CN106366832A - Boron modified phenolic resin priming paint - Google Patents

Boron modified phenolic resin priming paint Download PDF

Info

Publication number
CN106366832A
CN106366832A CN201610773356.8A CN201610773356A CN106366832A CN 106366832 A CN106366832 A CN 106366832A CN 201610773356 A CN201610773356 A CN 201610773356A CN 106366832 A CN106366832 A CN 106366832A
Authority
CN
China
Prior art keywords
parts
modified phenolic
powder
boron modified
phenolic resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610773356.8A
Other languages
Chinese (zh)
Inventor
朱燕华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201610773356.8A priority Critical patent/CN106366832A/en
Publication of CN106366832A publication Critical patent/CN106366832A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/04Condensation polymers of aldehydes or ketones with phenols only
    • C09D161/06Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
    • C09D161/14Modified phenol-aldehyde condensates
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • C09D5/10Anti-corrosive paints containing metal dust
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses boron modified phenolic resin priming paint. The boron modified phenolic resin priming paint is prepared from the following raw material components in a formula in percentage by mass: 180 to 200 parts of boron modified phenolic resin, 10 to 12 parts of xylol, 5 to 8 parts of titanium dioxide, 10 to 12 parts of white emulsion, 3 to 5 parts of rosin, 10 to 15 parts of mica powder, 8 to 10 parts of coal gangue powder, 12 to 15 parts of bismaleimide resin, 10 to 15 pats of micro-crystallite graphene, 5 to 7 parts of methyl acetate, 3 to 5 parts of sodium carbonate, 2 to 3 parts of diethylene glycol diethylether, 3 to 4 parts of isopentane, 3 to 5 parts of stearic acid, 4 to 5 parts of magnesium aluminum silicate, 2 to 3 parts of sodium methionate, 8 to 10 parts of diatom ooze, 8 to 10 parts of gas-phase white carbon black, 40 to 50 parts of nano-silver powder, 40 to 50 parts of nano-copper powder and 40 to 50 parts of nano-iron powder. The boron modified phenolic resin priming paint provided by the invention has an extremely high dispersion capability and achieves an optimal anticorrosion effect; a paint film is more dense; a path from which corrosion gas enters becomes long, so that the anticorrosion effect is enhanced.

