CN105859188A - Strengthening agent prepared from fly ash - Google Patents
Strengthening agent prepared from fly ash Download PDFInfo
- Publication number
- CN105859188A CN105859188A CN201610245006.4A CN201610245006A CN105859188A CN 105859188 A CN105859188 A CN 105859188A CN 201610245006 A CN201610245006 A CN 201610245006A CN 105859188 A CN105859188 A CN 105859188A
- Authority
- CN
- China
- Prior art keywords
- component
- parts
- flyash
- mass ratio
- prepared
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/01—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to unsaturated polyesters
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00724—Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a strengthening agent prepared from fly ash. The strengthening agent contains a component A and a component B, wherein the component A is prepared from the following raw materials in parts by mass: 100 parts of unsaturated polyester resin, 0.5-2 parts of cross-linker, 0.5-2.5 parts of white carbon black, 0.5-1.5 parts of dimethylaniline and 300-450 parts of fly ash; the component B is prepared from the following raw materials in parts by mass: 50 parts of 50% benzoyl peroxide paste and 50 parts of one or a mixture of more of heavy calcium carbonate, talcum powder and kaolin. The finished product, i.e., the strengthening agent is obtained through separately preparing the component A and the component B, and then, sampling and mixing the component A and the component B according to the mass ratio of 100: (2 to 10). According to the strengthening agent prepared from the fly ash, disclosed by the invention, the preparation process is simple, the cost is low, and the strengthening agent has the advantages of being cost effective and environment-protective and being capable of changing wastes into valuables.
Description
Technical field
The present invention relates to a kind of strengthening agent, particularly relate to a kind of strengthening agent prepared by flyash.
Background technology
In coalfield, the deformation low, broken of coal seam comprcssive strength, easily produce crack and bigger fracture belt, crush loose enclosing
Petrographic province and fracture extension zone easily roof fall in the case of dynamic pressure increases, generation underground floods etc., by noting in the broken rock of coal seam
Enter polymer chemistry strengthening agent can be bonded together in crack and crack, be finally reached the purpose of reinforcement of coal and rock.Existing reinforcing
Agent has the shortcomings such as slurry deficiency stiff, pliable and tough, expensive, comprcssive strength is low, poor durability, and some serosity also has poison
Property, environmental pollution can be caused, so being badly in need of developing a kind of low cost, the strengthening agent of protection environment.
Summary of the invention
The technical problem to be solved in the present invention is to provide that a kind of preparation process is simple, low cost, have economic benefit, protection environment,
The strengthening agent prepared by flyash that can turn waste into wealth.
A kind of strengthening agent prepared by flyash, including component A and B component, described component A is by the raw material structure of following mass parts
Become:
Unsaturated polyester resin 100 parts；
Cross-linking agent: 0.5～2 part；
White carbon: 0.5～2.5 part；
Dimethylaniline: 0.5～1.5 part；
Flyash: 300～450 parts；
Described B component includes the raw material of following mass parts:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, Pulvis Talci, Kaolin: 50 parts；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The strengthening agent prepared by flyash of the present invention, wherein, described unsaturated polyester resin is MG Anchor Agent resin, institute
Stating cross-linking agent is styrene, and described flyash is 10～80 mesh.
The strengthening agent prepared by flyash of the present invention, wherein, described B component also includes 2,4-dichlorobenzoperoxide:
1.5～2.5 parts.
