CN111718156A - Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof - Google Patents

Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof Download PDF

Info

Publication number
CN111718156A
CN111718156A CN202010385675.8A CN202010385675A CN111718156A CN 111718156 A CN111718156 A CN 111718156A CN 202010385675 A CN202010385675 A CN 202010385675A CN 111718156 A CN111718156 A CN 111718156A
Authority
CN
China
Prior art keywords
alkali
parts
water
loess
modifier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010385675.8A
Other languages
Chinese (zh)
Inventor
吕擎峰
陈臆
刘备
郭连星
韩启亮
王子帅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lanzhou University
Original Assignee
Lanzhou University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanzhou University filed Critical Lanzhou University
Priority to CN202010385675.8A priority Critical patent/CN111718156A/en
Publication of CN111718156A publication Critical patent/CN111718156A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/006Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B12/00Cements not provided for in groups C04B7/00 - C04B11/00
    • C04B12/04Alkali metal or ammonium silicate cements ; Alkyl silicate cements; Silica sol cements; Soluble silicate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/06Combustion residues, e.g. purification products of smoke, fumes or exhaust gases
    • C04B18/08Flue dust, i.e. fly ash
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/002Water
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/08Acids or salts thereof
    • C04B22/14Acids or salts thereof containing sulfur in the anion, e.g. sulfides
    • C04B22/142Sulfates
    • C04B22/147Alkali-metal sulfates; Ammonium sulfate
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00732Uses not provided for elsewhere in C04B2111/00 for soil stabilisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Civil Engineering (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Consolidation Of Soil By Introduction Of Solidifying Substances Into Soil (AREA)

Abstract

The invention discloses an alkali-activated geopolymer grouting material for a loess foundation and a preparation method thereof. The water-soluble fly ash modifier is prepared from 100 parts of fly ash, 3.6-4.0 parts of alkali activator (water glass), 7-10 parts of tap water, 1.3-1.9 parts of modifier and 1.5-3.0 parts of water glass in modulus. And a grouting technique for the loess foundation is adopted for grouting. The invention has the advantages of good viscosity, good water solubility, high middle and later stage strength and good consolidation, compared with the traditional alkali-activated geopolymer material, the material is a composite material formed by mixing various powdery and liquid raw materials, can be used by adding water and stirring on site, has simple preparation process, low cost, convenient operation, loess reinforcement, no collapsibility, no disintegration phenomenon, good water stability and higher foundation soil strength. Can be widely applied to loess reinforcement, road grouting, crack repair and the like in northwest areas.

