CN106365556A - Anti-permeability anti-corrosion concrete - Google Patents

Anti-permeability anti-corrosion concrete Download PDF

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Publication number
CN106365556A
CN106365556A CN201610750009.3A CN201610750009A CN106365556A CN 106365556 A CN106365556 A CN 106365556A CN 201610750009 A CN201610750009 A CN 201610750009A CN 106365556 A CN106365556 A CN 106365556A
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parts
sodium
concrete
corrosion resistance
rubble
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贾军
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Bengbu Bao Bao Commodity Concrete Co Ltd
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Bengbu Bao Bao Commodity Concrete Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses anti-permeability anti-corrosion concrete. The anti-permeability anti-corrosion concrete is prepared from the following components: silicate cement, coarse sand, medium-coarse sand, broken stone, water, steel slag, siliceous iron tailing powder, plaster, high calcium ash, ganister sand, vitrified microspheres, polycarboxylic water reducer, sodium molybdate, sodium nitrite, stannous chloride, ultrafine natural zeolite powder, hybrid fibres, an air entraining agent, urea and triethanolamine. According to the anti-permeability anti-corrosion concrete disclosed by the invention, the components are reasonable and act synergistically; the anti-permeability anti-corrosion concrete has high strength and high durability, such as freezing resistance, permeability resistance and corrosion resistance, and also has the advantage of preventing noise.

Description

A kind of impervious corrosion resistance concrete
Technical field
The present invention relates to technical field of concrete, more particularly, to a kind of impervious corrosion resistance concrete.
Background technology
Concrete is the maximum construction material of current consumption, and high performance concrete represents the development side of concrete technology To.Wall column is the important component part in architectural engineering, and it carries the stress of whole building engineering, and it is as whole building work The agent structure of journey, prescription is very high.Concrete be wall construction during one of main construction material, concrete material The quality of material produces serious influence to the construction quality of wall column, and has influence on the service life of engineering and use function.Mesh Before, its impermeability of concrete need to be improved with corrosion resistance.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of impervious corrosion resistance concrete, its component Rationally, act on and working in coordination with, there is intensity height, frost resistance, the impervious and good contour endurance quality of corrosion resistance, also there is its anti-noise etc. Advantage.
A kind of impervious corrosion resistance concrete proposed by the present invention, its raw material of described concrete is included by weight with the following group Point: portland cement 310-375 part, coarse sand 400-490 part, medium coarse sand 185-285 part, rubble 980-1150 part, water 125-175 Part, slag 30-40 part, siliceous iron tailings powder 25-40 part, Gypsum Fibrosum 18-25 part, high calcium ash 12-20 part, silica flour 25-50 part, vitreous Microballon 30-50 part, poly carboxylic acid series water reducer 1.1-1.75 part, sodium molybdate 0.85-1.2 part, sodium nitrite 1.1-1.5 part, chlorination Stannous 0.7-0.95 part, natural zeolite micropowder 15-30 part, composite fibre 1.82-2.35 part, air entraining agent 0.95-1.4 part, urine Plain 0.8-1.15 part, triethanolamine 0.7-1.2 part.
Preferably, its raw material of described concrete includes following components: portland cement 345-360 part, coarse sand by weight 440-460 part, medium coarse sand 240-265 part, rubble 1040-1100 part, water 145-160 part, slag 35-37 part, siliceous iron tailings Powder 34-37 part, Gypsum Fibrosum 20-22 part, high calcium ash 15-16 part, silica flour 38-42 part, glass bead 38-44 part, polycarboxylic-acid diminishing Agent 1.3-1.55 part, sodium molybdate 1-1.1 part, sodium nitrite 1.3-1.4 part, stannous chloride 0.8-0.9 part, natural zeolite micropowder 22-24 part, composite fibre 2.1-2.2 part, air entraining agent 1-1.15 part, carbamide 0.95-1.05 part, triethanolamine 0.9-1.1 part.
