CN106367217A - Anti-ultraviolet self-cleaning water scattering vehicle glass water - Google Patents

Anti-ultraviolet self-cleaning water scattering vehicle glass water Download PDF

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Publication number
CN106367217A
CN106367217A CN201610751761.XA CN201610751761A CN106367217A CN 106367217 A CN106367217 A CN 106367217A CN 201610751761 A CN201610751761 A CN 201610751761A CN 106367217 A CN106367217 A CN 106367217A
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CN
China
Prior art keywords
water
ultraviolet
titanium oxide
cleaning
nano titanium
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610751761.XA
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Chinese (zh)
Inventor
周鹏伟
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Suzhou Heng En New Energy Vehicle Components Ltd
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Suzhou Heng En New Energy Vehicle Components Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Suzhou Heng En New Energy Vehicle Components Ltd filed Critical Suzhou Heng En New Energy Vehicle Components Ltd
Priority to CN201610751761.XA priority Critical patent/CN106367217A/en
Publication of CN106367217A publication Critical patent/CN106367217A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/1213Oxides or hydroxides, e.g. Al2O3, TiO2, CaO or Ca(OH)2
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses anti-ultraviolet self-cleaning water scattering vehicle glass water which comprises the following raw materials in percentage by weight: 97.49-99.48 percent of water, 0.3-0.8 percent of coconut oil diethanolamide, 0.01-2 percent of nano titania and 0.01-0.05 percent of a corrosion inhibitor, and the sum of the percentages by weight of all the components is 100 percent. The anti-ultraviolet self-cleaning water scattering vehicle glass water disclosed by the invention not only has self-cleaning, antibacterial and deodorant functions, but also has an anti-ultraviolet function and a water scattering function.