Description

Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof
Technical Field
The invention belongs to the technical field of inorganic composite materials, and relates to an alkali-activated geopolymer grouting material for a loess foundation and a preparation method thereof.
Background
The alkali-activated geopolymer is a novel aluminosilicate inorganic cementing material generated by reacting an active aluminosilicate material, namely metakaolin, clay, slag, fly ash, silica fume and the like, with a strong alkali or a strong alkali silicate solution. In 1978, Davidovits, a famous French scientist, named this material as an alkali-activated geopolymer for the first time and proposed the reaction mechanism of the alkali-activated geopolymer. The alkali-activated geopolymer has the advantages of fast hardening, early strength, corrosion resistance, environmental protection, high temperature resistance, good durability and the like, and is widely applied to the fields of building materials, grouting and joint repairing, loess curing and the like.
The deformation of collapsible loess foundation is mainly collapsible deformation except compression deformation. In the state of natural water content, collapsible loess has low compressibility and high strength. The natural water content is generally within 10-22%, and the saturation is between 40-60%. The compression deformation is caused by the load on the upper part of the building with the foundation under the natural humidity, the compression deformation is gradually reduced along with the prolonging of the time, the stability is fast, and the compression deformation tends to be stable about one year after the completion of the engineering. When the base pressure is not greater than the characteristic bearing capacity of the foundation soil, the compression deformation value is small and usually does not exceed the allowable deformation value of the superstructure, and the building is not adversely affected.
When the collapsible loess with natural humidity is soaked in water, the collapsible deformation occurs under the action of the applied pressure or the load of the building, and the foundation has the characteristics of obviously reduced strength, increased deformation and sudden tendency. Engineering practices have shown that when building foundations are left untreated or mishandled, collapsible deformation of loess foundations occurs frequently and is not uniform when water leaks, water seepage, or the ground water level rises for various reasons. At the initial stage of soaking the foundation by water, 150-250 mm of settlement can be generated day and night, the upper structure of a building or a structure is difficult to adapt to and resist the foundation deformation with high speed, large settlement and unevenness, and the foundation has large destructiveness and serious harmfulness to the building. Therefore, when the collapsible loess area is constructed, various engineering measures are required to be taken for treating the foundation so as to improve the physical and mechanical properties of the soil, increase the water stability, eliminate or reduce the collapsible amount of the loess foundation and ensure the safety and normal use of the building. Most foundations in northwest areas of China are loess, and various building construction activities carried out on the loess foundations are inevitably seriously influenced.
Disclosure of Invention
In view of the above, the invention provides an alkali-activated geopolymer grouting material for a loess foundation and a preparation method thereof.
The invention solves the technical problems by the following technical means:
the invention relates to an alkali-activated geopolymer grouting material for a loess foundation, which consists of 100 parts of fly ash, 3.6-4.0 parts of alkali activator, 7-10 parts of tap water and 1.3-1.9 parts of modifier in parts by weight.
The modifier is AR-grade sodium sulfate, the fly ash is 600-mesh particles, the quality reaches more than two grades, the alkali activator is liquid water glass with a modulus of 1.5-3.0, and the fineness of the modifier is more than 120 meshes.
A preparation method of an alkali-activated geopolymer grouting material for a loess foundation comprises the following steps:
(1) preparing an inorganic silicate composite material, namely putting the fly ash, the alkali activator and the modifier into a stirrer, and uniformly stirring at normal temperature and normal pressure to obtain the inorganic silicate composite material;
(2) and (3) mixing the mass ratio of the sum of water in tap water and water glass to the pulverized coal ash in the inorganic silicate composite material is 0.25: 1, placing the slurry in a stirrer, and stirring and mixing uniformly to obtain the alkali-activated geopolymer grouting material.
The stirring time of the step (1) is 1-2 minutes, and the stirring time of the step (2) is 5-8 minutes.
The invention has the advantages of good viscosity, good water solubility, high middle and later stage strength and good consolidation, compared with the traditional alkali-activated geopolymer material, the material is a composite material formed by mixing various powdery and liquid raw materials, can be used by adding water and stirring on site, has simple preparation process, low cost, convenient operation, loess reinforcement, no collapsibility, no disintegration phenomenon, good water stability and higher foundation soil strength. Can be widely applied to loess reinforcement, road grouting, crack repair and the like in northwest areas.
The invention has the beneficial effects that:
1. the modifier is sodium sulfate, and then the alkali activator, the fly ash, the modifier and tap water are flexibly selected and mixed to prepare the alkali-activated geopolymer grouting material, so that the performance indexes of the gelation time and the fluidity of the alkali-activated geopolymer grouting material can achieve the stable and adjustable effect, and the comprehensive use performance of the alkali-activated geopolymer grouting material is greatly improved.
