WO2014047744A1 - Environmentally-friendly phosphorus-free cleaning agent for toilet - Google Patents

Environmentally-friendly phosphorus-free cleaning agent for toilet Download PDF

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Publication number
WO2014047744A1
WO2014047744A1 PCT/CN2012/001302 CN2012001302W WO2014047744A1 WO 2014047744 A1 WO2014047744 A1 WO 2014047744A1 CN 2012001302 W CN2012001302 W CN 2012001302W WO 2014047744 A1 WO2014047744 A1 WO 2014047744A1
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Prior art keywords
cleaning agent
water
environmentally
polyoxyethylene ether
toilet
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PCT/CN2012/001302
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French (fr)
Chinese (zh)
Inventor
李代虹
Original Assignee
Li Daihong
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Priority to PCT/CN2012/001302 priority Critical patent/WO2014047744A1/en
Priority to CN201280018794.3A priority patent/CN103635566B/en
Publication of WO2014047744A1 publication Critical patent/WO2014047744A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0068—Deodorant compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the invention relates to an environmental protection non-phosphorus cleaning agent for a bathroom.
  • toilet cleaning agents contain a variety of toxic chemical components, serious pollution of the water environment, and damage to human health.
  • toilet cleaning agents mainly rely on acid to achieve decontamination and sterilization.
  • Hydrochloric acid is the most commonly used acid in toilet cleaning agents, while hydrochloric acid has a strong pungent odor. In order to cover up this unpleasant smell, Most products are supplemented with flavors and other substances.
  • the stimulating odor of hydrochloric acid is difficult to cover, toxic, and water pollution is very serious. 93107679.
  • the X patent relates to a bactericidal multi-functional toilet cleaning agent for bathroom use, which is composed of 15 to 30% hydrochloric acid, 0.5 to 4% of surfactant, 0.5 to 5 % of corrosion inhibitor, and fungicide 0. 5 - 3 % of bright green transparent liquid, with the ability to quickly and thoroughly remove all kinds of organic and inorganic dirt such as rust, urinary scale, scale, grease, etc., and can form a stable protective film on the surface of metal iron.
  • the environmental protection non-phosphorus cleaning agent of the invention is a non-toxic, non-VOS-like pollutant, environmentally-friendly and highly efficient water-based cleaning agent, which can be rapidly degraded into carbon dioxide and water in the natural environment (soil, seawater, river water). It has good biodegradability; and it has no harmful effects on terrestrial, aquatic and vivid plants during the degradation process, and will not cause any harm to the soil and water environment; It does not contain phosphorus, and will not cause environmental damage such as red tide, in line with domestic environmental laws. And the requirements of international environmental protection conventions. Contains no chemical toxic and harmful substances.
  • the raw materials of the products are selected from green plants, as well as various degradable surfactants, penetrants and corrosion inhibitors.
  • the basic composition of environmentally friendly phosphorus-free cleaning agent for bathroom is: C-12 alkyl benzene sulfonic acid 6-10%, polyoxyethylene ether nonyl phenol 3-7%, coconut oleic acid diethanol amide 3-7%, fatty alcohol polyoxygen Vinyl ether 2-5.6%, sodium benzoate 0.5-1.5%, sodium hydroxide 2-6%, citral 5-8.5%, saponin powder 7-12.5%, thioglycoside 3-3.6%, betaine 5-8.5 %, nano-titanium dioxide 1.5-4.6%, tea saponin 2.8-4.1% and the balance of water; above are all weight percentage.
  • the thioglycoside is used as a surfactant, and the thioglycoside and betaine are used as substitutes for the phosphorus promoter.
  • Tea saponin also known as tea saponin, is a kind of glycoside compound extracted from tea seed. It is a kind of natural surfactant with good performance and good decontamination ability.
  • the structure of nano-titanium dioxide is a titanium dioxide crystal structure.
  • the nano-titanium dioxide has special physical and chemical properties not possessed by traditional materials, and has high chemical stability, non-toxicity and no pollution, and has the characteristics of small particle size, large specific surface area, high surface energy, and the like. Its three unique effects: surface effects, small size effects and macroscopic quantum tunneling.
  • Sub-Silai Nano Titanium Dioxide (Photocatalyst) is an anatase-type white powdery solid.
  • the product has a strong photocatalytic redox capability, and the electrons on the valence band of nano-titanium dioxide (photocatalyst) under the action of ultraviolet light, sunlight, and fluorescent lamps ( E-) is easily excited to transition to the conduction band, producing corresponding holes (h+) on the valence band. Then h+ and e interact with H20, 02, etc.
  • An environmentally friendly non-phosphorus cleaning agent for bathroom 6.5% C-12 mercaptobenzenesulfonic acid, 3.6% polyoxyethylene ether alkylphenol, 3.9% coconut oleic acid diethanolamide, 2.15% fatty alcohol polyoxyethylene ether, sodium benzoate 0.7%, sodium hydroxide 2.3%, citral 7.2%, saponin powder 9.1%, thioglycoside 3.2%, betaine 7.2% nano titanium dioxide 2.3%, tea saponin 3.8% and balance water; percentage.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