Preferably, its raw material of described concrete includes following components: 355 parts of portland cement, coarse sand 450 by weight Part, 255 parts of medium coarse sand, 1065 parts of rubble, 155 parts of water, 36.5 parts of slag, 35.6 parts of siliceous iron tailings powder, 21.2 parts of Gypsum Fibrosum, height 15.6 parts of calcium ash, 40.2 parts of silica flour, 40 parts of glass bead, 1.42 parts of poly carboxylic acid series water reducer, 1.05 parts of sodium molybdate, sodium nitrite 1.36 parts, 0.84 part of stannous chloride, 23.4 parts of natural zeolite micropowder, 2.15 parts of composite fibre, 1.1 parts of air entraining agent, carbamide 0.99 part, 0.98 part of triethanolamine.
Preferably, in described silica flour, the content of silicon dioxide is 94-96%.
Preferably, described composite fibre is by bamboo fibre, carbon fiber, steel fibre, polyester fiber, vinal by weight Form than for 1.5-2:3-5:2-3.5:1-1.5:1-2.
Preferably, described air entraining agent is contracted by abietate, magnesium oxide powder, sodium alkyl benzene sulfonate, alkyl phenol and oxirane Compound is obtained by weight for 2-3:2.5-4:1-1.5:1 mix homogeneously.
Preferably, described rubble by particle diameter be 1-5mm rubble, 5-16mm rubble, 16-25mm rubble be by weight 1-3: 85-92:5-8 forms.
Preferably, the specific surface area of described slag is 3700-5000cm2/g.
Preferably, described poly carboxylic acid series water reducer is prepared according to following technique: will be by weight by 25-40 part methoxy Base polyethylene glycol methacrylate-styrene polymer, 7-12 part methyl methacrylate, 12-18 part 1,4- butylene glycol, 8-12 part methyl-prop Alkene sodium sulfonate, 1.14-1.28 part sodium peroxydisulfate, 1.16-1.39 part Ammonium persulfate., 50-70 part deionized water add reaction unit, It is sufficiently stirred under nitrogen protection, after being warming up to 50-65 DEG C, react 14-20h, wherein heating rate is 1-3 DEG C/min;Again to Add sodium hydroxide solution to adjust ph value between 7-8 in reaction unit, be cooled to room temperature, obtain described polycarboxylic-acid diminishing Agent.
Preferably, described sodium peroxydisulfate, Ammonium persulfate. are respectively in the form of sodium persulfate aqueous solution, ammonium persulfate aqueous solution It is added drop-wise in reaction unit, time for adding is 30-60min;Wherein, the mass fraction of sodium persulfate aqueous solution is 85-95%, mistake The mass fraction of ammonium sulfate solution is 75-85%.
Coarse sand, medium coarse sand, slag, composite fibre, glass bead, natural zeolite micropowder, siliceous ferrum is added in the present invention Mine tailing, silica flour, using the difference in each group gradation footpath, realize being sufficient filling with concrete material, reduce each component particles Between space, improve pore structure, make concrete more closely knit, significantly improve the impermeability of concrete, corrosion resistance and strong Degree, wherein glass bead has good physical and chemical performance, and ageing-resistant weatherability is strong, has excellent thermal insulation, fire prevention, sound absorption properties Energy, and improve pumpability and the mobility of concrete, glass bead, natural zeolite micropowder, siliceous iron tailings powder, silica flour Mating reaction, reduces concrete shrinkage, improves service behaviour and the durability of concrete;High calcium ash is added to coordinate with Gypsum Fibrosum, There is good dilatancy, reduce the slump, increase the early strength of concrete, with siliceous iron tailings powder, sodium molybdate, nitrous acid Sodium, stannous chloride, triethanolamine use cooperatively, and effectively slow down or stop the erosion to concrete for the chemical substance, wherein siliceous ferrum Mine tailing increases the later strength of concrete with slag mating reaction.Performance is steady after modified for the poly carboxylic acid series water reducer adding Determine it is easy to storage, it is adaptable to the production of ready-mixed concrete needs, with air entraining agent compound use, increased amount of air entrainment, effectively improves Water-reducing rate, reduces the