2 the alkali-activated geopolymer grouting material for the loess foundation can be prepared at normal temperature and normal pressure, has no special requirements, is convenient to obtain materials, can be used for grouting while being prepared on a construction site, and greatly reduces the labor and material cost.
3. The material of the invention is fly ash, which is a misplaced resource, and the invention is reasonable in utilization, changes waste into valuable, saves resources and reduces pollution to environment. Promotes the application and popularization of the fly ash-based alkali-activated geopolymer, increases the resource utilization rate of industrial waste, has higher economic benefit and environmental protection value, meets the requirement of sustainable development, and is beneficial to the construction of ecological civilization.
Detailed Description
The invention is described below with reference to specific examples, and an alkali-activated geopolymer grouting material for a loess foundation and a preparation method thereof are provided, wherein the alkali-activated geopolymer grouting material for the loess foundation comprises, by mass, 100 parts of fly ash, 3.6-4.0 parts of an alkali activator, 7-10 parts of tap water and 1.3-1.9 parts of a modifier.
The modifier is AR-grade sodium sulfate, the fly ash is 600-mesh particles, the quality reaches more than two grades, the alkali activator is liquid water glass with a modulus of 1.5-3.0, and the fineness of the modifier is more than 120 meshes.
A preparation method of an alkali-activated geopolymer grouting material for a loess foundation comprises the following steps:
(1) preparing an inorganic silicate composite material, namely putting the fly ash, the alkali activator and the modifier into a stirrer, and uniformly stirring at normal temperature and normal pressure to obtain the inorganic silicate composite material;
(2) and (3) mixing the mass ratio of the sum of water in tap water and water glass to the pulverized coal ash in the inorganic silicate composite material is 0.25: 1, placing the slurry in a stirrer, and stirring and mixing uniformly to obtain the alkali-activated geopolymer grouting material.
The stirring time of the step (1) is 1-2 minutes, and the stirring time of the step (2) is 5-8 minutes.
Example 1
(1) Taking 100 parts of fly ash by weight after drying;
(2) adding 1.5 parts by mass of a modifier;
(3) putting the two raw materials into a stirring pot, and stirring uniformly for 1.5 minutes to obtain a mixture;
(4) taking 4 parts of prepared water glass with the modulus of 1.5;
(5) taking tap water according to the water-to-glue ratio of 0.25;
(6) uniformly stirring the solutions in the steps (4) and (5) for 2.5 minutes;
(7) putting the materials in the steps (3) and (7) into a stirrer, and uniformly stirring for 7 minutes;
(8) pouring the dispersed material into a shaping mold, and compacting and molding;
(9) demoulding the formed material within 3d, and maintaining for 28d in a natural state to obtain the product.
Further, the fly ash powder in the step (1) reaches 600 meshes.
Furthermore, the modulus of the water glass in the step (4) needs to be adjusted by adding NaOH.
Further, the water in the water-to-glue ratio of 0.25 in the step (5) contains the sum of the water glass and the external water, and the glue of 0.25 in the water-to-glue ratio refers to the mass of the fly ash.
Further, the mold in the step (7) is a 160x40x40mm cubic mold, and a casting process is completed and compacted.
The strength of the alkali-activated geopolymer obtained in example 1 is 48.05MPa, which is improved by 79% compared with that of the geopolymer (26.85MPa) based on fly ash in the conventional process.
Example 2
A certain residential building in Gansu province is selected, the foundation of the residential building is located on a loess foundation, and since the 90 s, the wall body of the residential building has a plurality of inclined cracks, so that the foundation sinks seriously. And (3) reinforcing by using an alkali-activated geopolymer grouting material for the loess foundation.
(1) Taking 1000 parts of fly ash by weight after drying;
(2) adding 10-15 parts by mass of a modifier;
(3) putting the two raw materials into a stirrer, and stirring uniformly for 1-2 minutes to obtain a mixture;
(4) 40 parts of prepared water glass with the modulus of 1.5;
(5) taking 70-100 parts of tap water according to the water-to-glue ratio of 0.25;
(6) uniformly stirring the solutions in the steps (4) and (5) for 2-3 minutes;
(7) putting the materials in the steps (3) and (6) into a stirrer, and stirring and mixing uniformly for 5-8 minutes;
(8) putting the materials in the steps (6) and (7) into a stirrer to be uniformly stirred;
(9) injecting the grouting material obtained in the step (8) into the loess foundation:
(10) selecting 6 points at random after 28d, taking original soil samples at different depths, and carrying out a cube strength test;
further, the fly ash powder in the step (1) reaches 600 meshes.
Furthermore, the modulus of the water glass in the step (4) needs to be adjusted by adding NaOH.
Further, the water in the water-to-gel ratio of 0.25 in the step (5) contains the sum of the water glass and the external water, and the gel of 0.25 in the water-to-gel ratio refers to the mass of the fly ash.
Further, the compressive strength of the soil sample cube in the step (10) is averaged.
The test result of example 2 shows that the foundation bearing capacity fk is 542kPa after the reinforcement, the detection result shows that the foundation reinforcement effect is better, the standard value of the foundation bearing capacity fk meeting the design requirement is more than or equal to 200kPa, and the reinforcement purpose is achieved.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.

