CN106810992A - High-temperature resistant one-component coating - Google Patents
High-temperature resistant one-component coating Download PDFInfo
- Publication number
- CN106810992A CN106810992A CN201710081234.7A CN201710081234A CN106810992A CN 106810992 A CN106810992 A CN 106810992A CN 201710081234 A CN201710081234 A CN 201710081234A CN 106810992 A CN106810992 A CN 106810992A
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- Prior art keywords
- resin
- phenol
- temperature resistant
- formaldehyde
- epoxy resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/34—Condensation polymers of aldehydes or ketones with monomers covered by at least two of the groups C09D161/04, C09D161/18 and C09D161/20
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to a kind of one-component thermostable anticorrosive paint and preparation method thereof.Described one-component thermostable anticorrosive paint composition is more than 2 various epoxy resin 15 25%, inorganic elements phenol-formaldehyde resin modified 15 25%, phenol cyanate resin 15 30%, amino resins 1 5%, inorganic filler 20 40%, auxiliary agent 1 3% and solvent 25 35% for functional group.The obtained coating normal temperature storage phase of the invention is not less than 1 year, and the cured film of the coating has adhesive force very high, heat resistance very high（Glass transition temperature is not less than 220 DEG C）, excellent high-temperature anticorrosion performance.
Description
Technical field
The present invention relates to a kind of preparation method of one-component thermostable anticorrosive paint.Have after the paint solidification very high resistance to
Hot property, its glass transition temperature is higher than 220 DEG C, and antiseptic property is excellent during high temperature.
Background technology
Anti-corrosive organic coatings are widely used in the fields such as chemical industry, building, Aero-Space, machinery as a kind of protection materials,
As coating is using the expansion in field, coating properties it is also proposed with requirement higher, wherein heat resistance is exactly one
Critically important technical indicator.
Most coatings that we use belong to organic coating, because its preparation method is simple, easy to use, product
Plant various.But also just because of being organic coating, so its temperature in use is limited in normal temperature or a little higher than normal temperature mostly.If using ring
Border temperature at 150 degree or it is higher when, the barrier propterty of most of organic coatings is substantially reduced or completely lost.
Since for a long time, many technological staffs are all being devoted to improving the heat resistance of organic coating.Its method has：
1）Improve the crosslink density of coating resin
2）Heatproof group is introduced in molecular resin
3）Inorganic elements is introduced in resin organic molecule or makes molecular resin that there is special structure.
The present invention is exactly to set about in terms of three above, and some special resins are preferentially combined, so that gained is applied
Layer has heat resistance very high.
Epoxy resin can provide good adhesive force, and good with the compatibility performance of other resins, in order to improve coating tree
The crosslink density of fat, the degree of functionality of the epoxy resin that the present invention is selected is more than 2.
The modified phenolic resin of inorganic elements has heat resistance very high, and heat decomposition temperature can be more than 500 DEG C, much
Higher than the decomposition temperature of general organic matter, it is widely used in the structural material of rocket, the high temperature resistant of guided missile and ablation.
Phenol cyanate resin（PT resins）It is a kind of high-performance novel synthetic material that have developed rapidly in recent years, it has similar
The excellent production process performance of epoxy resin, but with remarkable flame-proof heat-resistant performance, solidfied material glass transition temperature is reachable
380 DEG C, 460 DEG C just start to decompose.
In amino resins molecule contain-N-H keys, can and epoxy reaction, improve solidfied material crosslink density, while
Contribute to coating surface levelling during paint solidification.
The content of the invention
Goal of the invention：The problem solved needed for of the invention is to provide a kind of preparation side of one-component thermostable anticorrosive paint
Method.The method dope preparing process is simple, and easy construction, Storage period is long.
Technical scheme：
A kind of high-temperature resistant one-component coating, it is characterised in that：The coating includes following component：
Epoxy resin of the degree of functionality more than 2；
Inorganic elements phenol-formaldehyde resin modified；
Phenol cyanate resin；
Amino resins；
Inorganic filler；
Auxiliary agent and solvent.
Described high-temperature resistant one-component coating, it is characterised in that：Epoxy resin of the degree of functionality more than 2 is specially line style
Phenol formaldehyde (PF) epoxy resin, line style orthoresol formaldehyde epoxy resin, resorcinol formaldehyde epoxy resin, diaminodiphenyl-methane
One kind or wherein several mixtures in epoxy resin.
Described high-temperature resistant one-component coating, it is characterised in that：The amino resins is etherified melamine amine-formaldehyde resins.
Described high-temperature resistant one-component coating, it is characterised in that：The inorganic filler is the one kind in pigment, constitution filler
Or the two mixing.