ratio of mud, admixes in concrete, produces minute bubbles small and independent in a large number, improves pore structure simultaneously, improves The mobility of concrete, pumpability, water-retaining property and the slump, are used cooperatively with carbamide, triethanolamine, reduce concrete Freezing point, improves the frost resistance of concrete, reduces the ratio of mud and bleeding sedimentation is shunk, and reduce the big pore in system Number, decreases Free water and the passage of other media migration simultaneously, and the microbubble of introducing occupies certain free space, subtracts The little connectedness of system void network, improves the impermeability of concrete;The addition of composite fibre, decreases and draws because of addition The reduction of the concrete strength that gas agent, poly carboxylic acid series water reducer cause, improves the comprcssive strength of concrete, impact strength and anti- Folding intensity, and improve the early strength of concrete, prevent the early-age crack of concrete, simultaneously with siliceous iron tailings simultaneously Powder, Gypsum Fibrosum, high calcium ash, silica flour, glass bead, natural zeolite micropowder, poly carboxylic acid series water reducer, air entraining agent mating reaction, cut Capillary passage in disconnected concrete, and then reduce the effect of capillary tube, improve the impermeability of concrete, and then improve concrete Corrosion resistance.Rationally, effect is collaborative for impervious corrosion resistance concrete component that the present invention obtains, have intensity height, frost resistance, Impermeability and the good contour endurance quality of corrosion resistance, also have the advantages that its anti-noise.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of impervious corrosion resistance concrete proposed by the present invention, its raw material of described concrete is included by weight with the following group Point: 310 parts of portland cement, 400 parts of coarse sand, 185 parts of medium coarse sand, 980 parts of rubble, 125 parts of water, 30 parts of slag, siliceous ferrum tail 40 parts of breeze, 18 parts of Gypsum Fibrosum, 20 parts of high calcium ash, 25 parts of silica flour, 50 parts of glass bead, 1.75 parts of poly carboxylic acid series water reducer, molybdic acid 0.85 part of sodium, 1.5 parts of sodium nitrite, 0.7 part of stannous chloride, 30 parts of natural zeolite micropowder, 1.82 parts of composite fibre, air entraining agent 0.95 part, 0.8 part of carbamide, 1.2 parts of triethanolamine.
Embodiment 2
A kind of impervious corrosion resistance concrete proposed by the present invention, its raw material of described concrete is included by weight with the following group Point: 325 parts of portland cement, 430 parts of coarse sand, 200 parts of medium coarse sand, 1030 parts of rubble, 135 parts of water, 32.5 parts of slag, siliceous ferrum 30 parts of mine tailing, 22.6 parts of Gypsum Fibrosum, 13.8 parts of high calcium ash, 42.6 parts of silica flour, 36.2 parts of glass bead, poly carboxylic acid series water reducer 1.65 parts, 0.96 part of sodium molybdate, 1.25 parts of sodium nitrite, 0.86 part of stannous chloride, 18.5 parts of natural zeolite micropowder, mixing fine 2.08 parts of dimension, 1.12 parts of air entraining agent, 0.94 part of carbamide, 0.85 part of triethanolamine.
Embodiment 3
A kind of impervious corrosion resistance concrete proposed by the present invention, its raw material of described concrete is included by weight with the following group Point: 355 parts of portland cement, 450 parts of coarse sand, 255 parts of medium coarse sand, 1065 parts of rubble, 155 parts of water, 36.5 parts of slag, siliceous ferrum 35.6 parts of mine tailing, 21.2 parts of Gypsum Fibrosum, 15.6 parts of high calcium ash, 40.2 parts of silica flour, 40 parts of glass bead, poly carboxylic acid series water reducer 1.42 parts, 1.05 parts of sodium molybdate, 1.36 parts of sodium nitrite, 0.84 part of stannous chloride, 23.4 parts of natural zeolite micropowder, mixing fine 2.15 parts of dimension, 1.1 parts of air entraining agent, 0.99 part of carbamide, 0.98 part of triethanolamine.
