29 | 2022-03-25 | 安徽全民环保科技有限公司 | Natural plant type deodorizing and insect expelling preparation and preparation method thereof |
| CN114457594A (en) * | 2022-02-15 | 2022-05-10 | 绍兴柯桥春意居室用品有限公司 | Production method of aromatic home textile fabric |
| CN114481632A (en) * | 2022-02-28 | 2022-05-13 | 江苏锐晟纺织科技有限公司 | Long-acting biological antibacterial washable rayon crepe and preparation method thereof |
| CN115387128A (en) * | 2022-07-08 | 2022-11-25 | 杭州英诺克新材料有限公司 | Skin-care moisture-retention finishing agent based on two-phase microcapsules |
Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62129141A (en) * | 1985-11-29 | 1987-06-11 | Fuji Photo Film Co Ltd | Preparation of microcapsule |
| AU8657798A (en) * | 1997-07-08 | 1999-02-08 | Henry B. Schur | Flavor enhancement process |
| WO2005013941A1 (en) * | 2003-08-06 | 2005-02-17 | Fondazione Carlo E Dirce Callerio Onlus | Polysaccharide double-layer microcapsules as carriers for biologically active substance oral administration |
| EP2266546A1 (en) * | 2009-06-08 | 2010-12-29 | Advancell Advanced in Vitro Cell Technologies,S.A. | Process for the preparation of colloidal systems for the delivery of active compounds |
| US20130272950A1 (en) * | 2012-04-16 | 2013-10-17 | Electronics And Telecommunications Research Institute | Method of manufacturing a graphene fiber |
| CN104472646A (en) * | 2014-11-10 | 2015-04-01 | 天津科技大学 | Preparation method of Nisin double layer microcapsule suitable for high temperature baking food |
| CN105594755A (en) * | 2016-01-15 | 2016-05-25 | 达利(中国)有限公司 | Plant mosquito repellent and production method of textile with mosquito repelling effect |
| CN105951453A (en) * | 2016-06-16 | 2016-09-21 | 东莞市联洲知识产权运营管理有限公司 | Nerve-calming fabric based on double-wall microcapsule and preparation method thereof |
| CN107847441A (en) * | 2015-07-17 | 2018-03-27 | 雅盖隆大学 | Nano capsule for delivery lipophilic compound and preparation method thereof |
| CN108938436A (en) * | 2017-05-17 | 2018-12-07 | 程讌雯 | Washable skin care fabric product |
| CN109182069A (en) * | 2018-08-24 | 2019-01-11 | 湖北工业大学 | A kind of chitosan imbedded linoleic acid fermented vinegar and preparation method thereof |
-
2019
- 2019-03-08 CN CN201910176248.6A patent/CN109925983B/en active Active
Patent Citations (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62129141A (en) * | 1985-11-29 | 1987-06-11 | Fuji Photo Film Co Ltd | Preparation of microcapsule |
| AU8657798A (en) * | 1997-07-08 | 1999-02-08 | Henry B. Schur | Flavor enhancement process |
| WO2005013941A1 (en) * | 2003-08-06 | 2005-02-17 | Fondazione Carlo E Dirce Callerio Onlus | Polysaccharide double-layer microcapsules as carriers for biologically active substance oral administration |
| EP2266546A1 (en) * | 2009-06-08 | 2010-12-29 | Advancell Advanced in Vitro Cell Technologies,S.A. | Process for the preparation of colloidal systems for the delivery of active compounds |
| US20130272950A1 (en) * | 2012-04-16 | 2013-10-17 | Electronics And Telecommunications Research Institute | Method of manufacturing a graphene fiber |
| CN104472646A (en) * | 2014-11-10 | 2015-04-01 | 天津科技大学 | Preparation method of Nisin double layer microcapsule suitable for high temperature baking food |
| CN107847441A (en) * | 2015-07-17 | 2018-03-27 | 雅盖隆大学 | Nano capsule for delivery lipophilic compound and preparation method thereof |
| CN105594755A (en) * | 2016-01-15 | 2016-05-25 | 达利(中国)有限公司 | Plant mosquito repellent and production method of textile with mosquito repelling effect |
| CN105951453A (en) * | 2016-06-16 | 2016-09-21 | 东莞市联洲知识产权运营管理有限公司 | Nerve-calming fabric based on double-wall microcapsule and preparation method thereof |
| CN108938436A (en) * | 2017-05-17 | 2018-12-07 | 程讌雯 | Washable skin care fabric product |
| CN109182069A (en) * | 2018-08-24 | 2019-01-11 | 湖北工业大学 | A kind of chitosan imbedded linoleic acid fermented vinegar and preparation method thereof |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110656504A (en) * | 2019-09-03 | 2020-01-07 | 无锡德冠生物科技有限公司 | Biomass aromatic finishing agent and preparation method thereof |
| KR20210051807A (en) * | 2019-10-31 | 2021-05-10 | 박순영 | Capsule-type moisturizing processing agent, moisturizing fiber fabric to which the same is applied, and respective manufacturing methods |
| KR102375120B1 (en) * | 2019-10-31 | 2022-03-17 | 박순영 | Capsule-type moisturizing processing agent, moisturizing fiber fabric to which the same is applied, and respective manufacturing methods |
| CN111088694A (en) * | 2019-12-11 | 2020-05-01 | 李慧峰 | Finishing process for home textile fabric based on shea butter |
| CN111359552A (en) * | 2020-03-02 | 2020-07-03 | 浙江理工大学 | Self-crosslinking essential oil microcapsule and preparation method thereof |
| CN112062932A (en) * | 2020-08-07 | 2020-12-11 | 宁波芬畅凝科香精香料有限公司 | Essence microcapsule and preparation method thereof |
| CN112451423A (en) * | 2020-10-28 | 2021-03-09 | 杭州乐铭科技有限公司 | Skin aging resistant microcapsule, microcapsule fiber and preparation method thereof |
| CN112553908A (en) * | 2020-12-28 | 2021-03-26 | 江苏全球康功能纺织品有限公司 | Manufacturing method of sleep-aiding fabric based on plant essential oil |
| CN114225086A (en) * | 2021-12-29 | 2022-03-25 | 安徽全民环保科技有限公司 | Natural plant type deodorizing and insect expelling preparation and preparation method thereof |
| CN114225086B (en) * | 2021-12-29 | 2024-02-02 | 安徽全民环保科技有限公司 | Natural plant type deodorizing and insect-repellent preparation and preparation method thereof |
| CN114457594A (en) * | 2022-02-15 | 2022-05-10 | 绍兴柯桥春意居室用品有限公司 | Production method of aromatic home textile fabric |
| CN114481632A (en) * | 2022-02-28 | 2022-05-13 | 江苏锐晟纺织科技有限公司 | Long-acting biological antibacterial washable rayon crepe and preparation method thereof |
| CN114481632B (en) * | 2022-02-28 | 2023-11-28 | 江苏锐晟纺织科技有限公司 | Long-acting biological antibacterial washable human cotton crepe and preparation method thereof |
| CN115387128A (en) * | 2022-07-08 | 2022-11-25 | 杭州英诺克新材料有限公司 | Skin-care moisture-retention finishing agent based on two-phase microcapsules |
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