Description

A kind of anti-ultraviolet automatically cleaning aproll automobile glass water
Technical field
The present invention relates to a kind of automotive glass water, in particular to a kind of anti-ultraviolet automatically cleaning aproll glass of automobile Glass water.
Background technology
Existing products in markets only possesses the function of cleaning cleaning glass, and common formula is as follows:
Formula 1: propylene glycol monomethyl ether 2.5%, ethylene glycol 7%, isopropanol 40%, nonyl phenol (eo) 9~10 ether 0.5%, water 50%.
Formula 2: propylene glycol monomethyl ether 3%, isopropanol 19%, propylene glycol 3%, water 75%.
The raw material of these formula is mainly some alcohol derivatives, and in bath of glass, proportion is larger, not only wastes Material can produce considerable degree of pollution to environment simultaneously.
Content of the invention
It is an object of the invention to the problem above overcoming prior art to exist, one kind is provided to possess automatically cleaning bacteriostasis, and deodorization The anti-ultraviolet automatically cleaning aproll automobile glass water of function, anti-ultraviolet function and aproll function.
For realizing above-mentioned technical purpose, reach above-mentioned technique effect, the present invention is achieved through the following technical solutions:
A kind of anti-ultraviolet automatically cleaning aproll automobile glass water, formula includes following raw material by weight percentage:
Water: 97.49-99.48%;
Coconut oil diethanol amide: 0.3-0.8%;
Nano titanium oxide: 0.01-2%;
Corrosion inhibiter: 0.01-0.05%;
The summation of above-mentioned all components percentage composition is 100%.
Preferably, formula includes following raw material by weight percentage:
Water: 98.49%;
Coconut oil diethanol amide: 0.5%;
Nano titanium oxide: 1%;
Corrosion inhibiter: 0.01%.
Further, the granular size of described nano titanium oxide is 25-100 nanometer.
The present invention possesses following beneficial effect:
1. possess cleaning vehicle glass surface blot, be also equipped with self-cleaning function it is not easy to be infected with dirt;
2. deodorization, antibacterial, antifreeze;
3. make glass surface form one layer and stop the protecting film that penetrates of ultraviolet, isolation ultraviolet, sun-proof;
4. make glass surface form one layer and possess self-cleaning soiling protective film;
5. make glass surface form one layer of aproll nanometer film, be integrated into dewdrop on Folium Nelumbinis when rainwater falls immediately on glass when Shape disperses rapidly, makes rainy day clear visual field such as no rain shape.
Described above is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of description, after being described in detail such as with presently preferred embodiments of the present invention below.The tool of the present invention Body embodiment is shown in detail in by following examples.
Specific embodiment
Below in conjunction with embodiment, to describe the present invention in detail.
Embodiment 1: a kind of anti-ultraviolet automatically cleaning aproll automobile glass water, formula includes following former by weight percentage Material:
Water: 98.49%;
Coconut oil diethanol amide: 0.5%;
Nano titanium oxide: 1%;
Corrosion inhibiter: 0.01%.
Embodiment 2: a kind of anti-ultraviolet automatically cleaning aproll automobile glass water, formula includes following former by weight percentage Material:
Water: 97.49%;
Coconut oil diethanol amide: 0.5%;
Nano titanium oxide: 2%;
Corrosion inhibiter: 0.01%.
Embodiment 3: a kind of anti-ultraviolet automatically cleaning aproll automobile glass water, formula includes following former by weight percentage Material:
Water: 99.48%;
Coconut oil diethanol amide: 0.5%;
Nano titanium oxide: 0.01%;
Corrosion inhibiter: 0.01%.
Embodiment 4: a kind of anti-ultraviolet automatically cleaning aproll automobile glass water, formula includes following former by weight percentage Material:
Water: 99%;
Coconut oil diethanol amide: 0.3%;
Nano titanium oxide: 0.65%;
Corrosion inhibiter: 0.05%.
Embodiment 5: a kind of anti-ultraviolet automatically cleaning aproll automobile glass water, formula includes following former by weight percentage Material:
Water: 99%;
Coconut oil diethanol amide: 0.8%;
Nano titanium oxide: 0.15%;
Corrosion inhibiter: 0.05%.
Embodiment 6: a kind of anti-ultraviolet automatically cleaning aproll automobile glass water, formula includes following former by weight percentage Material:
Water: 97.49%;
Coconut oil diethanol amide: 0.5%;
Nano titanium oxide: 1.98%;
Corrosion inhibiter: 0.03%.
In the formula of embodiment 1-6, coconut oil diethanol amide is a kind of neutral active agent, has stronger dirt-removing power, Possesses cleaning vehicle glass surface blot function;Titanium dioxide nanoparticle in formula only has 25-100 nanosized, permissible Fusion hydrone is sprayed at trickle after wiper scrapes repeatedly nano titanium oxide during glass surface and is attached to well The surface of glass forms one layer of nanometer film, looks just as the structure of lotus leaf surface floss floss, when rainwater falls under high power microscope When on the glass surface, nanometer film just serves the effect on similar Folium Nelumbinis top layer, globule landing quickly.
Nano titanium oxide under visible light illumination can be to Hydrocarbon decomposition, using the photocatalysis of titanium oxide Reaction just can be decomposed into co by the organic pollution on nano titanium dioxide film surface absorption2And h2O, with remaining inorganic matters Together can be clean by rain drop erosion, thus realizing self-cleaning function.
As above-mentioned glass surface defines one layer of nanometer layer, its thickness, between 25-100 nanometer, just can stop purple Outside line passes through.
The strong anti-uv-ray of nano titanium oxide is because it has high refractivity and high photolytic activity.Its uvioresistant Ability and its mechanism are relevant with its particle diameter: when particle diameter is larger, the obstruct to ultraviolet is based on reflecting, scattering, and centering Ripple area and long-wavelength region ultraviolet are all effective.
The antibacterial mechanisms of nano titanium oxide are:
Nano titanium oxide makes bacterial decomposition reach antibacterial effect under photocatalysiss.Due to nano titanium oxide Electronic structure feature be a full tio2Valence band and an empty conduction band, in the system of water and air, nanometer titanium dioxide , in sunlight especially under ultraviolet irradiation, when electron energy meets or exceeds its band-gap energy, electronics can be from valence band for titanium It is energized into conduction band, produces corresponding hole in valence band simultaneously, that is, generate electronics, hole, in the presence of electric field, electronics and hole Occur to separate, move to the diverse location of particle surface, after then there is series reaction, absorption is dissolved in tio2The oxygen on surface The ultra-oxygen anion free radical generating after trapped electron is reacted with most Organic substances, can react with the Organic substance in antibacterial simultaneously, Generate co2And h2o;And hole then will be adsorbed in tio2Behind surface and h2O is oxidized to hydroxy radical, and hydroxy radical has very strong oxygen Change ability, attacks the unsaturated bond of Organic substance or extracts the h atom new free radical of generation, excite chain reaction, finally cause antibacterial Decompose.
tio2Bactericidal action be its quantum size effect although titanium dioxide (common tio2) also there are photocatalysiss, Also electronics, hole pair can be produced, but it reaches the time of material surface more than Microsecond grade, easily occur compound, be difficult to send out Wave antibacterial effect, and reach the tio of nanoscale degree of scatter2, by light activated electronics, hole from vivo migration to surface, only Need the time of nanosecond, psec, even femtosecond, the compound in light induced electron and hole, in nanosecond order, can move to surface quickly, Attack bacteria organism, plays corresponding antibacterial action.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for the skill of this area For art personnel, the present invention can have various modifications and variations.All within the spirit and principles in the present invention, made any repair Change, equivalent, improvement etc., should be included within the scope of the present invention.