The strengthening agent prepared by flyash of the present invention, including triple superphosphate, Pulvis Talci, kaolinic mixture, mass ratio is
2:2:1。
The strengthening agent prepared by flyash of the present invention, is made up of component A and B component, and described component A is by following quality
The raw material of part is constituted:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5～2 part；
White carbon: consumption 0.5～2 parts；
Dimethylaniline: 0.6～1.2 part；
Flyash: 320～420 parts；
Described B component is made up of the raw material of following mass parts:
50% benzoyl peroxide is stuck with paste: 50 parts；
2,4-dichlorobenzoperoxide: 2.5 parts；
One or both mixture in triple superphosphate, slider powder: 50 parts；
When selecting mixture, triple superphosphate and talcous mass ratio are 3:2 or 1:1；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The strengthening agent prepared by flyash of the present invention, is made up of component A and B component, and described component A is by following quality
Raw material constitute:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5～2 part；
White carbon: 0.5～2 part；
Dimethylaniline: 0.5～1.5 part；
Flyash: 350～450 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
2,4-dichlorobenzoperoxide: 1.5～2.5 parts；
One or both mixture in triple superphosphate, slider powder: 50 parts；
When selecting mixture, triple superphosphate and talcous mass ratio are 3:2 or 1:1；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The strengthening agent prepared by flyash of the present invention, is made up of component A and B component, and described component A is by following quality
Raw material constitute:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5～1.5 part；
White carbon: 0.5～1.5 part；
Dimethylaniline: 0.5～1.5 part；
Flyash: 340～440 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, slider powder, Kaolin: 50 parts；
When using three kinds of mixing when, triple superphosphate, Pulvis Talci, kaolinic mass ratio is 2:2:1 or 3:1:1 or 1:3:1；
When using triple superphosphate and Kaolin mixing, mass ratio is 3:2 or 1:1；
When using triple superphosphate and Pulvis Talci mixing, mass ratio is 1:1 or 3:2；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The strengthening agent prepared by flyash of the present invention, is made up of component A and B component, and described component A is by following quality
Raw material constitute:
MG Anchor Agent resin: 100 parts；
Styrene: 1～2 part；
White carbon: 0.5～2.5 part；
Dimethylaniline: 1～1.5 part；
Flyash: 300～400 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, slider powder, Kaolin: 50 parts；
When using three kinds of mixing when, triple superphosphate, Pulvis Talci, kaolinic mass ratio is 2:2:1 or 3:1:1,
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The preparation method of the strengthening agent prepared by flyash of the present invention, comprises the steps:
Preparation component A and B component respectively:
Component A: prepare raw material in proportion, pours into unsaturated polyester resin in container tank, starts agitator, stirs 20 minutes
After, white carbon being put in container, be mixed and stirred for 30 minutes, observe solution colour, solid colour is and stirs, stirs
Mixing speed controlling within 200r/min, winter suitably heats, and temperature, within 60 DEG C, adds dimethylaniline and stirs,
Add flyash after standing 30min, be stirred into clay shape standby；
B component: prepare raw material in proportion, puts into rustless steel by the mixture of one or more in triple superphosphate, slider powder, Kaolin
Blender in, feed intake while stir, mix homogeneously, then by 50% benzoyl peroxide stick with paste put in the powder stirred,
Feed intake while stir, after 50% benzoyl peroxide magma feeds intake, continue stirring 30 minutes, standby after mixing and stirring.
After having prepared, component A is mixed with mass ratio 100:2～10 sampling with B component, obtain final products.
The preparation method of the strengthening agent prepared by flyash of the present invention, wherein, the system that described 50% benzoyl peroxide is stuck with paste
Preparation Method comprises the steps:
In the porcelain enamel barrel of 20 liters, put into the sodium hydroxide solution that 2400ml contains 40%, start stirring, be cooled to 0 DEG C, slow
The slow 40% hydrogen peroxide 1200ml that adds, continuation cooling, control temperature, between 0～3 DEG C, drips Benzenecarbonyl chloride. 2820g by pipette,
Rate of addition wants slow, and when in bucket there to be White Flocculus to occur, benzoyl peroxide nucleus has been formed, and rate of addition is the fastest
A bit, Benzenecarbonyl chloride. dripped off in 90 minutes；
By reactant transfer washing and filtering, until neutral, get product, keep water content 20%～30%；
After the product keeping 20%-30% water content is measured water content, benzoyl peroxide is added dibutyl phthalate
The benzoyl peroxide obtaining 50% is stuck with paste；
Wherein, described cooling procedure uses refrigerated with ice or cools down at porcelain enamel barrel external adding water.