Description

A kind of boron modified phenolic resin priming paint
Technical field
The present invention relates to a kind of priming paint technical field, more particularly, to a kind of boron modified phenolic resin priming paint.
Background technology
Priming paint is with resin, metal powder material as primary raw material, the sapecial coating of the composition such as filler, auxiliary agent, solvent, and it is prevented Rotten excellent performance, attached work power is strong, and in paint film, metal powder material content is high, has cathodic protection effect, water resistance excellent it is adaptable to Storage tank, container, steel construction, steel pipe, ocean platform, priming coat of ship, harbour facility and severe anticorrosion environment etc..
Chinese patent application 201310538981.0, a kind of entitled high-temperature resistant anti-corrosive based on Graphene and its preparation Method, this patent fire-resistant anticorrosion paint consists of: epoxy resin 5-60%, polyphenylene sulfide 3-30%.Amino resins 3-30%, pigment 1-10%, Graphene 1-20%, n-butyl alcohol 3-50%, defoamer 0.1-0.3%, poly- hydroxy acid sodium salt 0.1-10%, dibutyl phthalate 0.1-5%, bentonite 0.5-1.0%, levelling agent 0.2-0.5%.Preparation method For first Graphene, epoxy resin, polyphenylene sulfide being added in n-butyl alcohol, ultrasonic agitation, then other raw materials are added Enter grinding machine for grinding, finally by the two stirring mixing.
Chinese patent application 201410097011.6, entitled zinc alkene anticorrosive paint and preparation method thereof, this coating bag Include a component and b component, b group is divided into firming agent.A component includes Graphene epoxy resin solution 10-20%, anti-settling agent 0.5-2%, zinc powder 15-30%, aluminium powder 2-10%, antirust color stuffing 35-50%, organic solvent 5-10%.Graphene ring Oxygen tree lipoprotein solution comprises Graphene 1-10%, epoxy resin liquid 80-90%, organic solvent 5-10%, auxiliary agent 1-2%.System First prepare Graphene epoxy resin liquid when standby, that is, use organic solvent and auxiliary agent pre-preg Graphene, use organic solvent molten simultaneously Solution epoxy resin, then pre-preg Graphene is added to mix homogeneously in the epoxy resin liquid having dissolved.
Graphene is easy to when using in coating assemble, and is difficult to be uniformly dispersed in system, ultrasonic in above-mentioned prior art Stirring or pre-preg, can not solve the problems, such as that all by the way of physics the dispersion of Graphene is uneven very well.
Content of the invention
The invention aims to overcoming the shortcoming of above-mentioned prior art, provide a kind of boron modified phenolic resin priming paint, It is extremely strong and reach optimal antiseptic effect that this boron modified phenolic resin priming paint has dispersibility;Paint film is finer and close, etchant gas The path entering is elongated, further enhances anti-corrosion effects.
The technical solution adopted for the present invention to solve the technical problems is: a kind of boron modified phenolic resin priming paint, by following The composition of raw materials group of mass percent is grouped into: 180-200 part boron modified phenolic resin, 10-12 part dimethylbenzene, 5-8 part titanium white Powder, 10-12 part white glue with vinyl, 3-5 part Colophonium, 10-15 part mica powder, 8-10 part gangue powder, 12-15 part BMI Resin, 10-15 part micro crystal graphite alkene, 5-7 part methyl acetate, 3-5 part sodium carbonate, 2-3 part diethylene glycol ether, 3-4 part isoamyl Alkane, 3-5 part stearic acid, 4-5 part aluminium-magnesium silicate, 2-3 part sodium methanedisulfonate sodium, 8-10 part diatom ooze, 8-10 part gas-phase silica, 40-50 part nanometer silver powder, 40-50 part copper nanoparticle, 40-50 part nanometer iron powder.
Further, each composition of raw materials group is divided into: 180 parts of boron modified phenolic resins, 10 parts of dimethylbenzene, 5 parts of titanium dioxides, 10 Part white glue with vinyl, 3 parts of Colophonium, 10 parts of mica powders, 8 parts of gangue powder, 12 parts of bimaleimide resins, 10 parts of micro crystal graphites Alkene, 5 parts of methyl acetates, 3 parts of sodium carbonate, 2 parts of diethylene glycol ethers, 3 parts of isopentane, 3 parts of stearic acid, 4 parts of aluminium-magnesium silicates, 2 parts Sodium methanedisulfonate sodium, 8 parts of diatom oozes, 8 parts of gas-phase silicas, 40 parts of nanometer silver powder, 40 parts of copper nanoparticles, 40 parts of nanometer iron powders.
Or, each composition of raw materials group is divided into: 200 parts of boron modified phenolic resins, 12 parts of dimethylbenzene, 8 parts of titanium dioxides, 12 parts White glue with vinyl, 5 parts of Colophonium, 15 parts of mica powders, 10 parts of gangue powder, 15 parts of bimaleimide resins, 15 parts of micro crystal graphite alkene, 7 parts of methyl acetates, 5 parts of sodium carbonate, 3 parts of diethylene glycol ethers, 4 parts of isopentane, 5 parts of stearic acid, 5 parts of aluminium-magnesium silicates, 3 parts of methyl Sodium disulfonate, 10 parts of diatom oozes, 10 parts of gas-phase silicas, 50 parts of nanometer silver powder, 50 parts of copper nanoparticles, 50 parts of nanometer iron powders.
In sum, the invention has the beneficial effects as follows: the boron modified phenolic resin priming paint of the present invention has dispersibility pole Strong and reach optimal antiseptic effect;Paint film is finer and close, and the path that etchant gas enters is elongated, further enhances anticorrosive effect Really.
Specific embodiment
Embodiment 1
A kind of boron modified phenolic resin priming paint described by the present embodiment 1, by the composition of raw materials group packet of following mass percent Become: 180 parts of boron modified phenolic resins, 10 parts of dimethylbenzene, 5 parts of titanium dioxides, 10 parts of white glue with vinyl, 3 parts of Colophonium, 10 parts of mica powders, 8 Part gangue powder, 12 parts of bimaleimide resins, 10 parts of micro crystal graphite alkene, 5 parts of methyl acetates, 3 parts of sodium carbonate, 2 part two Ethylene glycol, 3 parts of isopentane, 3 parts of stearic acid, 4 parts of aluminium-magnesium silicates, 2 parts of sodium methanedisulfonate sodium, 8 parts of diatom oozes, 8 parts of gas phases White carbon, 40 parts of nanometer silver powder, 40 parts of copper nanoparticles, 40 parts of nanometer iron powders.
Embodiment 2
A kind of boron modified phenolic resin priming paint described by the present embodiment 2, by the composition of raw materials group packet of following mass percent Become: 200 parts of boron modified phenolic resins, 12 parts of dimethylbenzene, 8 parts of titanium dioxides, 12 parts of white glue with vinyl, 5 parts of Colophonium, 15 parts of mica powders, 10 Part gangue powder, 15 parts of bimaleimide resins, 15 parts of micro crystal graphite alkene, 7 parts of methyl acetates, 5 parts of sodium carbonate, 3 part two Ethylene glycol, 4 parts of isopentane, 5 parts of stearic acid, 5 parts of aluminium-magnesium silicates, 3 parts of sodium methanedisulfonate sodium, 10 parts of diatom oozes, 10 parts of gas Phase white carbon, 50 parts of nanometer silver powder, 50 parts of copper nanoparticles, 50 parts of nanometer iron powders.
The above, be only that presently preferred embodiments of the present invention, the not principle to the present invention and framework make any shape Restriction in formula.Any simple modification that every technical spirit according to the present invention is made to above example, equivalent variations with Modify, all still fall within the range of technical scheme.