Described high-temperature resistant one-component coating, it is characterised in that：The auxiliary agent be specially dispersant, defoamer, levelling agent,
One kind or many of mixture in coupling agent, anti-settling agent.
Described high-temperature resistant one-component coating, it is characterised in that：The solvent is specially dimethylbenzene, n-butanol, butanone, ring
One or more mixture in hexanone, ethanol, dimethylformamide.
Described high-temperature resistant one-component coating, it is characterised in that：The inorganic elements phenol-formaldehyde resin modified for be boron, molybdenum,
One or more mixture in phosphorus, Si modification phenolic resin.
The preparation method of described one-component thermostable coating, it is characterised in that：
The preparation method is comprised the following steps：
Step one：Ethanol is added in a reservoir, adds fineness to be not less than the modified phenol of inorganic elements of 100 mesh during stirring
The weight ratio of urea formaldehyde, ethanol and phenolic resin is 1：1, fully it is dissolved into transparency liquid；
Step 2：Phenol cyanate resin dimethylbenzene and n-butanol are diluted to the weight of 80% resin liquid, dimethylbenzene and n-butanol
Than being 1：1；
Step 3：Epoxy resin, solvent and inorganic filler are stirred after grinding, be put into scattered container, open stirring
Device, control rotating speed adds amino resins and auxiliary agent at 250-350 revs/min, and step one gained resin liquid is slowly added to, then
Step 2 gained resin liquid is slowly added to；Agitator speed is improved to 550-650 revs/min, is sufficiently stirred for 30 minutes；
Stop stirring, discharging filtering, packed for standby use.
Advantage and effect：The obtained coating normal temperature storage phase of the invention is not less than 1 year, and the cured film of the coating is with very high
Adhesive force, heat resistance very high（Glass transition temperature is not less than 220 DEG C）, excellent high-temperature anticorrosion performance.
Specific embodiment：
The one-component thermostable anticorrosive paint that the present invention is provided is by multiple functionality epoxide resin, inorganic elements modified phenolic resin
Fat, phenol cyanate resin, amino resins, auxiliary agent and solvent by dissolving, mixing, grinding, disperse at a high speed, most in a certain order
After filter and package and obtain.Required raw material is matched with weight percent：
Epoxy resin 15-25%
Inorganic elements phenol-formaldehyde resin modified 15-25%
Phenol cyanate resin 15-30%
Amino resins 1-5%
Inorganic filler 15-40%
Auxiliary agent 1-3%
Solvent 25-35%
Wherein above-mentioned epoxy resin is line style phenol formaldehyde (PF) epoxy resin（Abbreviation novolac epoxy resin, EPN）, line style orthoresol first
Formaldehyde epoxy resin（ECN）, resorcinol formaldehyde epoxy resin, diamino diphenyl methane epoxy resin, their denominator
It is at least three epoxy radicals in each molecule, the crosslink density of solidfied material can be greatly improved.Can select in the present invention
One kind therein, it is also possible to be used in mixed way from several.
Above-mentioned inorganic elements phenol-formaldehyde resin modified refers generally to boron modified phenolic resin, molybdenum phenol-formaldehyde resin modified, P Modification phenol
Urea formaldehyde, Si modification phenolic resin, the present invention recommend one kind therein.
Above-mentioned phenol cyanate resin does not have volatile small molecule thing to produce as self-curing system in its solidification process, shrink
Rate is low, is a kind of preferable resin for manufacturing polymer matrix composites.Why it has heat resistance very high, because except this
Body has outside phenyl ring, produces triazine ring in solidification process again.
Above-mentioned amino resins selects etherified melamine amine-formaldehyde resins.
Above-mentioned inorganic filler selects the talcum powder, mica powder, glass flake, stainless steel flakes effectively to control coating to exist
Cracking trend during high temperature.If having color needs, inorganic pigment should be also selected, because easily changing colour during organic pigment high temperature.
Above-mentioned solvent is therein a kind of or several from dimethylbenzene, n-butanol, butanone, cyclohexanone, ethanol, dimethylformamide
Kind, phenol-formaldehyde resin modified is reused after typically being diluted with ethanol.
Above-mentioned auxiliary agent is a kind of or therein several in dispersant, defoamer, coupling agent, levelling agent, anti-settling agent.
The present invention provide one-component thermostable anticorrosive paint preparation procedure be：
The first step：Ethanol is added in a reservoir, adds fineness to be not less than the modified phenol of inorganic elements of 100 mesh during stirring
The weight ratio of urea formaldehyde, ethanol and phenolic resin is 1：1.Fully it is dissolved into fully transparent liquid.