In the present invention, unsaturated polyester resin is exactly MG Anchor Agent resin, is commercially available prod, such as: Huainan City of Anhui Province
The most on sale along brightness anchoring company limited, Handan, Hebei.2,4-dichlorobenzoperoxides are a kind of strong oxidizers, rise in this formula
To playing quick-setting effect.
The strengthening agent difference from prior art that the present invention is prepared by flyash is:
The present invention sets up and reduces in resource, on the basis of country greatly develops the strategy of sustainable development.Utilize the powder that coal burning produces
Coal ash extracts the pure rejected fly ash high-efficiency comprehensive utilization once again after the metals such as ferrum therein, aluminum.Flyash is utilized to produce strengthening agent,
Big by ash quantity, be easy to promote.The yield of strengthening agent can be increased, also can improve the performance of strengthening agent, again flyash be used coal
Charcoal is exploited, it is achieved that recycles, decreases the pollution to environment, make use of again industrial waste.
The strengthening agent of the flyash preparation of the present invention is as main material by the flyash to turn waste into wealth, special macromolecular material,
The compound formulated double-component product such as firming agent and auxiliary additive, the product plasticity of the present invention is good, intensity is high, gel
Hardening time, degree of amplitude modulation was big, and comprcssive strength, withdrawal resistance, anchor force, thermal stability etc. will be higher than strengthening agent on the market
Go out many.And coordinative construction environment can be required according to technology, it is possible to make Different Package form as required and use.There is use
Property wide, for mine down-hole work surface, bridge, the support reinforcement in tunnel, building aspect may be used on the ground that whole construction completes
Base and the construction of girder, bridge, tunnel, bank protection and seismic hardening etc. all can use.The present invention not only has economic benefit
And the social effect having protection environment, turning waste into wealth.
Below in conjunction with specific embodiment, the strengthening agent prepared by flyash of the present invention is described further.
Detailed description of the invention
Embodiment 1
A kind of strengthening agent prepared by flyash, including component A and B component, described component A is by the raw material structure of following mass parts
Become:
Unsaturated polyester resin 100 parts；
Cross-linking agent: 2 parts；
White carbon: 2.5 parts；
Dimethylaniline: 1.5 parts；
Flyash: 450 parts；
Described B component includes the raw material of following mass parts:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, Pulvis Talci, Kaolin: 50 parts.
Described unsaturated polyester resin is MG Anchor Agent resin, and described cross-linking agent is styrene, and described flyash is 10～80 mesh.
Preparation component A and B component respectively, mixes component A with mass ratio 100:2 sampling with B component after having prepared,
To final products.
Embodiment 2
A kind of strengthening agent prepared by flyash, including component A and B component, described component A is by the raw material structure of following mass parts
Become:
Unsaturated polyester resin 100 parts；
Cross-linking agent: 0.5 part；
White carbon: 0.5 part；
Dimethylaniline: 0.5 part；
Flyash: 300 parts；
Described B component includes the raw material of following mass parts:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, Pulvis Talci, Kaolin: 50 parts.
Described unsaturated polyester resin is MG Anchor Agent resin, and described cross-linking agent is styrene, and described flyash is 10～80 mesh.
Preparation component A and B component respectively, mixes component A with mass ratio 100:10 sampling with B component after having prepared,
Obtain final products.
Embodiment 3
Difference with embodiment 1 is: described B component also includes 2,4-dichlorobenzoperoxide: 1.5 parts.Prepare A respectively
Component and B component, mix component A with mass ratio 100:3 sampling with B component after having prepared, obtain final products.