Claims (3)

1. a kind of boron modified phenolic resin priming paint is it is characterised in that be grouped into by the composition of raw materials group of following mass percent: 180-200 part boron modified phenolic resin, 10-12 part dimethylbenzene, 5-8 part titanium dioxide, 10-12 part white glue with vinyl, 3-5 part Colophonium, 10- 15 parts of mica powders, 8-10 part gangue powder, 12-15 part bimaleimide resin, 10-15 part micro crystal graphite alkene, 5-7 part second Sour methyl ester, 3-5 part sodium carbonate, 2-3 part diethylene glycol ether, 3-4 part isopentane, 3-5 part stearic acid, 4-5 part aluminium-magnesium silicate, 2- 3 parts of sodium methanedisulfonate sodium, 8-10 part diatom ooze, 8-10 part gas-phase silica, 40-50 part nanometer silver powder, 40-50 part Nanometer Coppers Powder, 40-50 part nanometer iron powder.
2. a kind of boron modified phenolic resin priming paint according to claim 1 is it is characterised in that each composition of raw materials group is divided into: 180 parts of boron modified phenolic resins, 10 parts of dimethylbenzene, 5 parts of titanium dioxides, 10 parts of white glue with vinyl, 3 parts of Colophonium, 10 parts of mica powders, 8 parts of coals Spoil powder, 12 parts of bimaleimide resins, 10 parts of micro crystal graphite alkene, 5 parts of methyl acetates, 3 parts of sodium carbonate, 2 parts of diethyls two Alcohol ether, 3 parts of isopentane, 3 parts of stearic acid, 4 parts of aluminium-magnesium silicates, 2 parts of sodium methanedisulfonate sodium, 8 parts of diatom oozes, 8 parts of gas phase Linesless charcoal Black, 40 parts of nanometer silver powder, 40 parts of copper nanoparticles, 40 parts of nanometer iron powders.
3. a kind of boron modified phenolic resin priming paint according to claim 1 is it is characterised in that each composition of raw materials group is divided into: 200 parts of boron modified phenolic resins, 12 parts of dimethylbenzene, 8 parts of titanium dioxides, 12 parts of white glue with vinyl, 5 parts of Colophonium, 15 parts of mica powders, 10 parts of coals Spoil powder, 15 parts of bimaleimide resins, 15 parts of micro crystal graphite alkene, 7 parts of methyl acetates, 5 parts of sodium carbonate, 3 parts of diethyls two Alcohol ether, 4 parts of isopentane, 5 parts of stearic acid, 5 parts of aluminium-magnesium silicates, 3 parts of sodium methanedisulfonate sodium, 10 parts of diatom oozes, 10 parts of gas phases are white White carbon black, 50 parts of nanometer silver powder, 50 parts of copper nanoparticles, 50 parts of nanometer iron powders.
CN201610773356.8A 2016-08-31 2016-08-31 Boron modified phenolic resin priming paint Pending CN106366832A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610773356.8A CN106366832A (en) 2016-08-31 2016-08-31 Boron modified phenolic resin priming paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610773356.8A CN106366832A (en) 2016-08-31 2016-08-31 Boron modified phenolic resin priming paint

Publications (1)

Publication Number Publication Date
CN106366832A true CN106366832A (en) 2017-02-01

Family

ID=57900830

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610773356.8A Pending CN106366832A (en) 2016-08-31 2016-08-31 Boron modified phenolic resin priming paint

Country Status (1)

