CN106366920A - Emulsion used in leather processing process and preparation method thereof - Google Patents

Emulsion used in leather processing process and preparation method thereof Download PDF

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Publication number
CN106366920A
CN106366920A CN201610760875.0A CN201610760875A CN106366920A CN 106366920 A CN106366920 A CN 106366920A CN 201610760875 A CN201610760875 A CN 201610760875A CN 106366920 A CN106366920 A CN 106366920A
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CN
China
Prior art keywords
parts
emulsion
processing procedure
leather processing
polyoxyethylene ether
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610760875.0A
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Chinese (zh)
Inventor
宋聿啸
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang King King Garments Co Ltd
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Zhejiang King King Garments Co Ltd
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Publication date
Application filed by Zhejiang King King Garments Co Ltd filed Critical Zhejiang King King Garments Co Ltd
Priority to CN201610760875.0A priority Critical patent/CN106366920A/en
Publication of CN106366920A publication Critical patent/CN106366920A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
    • C09D191/06—Waxes
    • C—CHEMISTRY; METALLURGY
    • C14—SKINS; HIDES; PELTS; LEATHER
    • C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00—Surface finishing of leather
    • C14C11/003—Surface finishing of leather using macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention discloses an emulsion used in the leather processing process and a preparation method thereof. The emulsion is prepared from, by weight, 30-45 parts of palm wax, 15-25 parts of organic silicone oil, 2-4 parts of sorbide trioleate, 8-15 parts of dibenzyl biphenyl polyoxyethylene ether, 10-18 parts of polyoxyethylene ether, 4-10 parts of sodium dodecyl sulfate, 5-8 parts of laurate, 1-3 parts of zinc stearate, 10-18 parts of polyglycerol ester, 7-12 parts of triisopropanolamine, 0.1-0.4 part of methylbenzotriazole, 0.1-0.8 part of ammonium aluminum sulfate and 8-10 parts of octylene succinic anhydride. The emulsion has the advantages of being good in stability, good in water emulsibility, prominent in performance characteristic, environmentally friendly and the like, enables leather to enhance wetness and softness and is used for improving the hand feeling of the leather.