Claims (3)

1. a kind of anti-ultraviolet automatically cleaning aproll automobile glass water it is characterised in that: formula includes following former by weight percentage Material:
Water: 97.49-99.48%;
Coconut oil diethanol amide: 0.3-0.8%;
Nano titanium oxide: 0.01-2%;
Corrosion inhibiter: 0.01-0.05%;
The summation of above-mentioned all components percentage composition is 100%.
2. a kind of anti-ultraviolet automatically cleaning aproll automobile glass water according to claim 1 it is characterised in that: optimization formula Include following raw material by weight percentage:
Water: 98.49%;
Coconut oil diethanol amide: 0.5%;
Nano titanium oxide: 1%;
Corrosion inhibiter: 0.01%.
3. a kind of anti-ultraviolet automatically cleaning aproll automobile glass water according to claim 1 and 2 it is characterised in that: described The granular size of nano titanium oxide is 25-100 nanometer.
CN201610751761.XA 2016-08-24 2016-08-24 Anti-ultraviolet self-cleaning water scattering vehicle glass water Pending CN106367217A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107488522A (en) * 2017-08-04 2017-12-19 辽宁兰晶科技有限公司 A kind of antiultraviolet antibacterial selfreparing aproll environmental protection summer vehicle glass water
CN107488523A (en) * 2017-08-04 2017-12-19 辽宁兰晶科技有限公司 A kind of antifog anti-icing uvioresistant selfreparing winter vehicle glass water
CN107574031A (en) * 2017-09-29 2018-01-12 成都意町工业产品设计有限公司 A kind of glass cleaner for cold environment
CN107653083A (en) * 2017-10-19 2018-02-02 徐宏伟 A kind of ultraviolet ray proof automobile glass cleaner and its preparation technology
CN108048230A (en) * 2017-12-15 2018-05-18 重庆友拓汽车零部件有限公司 A kind of ultraviolet ray proof automobile bath of glass and its preparation process
CN108774592A (en) * 2018-07-31 2018-11-09 江苏今日卫生用品有限公司 A kind of summer automobile glass water and preparation method thereof
CN108893206A (en) * 2018-07-31 2018-11-27 江苏今日卫生用品有限公司 A kind of preparation method of summer automobile glass water and automobile glass water
CN109181891A (en) * 2018-07-31 2019-01-11 江苏今日卫生用品有限公司 A kind of summer automobile glass water and preparation method
CN111057625A (en) * 2019-12-30 2020-04-24 江苏苏龙幕墙工程有限公司 Curtain wall wear-resistant corrosion-resistant self-cleaning agent and preparation method thereof
CN111304019A (en) * 2020-03-30 2020-06-19 河北益飞特化工科技有限公司 Northern winter multifunctional automobile glass water
CN111575119A (en) * 2020-05-27 2020-08-25 山东中特新能源有限公司 Photocatalytic disinfection and sterilization self-cleaning agent