Disclosed in the present invention is an environmentally-friendly phosphorus-free cleaning agent for a toilet, the cleaning agent having the composition of: 6-10% of C-12 alkylbenzene sulfonic acid, 3-7% of polyoxyethylene ether alkylphenol, 3-7% of coconut oil acid diethanolamide, 2-5.6% of fatty alcohol polyoxyethylene ether, 0.5-1.5% of sodium benzoate, 2-6% of sodium hydroxide, 5-8.5% of citral, 7-12.5% of gleditsia powder, 3-3.6% of alkylglycoside, 5-8.5% of betaine, 1.5-4.6% of nano titanium dioxide, 2.8-4.1% of tea saponin and the balance being water; all of the above are in weight percentage; the cleaning agent is a water-based cleaning agent which is nontoxic, free of ODS materials, environmentally friendly and highly efficient, can quickly be degraded into carbon dioxide and water in natural environments (soil, sea water, river water), and has good biodegradability.

Description

一种卫生间环保无磷清洗剂  Environmental protection non-phosphorus cleaning agent for bathroom
一、 技术领域 First, the field of technology
本发明涉及一种卫生间环保无磷清洗剂。  The invention relates to an environmental protection non-phosphorus cleaning agent for a bathroom.
二、 背景技术 Second, the background technology
目前， 卫生间清洗剂存在含有多种有毒化学成分、 严重污染水体环境、 损 害人体健康等问题。 目前卫生间清洗剂主要是靠酸来达到去污杀菌作用的， 其 中盐酸是卫生间清洗剂中最普遍使用的一种酸， 而盐酸具有很强的刺激性气味， 为了掩盖这种难闻的气味， 多数产品都添加有香精等物质。 但盐酸的剌激性气 味很难掩盖、 有毒， 水污染十分严重。 93107679. X专利涉及卫生间使用的杀菌 型多功能卫生间清洗剂， 它由盐酸 1 5— 3 0 % , 表面活性剂 0 . 5— 4 % , 缓蚀剂 0 . 5— 5 % , 杀菌剂 0 . 5— 3 %构成的亮绿色透明液体， 具有快速 彻底清除铁锈、 尿垢、 水垢、 油垢等各类有机、 无机污垢的能力， 并能在金属 铁表面形成一层稳定的保护膜。  At present, toilet cleaning agents contain a variety of toxic chemical components, serious pollution of the water environment, and damage to human health. At present, toilet cleaning agents mainly rely on acid to achieve decontamination and sterilization. Hydrochloric acid is the most commonly used acid in toilet cleaning agents, while hydrochloric acid has a strong pungent odor. In order to cover up this unpleasant smell, Most products are supplemented with flavors and other substances. However, the stimulating odor of hydrochloric acid is difficult to cover, toxic, and water pollution is very serious. 93107679. The X patent relates to a bactericidal multi-functional toilet cleaning agent for bathroom use, which is composed of 15 to 30% hydrochloric acid, 0.5 to 4% of surfactant, 0.5 to 5 % of corrosion inhibitor, and fungicide 0. 5 - 3 % of bright green transparent liquid, with the ability to quickly and thoroughly remove all kinds of organic and inorganic dirt such as rust, urinary scale, scale, grease, etc., and can form a stable protective film on the surface of metal iron.
三、 发明内容 Third, the invention content