Claims (4)

1. An alkali-activated geopolymer grouting material for a loess foundation, characterized in that: the fly ash modifier consists of 100 parts of fly ash, 3.6-4.0 parts of alkali activator, 7-10 parts of tap water and 1.3-1.9 parts of modifier in parts by mass.
2. The alkali-activated geopolymer grouting material for a loess foundation according to claim 1, wherein: the modifier is AR-grade sodium sulfate, the fly ash is 600-mesh particles, the quality reaches more than two grades, the alkali activator is liquid water glass with a modulus of 1.5-3.0, and the fineness of the modifier is more than 120 meshes.
3. A preparation method of an alkali-activated geopolymer grouting material for a loess foundation is characterized by comprising the following steps of:
(1) preparing an inorganic silicate composite material, namely putting the fly ash, the alkali activator and the modifier into a stirrer, and uniformly stirring at normal temperature and normal pressure to obtain the inorganic silicate composite material;
(2) and (3) mixing the mass ratio of the sum of water in tap water and water glass to the pulverized coal ash in the inorganic silicate composite material is 0.25: 1, placing the slurry in a stirrer, and stirring and mixing uniformly to obtain the alkali-activated geopolymer grouting material.
4. The method for preparing the alkali-activated geopolymer grouting material for the loess foundation according to claim 3, wherein: the stirring time of the step (1) is 1-2 minutes, and the stirring time of the step (2) is 5-8 minutes.
CN202010385675.8A 2020-05-09 2020-05-09 Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof Pending CN111718156A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010385675.8A CN111718156A (en) 2020-05-09 2020-05-09 Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202010385675.8A CN111718156A (en) 2020-05-09 2020-05-09 Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof

Publications (1)

Publication Number Publication Date
CN111718156A true CN111718156A (en) 2020-09-29

Family

ID=72564374

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202010385675.8A Pending CN111718156A (en) 2020-05-09 2020-05-09 Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof

Country Status (1)

Country Link
CN (1) CN111718156A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112608188A (en) * 2021-01-25 2021-04-06 西北师范大学 Preparation method of loess-based geopolymer compound slow-release fertilizer

Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1641107A (en) * 2004-01-08 2005-07-20 孙家瑛 Soil consolidation grouting material
CN101407395A (en) * 2008-11-06 2009-04-15 昆明理工大学 Fly ash-based grouting filler for mine
CN101955341A (en) * 2010-09-27 2011-01-26 丁雅荣 Fly ash-based grouting filling material
CN102526921A (en) * 2011-12-27 2012-07-04 煤炭科学研究总院 Novel coal ash grouting material
CN103880377A (en) * 2014-02-20 2014-06-25 广西交通科学研究院 Geopolymer grouting material and preparation method thereof
CN104045292A (en) * 2014-06-16 2014-09-17 江苏固维特材料科技有限公司 Curing agent for filling iron tailings and preparation method thereof
CN104498001A (en) * 2014-12-26 2015-04-08 江西省萍乡市安华生物科技有限公司 High-dehydration curing plugging agent and preparation method thereof
CN105859188A (en) * 2016-04-19 2016-08-17 鄂尔多斯市益山煤炭应用化学研究所 Strengthening agent prepared from fly ash
CN105906240A (en) * 2016-04-19 2016-08-31 山西云泉岩土工程有限公司 A fly ash grouting material
CN106032313A (en) * 2015-12-02 2016-10-19 上海久坚加固科技股份有限公司 Alkali-activated slag powder geopolymer mortar for structure reinforcement and preparation method thereof
US20170130116A1 (en) * 2015-11-11 2017-05-11 Pq Corporation Self-Pressurizing Soluble Alkali Silicate for use in Sealing Subterranean Spaces
CN108455941A (en) * 2018-01-16 2018-08-28 河南理工大学 A kind of mining foam filling material of alkaline residue and preparation method thereof
CN110092597A (en) * 2019-05-21 2019-08-06 中国地质大学(北京) The high temperature resistant cementing slurry of a kind of ground polymer material, adaptation retarder and preparation

Patent Citations (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1641107A (en) * 2004-01-08 2005-07-20 孙家瑛 Soil consolidation grouting material
CN101407395A (en) * 2008-11-06 2009-04-15 昆明理工大学 Fly ash-based grouting filler for mine
CN101955341A (en) * 2010-09-27 2011-01-26 丁雅荣 Fly ash-based grouting filling material
CN102526921A (en) * 2011-12-27 2012-07-04 煤炭科学研究总院 Novel coal ash grouting material
CN103880377A (en) * 2014-02-20 2014-06-25 广西交通科学研究院 Geopolymer grouting material and preparation method thereof
CN104045292A (en) * 2014-06-16 2014-09-17 江苏固维特材料科技有限公司 Curing agent for filling iron tailings and preparation method thereof
CN104498001A (en) * 2014-12-26 2015-04-08 江西省萍乡市安华生物科技有限公司 High-dehydration curing plugging agent and preparation method thereof
US20170130116A1 (en) * 2015-11-11 2017-05-11 Pq Corporation Self-Pressurizing Soluble Alkali Silicate for use in Sealing Subterranean Spaces
CN106032313A (en) * 2015-12-02 2016-10-19 上海久坚加固科技股份有限公司 Alkali-activated slag powder geopolymer mortar for structure reinforcement and preparation method thereof
CN105859188A (en) * 2016-04-19 2016-08-17 鄂尔多斯市益山煤炭应用化学研究所 Strengthening agent prepared from fly ash
CN105906240A (en) * 2016-04-19 2016-08-31 山西云泉岩土工程有限公司 A fly ash grouting material
CN108455941A (en) * 2018-01-16 2018-08-28 河南理工大学 A kind of mining foam filling material of alkaline residue and preparation method thereof
CN110092597A (en) * 2019-05-21 2019-08-06 中国地质大学(北京) The high temperature resistant cementing slurry of a kind of ground polymer material, adaptation retarder and preparation