Wherein, in described silica flour, the content of silicon dioxide is 95%;
Described composite fibre by bamboo fibre, carbon fiber, steel fibre, polyester fiber, vinal is by weight 1.5:3:2:1:1 composition;
Described air entraining agent presses weight by abietate, magnesium oxide powder, sodium alkyl benzene sulfonate, condensation compound of alkyl phenol and epoxy ethane Amount is obtained than for 2:2.5:1:1 mix homogeneously;
Described rubble by particle diameter be 1-5mm rubble, 5-16mm rubble, 16-25mm rubble form by weight 1:92:8;
The specific surface area of described slag is 4500cm2/g;
Described poly carboxylic acid series water reducer is prepared according to following technique: by weight by 34 parts of methoxy poly (ethylene glycol) first Base acrylate, 10 parts of methyl methacrylates, 15 parts of 1,4- butylene glycols, 10.6 parts of methylpropene sodium sulfonates, 1.21 parts of mistakes Sodium sulfate, 1.25 parts of Ammonium persulfate .s, 60-65 part deionized waters add reaction unit, are sufficiently stirred under nitrogen protection, are warming up to After 60 DEG C, react 17.5h, wherein heating rate is 2.5 DEG C/min;Sodium hydroxide solution is added to adjust ph again in reaction unit It is worth for 7.5, be cooled to room temperature, obtain described poly carboxylic acid series water reducer.
Described sodium peroxydisulfate, Ammonium persulfate. are added drop-wise to respectively in the form of sodium persulfate aqueous solution, ammonium persulfate aqueous solution In reaction unit, time for adding is 45min;Wherein, the mass fraction of sodium persulfate aqueous solution is 90%, ammonium persulfate aqueous solution Mass fraction be 80%.
Embodiment 4
A kind of impervious corrosion resistance concrete proposed by the present invention, its raw material of described concrete is included by weight with the following group Point: 375 parts of portland cement, 490 parts of coarse sand, 285 parts of medium coarse sand, 1150 parts of rubble, 175 parts of water, 40 parts of slag, siliceous ferrum tail 25 parts of breeze, 25 parts of Gypsum Fibrosum, 12 parts of high calcium ash, 50 parts of silica flour, 30 parts of glass bead, 1.1 parts of poly carboxylic acid series water reducer, sodium molybdate 1.2 parts, 1.1 parts of sodium nitrite, 0.95 part of stannous chloride, 15 parts of natural zeolite micropowder, 2.35 parts of composite fibre, air entraining agent 1.4 part, 1.15 parts of carbamide, 0.7 part of triethanolamine.
Wherein, in described silica flour, the content of silicon dioxide is 94%;
Described composite fibre is by bamboo fibre, carbon fiber, steel fibre, polyester fiber, vinal by weight for 2: 5:3.5:1.5:2 composition;
Described air entraining agent presses weight by abietate, magnesium oxide powder, sodium alkyl benzene sulfonate, condensation compound of alkyl phenol and epoxy ethane Amount is obtained than for 3:4:1.5:1 mix homogeneously;
Preferably, described rubble by particle diameter be 1-5mm rubble, 5-16mm rubble, 16-25mm rubble be by weight 3:85:5 Composition;
The specific surface area of described slag is 3700cm2/g;
Described poly carboxylic acid series water reducer is prepared according to following technique: by weight by 25 parts of methoxy poly (ethylene glycol) first Base acrylate, 7 parts of methyl methacrylates, 12 parts of 1,4- butylene glycols, 8 parts of methylpropene sodium sulfonates, 1.14 parts of persulfuric acid Sodium, 1.16 parts of Ammonium persulfate .s, 50 parts of deionized waters add reaction unit, are sufficiently stirred under nitrogen protection, after being warming up to 50 DEG C, Reaction 20h, wherein heating rate are 1 DEG C/min;Adding sodium hydroxide solution to adjust ph value again in reaction unit is 7, cooling To room temperature, obtain described poly carboxylic acid series water reducer.
Described sodium peroxydisulfate, Ammonium persulfate. are added drop-wise to respectively in the form of sodium persulfate aqueous solution, ammonium persulfate aqueous solution In reaction unit, time for adding is 30min;Wherein, the mass fraction of sodium persulfate aqueous solution is 95%, ammonium persulfate aqueous solution Mass fraction be 85%.