Second step：Phenol cyanate resin dimethylbenzene and n-butanol are diluted to 80% resin liquid, dimethylbenzene and n-butanol
Weight ratio is 1：1.
3rd step：Epoxy resin, solvent and inorganic filler are stirred after being ground to the fineness of requirement, be put into container
In, agitator is then turned on, control rotating speed adds amino resins and auxiliary agent at 300 revs/min or so, and first step gained is set
Fat liquid is slowly added to, then second step gained resin liquid is slowly added to.Then proceed to improve agitator speed to 600 revs/min,
It is sufficiently stirred for 30 minutes.
Then stirring, discharging filtering, packed for standby use are stopped.
After coating application is finished, solidification process is that advance air drying is no less than 4 hours, is then warmed up to 100-120 DEG C,
Solidification 3-4 hours, is finally warmed up to 200 DEG C and solidifies 4-5 hours.
Further the present invention is described in further detail by the following examples.
Embodiment 1
The first step：15gG ethanol is added in a reservoir, agitator is started, and the 15Kg boron modified phenolic resins crushed progressively are added
In entering container, continue to stir more than 4 hours, until resin to be completely dissolved into clear solution stand-by.
Second step：2Kg n-butanols and 2Kg dimethylbenzene are added in a reservoir, agitator are started, thick 16Kg phenol triazine
Resin（50 DEG C can be previously heated to, viscosity is reduced）It is slowly added in container, until resin is completely dissolved into clear solution and treats
With.
3rd step：4Kg dimethylformamides, 3Kg n-butanols and 3Kg cyclohexanone are added in a reservoir, start agitator,
15KgF-51 novolac epoxy resins（It is previously heated to 60-70 DEG C）It is slowly added in container.Until resin be completely dissolved into it is transparent
Solution, being that resin liquid is cooled to room temperature, under agitation add 0.5Kg organobentonites（Anti-settling agent）, 4Kg carbon blacks, 7Kg slide
Stone flour, 4Kg mica powders, are then ground to fineness to less than 50 microns with grinder again.Resulting material is put back in container, is started
Stirring, control rotating speed adds 5Kg amino resins, 2Kg dispersants, 1Kg defoamers, 1.5Kg levellings at 300 revs/min or so
Agent, then the first step and second step gained resin liquid are slowly added to.Then proceed to improve agitator speed to 600 revs/min, fill
Divide stirring 30 minutes.
Then stirring, discharging filtering, packed for standby use are stopped.
Embodiment 2
The first step：15gG ethanol is added in a reservoir, agitator is started, and the 15Kg molybdenum phenol-formaldehyde resin modifieds crushed progressively are added
In entering container, continue to stir more than 4 hours, until resin to be completely dissolved into clear solution stand-by.
Second step：2Kg n-butanols and 2Kg dimethylbenzene are added in a reservoir, agitator are started, thick 16Kg phenol triazine
Resin（50 DEG C can be previously heated to, viscosity is reduced）It is slowly added in container, until resin is completely dissolved into clear solution and treats
With.
3rd step：4Kg dimethylformamides, 3Kg n-butanols and 3Kg cyclohexanone are added in a reservoir, start agitator,
15Kg diamino diphenyl methane epoxy resins（It is previously heated to 60-70 DEG C）It is slowly added in container.Until resin is completely molten
Solution, being that resin liquid is cooled to room temperature, adds 0.5Kg organobentonites under agitation into transparent solution（Anti-settling agent）、11Kg
Titanium dioxide, 4Kg mica powders, are then ground to fineness to less than 50 microns with grinder again.Resulting material is put back in container, is opened
Dynamic stirring, control rotating speed adds 5Kg amino resins, 2Kg dispersants, 1Kg defoamers, 1.5Kg levellings at 300 revs/min or so
Agent, then the first step and second step gained resin liquid are slowly added to.Then proceed to improve agitator speed to 600 revs/min, fill
Divide stirring 30 minutes.
Then stirring, discharging filtering, packed for standby use are stopped.
Two above example gained coating, after construction finishes rear air drying more than 4 hours, is then warmed up to 100-120
DEG C, solidify 3-4 hours, finally it is warmed up to 200 DEG C resolidification 4-5 hours.
There is following masses technical indicator by above method gained coating：
Claims (8)
1. a kind of high-temperature resistant one-component coating, it is characterised in that：The coating includes following component：
Epoxy resin of the degree of functionality more than 2；
Inorganic elements phenol-formaldehyde resin modified；
Phenol cyanate resin；
Amino resins；
Inorganic filler；
Auxiliary agent and solvent.
