CN106380582A - Low-viscosity unsaturated polyester resin for anchoring agents - Google Patents
Low-viscosity unsaturated polyester resin for anchoring agents Download PDFInfo
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- CN106380582A CN106380582A CN201610735569.1A CN201610735569A CN106380582A CN 106380582 A CN106380582 A CN 106380582A CN 201610735569 A CN201610735569 A CN 201610735569A CN 106380582 A CN106380582 A CN 106380582A
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- unsaturated polyester
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 22
- 229920006337 unsaturated polyester resin Polymers 0.000 title claims abstract description 21
- 238000004873 anchoring Methods 0.000 title abstract description 3
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims abstract description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 24
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract description 16
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000001530 fumaric acid Substances 0.000 claims abstract description 13
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims abstract description 13
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical class [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims abstract description 13
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 13
- YYQRGCZGSFRBAM-UHFFFAOYSA-N Triclofos Chemical compound OP(O)(=O)OCC(Cl)(Cl)Cl YYQRGCZGSFRBAM-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 229960001147 triclofos Drugs 0.000 claims abstract description 10
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims abstract description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 6
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229960004063 propylene glycol Drugs 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 53
- 238000003756 stirring Methods 0.000 claims description 52
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 235000013871 bee wax Nutrition 0.000 claims description 22
- 239000012166 beeswax Substances 0.000 claims description 22
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- RSWGJHLUYNHPMX-ONCXSQPRSA-N abietic acid Chemical compound C([C@@H]12)CC(C(C)C)=CC1=CC[C@@H]1[C@]2(C)CCC[C@@]1(C)C(O)=O RSWGJHLUYNHPMX-ONCXSQPRSA-N 0.000 claims description 13
- 239000002808 molecular sieve Substances 0.000 claims description 12
- -1 polyhexamethylene Guanidine Polymers 0.000 claims description 12
- 150000001718 carbodiimides Chemical class 0.000 claims description 11
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- 239000005995 Aluminium silicate Substances 0.000 claims description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims description 10
- 238000001035 drying Methods 0.000 claims description 10
- 238000002360 preparation method Methods 0.000 claims description 10
- 238000001354 calcination Methods 0.000 claims description 9
- 239000007766 cera flava Substances 0.000 claims description 9
- HOGDNTQCSIKEEV-UHFFFAOYSA-N n'-hydroxybutanediamide Chemical compound NC(=O)CCC(=O)NO HOGDNTQCSIKEEV-UHFFFAOYSA-N 0.000 claims description 9
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 9
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 9
- 239000008367 deionised water Substances 0.000 claims description 8
- 229910021641 deionized water Inorganic materials 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 2
- 230000003213 activating effect Effects 0.000 claims 1
- VGGRCVDNFAQIKO-UHFFFAOYSA-N formic anhydride Chemical compound O=COC=O VGGRCVDNFAQIKO-UHFFFAOYSA-N 0.000 claims 1
- 229910052622 kaolinite Inorganic materials 0.000 claims 1
- 238000012986 modification Methods 0.000 claims 1
- 230000004048 modification Effects 0.000 claims 1
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 abstract 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 abstract 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 230000000845 anti-microbial effect Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003245 coal Substances 0.000 description 4
- 239000011435 rock Substances 0.000 description 4
- 229920006305 unsaturated polyester Polymers 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000013011 mating Effects 0.000 description 3
- 230000002787 reinforcement Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 230000003115 biocidal effect Effects 0.000 description 2
- 238000002242 deionisation method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- SEGBQNJGOCXIGC-FHERZECASA-N benzyl n-[(2s)-1-[(4-hydroxyoxolan-3-yl)amino]-4-methyl-1-oxopentan-2-yl]carbamate Chemical group N([C@@H](CC(C)C)C(=O)NC1C(COC1)O)C(=O)OCC1=CC=CC=C1 SEGBQNJGOCXIGC-FHERZECASA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000013521 mastic Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000007569 slipcasting Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