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1106864A (en) * 1994-11-11 1995-08-16 开封空分设备厂 Cleaning agent
CN1788794A (en) * 2004-12-13 2006-06-21 谢家忠 Nanometer photo-catalytic sterilizing and air-cleaning agent
CN102766551A (en) * 2012-07-19 2012-11-07 山东商业职业技术学院 Multifunctional cleaning solution for automobile windshield
CN103911231A (en) * 2013-01-07 2014-07-09 上海希洛商务咨询有限公司 Automobile windshield cleaning agent
CN104861930A (en) * 2015-05-28 2015-08-26 青岛德翕拓创高新技术有限公司 High-performance antifogging agent for automotive glass
CN104893839A (en) * 2015-05-28 2015-09-09 青岛德翕拓创高新技术有限公司 Anticorrosive windshield water
CN105273860A (en) * 2015-11-12 2016-01-27 扬州大学 Efficient photocatalytic glass water

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1106864A (en) * 1994-11-11 1995-08-16 开封空分设备厂 Cleaning agent
CN1788794A (en) * 2004-12-13 2006-06-21 谢家忠 Nanometer photo-catalytic sterilizing and air-cleaning agent
CN102766551A (en) * 2012-07-19 2012-11-07 山东商业职业技术学院 Multifunctional cleaning solution for automobile windshield
CN103911231A (en) * 2013-01-07 2014-07-09 上海希洛商务咨询有限公司 Automobile windshield cleaning agent
CN104861930A (en) * 2015-05-28 2015-08-26 青岛德翕拓创高新技术有限公司 High-performance antifogging agent for automotive glass
CN104893839A (en) * 2015-05-28 2015-09-09 青岛德翕拓创高新技术有限公司 Anticorrosive windshield water
CN105273860A (en) * 2015-11-12 2016-01-27 扬州大学 Efficient photocatalytic glass water

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107488522A (en) * 2017-08-04 2017-12-19 辽宁兰晶科技有限公司 A kind of antiultraviolet antibacterial selfreparing aproll environmental protection summer vehicle glass water
CN107488523A (en) * 2017-08-04 2017-12-19 辽宁兰晶科技有限公司 A kind of antifog anti-icing uvioresistant selfreparing winter vehicle glass water
CN107574031A (en) * 2017-09-29 2018-01-12 成都意町工业产品设计有限公司 A kind of glass cleaner for cold environment
CN107653083A (en) * 2017-10-19 2018-02-02 徐宏伟 A kind of ultraviolet ray proof automobile glass cleaner and its preparation technology
CN108048230A (en) * 2017-12-15 2018-05-18 重庆友拓汽车零部件有限公司 A kind of ultraviolet ray proof automobile bath of glass and its preparation process
CN108774592A (en) * 2018-07-31 2018-11-09 江苏今日卫生用品有限公司 A kind of summer automobile glass water and preparation method thereof
CN108893206A (en) * 2018-07-31 2018-11-27 江苏今日卫生用品有限公司 A kind of preparation method of summer automobile glass water and automobile glass water
CN109181891A (en) * 2018-07-31 2019-01-11 江苏今日卫生用品有限公司 A kind of summer automobile glass water and preparation method
CN111057625A (en) * 2019-12-30 2020-04-24 江苏苏龙幕墙工程有限公司 Curtain wall wear-resistant corrosion-resistant self-cleaning agent and preparation method thereof
CN111304019A (en) * 2020-03-30 2020-06-19 河北益飞特化工科技有限公司 Northern winter multifunctional automobile glass water
CN111575119A (en) * 2020-05-27 2020-08-25 山东中特新能源有限公司 Photocatalytic disinfection and sterilization self-cleaning agent

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Application publication date: 20170201