Embodiment 4
Difference with embodiment 1 is: described B component also includes 2,4-dichlorobenzoperoxide: 2.5 parts, and include triple superphosphate,
Pulvis Talci, kaolinic mixture, mass ratio is 2:2:1.Preparation component A and B component respectively, by A group after having prepared
Divide and mix with mass ratio 100:4 sampling with B component, obtain final products.
Embodiment 5
A kind of strengthening agent prepared by flyash, is made up of component A and B component, and described component A is by the raw material of following mass parts
Constitute:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5 part；
White carbon: consumption 0.5 part；
Dimethylaniline: 0.6 part；
Flyash: 320 parts；
Described B component is made up of the raw material of following mass parts:
50% benzoyl peroxide is stuck with paste: 50 parts；
2,4-dichlorobenzoperoxide: 2.5 parts；
One or both mixture in triple superphosphate, slider powder: 50 parts；
When selecting mixture, triple superphosphate and talcous mass ratio are 3:2.
Preparation component A and B component respectively, mixes component A with mass ratio 100:5 sampling with B component after having prepared,
To final products.
Embodiment 6
A kind of strengthening agent prepared by flyash, is made up of component A and B component, and described component A is by the raw material of following mass parts
Constitute:
MG Anchor Agent resin: 100 parts；
Styrene: 2 parts；
White carbon: consumption 2 parts；
Dimethylaniline: 1.2 parts；
Flyash: 420 parts；
Described B component is made up of the raw material of following mass parts:
50% benzoyl peroxide is stuck with paste: 50 parts；
2,4-dichlorobenzoperoxide: 2.5 parts；
One or both mixture in triple superphosphate, slider powder: 50 parts；
When selecting mixture, triple superphosphate and talcous mass ratio are 1:1.
Preparation component A and B component respectively, mixes component A with mass ratio 100:6 sampling with B component after having prepared,
To final products.
Embodiment 7
A kind of strengthening agent prepared by flyash, is made up of component A and B component, and described component A is by the raw material structure of following quality
Become:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5 part；
White carbon: 0.5 part；
Dimethylaniline: 0.5 part；
Flyash: 350 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
2,4-dichlorobenzoperoxide: 1.5 parts；
One or both mixture in triple superphosphate, slider powder: 50 parts；
When selecting mixture, triple superphosphate and talcous mass ratio are 3:2 or 1:1.
Preparation component A and B component respectively, mixes component A with mass ratio 100:7 sampling with B component after having prepared,
To final products.
Embodiment 8
A kind of strengthening agent prepared by flyash, is made up of component A and B component, and described component A is by the raw material structure of following quality
Become:
MG Anchor Agent resin: 100 parts；
Styrene: 2 parts；
White carbon: 2 parts；
Dimethylaniline: 1.5 parts；
Flyash: 450 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
2,4-dichlorobenzoperoxide: 2.5 parts；
One or both mixture in triple superphosphate, slider powder: 50 parts；
When selecting mixture, triple superphosphate and talcous mass ratio are 3:2 or 1:1.
Preparation component A and B component respectively, mixes component A with mass ratio 100:8 sampling with B component after having prepared,
To final products.
Embodiment 9
A kind of strengthening agent prepared by flyash, is made up of component A and B component, and described component A is by the raw material structure of following quality
Become:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5 part；
White carbon: 0.5 part；
Dimethylaniline: 0.5 part；
Flyash: 340 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, slider powder, Kaolin: 50 parts；
When using three kinds of mixing when, triple superphosphate, Pulvis Talci, kaolinic mass ratio is 2:2:1 or 3:1:1；
When using triple superphosphate and Kaolin mixing, mass ratio is 3:2；
When using triple superphosphate and Pulvis Talci mixing, mass ratio is 1:1.
Preparation component A and B component respectively, mixes component A with mass ratio 100:9 sampling with B component after having prepared,
To final products.