- C08G63/553—Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
- C08K7/24—Expanded, porous or hollow particles inorganic
- C08K7/26—Silicon- containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/08—Ingredients agglomerated by treatment with a binding agent
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21D—SHAFTS; TUNNELS; GALLERIES; LARGE UNDERGROUND CHAMBERS
- E21D20/00—Setting anchoring-bolts
- E21D20/02—Setting anchoring-bolts with provisions for grouting
- E21D20/025—Grouting with organic components, e.g. resin
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mining & Mineral Resources (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a low-viscosity unsaturated polyester resin for anchoring agents. The low-viscosity unsaturated polyester resin comprises the following raw materials by weight: 20-40 parts of phthalic anhydride, 5-15 parts of abietic acid, 10-18 parts of cis-methyl butenedioic acid, 8-16 parts of fumaric acid, 20-35 parts of neopentyl glycol, 5-15 parts of ethylene glycol, 10-20 parts of 1, 2-propylene glycol, 5-15 parts of methyl methacrylate, 20-50 parts of trichloroethyl phosphate, 1-6 parts of a modified molecular sieve, and 1-5 parts of hydroquinone. The low-viscosity unsaturated polyester resin provided by the invention has the advantages of low viscosity, high strength, good antibacterial properties and high rigidity, thus being able to satisfy the demands in actual use.
Description
Technical field
The present invention relates to unsaturated polyester resin technical field, more particularly, to a kind of Anchor Agent low viscosity unsaturated polyester (UP)
Resin.
Background technology
In the underground engineerings such as mine, tunnel, particularly in coal mining engineering, be frequently encountered broken coal and rock and
The problem that other country rocks need reinforcement is it is common practice to being supported using canopy formula support or coordinating resin with anchor pole and anchor cable
Anchor Agent carries out its support reinforcement.Resin anchoring agent typically uses the resin-bonded mastic that the filler such as unsaturated polyester resin and stone powder is constituted to make
For adhesive, but current unsaturated polyester resin is as slip casting strengthening material, there is that viscosity is big, antibiotic property is poor, and rigidity
Can not meet the defect of demand it would be highly desirable to solve.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of Anchor Agent low viscosity unsaturated polyester (UP) tree
Fat, viscosity is low, and intensity is high, and anti-microbial property is good, and has higher rigidity, can meet the demand during reality uses.
A kind of Anchor Agent low viscosity unsaturated polyester resin proposed by the present invention, its raw material includes by weight：Adjacent benzene
Dicarboxylic acid anhydride 20-40 part, rosin acid 5-15 part, cis-methyl-butene diacid 10-18 part, fumaric acid 8-16 part, new penta 2
Alcohol 20-35 part, ethylene glycol 5-15 part, 1,2-PD 10-20 part, methyl methacrylate 5-15 part, trichloroethyl phosphate
20-50 part, modified molecular screen 1-6 part, hydroquinone 1-5 part.
Preferably, modified molecular screen adopts following technique preparation：By Cera Flava, deionized water mix and blend, surface is added to live
Property agent BS-12 stirring, add polyhexamethylene guanidine, carbodiimides, N-hydroxy-succinamide stirring, heat up, stirring, adjust
System pH, to 7.5-8, continues stirring and obtains modified beeswaxes；By sodium polyacrylate, water mix and blend, add molecular sieve, adjust
System pH, to 7.5-8, stirs, and adds Kaolin, modified beeswaxes mix homogeneously, microwave drying, calcining, pulverizes and obtains modified point
Son sieve.
Preferably, modified molecular screen adopts following technique preparation：By weight by 2-10 part Cera Flava, 30-60 part deionization
Water mix and blend, adds the stirring of 0.2-0.9 part surfactant B S-12, adds 0.2-0.8 part polyhexamethylene guanidine, 0.5-1.2
Part carbodiimides, the stirring of 1-2 part N-hydroxy-succinamide, heat up, stirring, and regulation system pH value to 7.5-8 continues to stir
Obtain modified beeswaxes；By weight by 2-8 part sodium polyacrylate, 50-80 part water mix and blend, add 2-10 part molecular sieve, adjust
Section system pH, to 7.5-8, stirs, and adds 2-10 part Kaolin, 1-4 part modified beeswaxes mix homogeneously, microwave drying, calcines,
Pulverizing obtains modified molecular screen.