Non-Patent Citations (8)

* Cited by examiner, † Cited by third party
Title
《中国建设科技文库》编委会: "《中国建设科技文库》", 31 December 1998, 中国建材工业出版社 *
刘绍卿等: "浅谈注浆法治理煤炭采空区中的浆液控制", 《煤》 *
张向荣等: "矿井火区粉煤灰胶体充填封堵材料的试验研究", 《西安科技大学学报》 *
朱伶俐等: "粉煤灰注浆试验研究", 《粉煤灰综合利用》 *
竹涛: "《矿山固体废弃物处理与处置工程》", 30 June 2016, 冶金工业出版社 *
谌文武等: "土遗址裂隙注浆用SH-(C+F+CaO)浆液耐久性试验研究", 《岩石力学与工程学报》 *
邓新等: "粉煤灰基地聚合物修补材料的组成设计与性能", 《土木建筑与环境工程》 *
郭晓潞: "复合碱激发剂协同处理高钙粉煤灰研制土聚水泥", 《水泥》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112608188A (en) * 2021-01-25 2021-04-06 西北师范大学 Preparation method of loess-based geopolymer compound slow-release fertilizer
CN112608188B (en) * 2021-01-25 2022-06-14 西北师范大学 Preparation method of loess-based geopolymer compound slow-release fertilizer

Similar Documents

Publication Publication Date Title
EP4129949A1 (en) Unfired construction material using original state shielding soil and preparation method therefor
CN101323515B (en) Ultra-high strong concrete having ultra-high pumping performance and method for preparing the same
CN114031340B (en) Plastering mortar containing recycled aggregate of waste clay brick
CN112456891B (en) Pervious concrete material prepared from waste sintered bricks and application thereof
CN105347752A (en) High-strength concrete
CN109516733A (en) A kind of freeze proof pervious concrete of alkali-activated slag/flyash and preparation method thereof
CN110092623A (en) A kind of dredging and reclamation silt curing agent
CN114538843A (en) Low-energy-consumption ecological type ultrahigh-performance concrete and preparation method thereof
CN111116106B (en) Composite grouting slurry mixing proportion design method
CN108358566A (en) A kind of ultra-high performance concrete and its manufacturing method
CN113636802A (en) Ultrahigh-performance concrete and preparation method thereof
CN113429148B (en) Concrete crack-resistant and anti-permeability additive and preparation method thereof
CN110304883A (en) A kind of protofibre cement-base composite material and preparation method thereof
CN111718156A (en) Alkali-activated geopolymer grouting material for loess foundation and preparation method thereof
CN101456713A (en) Inorganic mineral earth surface insulating mortar
CN113336488A (en) Low-segregation and low-carbon concrete and preparation method thereof
CN106478018A (en) A kind of ecological environment-friendly type nano cement based composites
CN114853411B (en) High-damping full-recycled aggregate concrete ink material for 3D printing and preparation method
CN105347744A (en) High-strength prefabricated reinforced concrete hollow square pile
CN115286315A (en) Preparation method of cement paste reinforced and toughened coral aggregate seawater sea sand concrete
CN114656200A (en) Backfill material prepared from engineering waste slurry and preparation method thereof
CN107739171A (en) A kind of pipe of concrete and preparation method thereof
CN112094099A (en) Steel slag-based pervious concrete
CN112479654A (en) Recycled concrete and preparation method thereof
CN105347743A (en) Novel high-strength concrete for prefabricated reinforced concrete hollow square piles

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20200929