本发明卫生间环保无磷清洗剂， 是一种无毒、 不含 0DS类污染物质、 环保、 高效的水基清洗剂， 在自然环境 （土壤、 海水、 河水） 中可迅速降解为二氧化 碳和水， 有良好的生物降解性； 并且降解过程中对陆生、 水生动植物无任何有 害影响， 不会对土壤、 水体环境造成任何危害； 不含磷， 不会造成赤潮等环境 破坏， 符合国内环保法律和国际环保公约的要求。 不含化学有毒有害物质， 产 品原料选自绿色植物， 以及各种可降解表面活性剂、 渗透剂、 缓蚀剂， 安全无 毒， 对人体无任何损害影响。 对矿物性油脂 （原油、 机油、 润滑脂） 和动植物 性油脂 （豆油、 猪油、 人体分泌油脂） 以及油脂与泥土、 粉尘、 颗粒物形成的 顽固油垢均有极佳的溶解去除能力； 具有去污力强， 能彻底除去油脂污垢， 低 泡等优点， 而且不腐蚀金属， 适合各种广泛应用。 The environmental protection non-phosphorus cleaning agent of the invention is a non-toxic, non-VOS-like pollutant, environmentally-friendly and highly efficient water-based cleaning agent, which can be rapidly degraded into carbon dioxide and water in the natural environment (soil, seawater, river water). It has good biodegradability; and it has no harmful effects on terrestrial, aquatic and vivid plants during the degradation process, and will not cause any harm to the soil and water environment; It does not contain phosphorus, and will not cause environmental damage such as red tide, in line with domestic environmental laws. And the requirements of international environmental protection conventions. Contains no chemical toxic and harmful substances. The raw materials of the products are selected from green plants, as well as various degradable surfactants, penetrants and corrosion inhibitors. They are safe and non-toxic and have no harmful effects on the human body. For mineral oils (crude oil, motor oil, grease) and animal and vegetable oils (soybean oil, lard, human body fats and oils) and oils and dirt, dust, particulate matter The stubborn grease has excellent dissolving and removing ability; it has strong detergency, can completely remove grease and dirt, and has low foaming. It does not corrode metal and is suitable for various applications.
卫生间环保无磷清洗剂基本组成为： C-12烷基苯磺酸 6-10%、 聚氧乙烯醚 垸基酚 3-7%、 椰子油酸二乙醇酰胺 3-7%、 脂肪醇聚氧乙烯醚 2-5.6%、 苯甲酸 钠 0.5-1.5 %、 氢氧化钠 2-6%、 柠檬醛 5-8.5% 、 皂角粉 7-12.5% 、 垸基糖苷 3-3.6%,甜菜碱 5-8.5% 、纳米二氧化钛 1.5-4.6% 、茶皂素 2.8-4.1%和余量水组 成； 以上均为重量百分比。  The basic composition of environmentally friendly phosphorus-free cleaning agent for bathroom is: C-12 alkyl benzene sulfonic acid 6-10%, polyoxyethylene ether nonyl phenol 3-7%, coconut oleic acid diethanol amide 3-7%, fatty alcohol polyoxygen Vinyl ether 2-5.6%, sodium benzoate 0.5-1.5%, sodium hydroxide 2-6%, citral 5-8.5%, saponin powder 7-12.5%, thioglycoside 3-3.6%, betaine 5-8.5 %, nano-titanium dioxide 1.5-4.6%, tea saponin 2.8-4.1% and the balance of water; above are all weight percentage.
以垸基糖苷为表面活性剂， 以垸基糖苷、 甜菜碱为替代磷助剂。 The thioglycoside is used as a surfactant, and the thioglycoside and betaine are used as substitutes for the phosphorus promoter.