Preferably, modified molecular screen adopts following technique preparation：By weight by 2-10 part Cera Flava, 30-60 part deionization
Water mix and blend 30-80min, whipping temp is 75-88 DEG C, adds 0.2-0.9 part surfactant B S-12 stirring 30-
70min, mixing speed be 2000-3500r/min, add 0.2-0.8 part polyhexamethylene guanidine, 0.5-1.2 part carbodiimides,
The stirring of 1-2 part N-hydroxy-succinamide stirs 20-40min in temperature 34-45 DEG C, and regulation system pH value, to 7.5-8, continues to stir
Mix 40-100min, obtain modified beeswaxes；By weight by 2-8 part sodium polyacrylate, 50-80 part water mix and blend 6-10h, stir
Mixing speed is 3000-6000r/min, adds 2-10 part molecular sieve, regulation system pH value to 7.5-8, stirs 2-4h, whipping temp
For 65-75 DEG C, add 2-10 part Kaolin, 1-4 part modified beeswaxes mix homogeneously, microwave drying to water content is 20-30wt%,
700-900 DEG C of calcining 40-100min, pulverizes and obtains modified molecular screen.
Preferably, phthalic anhydride, rosin acid, cis-methyl-butene diacid, fumaric acid, neopentyl glycol, second two
Alcohol, the weight of 1,2- propylene glycol are than for 25-35：8-12：12-16：10-14：25-30：8-12：13-17.
Preferably, the weight of modified molecular screen, hydroquinone, methyl methacrylate is than for 3-5：2-4：8-12.
Preferably, its raw material includes by weight：Phthalic anhydride 25-35 part, rosin acid 8-12 part, cis methyl fourth
Enedioic acid 12-16 part, fumaric acid 10-14 part, neopentyl glycol 25-30 part, ethylene glycol 8-12 part, 1,2-PD 13-17
Part, methyl methacrylate 8-12 part, trichloroethyl phosphate 30-40 part, modified molecular screen 3-5 part, hydroquinone 2-4 part.
The present invention adopts conventional fabrication process to be obtained.
The present invention adopt phthalic anhydride, rosin acid, cis-methyl-butene diacid, fumaric acid and neopentyl glycol,
Ethylene glycol, 1,2-PD mating reaction, make viscosity of the present invention low, and intensity is high, then with modified molecular screen mating reaction, antibiotic property
Can be good, rigidity is strong；The modified molecular screen mechanical property of the present invention is good, high temperature resistant, and absorption property is excellent, even if high/low temperature is handed over
Also can keep constant for lower mechanical property, and modified beeswaxes and Kaolin, molecular sieve mating reaction, mutual dispersibility is fabulous,
Make modified molecular screen anti-microbial property fabulous, Kaolin, molecular sieve can make modified beeswaxes slowly discharge simultaneously, extend antibacterial time,
Due to the good waterproof performance of modified beeswaxes, anti-microbial property is excellent, by graft reaction, polyhexamethylene guanidine is grafted on Cera Flava surface,
The coupling reagent carbodiimides adding, N-hydroxy-succinamide can effectively improve grafting efficiency, and anti-microbial property is extremely excellent,
And good dispersion, with phthalic anhydride, rosin acid, cis-methyl-butene diacid, fumaric acid, neopentyl glycol, second two
Alcohol, 1,2-PD are uniformly dispersed, cooperation methyl methacrylate, hydroquinone effect, make viscosity of the present invention little, can be easy to
Penetrate in minute fissure or the loose structure of coal and rock, loose, broken coal and rock are bonded to firm overall structure,
Play the effect of structural strengthening and reinforcement, thus preventing the generation of the disasters such as roof fall, wall caving.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of Anchor Agent low viscosity unsaturated polyester resin proposed by the present invention, its raw material includes by weight：Adjacent benzene
20 parts of dicarboxylic acid anhydride, 15 parts of rosin acid, 10 parts of cis-methyl-butene diacid, 16 parts of fumaric acid, 20 parts of neopentyl glycol, second two
15 parts of alcohol, 10 parts of 1,2-PD, 15 parts of methyl methacrylate, 20 parts of trichloroethyl phosphate, 6 parts of modified molecular screen, right
1 part of Benzodiazepiness.