Description

A kind of emulsion of used in leather processing procedure and preparation method thereof
Technical field
The present invention relates to leather processing technique field, specifically a kind of emulsion of used in leather processing procedure and its preparation side Method.
Background technology
Emulsion in leather industry mainly as leather finish auxiliary agent, for bottom, in, top coat, there is preferable performance.Breast The liquid content of wax had both had the general character of water proofing property and lubricity, had such as oiliness, viscosity, fragility, toughness, fusibleness and gloss side again The characteristic in face, is very different to each other.In actual applications, a kind of wax can not possibly have and meet required for a certain special-purpose All properties.Therefore, when selecting the raw material of leather finish emulsion, the serviceability of wax to be considered, improves leather The Spraying technique covered with paint, lacquer, colour wash, etc..Therefore, develop a kind of stability higher, water emulsification is more preferable, performance characteristics are prominent and environmental protection breast Liquid product has great importance.
Content of the invention
It is an object of the invention to provide a kind of emulsion of used in leather processing procedure and preparation method thereof.
For achieving the above object, the following technical scheme of present invention offer:
A kind of emulsion of used in leather processing procedure, the raw material according to weight portion includes: palm wax 30-45 part, organic silicone oil 15-25 part, sorbitan trioleate 2-4 part, dibenzyl xenyl polyoxyethylene ether 8-15 part, polyoxyethylene ether 10-18 Part, dodecyl sodium sulfate 4-10 part, laurate 5-8 part, zinc stearate 1-3 part, polyglycerin ester 10-18 part, three isopropanols Amine 7-12 part, methyl benzotriazazole 0.1-0.4 part, Burnt ammonium alum 0.1-0.8 part, octenyl succinic acid anhydride 8-10 part.
As the further scheme of the present invention: the raw material according to weight portion includes: palm wax 34-41 part, organic silicone oil 19- 22 parts, sorbitan trioleate 2-4 part, dibenzyl xenyl polyoxyethylene ether 10-14 part, polyoxyethylene ether 14-16 part, Dodecyl sodium sulfate 6-9 part, laurate 5-8 part, zinc stearate 1-3 part, polyglycerin ester 14-18 part, triisopropanolamine 9- 10 parts, methyl benzotriazazole 0.1-0.4 part, Burnt ammonium alum 0.1-0.8 part, octenyl succinic acid anhydride 8-10 part.
As the further scheme of the present invention: the raw material according to weight portion includes: 37 parts of palm wax, 20 parts of organic silicone oil, 3 parts of sorbitan trioleate, 12 parts of dibenzyl xenyl polyoxyethylene ether, 15 parts of polyoxyethylene ether, dodecyl sodium sulfonate 8 parts of sodium, 7 parts of laurate, 2 parts of zinc stearate, 17 parts of polyglycerin ester, 10 parts of triisopropanolamine, methyl benzotriazazole 0.3 Part, 0.6 part of Burnt ammonium alum, 9 parts of octenyl succinic acid anhydride.
As the further scheme of the present invention: the purity of described organic silicone oil is more than 99%.
As the further scheme of the present invention: the mesh number of described dodecyl sodium sulfate is 300 mesh.
As the further scheme of the present invention: the mesh number of described zinc stearate is 600 mesh.
As the further scheme of the present invention: the mesh number of described Burnt ammonium alum is 1200 mesh.
A kind of preparation method of the emulsion of used in leather processing procedure, comprises the following steps: each more former than weighing by above-mentioned metering Material, is uniformly mixed, you can the emulsion of prepared used in leather processing procedure.
Compared with prior art, the invention has the beneficial effects as follows:
The present invention has the advantages that good stability, water emulsification be good, performance characteristics are prominent and environmental protection, and leather can be made to increase profit Wet sense and pliability, for improving leather hand feeling.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiments.Based in the present invention Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of not making creative work, all Belong to the scope of protection of the invention.
Embodiment 1
A kind of emulsion of used in leather processing procedure, the raw material according to weight portion includes: 30 parts of palm wax, organic silicone oil 15 Part, 2 parts of sorbitan trioleate, 8 parts of dibenzyl xenyl polyoxyethylene ether, 10 parts of polyoxyethylene ether, dodecyl sulphur 4 parts of sour sodium, 5 parts of laurate, 1 part of zinc stearate, 10 parts of polyglycerin ester, 7 parts of triisopropanolamine, methyl benzotriazazole 0.1 Part, 0.1 part of Burnt ammonium alum, 8 parts of octenyl succinic acid anhydride；The purity of described organic silicone oil is more than 99%；Described dodecyl The mesh number of sodium sulfonate is 300 mesh；The mesh number of described zinc stearate is 600 mesh；The mesh number of described Burnt ammonium alum is 1200 mesh.