茶皂素又名茶皂甙，是由茶树种子中提取出来的一类醣甙化合物，是一种性能良 好的天然表面活性剂，有较好的去污能力。 Tea saponin, also known as tea saponin, is a kind of glycoside compound extracted from tea seed. It is a kind of natural surfactant with good performance and good decontamination ability.
纳米二氧化钛的结构为二氧化钛晶体结构， 纳米二氧化钛具有传统材料所不具 备的特殊物理、 化学特性， 其化学稳定性高， 无毒无污染， 具有颗粒尺寸小、 比表面积大、 表面能高等特点， 以及其特有的三大效应： 表面效应、 小尺寸效 应和宏观量子隧道效应。 二氧化钛晶体结构主要有三种： 锐钛型、 金红石型及 板钛矿。 子西莱纳米二氧化钛 （光触媒） 为锐钛型白色粉末状固态物， 产品具 有强大的光催化氧化还原能力， 在紫外光、 太阳光、 日光灯的作用下纳米二氧 化钛 （光触媒） 价带上的电子 （e— ) 很容易被激发跃迁到导带， 在价带上产生 相应的空穴 （h+)。 随后 h+和 e 与吸附在纳米二氧化钛表面上的 H20、 02等 发生作用， 生成 OH _、 02—、 OOH—等高活性集团， 具有极强氧化作用的超 氧离子自由基、 羟基自由基、 超氧羟基自由基， 能将甲醛、 苯、 甲苯、 二甲苯、 氨、 TVOC 等多数有害有机物、 污染物臭气、 细菌、 病毒等氧化分解成无害的 C02禾口 H20。 The structure of nano-titanium dioxide is a titanium dioxide crystal structure. The nano-titanium dioxide has special physical and chemical properties not possessed by traditional materials, and has high chemical stability, non-toxicity and no pollution, and has the characteristics of small particle size, large specific surface area, high surface energy, and the like. Its three unique effects: surface effects, small size effects and macroscopic quantum tunneling. There are three main crystal structures of titanium dioxide: anatase, rutile and brookite. Sub-Silai Nano Titanium Dioxide (Photocatalyst) is an anatase-type white powdery solid. The product has a strong photocatalytic redox capability, and the electrons on the valence band of nano-titanium dioxide (photocatalyst) under the action of ultraviolet light, sunlight, and fluorescent lamps ( E-) is easily excited to transition to the conduction band, producing corresponding holes (h+) on the valence band. Then h+ and e interact with H20, 02, etc. adsorbed on the surface of nano-titanium dioxide to form high-activity groups such as OH_, 02-, OOH-, superoxide ion radicals with strong oxidation, hydroxyl radicals, super Oxyl hydroxyl radicals can oxidize and decompose most harmful organic substances such as formaldehyde, benzene, toluene, xylene, ammonia, TVOC, pollutants, bacteria, viruses, etc. into harmless C02 and H20.
四、 具体实施方式 一种卫生间环保无磷清洗剂： C-12垸基苯磺酸 6.5%、 聚氧乙烯醚烷基酚 3.6%,椰子油酸二乙醇酰胺 3.9%、脂肪醇聚氧乙烯醚 2.15%、苯甲酸钠 0.7%、 氢氧化钠 2.3%、柠檬醛 7.2% 、皂角粉 9.1% 、垸基糖苷 3.2%、甜菜碱 7.2%纳 米二氧化钛 2.3% 、 茶皂素 3.8%和余量水组成； 以上均为重量百分比。 Fourth, the specific implementation An environmentally friendly non-phosphorus cleaning agent for bathroom: 6.5% C-12 mercaptobenzenesulfonic acid, 3.6% polyoxyethylene ether alkylphenol, 3.9% coconut oleic acid diethanolamide, 2.15% fatty alcohol polyoxyethylene ether, sodium benzoate 0.7%, sodium hydroxide 2.3%, citral 7.2%, saponin powder 9.1%, thioglycoside 3.2%, betaine 7.2% nano titanium dioxide 2.3%, tea saponin 3.8% and balance water; percentage.