Embodiment 2
A kind of Anchor Agent low viscosity unsaturated polyester resin proposed by the present invention, its raw material includes by weight：Adjacent benzene
40 parts of dicarboxylic acid anhydride, 5 parts of rosin acid, 18 parts of cis-methyl-butene diacid, 8 parts of fumaric acid, 35 parts of neopentyl glycol, ethylene glycol
5 parts, 20 parts of 1,2-PD, 5 parts of methyl methacrylate, 50 parts of trichloroethyl phosphate, 1 part of modified molecular screen, to benzene two
5 parts of phenol.
Modified molecular screen adopts following technique preparation：By Cera Flava, deionized water mix and blend, add surfactant B S-
12 stirrings, add polyhexamethylene guanidine, carbodiimides, N-hydroxy-succinamide stirring, heat up, stirring, regulation system pH
It is worth to 7.5-8, continue stirring and obtain modified beeswaxes；By sodium polyacrylate, water mix and blend, add molecular sieve, regulation system pH
It is worth to 7.5-8, stirs, add Kaolin, modified beeswaxes mix homogeneously, microwave drying, calcining, pulverize and obtain modified molecular screen.
Embodiment 3
A kind of Anchor Agent low viscosity unsaturated polyester resin proposed by the present invention, its raw material includes by weight：Adjacent benzene
25 parts of dicarboxylic acid anhydride, 12 parts of rosin acid, 12 parts of cis-methyl-butene diacid, 14 parts of fumaric acid, 25 parts of neopentyl glycol, second two
12 parts of alcohol, 13 parts of 1,2-PD, 12 parts of methyl methacrylate, 30 parts of trichloroethyl phosphate, 5 parts of modified molecular screen, right
2 parts of Benzodiazepiness.
Modified molecular screen adopts following technique preparation：By weight by 10 parts of Cera Flavas, 30 parts of deionized water mix and blends
80min, whipping temp is 75 DEG C, adds 0.9 part of surfactant B S-12 to stir 30min, and mixing speed is 3500r/min, plus
Enter 0.2 part of polyhexamethylene guanidine, 1.2 parts of carbodiimides, 1 part of N-hydroxy-succinamide stirring in temperature 45 C stirring
20min, regulation system pH value to 7.5-8, continues stirring 100min, obtains modified beeswaxes；By weight by 2 parts of polyacrylic acid
Sodium, 80 parts of water mix and blend 6h, mixing speed is 6000r/min, adds 2 parts of molecular sieves, and regulation system pH value, to 7.5-8, stirs
Mix 4h, whipping temp is 65 DEG C, add 10 parts of Kaolin, 1 part of modified beeswaxes mix homogeneously, microwave drying to water content is
30wt%, 700 DEG C of calcining 100min, pulverize and obtain modified molecular screen.
Embodiment 4
A kind of Anchor Agent low viscosity unsaturated polyester resin proposed by the present invention, its raw material includes by weight：Adjacent benzene
35 parts of dicarboxylic acid anhydride, 8 parts of rosin acid, 16 parts of cis-methyl-butene diacid, 10 parts of fumaric acid, 30 parts of neopentyl glycol, second two
8 parts of alcohol, 17 parts of 1,2-PD, 8 parts of methyl methacrylate, 40 parts of trichloroethyl phosphate, 3 parts of modified molecular screen, to benzene
4 parts of diphenol.