Embodiment 5
A kind of impervious corrosion resistance concrete proposed by the present invention, its raw material of described concrete is included by weight with the following group Point: 360 parts of portland cement, 465 parts of coarse sand, 260 parts of medium coarse sand, 1100 parts of rubble, 164 parts of water, 37.5 parts of slag, siliceous ferrum 28 parts of mine tailing, 20.5 parts of Gypsum Fibrosum, 17.6 parts of high calcium ash, 31.2 parts of silica flour, 43.6 parts of glass bead, poly carboxylic acid series water reducer 1.26 parts, 1.11 parts of sodium molybdate, 1.36 parts of sodium nitrite, 0.76 part of stannous chloride, 26.5 parts of natural zeolite micropowder, mixing fine 2.16 parts of dimension, 1.28 parts of air entraining agent, 1.08 parts of carbamide, 1.06 parts of triethanolamine.
Wherein, in described silica flour, the content of silicon dioxide is 96%;
Preferably, described composite fibre is by bamboo fibre, carbon fiber, steel fibre, polyester fiber, vinal by weight Form than for 1.8:4:3:1.2:1.5;
Preferably, described air entraining agent is contracted by abietate, magnesium oxide powder, sodium alkyl benzene sulfonate, alkyl phenol and oxirane Compound is obtained by weight for 2.5:3:1.3:1 mix homogeneously;
Preferably, described rubble by particle diameter be 1-5mm rubble, 5-16mm rubble, 16-25mm rubble be by weight 2:88: 6.6 composition;
Preferably, the specific surface area of described slag is 5000cm2/g;
Preferably, described poly carboxylic acid series water reducer is prepared according to following technique: gathers 40 parts of methoxyl groups by weight Glycolmethacrylate, 12 parts of methyl methacrylates, 18 parts of 1,4- butylene glycols, 12 parts of methylpropene sodium sulfonates, 1.28 parts of sodium peroxydisulfates, 1.39 parts of Ammonium persulfate .s, 70 parts of deionized waters add reaction unit, are sufficiently stirred under nitrogen protection, After being warming up to 65 DEG C, react 14h, wherein heating rate is 3 DEG C/min;Sodium hydroxide solution is added to adjust again in reaction unit Ph value is 8, is cooled to room temperature, obtains described poly carboxylic acid series water reducer.
Described sodium peroxydisulfate, Ammonium persulfate. are added drop-wise to respectively in the form of sodium persulfate aqueous solution, ammonium persulfate aqueous solution In reaction unit, time for adding is 60min;Wherein, the mass fraction of sodium persulfate aqueous solution is 85%, ammonium persulfate aqueous solution Mass fraction be 75%.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto, Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.

Claims (10)

1. a kind of impervious corrosion resistance concrete is it is characterised in that its raw material of described concrete includes following components by weight: Portland cement 310-375 part, coarse sand 400-490 part, medium coarse sand 185-285 part, rubble 980-1150 part, water 125-175 part, Slag 30-40 part, siliceous iron tailings powder 25-40 part, Gypsum Fibrosum 18-25 part, high calcium ash 12-20 part, silica flour 25-50 part, vitreous are micro- Pearl 30-50 part, poly carboxylic acid series water reducer 1.1-1.75 part, sodium molybdate 0.85-1.2 part, sodium nitrite 1.1-1.5 part, protochloride Stannum 0.7-0.95 part, natural zeolite micropowder 15-30 part, composite fibre 1.82-2.35 part, air entraining agent 0.95-1.4 part, carbamide 0.8-1.15 part, triethanolamine 0.7-1.2 part.
2. according to claim 1 impervious corrosion resistance concrete it is characterised in that its raw material of described concrete by weight Including following components: portland cement 345-360 part, coarse sand 440-460 part, medium coarse sand 240-265 part, rubble 1040-1100 Part, water 145-160 part, slag 35-37 part, siliceous iron tailings powder 34-37 part, Gypsum Fibrosum 20-22 part, high calcium ash 15-16 part, silica flour 38-42 part, glass bead 38-44 part, poly carboxylic acid series water reducer 1.3-1.55 part, sodium molybdate 1-1.1 part, sodium nitrite 1.3- 1.4 parts, stannous chloride 0.8-0.9 part, natural zeolite micropowder 22-24 part, composite fibre 2.1-2.2 part, air entraining agent 1-1.15 Part, carbamide 0.95-1.05 part, triethanolamine 0.9-1.1 part.