Country Link
CN (1) CN106366832A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106810992A (en) * 2017-02-15 2017-06-09 盘锦群益管道防腐有限公司 High-temperature resistant one-component coating
CN109620604A (en) * 2018-12-27 2019-04-16 南通市第人民医院 A kind of medical vehicle
WO2019090562A1 (en) * 2017-11-08 2019-05-16 常熟市晓轶金属配件厂 Ultrasonic atomizing nozzle for mining
CN110655682A (en) * 2019-09-10 2020-01-07 安徽省通信产业服务有限公司 Method for strengthening flame-retardant optical cable filler
CN114989692A (en) * 2022-07-01 2022-09-02 上海天阳钢管有限公司 Composite polymer carbon steel pipe and production method thereof
CN116889965A (en) * 2023-09-11 2023-10-17 山东正诺化工设备有限公司 Preparation method of high-flux reinforced pipe

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106810992A (en) * 2017-02-15 2017-06-09 盘锦群益管道防腐有限公司 High-temperature resistant one-component coating
WO2019090562A1 (en) * 2017-11-08 2019-05-16 常熟市晓轶金属配件厂 Ultrasonic atomizing nozzle for mining
CN109620604A (en) * 2018-12-27 2019-04-16 南通市第人民医院 A kind of medical vehicle
CN109620604B (en) * 2018-12-27 2020-01-14 南通市第一人民医院 Medical vehicle
CN110693662A (en) * 2018-12-27 2020-01-17 南通市第一人民医院 Formula and manufacturing method of medical vehicle anti-rust layer
CN110693662B (en) * 2018-12-27 2020-11-20 南通市第一人民医院 Formula and manufacturing method of medical vehicle anti-rust layer
CN110655682A (en) * 2019-09-10 2020-01-07 安徽省通信产业服务有限公司 Method for strengthening flame-retardant optical cable filler
CN114989692A (en) * 2022-07-01 2022-09-02 上海天阳钢管有限公司 Composite polymer carbon steel pipe and production method thereof
CN116889965A (en) * 2023-09-11 2023-10-17 山东正诺化工设备有限公司 Preparation method of high-flux reinforced pipe
CN116889965B (en) * 2023-09-11 2024-01-05 山东正诺化工设备有限公司 Preparation method of high-flux reinforced pipe

Similar Documents

Publication Publication Date Title
CN106366832A (en) Boron modified phenolic resin priming paint
CN103450725B (en) A kind of Environment-friendlyfluorine/silicon-conheavyng fluorine/silicon-conheavyng heavyng anticorrosive epoxy resin paint and preparation method thereof
CN102746766B (en) Water-borne anticorrosion paint and method for preparing same
CN103497636B (en) Water-thinned epoxy zinc-rich coating that conductive nano material with carbon element is modified and preparation method thereof
CN105086529B (en) Environment-friendly water-based ceramic base anti-corrosion material
CN103319981B (en) A kind of double-component aqueous epoxy zinc-enriched paint of high-performance easily construction type and preparation method thereof
CN104530911B (en) Preparation method for high-performance water-based environmentally-friendly anticorrosive paint used for metal base material
CN108997889A (en) A kind of ocean naval vessel graphene heavy antisepsis priming paint and preparation method thereof
CN105623473A (en) Zinc-containing graphene anti-corrosive primer based on graphene dispersoid
CN105419564A (en) Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof
CN106189719A (en) A kind of Graphene anticorrosive paint and preparation method thereof
CN101633808A (en) High chlorinated polyethylene coating containing stainless steel flakes and preparation method thereof
CN105969025A (en) Anticorrosive coating material with physically stripped graphene and method for preparing anticorrosive coating material
CN105713481A (en) Graphene-modified epoxy zinc-rich primer and preparation method thereof
CN106047077A (en) Carbon nanomaterial composite conductive mica/epoxy-group static conducting anticorrosive coating material and preparation method
CN109181490A (en) A kind of water corrosion-resistant epoxy paint and preparation method thereof
CN105925178A (en) Water-based organic and inorganic hybrid anticorrosive paint composition and preparing method thereof
CN106318105A (en) Waterproof and anticorrosive paint special for marine ships
CN105219230A (en) A kind of oceanographic engineering heavy-duty coating
CN107189618A (en) A kind of waterborne inorganic einc-rich primer and preparation method thereof
CN109401526A (en) A kind of graphene anticorrosive paint and preparation method thereof
CN106519779A (en) Graphene-supported nano zinc and epoxy zinc-rich primer containing graphene-supported nano zinc
CN108912952A (en) A kind of water-base epoxy heavy antisepsis priming paint and preparation method thereof that liquid petroleum resin is modified
CN107556886A (en) A kind of graphite-epoxy alkene zinc powder coating
CN112457698A (en) Graphene-modified zinc powder, preparation method and application of graphene-modified zinc powder in zinc-rich anticorrosive coating

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170201

WD01 Invention patent application deemed withdrawn after publication