2. high-temperature resistant one-component coating according to claim 1, it is characterised in that：Asphalt mixtures modified by epoxy resin of the degree of functionality more than 2
Fat is specially line style phenol formaldehyde (PF) epoxy resin, line style orthoresol formaldehyde epoxy resin, resorcinol formaldehyde epoxy resin, diamino
One kind or wherein several mixtures in base diphenyl methane epoxy resin.
3. high-temperature resistant one-component coating according to claim 1, it is characterised in that：The amino resins is etherified melamine
Amine-formaldehyde resins.
4. high-temperature resistant one-component coating according to claim 1, it is characterised in that：The inorganic filler is pigment, constitution
One or both mixing in filler.
5. high-temperature resistant one-component coating according to claim 1, it is characterised in that：The auxiliary agent is specially dispersant, disappears
One kind or many of mixture in infusion, levelling agent, coupling agent, anti-settling agent.
6. high-temperature resistant one-component coating according to claim 1, it is characterised in that：The solvent is specially dimethylbenzene, just
One or more mixture in butanol, butanone, cyclohexanone, ethanol, dimethylformamide.
7. high-temperature resistant one-component coating according to claim 1, it is characterised in that：The inorganic elements phenol-formaldehyde resin modified
To be one or more mixture in boron, molybdenum, phosphorus, Si modification phenolic resin.
8. the preparation method of one-component thermostable coating as claimed in claim 1, it is characterised in that：
The preparation method is comprised the following steps：
Step one：Ethanol is added in a reservoir, adds fineness to be not less than the modified phenol of inorganic elements of 100 mesh during stirring
The weight ratio of urea formaldehyde, ethanol and phenolic resin is 1：1, fully it is dissolved into transparency liquid；
Step 2：Phenol cyanate resin dimethylbenzene and n-butanol are diluted to the weight of 80% resin liquid, dimethylbenzene and n-butanol
Than being 1：1；
Step 3：Epoxy resin, solvent and inorganic filler are stirred after grinding, be put into scattered container, open stirring
Device, control rotating speed adds amino resins and auxiliary agent at 250-350 revs/min, and step one gained resin liquid is slowly added to, then
Step 2 gained resin liquid is slowly added to；Agitator speed is improved to 550-650 revs/min, is sufficiently stirred for 30 minutes；
Stop stirring, discharging filtering, packed for standby use.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710081234.7A CN106810992A (en) | 2017-02-15 | 2017-02-15 | High-temperature resistant one-component coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710081234.7A CN106810992A (en) | 2017-02-15 | 2017-02-15 | High-temperature resistant one-component coating |
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| Publication Number | Publication Date |
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| CN106810992A true CN106810992A (en) | 2017-06-09 |
Family
ID=59111766
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710081234.7A Pending CN106810992A (en) | 2017-02-15 | 2017-02-15 | High-temperature resistant one-component coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109575742A (en) * | 2018-12-10 | 2019-04-05 | 中国人民解放军国防科技大学 | Low-cost high-temperature-resistant anti-oxidation coating and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN103289033A (en) * | 2013-04-08 | 2013-09-11 | 西安交通大学 | Aryl boron-containing phenolic resin and preparation method thereof |
| CN103382345A (en) * | 2013-05-02 | 2013-11-06 | 鑫洲科技有限公司 | Preparation method of high temperature resistant epoxy insulating coating |
| CN106366832A (en) * | 2016-08-31 | 2017-02-01 | 朱燕华 | Boron modified phenolic resin priming paint |
-
2017
- 2017-02-15 CN CN201710081234.7A patent/CN106810992A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008066319A1 (en) * | 2006-11-28 | 2008-06-05 | Woo-Jae Lee | Inorganic pigments composition having high hardness |
| CN103289033A (en) * | 2013-04-08 | 2013-09-11 | 西安交通大学 | Aryl boron-containing phenolic resin and preparation method thereof |
| CN103382345A (en) * | 2013-05-02 | 2013-11-06 | 鑫洲科技有限公司 | Preparation method of high temperature resistant epoxy insulating coating |
| CN106366832A (en) * | 2016-08-31 | 2017-02-01 | 朱燕华 | Boron modified phenolic resin priming paint |
Non-Patent Citations (2)
| Title |
|---|
| 李桂林: "《环氧树脂与环氧涂料》", 31 March 2003, 北京：化学工业出版社 * |
| 贾红兵等: "《高分子材料》", 31 December 2013, 南京：南京大学出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109575742A (en) * | 2018-12-10 | 2019-04-05 | 中国人民解放军国防科技大学 | Low-cost high-temperature-resistant anti-oxidation coating and preparation method thereof |
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Application publication date: 20170609 |
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