3. according to claim 2 impervious corrosion resistance concrete it is characterised in that its raw material of described concrete by weight Including following components: 355 parts of portland cement, 450 parts of coarse sand, 255 parts of medium coarse sand, 1065 parts of rubble, 155 parts of water, slag 36.5 parts, 35.6 parts of siliceous iron tailings powder, 21.2 parts of Gypsum Fibrosum, 15.6 parts of high calcium ash, 40.2 parts of silica flour, 40 parts of glass bead, poly- 1.42 parts of carboxylic acid water reducing agent, 1.05 parts of sodium molybdate, 1.36 parts of sodium nitrite, 0.84 part of stannous chloride, natural zeolite micropowder 23.4 parts, 2.15 parts of composite fibre, 1.1 parts of air entraining agent, 0.99 part of carbamide, 0.98 part of triethanolamine.
4. according to any one of claim 1-3 impervious corrosion resistance concrete it is characterised in that dioxy in described silica flour The content of SiClx is 95-97wt%.
5. according to any one of claim 1-3 impervious corrosion resistance concrete it is characterised in that described composite fibre by Bamboo fibre, carbon fiber, steel fibre, polyester fiber, vinal are by weight for 1.5-2:3-5:2-3.5:1-1.5:1-2 Composition.
6. according to any one of claim 1-3 impervious corrosion resistance concrete it is characterised in that described air entraining agent is by pine Fragrant salt, magnesium oxide powder, sodium alkyl benzene sulfonate, condensation compound of alkyl phenol and epoxy ethane are by weight for 2-3:2.5-4:1-1.5: 1 mix homogeneously is obtained.
7. according to any one of claim 1-3 impervious corrosion resistance concrete it is characterised in that described rubble is by particle diameter Form by weight 1-3:85-92:5-8 for 1-5mm rubble, 5-16mm rubble, 16-25mm rubble.
8. according to any one of claim 1-3 impervious corrosion resistance concrete it is characterised in that the ratio table of described slag Area is 3700-5000cm2/g.
9. according to any one of claim 1-3 impervious corrosion resistance concrete it is characterised in that described polycarboxylic-acid subtracts Water preparation is prepared according to following technique: by weight by 25-40 part methoxy polyethylene glycol methacrylate-styrene polymer, 7-12 part first Base acrylic acid methyl ester., 12-18 part 1,4- butylene glycol, 8-12 part methylpropene sodium sulfonate, 1.14-1.28 part sodium peroxydisulfate, 1.16-1.39 part Ammonium persulfate., 50-70 part deionized water add reaction unit, are sufficiently stirred under nitrogen protection, are warming up to After 50-65 DEG C, react 14-20h, wherein heating rate is 1-3 DEG C/min;Sodium hydroxide solution is added to adjust again in reaction unit Section ph value, between 7-8, is cooled to room temperature, obtains described poly carboxylic acid series water reducer.
10. according to claim 9 impervious corrosion resistance concrete it is characterised in that described sodium peroxydisulfate, Ammonium persulfate. divide It is not added drop-wise in reaction unit in the form of sodium persulfate aqueous solution, ammonium persulfate aqueous solution, time for adding is 30-60min;Its In, the mass fraction of sodium persulfate aqueous solution is 85-95%, and the mass fraction of ammonium persulfate aqueous solution is 75-85%.