Claims

权 利 要 求 书 Claims
1、 一种环保卫生间无磷清洗剂， 其特征在于组成为： C-12垸基苯磺酸 6-10%、 聚氧乙烯醚垸基酚 3-7%、 椰子油酸二乙醇酰胺 3-7%、 脂肪醇聚氧乙烯醚 2-5.6 %、 苯甲酸钠 0.5-1.5 %、 氢氧化钠 2-6%、 柠檬醛 5-8.5%、 皂角粉 7-12.5% 、 垸基糖苷 3-3.6%、 甜菜碱 5-8.5%、 纳米二氧化钛 1.5-4.6%、 茶皂素 2.8-4.1%和 余量水组成； 以上均为重量百分比。 1. An environmentally friendly toilet non-phosphorus cleaning agent, characterized in that the composition is: C-12 mercaptobenzenesulfonic acid 6-10%, polyoxyethylene ether nonylphenol 3-7%, coconut oleic acid diethanolamide 3- 7%, fatty alcohol polyoxyethylene ether 2-5.6%, sodium benzoate 0.5-1.5%, sodium hydroxide 2-6%, citral 5-8.5%, saponin powder 7-12.5%, thioglycoside 3-3.6 %, betaine 5-8.5%, nano-titanium dioxide 1.5-4.6%, tea saponin 2.8-4.1% and balance water; above are all weight percentages.
PCT/CN2012/001302 2012-09-25 2012-09-25 Environmentally-friendly phosphorus-free cleaning agent for toilet WO2014047744A1 (en)

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* Cited by examiner, † Cited by third party
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CN104403578A (en) * 2014-12-06 2015-03-11 韦良富 Automobile cleaning glazing agent
CN105002006A (en) * 2015-07-03 2015-10-28 陈明志 Toilet cleaning agent
CN105349282A (en) * 2015-11-20 2016-02-24 张玉奇 Multifunctional natural cleansing and protecting liquid
CN106221964A (en) * 2016-07-21 2016-12-14 南京信息工程大学 A kind of environment-friendly cleaning agent and preparation method thereof
CN107794533A (en) * 2016-08-31 2018-03-13 天津市民兴科技发展有限公司 A kind of detergent for degreasing and rust removal and preparation method thereof
CN106833936A (en) * 2017-02-15 2017-06-13 中卫市创科知识产权投资有限公司 A kind of aqueous treatment agent producing process
CN107474966A (en) * 2017-08-21 2017-12-15 马鞍山中粮生物化学有限公司 A kind of sewer dirt detergent and its preparation technology

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183463A (en) * 1997-03-31 1998-06-03 白志信 Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof
CN1401753A (en) * 2002-09-23 2003-03-12 辽宁北方华兴机械有限公司 Multifunctional phosphateless washing agent
WO2005093028A1 (en) * 2004-03-09 2005-10-06 Johnsondiversey, Inc. Concentrated neutral detergent composition
CN1696262A (en) * 2004-05-13 2005-11-16 崔生 Phosphorus free Nano Hyperconcentrated liquid detergent
CN101372649A (en) * 2008-09-24 2009-02-25 北京洛娃日化有限公司 Acidic bathroom detergent
CN101921670A (en) * 2010-07-18 2010-12-22 山东科技大学 High-efficiency low-foam phosphorus-free sterilizing tableware cleanser applicable to large-scale machine washing
CN102115696A (en) * 2010-01-05 2011-07-06 哈尔滨理工大学 Non-phosphate liquid detergent and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1183463A (en) * 1997-03-31 1998-06-03 白志信 Long-acting bactericidal sterilizing descaling deodorizing composition for toilet bowl, and preparing process thereof
CN1401753A (en) * 2002-09-23 2003-03-12 辽宁北方华兴机械有限公司 Multifunctional phosphateless washing agent
WO2005093028A1 (en) * 2004-03-09 2005-10-06 Johnsondiversey, Inc. Concentrated neutral detergent composition
CN1696262A (en) * 2004-05-13 2005-11-16 崔生 Phosphorus free Nano Hyperconcentrated liquid detergent
CN101372649A (en) * 2008-09-24 2009-02-25 北京洛娃日化有限公司 Acidic bathroom detergent
CN102115696A (en) * 2010-01-05 2011-07-06 哈尔滨理工大学 Non-phosphate liquid detergent and preparation method thereof
CN101921670A (en) * 2010-07-18 2010-12-22 山东科技大学 High-efficiency low-foam phosphorus-free sterilizing tableware cleanser applicable to large-scale machine washing

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CN103635566A (en) 2014-03-12

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