A kind of preparation method of the emulsion of used in leather processing procedure, comprises the following steps: each more former than weighing by above-mentioned metering Material, is uniformly mixed, you can the emulsion of prepared used in leather processing procedure.
Embodiment 2
A kind of emulsion of used in leather processing procedure, the raw material according to weight portion includes: 34 parts of palm wax, organic silicone oil 19 Part, 2 parts of sorbitan trioleate, 10 parts of dibenzyl xenyl polyoxyethylene ether, 14 parts of polyoxyethylene ether, dodecyl sulphur 6 parts of sour sodium, 5 parts of laurate, 1 part of zinc stearate, 14 parts of polyglycerin ester, 9 parts of triisopropanolamine, methyl benzotriazazole 0.1 Part, 0.1 part of Burnt ammonium alum, 8 parts of octenyl succinic acid anhydride；The purity of described organic silicone oil is more than 99%；Described dodecyl The mesh number of sodium sulfonate is 300 mesh；The mesh number of described zinc stearate is 600 mesh；The mesh number of described Burnt ammonium alum is 1200 mesh.
A kind of preparation method of the emulsion of used in leather processing procedure, comprises the following steps: each more former than weighing by above-mentioned metering Material, is uniformly mixed, you can the emulsion of prepared used in leather processing procedure.
Embodiment 3
A kind of emulsion of used in leather processing procedure, the raw material according to weight portion includes: 37 parts of palm wax, organic silicone oil 20 Part, 3 parts of sorbitan trioleate, 12 parts of dibenzyl xenyl polyoxyethylene ether, 15 parts of polyoxyethylene ether, dodecyl sulphur 8 parts of sour sodium, 7 parts of laurate, 2 parts of zinc stearate, 17 parts of polyglycerin ester, 10 parts of triisopropanolamine, methyl benzotriazazole 0.3 Part, 0.6 part of Burnt ammonium alum, 9 parts of octenyl succinic acid anhydride；The purity of described organic silicone oil is more than 99%；Described dodecyl The mesh number of sodium sulfonate is 300 mesh；The mesh number of described zinc stearate is 600 mesh；The mesh number of described Burnt ammonium alum is 1200 mesh.
A kind of preparation method of the emulsion of used in leather processing procedure, comprises the following steps: each more former than weighing by above-mentioned metering Material, is uniformly mixed, you can the emulsion of prepared used in leather processing procedure.
Embodiment 4
A kind of emulsion of used in leather processing procedure, the raw material according to weight portion includes: 41 parts of palm wax, organic silicone oil 22 Part, 4 parts of sorbitan trioleate, 14 parts of dibenzyl xenyl polyoxyethylene ether, 16 parts of polyoxyethylene ether, dodecyl sulphur 9 parts of sour sodium, 8 parts of laurate, 3 parts of zinc stearate, 18 parts of polyglycerin ester, 10 parts of triisopropanolamine, methyl benzotriazazole 0.4 Part, 0.8 part of Burnt ammonium alum, 10 parts of octenyl succinic acid anhydride；The purity of described organic silicone oil is more than 99%；Described dodecyl The mesh number of sodium sulfonate is 300 mesh；The mesh number of described zinc stearate is 600 mesh；The mesh number of described Burnt ammonium alum is 1200 mesh.
A kind of preparation method of the emulsion of used in leather processing procedure, comprises the following steps: each more former than weighing by above-mentioned metering Material, is uniformly mixed, you can the emulsion of prepared used in leather processing procedure.
Embodiment 5
A kind of emulsion of used in leather processing procedure, the raw material according to weight portion includes: 45 parts of palm wax, organic silicone oil 25 Part, 4 parts of sorbitan trioleate, 15 parts of dibenzyl xenyl polyoxyethylene ether, 18 parts of polyoxyethylene ether, dodecyl sulphur 10 parts of sour sodium, 8 parts of laurate, 3 parts of zinc stearate, 18 parts of polyglycerin ester, 12 parts of triisopropanolamine, methyl benzotriazazole 0.4 part, 0.8 part of Burnt ammonium alum, 10 parts of octenyl succinic acid anhydride；The purity of described organic silicone oil is more than 99%；Described 12 The mesh number of sodium alkyl sulfonate is 300 mesh；The mesh number of described zinc stearate is 600 mesh；The mesh number of described Burnt ammonium alum is 1200 mesh.
A kind of preparation method of the emulsion of used in leather processing procedure, comprises the following steps: each more former than weighing by above-mentioned metering Material, is uniformly mixed, you can the emulsion of prepared used in leather processing procedure.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie In the case of the spirit or essential attributes of the present invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling Change is included in the present invention.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, not each embodiment only wraps Containing an independent technical scheme, only for clarity, those skilled in the art should for this narrating mode of description Using description as an entirety, the technical scheme in each embodiment can also form those skilled in the art through appropriately combined Understandable other embodiment.