Modified molecular screen adopts following technique preparation：By weight by 2 parts of Cera Flavas, 60 parts of deionized water mix and blends
30min, whipping temp is 88 DEG C, adds 0.2 part of surfactant B S-12 to stir 70min, and mixing speed is 2000r/min, plus
Enter 0.8 part of polyhexamethylene guanidine, 0.5 part of carbodiimides, 2 parts of N-hydroxy-succinamide stirrings in 34 DEG C of stirrings of temperature
40min, regulation system pH value to 7.5-8, continues stirring 40min, obtains modified beeswaxes；By weight by 8 parts of sodium polyacrylate,
50 parts of water mix and blend 10h, mixing speed is 3000r/min, adds 10 parts of molecular sieves, regulation system pH value to 7.5-8, stirring
2h, whipping temp is 75 DEG C, adds 2 parts of Kaolin, 4 parts of modified beeswaxes mix homogeneously, microwave drying to water content is 20wt%,
900 DEG C of calcining 40min, pulverize and obtain modified molecular screen.
Embodiment 5
A kind of Anchor Agent low viscosity unsaturated polyester resin proposed by the present invention, its raw material includes by weight：Adjacent benzene
30 parts of dicarboxylic acid anhydride, 10 parts of rosin acid, 14 parts of cis-methyl-butene diacid, 12 parts of fumaric acid, 28 parts of neopentyl glycol, second two
10 parts of alcohol, 15 parts of 1,2-PD, 10 parts of methyl methacrylate, 35 parts of trichloroethyl phosphate, 4 parts of modified molecular screen, right
3 parts of Benzodiazepiness.
Modified molecular screen adopts following technique preparation：By weight by 6 parts of Cera Flavas, 45 parts of deionized water mix and blends, plus
Enter 0.5 part of surfactant B S-12 stirring, add 0.5 part of polyhexamethylene guanidine, 0.7 part of carbodiimides, 1.2 parts of N- hydroxyls
Butanimide stirs, and heats up, stirring, regulation system pH value to 7.5-8, continues stirring and obtains modified beeswaxes；By weight by 5
Part sodium polyacrylate, 65 parts of water mix and blends, add 6 parts of molecular sieves, regulation system pH value to 7.5-8, stirring, add 6 parts high
Ridge soil, 2.5 parts of modified beeswaxes mix homogeneously, microwave drying, calcining, pulverize and obtain modified molecular screen.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. a kind of Anchor Agent low viscosity unsaturated polyester resin is it is characterised in that its raw material includes by weight：O-phthalic
Anhydride 20-40 part, rosin acid 5-15 part, cis-methyl-butene diacid 10-18 part, fumaric acid 8-16 part, neopentyl glycol 20-
35 parts, ethylene glycol 5-15 part, 1,2-PD 10-20 part, methyl methacrylate 5-15 part, trichloroethyl phosphate 20-50
Part, modified molecular screen 1-6 part, hydroquinone 1-5 part.
2. according to claim 1 Anchor Agent low viscosity unsaturated polyester resin it is characterised in that modified molecular screen adopt
Following technique preparation：By Cera Flava, deionized water mix and blend, add the stirring of surfactant B S-12, add polyhexamethylene
Guanidine, carbodiimides, N-hydroxy-succinamide stirring, heat up, stirring, and regulation system pH value to 7.5-8 continues stirring and obtains
Modified beeswaxes；By sodium polyacrylate, water mix and blend, add molecular sieve, regulation system pH value to 7.5-8, stirring, add kaolinite
Soil, modified beeswaxes mix homogeneously, microwave drying, calcining, pulverize and obtain modified molecular screen.
3. Anchor Agent low viscosity unsaturated polyester resin according to claim 1 or claim 2 is it is characterised in that modified molecular screen
Using the preparation of following technique：By weight by 2-10 part Cera Flava, 30-60 part deionized water mix and blend, add 0.2-0.9 part table
Face activating agent BS-12 stirs, and adds 0.2-0.8 part polyhexamethylene guanidine, 0.5-1.2 part carbodiimides, 1-2 part N- hydroxyl amber
Amber acid imide stirs, and heats up, stirring, regulation system pH value to 7.5-8, continues stirring and obtains modified beeswaxes；By weight by 2-8
Part sodium polyacrylate, 50-80 part water mix and blend, add 2-10 part molecular sieve, regulation system pH value to 7.5-8, stirring, add
2-10 part Kaolin, 1-4 part modified beeswaxes mix homogeneously, microwave drying, calcining, pulverize and obtain modified molecular screen.