CN201610750009.3A 2016-08-29 2016-08-29 Anti-permeability anti-corrosion concrete Pending CN106365556A (en)

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CN110144783A (en) * 2019-04-26 2019-08-20 福建省昊立建设工程有限公司 A kind of roadbed construction method
CN110387878A (en) * 2019-08-02 2019-10-29 绍兴市上虞舜江管桩有限公司 A kind of anti-corrosion mixed mud precast square pile preparation process of internal layer impermeabilisation
CN112625654A (en) * 2020-12-31 2021-04-09 宁夏北极星化工有限公司 Coal railway transportation antifreezing solution containing reinforcing agent and reinforcing agent
CN113337922A (en) * 2021-07-03 2021-09-03 江苏狮腾工程材料有限公司 Engineering polyester fiber with good impermeability and preparation process thereof
CN113387652A (en) * 2021-06-30 2021-09-14 西安建祥建材科技有限公司 Anti-cracking anti-seepage self-repairing C35 mass concrete

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CN108503299A (en) * 2017-02-28 2018-09-07 北京城泰混凝土制品有限公司 Strong intensity steel fiber reinforced concrete
CN106892599A (en) * 2017-03-07 2017-06-27 河南城建学院 A kind of preparation method of fiber concrete, the New Buffering hard shoulder using it and New Buffering hard shoulder
CN106892599B (en) * 2017-03-07 2019-07-05 河南城建学院 A kind of fiber concrete, using its buffering hard shoulder and buffer the preparation method of hard shoulder
CN108341612A (en) * 2017-03-27 2018-07-31 温州创新新材料股份有限公司 A kind of anti-cracking and waterproofing concrete and preparation method thereof
CN107324719A (en) * 2017-07-07 2017-11-07 鞍钢集团矿业有限公司 The CS40 steel fiber shotcretes that a kind of utilization iron tailings sand is prepared
CN107352899A (en) * 2017-07-07 2017-11-17 鞍钢集团矿业有限公司 A kind of CS20 steel fiber shotcretes prepared using iron tailings sand
CN109956709A (en) * 2017-12-14 2019-07-02 颜小淋 A kind of concrete and preparation method thereof
WO2019135720A1 (en) * 2018-01-03 2019-07-11 Natchrungsunkh Phanawisittha Method of solving the separation problem of concrete and reinforced bamboo in bamboo-reinforced concrete by using waterproof concrete
CN108249815A (en) * 2018-01-16 2018-07-06 云南森博混凝土外加剂有限公司 A kind of composite concrete antiseptic agent
CN108529977A (en) * 2018-05-15 2018-09-14 佛山市华通混凝土有限公司 A kind of concrete of high-durability and preparation method thereof
CN108558325A (en) * 2018-06-29 2018-09-21 合肥信亚达智能科技有限公司 A kind of amendatory concrete of anti-permeability performance and preparation method thereof
CN108947407A (en) * 2018-08-30 2018-12-07 蚌埠市方阵商品混凝土有限公司 A kind of cracking resistance frost-resistant concrete
CN109020413A (en) * 2018-10-12 2018-12-18 蚌埠市方阵商品混凝土有限公司 A kind of high intensity frost-resistant concrete
CN110004839A (en) * 2019-04-18 2019-07-12 联建建设工程有限公司 Large span front fulcrum dragging suspension basket installation method
CN110144783A (en) * 2019-04-26 2019-08-20 福建省昊立建设工程有限公司 A kind of roadbed construction method
CN110144783B (en) * 2019-04-26 2020-04-28 福建省昊立建设工程有限公司 Roadbed construction method
CN110387878A (en) * 2019-08-02 2019-10-29 绍兴市上虞舜江管桩有限公司 A kind of anti-corrosion mixed mud precast square pile preparation process of internal layer impermeabilisation
CN110387878B (en) * 2019-08-02 2021-07-13 绍兴市上虞舜江管桩有限公司 Preparation process of inner-layer permeation-resistant corrosion-resistant concrete prefabricated square pile
CN112625654A (en) * 2020-12-31 2021-04-09 宁夏北极星化工有限公司 Coal railway transportation antifreezing solution containing reinforcing agent and reinforcing agent
CN113387652A (en) * 2021-06-30 2021-09-14 西安建祥建材科技有限公司 Anti-cracking anti-seepage self-repairing C35 mass concrete
CN113337922A (en) * 2021-07-03 2021-09-03 江苏狮腾工程材料有限公司 Engineering polyester fiber with good impermeability and preparation process thereof

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Application publication date: 20170201