Embodiment 10
A kind of strengthening agent prepared by flyash, is made up of component A and B component, and described component A is by the raw material structure of following quality
Become:
MG Anchor Agent resin: 100 parts；
Styrene: 1.5 parts；
White carbon: 1.5 parts；
Dimethylaniline: 1.5 parts；
Flyash: 440 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, slider powder, Kaolin: 50 parts；
When using three kinds of mixing when, triple superphosphate, Pulvis Talci, kaolinic mass ratio is 1:3:1；
When using triple superphosphate and Kaolin mixing, mass ratio is 1:1；
When using triple superphosphate and Pulvis Talci mixing, mass ratio is 3:2.
Preparation component A and B component respectively, mixes component A with mass ratio 100:2 sampling with B component after having prepared,
To final products.
Embodiment 11
The strengthening agent prepared by flyash of the present invention, is made up of component A and B component, and described component A is by following quality
Raw material constitute:
MG Anchor Agent resin: 100 parts；
Styrene: 1 part；
White carbon: 0.5 part；
Dimethylaniline: 1 part；
Flyash: 300 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, slider powder, Kaolin: 50 parts；
When using three kinds of mixing when, triple superphosphate, Pulvis Talci, kaolinic mass ratio is 2:2:1.
Preparation component A and B component respectively, mixes component A with mass ratio 100:10 sampling with B component after having prepared,
Obtain final products.
Embodiment 12
The strengthening agent prepared by flyash of the present invention, is made up of component A and B component, and described component A is by following quality
Raw material constitute:
MG Anchor Agent resin: 100 parts；
Styrene: 2 parts；
White carbon: 2.5 parts；
Dimethylaniline: 1.5 parts；
Flyash: 400 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, slider powder, Kaolin: 50 parts；
When using three kinds of mixing when, triple superphosphate, Pulvis Talci, kaolinic mass ratio is 3:1:1.
Preparation component A and B component respectively, mixes component A with mass ratio 100:3 sampling with B component after having prepared,
To final products.
Embodiment 13
The preparation method of a kind of strengthening agent prepared by flyash of the present invention, comprises the steps:
Preparation component A and B component respectively:
Component A: prepare raw material in proportion, pours into unsaturated polyester resin in container tank, starts agitator, stirs 20 minutes
After, white carbon being put in container, be mixed and stirred for 30 minutes, observe solution colour, solid colour is and stirs, stirs
Mixing speed controlling within 200r/min, winter suitably heats, and temperature, within 60 DEG C, adds dimethylaniline and stirs,
Add flyash after standing 30min, be stirred into clay shape standby；
B component: prepare raw material in proportion, puts into stainless by the mixture of one or more in triple superphosphate, slider powder, Kaolin
In the blender of steel, feed intake while stir, mix homogeneously, then 50% benzoyl peroxide paste is put into the powder stirred
In, feed intake while stir, after 50% benzoyl peroxide magma feeds intake, continue stirring 30 minutes, after mixing and stirring
Standby.
After having prepared, component A is mixed with mass ratio 100:2～10 sampling with B component, obtain final products.
Wherein, the preparation method that described 50% benzoyl peroxide is stuck with paste comprises the steps:
In the porcelain enamel barrel of 20 liters, put into the sodium hydroxide solution that 2400ml contains 40%, start stirring, be cooled to 0 DEG C, slow
The slow 40% hydrogen peroxide 1200ml that adds, continuation cooling, control temperature, between 0～3 DEG C, drips Benzenecarbonyl chloride. 2820g by pipette,
Rate of addition wants slow, and when in bucket there to be White Flocculus to occur, benzoyl peroxide nucleus has been formed, and rate of addition is the fastest
A bit, Benzenecarbonyl chloride. dripped off in 90 minutes；
By reactant transfer washing and filtering, until neutral, get product, keep water content 20%～30%；
After the product keeping 20%-30% water content is measured water content, benzoyl peroxide is added dibutyl phthalate
The benzoyl peroxide obtaining 50% is stuck with paste；
Described cooling procedure uses refrigerated with ice or cools down at porcelain enamel barrel external adding water.