4. according to any one of claim 1-3 Anchor Agent low viscosity unsaturated polyester resin it is characterised in that modified point
Son sieve is using following technique preparation：By weight by 2-10 part Cera Flava, 30-60 part deionized water mix and blend 30-80min, stir
Mix temperature and be 75-88 DEG C, add 0.2-0.9 part surfactant B S-12 stirring 30-70min, mixing speed is 2000-
3500r/min, adds 0.2-0.8 part polyhexamethylene guanidine, 0.5-1.2 part carbodiimides, 1-2 part N-hydroxy-succinamide
Stirring stirs 20-40min, regulation system pH value to 7.5-8 in temperature 34-45 DEG C, continues stirring 40-100min, obtains modification
Cera Flava；By weight by 2-8 part sodium polyacrylate, 50-80 part water mix and blend 6-10h, mixing speed is 3000-6000r/
Min, adds 2-10 part molecular sieve, regulation system pH value to 7.5-8, stirs 2-4h, whipping temp is 65-75 DEG C, add 2-10
Part Kaolin, 1-4 part modified beeswaxes mix homogeneously, microwave drying to water content is 20-30wt%, 700-900 DEG C of calcining 40-
100min, pulverizes and obtains modified molecular screen.
5. according to any one of claim 1-4 Anchor Agent low viscosity unsaturated polyester resin it is characterised in that adjacent benzene two
Formic anhydride, rosin acid, cis-methyl-butene diacid, fumaric acid, neopentyl glycol, ethylene glycol, the weight ratio of 1,2- propylene glycol
For 25-35：8-12：12-16：10-14：25-30：8-12：13-17.
6. according to any one of claim 1-5 Anchor Agent low viscosity unsaturated polyester resin it is characterised in that modified point
Sub- sieve, hydroquinone, the weight ratio of methyl methacrylate are for 3-5：2-4：8-12.
7. according to any one of claim 1-6 Anchor Agent low viscosity unsaturated polyester resin it is characterised in that its raw material
Include by weight：Phthalic anhydride 25-35 part, rosin acid 8-12 part, cis-methyl-butene diacid 12-16 part, anti-butylene
Diacid 10-14 part, neopentyl glycol 25-30 part, ethylene glycol 8-12 part, 1,2-PD 13-17 part, methyl methacrylate 8-12
Part, trichloroethyl phosphate 30-40 part, modified molecular screen 3-5 part, hydroquinone 2-4 part.
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| CN201610735569.1A CN106380582A (en) | 2016-08-27 | 2016-08-27 | Low-viscosity unsaturated polyester resin for anchoring agents |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107903601A (en) * | 2017-12-21 | 2018-04-13 | 吴江市强塑阀门管件厂 | A kind of preparation method and applications of anti-aging plastics tubing |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186779A (en) * | 2007-12-10 | 2008-05-28 | 华南理工大学 | Halogen-free anti-flaming transparent unsaturated polyester insulated dope and preparation method thereof |
| CN102516468A (en) * | 2011-12-28 | 2012-06-27 | 浙江天和树脂有限公司 | Unsaturated polyester resin with high cohesive force and high wettability and preparation method for unsaturated polyester resin |
-
2016
- 2016-08-27 CN CN201610735569.1A patent/CN106380582A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101186779A (en) * | 2007-12-10 | 2008-05-28 | 华南理工大学 | Halogen-free anti-flaming transparent unsaturated polyester insulated dope and preparation method thereof |
| CN102516468A (en) * | 2011-12-28 | 2012-06-27 | 浙江天和树脂有限公司 | Unsaturated polyester resin with high cohesive force and high wettability and preparation method for unsaturated polyester resin |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107903601A (en) * | 2017-12-21 | 2018-04-13 | 吴江市强塑阀门管件厂 | A kind of preparation method and applications of anti-aging plastics tubing |
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Application publication date: 20170208 |