Claims (8)

1. a kind of emulsion of used in leather processing procedure is it is characterised in that include according to the raw material of weight portion: palm wax 30-45 part, Organic silicone oil 15-25 part, sorbitan trioleate 2-4 part, dibenzyl xenyl polyoxyethylene ether 8-15 part, polyoxyethylene Ether 10-18 part, dodecyl sodium sulfate 4-10 part, laurate 5-8 part, zinc stearate 1-3 part, polyglycerin ester 10-18 part, three Isopropanolamine 7-12 part, methyl benzotriazazole 0.1-0.4 part, Burnt ammonium alum 0.1-0.8 part, octenyl succinic acid anhydride 8-10 Part.
2. the emulsion of used in leather processing procedure according to claim 1 is it is characterised in that raw material bag according to weight portion Include: palm wax 34-41 part, organic silicone oil 19-22 part, sorbitan trioleate 2-4 part, dibenzyl xenyl polyoxyethylene Ether 10-14 part, polyoxyethylene ether 14-16 part, dodecyl sodium sulfate 6-9 part, laurate 5-8 part, zinc stearate 1-3 part, Polyglycerin ester 14-18 part, triisopropanolamine 9-10 part, methyl benzotriazazole 0.1-0.4 part, Burnt ammonium alum 0.1-0.8 part, pungent Alkenyl succinic anhydride 8-10 part.
3. the emulsion of used in leather processing procedure according to claim 1 and 2 is it is characterised in that raw material according to weight portion Including: 37 parts of palm wax, 20 parts of organic silicone oil, 3 parts of sorbitan trioleate, dibenzyl xenyl polyoxyethylene ether 12 Part, 15 parts of polyoxyethylene ether, 8 parts of dodecyl sodium sulfate, 7 parts of laurate, 2 parts of zinc stearate, 17 parts of polyglycerin ester, three different 10 parts of Propanolamine, 0.3 part of methyl benzotriazazole, 0.6 part of Burnt ammonium alum, 9 parts of octenyl succinic acid anhydride.
4. the emulsion of used in leather processing procedure according to claim 3 is it is characterised in that the purity of described organic silicone oil is More than 99%.
5. the emulsion of used in leather processing procedure according to claim 4 is it is characterised in that described dodecyl sodium sulfate Mesh number is 300 mesh.
6. the emulsion of used in leather processing procedure according to claim 5 is it is characterised in that the mesh number of described zinc stearate is 600 mesh.
7. the emulsion of used in leather processing procedure according to claim 6 is it is characterised in that the mesh number of described Burnt ammonium alum is 1200 mesh.
8. a kind of preparation method of the described emulsion of used in leather processing procedure as arbitrary in claim 1-7 is it is characterised in that wrap Include following steps: weigh each raw material by above-mentioned metering ratio, be uniformly mixed, you can the emulsion of prepared used in leather processing procedure.
CN201610760875.0A 2016-08-29 2016-08-29 Emulsion used in leather processing process and preparation method thereof Pending CN106366920A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610760875.0A CN106366920A (en) 2016-08-29 2016-08-29 Emulsion used in leather processing process and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610760875.0A CN106366920A (en) 2016-08-29 2016-08-29 Emulsion used in leather processing process and preparation method thereof

Publications (1)

Publication Number Publication Date
CN106366920A true CN106366920A (en) 2017-02-01

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101585968A (en) * 2009-06-26 2009-11-25 温州大学 Cationic wax emulsion for leather manufacturing procedure and manufacturing method
CN104327746A (en) * 2014-10-19 2015-02-04 青岛文晟汽车零部件有限公司 Maintaining and nursing oil for leather product
CN105779670A (en) * 2016-04-29 2016-07-20 四川力久知识产权服务有限公司 Wax emulsion for leather finishing and preparing method of wax emulsion
CN105860856A (en) * 2016-04-29 2016-08-17 四川力久知识产权服务有限公司 Leather polishing wax emulsion and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101585968A (en) * 2009-06-26 2009-11-25 温州大学 Cationic wax emulsion for leather manufacturing procedure and manufacturing method
CN104327746A (en) * 2014-10-19 2015-02-04 青岛文晟汽车零部件有限公司 Maintaining and nursing oil for leather product
CN105779670A (en) * 2016-04-29 2016-07-20 四川力久知识产权服务有限公司 Wax emulsion for leather finishing and preparing method of wax emulsion
CN105860856A (en) * 2016-04-29 2016-08-17 四川力久知识产权服务有限公司 Leather polishing wax emulsion and preparation method thereof

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Application publication date: 20170201