Embodiment described above is only to be described the preferred embodiment of the present invention, not carries out the scope of the present invention
Limiting, on the premise of designing spirit without departing from the present invention, technical scheme is made by those of ordinary skill in the art
Various deformation and improvement, all should fall in the protection domain that claims of the present invention determines.
Claims (10)
1. the strengthening agent prepared by flyash, it is characterised in that: including component A and B component, described component A is by such as
The raw material of lower mass parts is constituted:
Unsaturated polyester resin 100 parts；
Cross-linking agent: 0.5～2 part；
White carbon: 0.5～2.5 part；
Dimethylaniline: 0.5～1.5 part；
Flyash: 300～450 parts；
Described B component includes the raw material of following mass parts:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, Pulvis Talci, Kaolin: 50 parts；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The strengthening agent prepared by flyash the most according to claim 1, it is characterised in that: described unsaturated polyester resin is
MG Anchor Agent resin, described cross-linking agent is styrene, and described flyash is 10～80 mesh.
The strengthening agent prepared by flyash the most according to claim 2, it is characterised in that: described B component also includes 2,4-
Dichlorobenzoperoxide: 1.5～2.5 parts.
The strengthening agent prepared by flyash the most according to claim 1, it is characterised in that: include triple superphosphate, Pulvis Talci, height
The mixture of ridge soil, mass ratio is 2:2:1.
The strengthening agent prepared by flyash the most according to claim 3, it is characterised in that: by component A and B component structure
Becoming, described component A is made up of the raw material of following mass parts:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5～2 part；
White carbon: consumption 0.5～2 parts；
Dimethylaniline: 0.6～1.2 part；
Flyash: 320～420 parts；
Described B component is made up of the raw material of following mass parts:
50% benzoyl peroxide is stuck with paste: 50 parts；
2,4-dichlorobenzoperoxide: 2.5 parts；
One or both mixture in triple superphosphate, slider powder: 50 parts；
When selecting mixture, triple superphosphate and talcous mass ratio are 3:2 or 1:1；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The strengthening agent prepared by flyash the most according to claim 3, it is characterised in that: by component A and B component structure
Becoming, described component A is made up of the raw material of following quality:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5～2 part；
White carbon: 0.5～2 part；
Dimethylaniline: 0.5～1.5 part；
Flyash: 350～450 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
2,4-dichlorobenzoperoxide: 1.5～2.5 parts；
One or both mixture in triple superphosphate, slider powder: 50 parts；
When selecting mixture, triple superphosphate and talcous mass ratio are 3:2 or 1:1；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The strengthening agent prepared by flyash the most according to claim 2, it is characterised in that: by component A and B component structure
Becoming, described component A is made up of the raw material of following quality:
MG Anchor Agent resin: 100 parts；
Styrene: 0.5～1.5 part；
White carbon: 0.5～1.5 part；
Dimethylaniline: 0.5～1.5 part；
Flyash: 340～440 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, slider powder, Kaolin: 50 parts；
When using three kinds of mixing when, triple superphosphate, Pulvis Talci, kaolinic mass ratio is 2:2:1 or 3:1:1 or 1:3:1；
When using triple superphosphate and Kaolin mixing, mass ratio is 3:2 or 1:1；
When using triple superphosphate and Pulvis Talci mixing, mass ratio is 1:1 or 3:2；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
The strengthening agent prepared by flyash the most according to claim 2, it is characterised in that: by component A and B component structure
Becoming, described component A is made up of the raw material of following quality:
MG Anchor Agent resin: 100 parts；
Styrene: 1～2 part；
White carbon: 0.5～2.5 part；
Dimethylaniline: 1～1.5 part；
Flyash: 300～400 parts；
Described B component is made up of the raw material of following quality:
50% benzoyl peroxide is stuck with paste: 50 parts；
The mixture of one or more in triple superphosphate, slider powder, Kaolin: 50 parts；
When using three kinds of mixing when, triple superphosphate, Pulvis Talci, kaolinic mass ratio is 2:2:1 or 3:1:1；
Preparation component A and B component respectively, mixes component A with mass ratio 100:2～10 sampling with B component after having prepared,
Obtain final products.
9. the preparation method of the strengthening agent prepared by flyash described in claim 1, it is characterised in that: comprise the steps:
Preparation component A and B component respectively:
Component A: prepare raw material in proportion, pours into unsaturated polyester resin in container tank, starts agitator, stirs 20 minutes
After, white carbon being put in container, be mixed and stirred for 30 minutes, observe solution colour, solid colour is and stirs, stirs
Mixing speed controlling within 200r/min, winter suitably heats, and temperature, within 60 DEG C, adds dimethylaniline and stirs,
Add flyash after standing 30min, be stirred into clay shape standby；
B component: prepare raw material in proportion, puts into stainless by the mixture of one or more in triple superphosphate, slider powder, Kaolin
In the blender of steel, feed intake while stir, mix homogeneously, then 50% benzoyl peroxide paste is put into the powder stirred
In, feed intake while stir, after 50% benzoyl peroxide magma feeds intake, continue stirring 30 minutes, after mixing and stirring
Standby；
After having prepared, component A is mixed with mass ratio 100:2～10 sampling with B component, obtain final products.
The preparation method of the strengthening agent prepared by flyash the most according to claim 8, it is characterised in that: described 50%
The preparation method that benzoyl peroxide is stuck with paste comprises the steps:
In the porcelain enamel barrel of 20 liters, put into the sodium hydroxide solution that 2400ml contains 40%, start stirring, be cooled to 0 DEG C, slow
The slow 40% hydrogen peroxide 1200ml that adds, continuation cooling, control temperature, between 0～3 DEG C, drips Benzenecarbonyl chloride. 2820g by pipette,
Rate of addition wants slow, and when in bucket there to be White Flocculus to occur, benzoyl peroxide nucleus has been formed, and rate of addition is the fastest
A bit, Benzenecarbonyl chloride. dripped off in 90 minutes；
By reactant transfer washing and filtering, until neutral, get product, keep water content 20%～30%；
After the product keeping 20%-30% water content is measured water content, benzoyl peroxide is added dibutyl phthalate
The benzoyl peroxide obtaining 50% is stuck with paste；
Wherein, described cooling procedure uses refrigerated with ice or cools down at porcelain enamel barrel external adding water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610245006.4A CN105859188A (en) | 2016-04-19 | 2016-04-19 | Strengthening agent prepared from fly ash |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610245006.4A CN105859188A (en) | 2016-04-19 | 2016-04-19 | Strengthening agent prepared from fly ash |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105859188A true CN105859188A (en) | 2016-08-17 |
Family
ID=56632974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610245006.4A Pending CN105859188A (en) | 2016-04-19 | 2016-04-19 | Strengthening agent prepared from fly ash |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105859188A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108751794A (en) * | 2018-06-26 | 2018-11-06 | 鄂尔多斯市益山煤炭应用化学研究所 | A kind of anchoring product prepared with lytag |
| CN111718156A (en) * | 2020-05-09 | 2020-09-29 | 兰州大学 | Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101508540A (en) * | 2009-04-07 | 2009-08-19 | 晋城宏圣科威矿用材料有限公司 | Resin mastic cement for anchorage agent and anchorage agent thereof |
| CN102161574A (en) * | 2011-02-17 | 2011-08-24 | 安徽淮河化工股份有限公司 | Resin anchoring agent for initiation system |
| CN102515627A (en) * | 2011-12-29 | 2012-06-27 | 安徽淮河化工股份有限公司 | Early-strength CK anchoring agent and application thereof |
| CN103058586A (en) * | 2012-12-07 | 2013-04-24 | 安徽淮河化工股份有限公司 | Resin anchoring agent |
-
2016
- 2016-04-19 CN CN201610245006.4A patent/CN105859188A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101508540A (en) * | 2009-04-07 | 2009-08-19 | 晋城宏圣科威矿用材料有限公司 | Resin mastic cement for anchorage agent and anchorage agent thereof |
| CN102161574A (en) * | 2011-02-17 | 2011-08-24 | 安徽淮河化工股份有限公司 | Resin anchoring agent for initiation system |
| CN102515627A (en) * | 2011-12-29 | 2012-06-27 | 安徽淮河化工股份有限公司 | Early-strength CK anchoring agent and application thereof |
| CN103058586A (en) * | 2012-12-07 | 2013-04-24 | 安徽淮河化工股份有限公司 | Resin anchoring agent |
Non-Patent Citations (3)
| Title |
|---|
| 周菊兴等: "《不饱和聚酯树脂》", 31 July 1985 * |
| 赵志曼: "《土木工程材料》", 31 August 2006 * |
| 郑重远等: "《树脂锚杆及锚固剂》", 30 April 1983 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108751794A (en) * | 2018-06-26 | 2018-11-06 | 鄂尔多斯市益山煤炭应用化学研究所 | A kind of anchoring product prepared with lytag |
| CN108751794B (en) * | 2018-06-26 | 2020-12-01 | 鄂尔多斯市东胜区益山煤炭应用化学研究所 | Anchoring product prepared from fly ash ceramsite |
| CN111718156A (en) * | 2020-05-09 | 2020-09-29 | 兰州大学 | Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106977153A (en) | The shield synchronous grouting serous fluid and its construction method prepared using shield discarded slurry | |
| CN102092984B (en) | Energy-saving environmental-protection thickener for mortar preblending and dry-mixing | |
| CN105414146A (en) | Method for improving large amount of red mud soil and method for burning haycite from improved red mud | |
| CN105837109B (en) | A kind of concrete material of high-strength corrosion-resisting and its application | |
| CN104987117A (en) | Environment-friendly building thermal insulation materials | |
| CN106495581B (en) | Grouting material reinforced for road and preparation method thereof | |
| CN105622023B (en) | A kind of sludge curing agent using clinker | |
| CN105906269A (en) | Construction waste-containing water permeable brick and preparation method thereof | |
| CN101445347A (en) | Dry-mixed mortar with coal gangue, and preparation method thereof | |
| CN103319123B (en) | Fly ash-based cemented filling material and preparation method thereof | |
| CN103880364A (en) | Pervious concrete prepared from industrial waste and preparation method thereof | |
| CN104387007B (en) | Colliery low cost rapid hardening dilatancy sealing material | |
| CN108358535A (en) | A kind of cement concrete bridge deck waterproof material and preparation method thereof | |
| CN105036516A (en) | Preparation method of industrial waste residue-based sludge drying agent | |
| CN103360013B (en) | A kind of preparation method of gypsum base thermal insulation mortar | |
| CN109626884A (en) | Composite curing additive cement stabilized road base mixture and its application method | |
| CN107746193A (en) | A kind of industrial residue oil-well cement and preparation method thereof | |
| CN105859188A (en) | Strengthening agent prepared from fly ash | |
| CN105110754A (en) | Water-free muddy mortar | |
| CN104591696A (en) | Blast furnace heavy slag heat-preservation ceramsite and preparation method thereof | |
| CN102745970B (en) | Composition for preparing dry-mixed mortar | |
| CN106045360B (en) | Alkali-slag concrete swelling agent and its application method | |
| CN104609837B (en) | Method of producing haydite for thermal insulation block by utilizing steel slag quenched with wind | |
| CN101481238A (en) | Green soil curing agent | |
| CN107572987A (en) | A kind of method of modifying of mud modifying agent and engineering slurry |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160817 |