CN106366673A - Natural resin composite and preparation method thereof - Google Patents
Natural resin composite and preparation method thereof Download PDFInfo
- Publication number
- CN106366673A CN106366673A CN201610767227.8A CN201610767227A CN106366673A CN 106366673 A CN106366673 A CN 106366673A CN 201610767227 A CN201610767227 A CN 201610767227A CN 106366673 A CN106366673 A CN 106366673A
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- natural resin
- resin composite
- red phosphorus
- bamboo charcoal
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L93/00—Compositions of natural resins; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a natural resin composite. The natural resin composite is made of raw material containing following components by weight part: 25-40 parts of natural resin, 10-25 parts of organic silicon resin, 1-8 parts of polyethylene wax, 2-10 parts of nanometer titanium dioxide, 1-5 parts of hollow glass beads, 2-8 parts of active carbon, 3-10 parts of bamboo charcoal powder, 0.1-0.8 part of trimethyl hexamethylene diamine, 0.2-1.5 parts of ethoxylated lauramide, 0.2-1 part of red phosphorus, 0.3-1 part of dibutyl phosphate, 1-2.5 parts of epoxy soybean oil, 1-2.5 parts of decabrominated dipheny ethane, 1-5 parts of glucose, 15-35 parts of solvent and 2-10 parts of auxiliaries. According to the natural resin composite and a preparation method thereof, the preparation method is simple, and easy to operate, and obtains the natural resin composite high in strength, excellent in antimicrobial performance and stain resistance, and good in fire resistance.
Description
Technical field
The present invention relates to resin technology field, more particularly, to a kind of natural resin composite and preparation method thereof.
Background technology
Natural resin is mainly derived from plant and oozes the amorphous semi-solid or solid organic matters that (secreting) goes out thing, by temperature time variance
Soft and fusible, there is flowing under stress, typically water insoluble, and alcohol, ether, ketone can be dissolved in and other are organic
Solvent, this kind of substance classes are various, from plant person, mainly have Colophonium, lacquer, succinum etc.；From animal person, mainly have
Lac, it is the secretions of lac insect.Natural resin is mainly used as coating it can also be used to papermaking, insulant, adhesive, doctor
The production process of medicine, spice etc..With social development, people put forward higher requirement to the performance of natural resin, merely
Its performance of natural resin can not meet the requirement of the society of high speed development, during the use of natural resin, it is right to need
It is modified and obtain natural resin composite.The method of modifying of natural resin has a lot, such as nano-material modified.Existing
Its intensity of natural resin composite, antibiotic property and anti-flammability are less desirable, limit the application of natural resin.
Content of the invention
The invention aims to shortcoming present in solution prior art, and a kind of natural resin composite wood proposing
Material and preparation method thereof, the simple natural resin composite material strength height it is easy to operate, obtaining of preparation method, antibacterial dirt-resistant
Excellent performance, good flame resistance.
To achieve these goals, present invention employs following technical scheme:
A kind of natural resin composite, its raw material includes following components: natural resin 25-40 part, organosilicon tree by weight
Fat 10-25 part, Tissuemat E 1-8 part, nano titanium oxide 2-10 part, hollow glass microbead 1-5 part, activated carbon 2-8 part, bamboo charcoal
Powder 3-10 part, trimethylhexamethylenediamine 0.1-0.8 are divided, ethoxylation lauramide 0.2-1.5 part, red phosphorus 0.2-1 part, phosphorus
Dibutyl phthalate 0.3-1 part, epoxy soybean oil 1-2.5 part, TDE 1-2.5 part, glucose 1-5 part, solvent 15-35
Part, auxiliary agent 2-10 part.
Preferably, the weight of nano titanium oxide, hollow glass microbead, activated carbon, bamboo charcoal powder is than for 3-8:3-4.5:4-
7:6-9.
Preferably, the weight of red phosphorus, dibutylphosphoric acid ester, TDE is than for 0.6-0.9:0.5-0.8:1.6-2.2.
Preferably, its raw material includes following components by weight: natural resin 30-37 part, organic siliconresin 16-22 part,
Tissuemat E 4-7 part, nano titanium oxide 5-9 part, hollow glass microbead 3-4.5 part, activated carbon 6-8 part, bamboo charcoal powder 7-9 part,
Trimethylhexamethylenediamine 0.4-0.7 divides, ethoxylation lauramide 0.7-1.2 part, red phosphorus 0.6-1 part, dibutylphosphoric acid ester
0.5-0.8 part, epoxy soybean oil 1.6-2.1 part, TDE 1.7-2.2 part, glucose 3-4.5 part, solvent 22-30
Part, auxiliary agent 7-9 part.
Preferably, its raw material includes following components: 36 parts of natural resin, 20 parts of organic siliconresin, polyethylene by weight
5.6 parts of wax, 7 parts of nano titanium oxide, 4 parts of hollow glass microbead, 7 parts of activated carbon, 8.6 parts of bamboo charcoal powder, tri-methyl hexamethylene
0.55 point of diamidogen, 1 part of ethoxylation lauramide, 0.8 part of red phosphorus, 0.57 part of dibutylphosphoric acid ester, 2 parts of epoxy soybean oil, ten bromines
2 parts of diphenylethane, 3.7 parts of glucose, 28 parts of solvent, 8 parts of auxiliary agent.
Preferably, described solvent is the mixture of ethanol and water.
Preferably, described auxiliary agent is one of defoamer, corrosion inhibiter, dispersant or multiple combinations.
Preferably, described natural resin is Pinus massoniana Lamb natural resin.
A kind of preparation method of described natural resin composite proposed by the present invention, comprises the following steps: by natural tree
Fat, organic siliconresin, Tissuemat E add solvent in, be warming up to 55-75 DEG C of mix homogeneously, be subsequently adding nano titanium oxide,
Hollow glass microbead, activated carbon and bamboo charcoal powder, are stirring evenly and then adding into trimethylhexamethylenediamine, ethoxylation lauroyl
Amine, red phosphorus, dibutylphosphoric acid ester, epoxy soybean oil, TDE, glucose, are stirring evenly and then adding into auxiliary agent, cured after
Obtain described natural resin composite.
With natural resin, organic siliconresin and Tissuemat E as main matter in the present invention, three's performance is mutually collaborative, carries
The high thermostability of composite and anti-stain characteristic；The nano titanium oxide of interpolation, hollow glass microbead, activated carbon, bamboo charcoal powder
Cooperate, by controlling match ratio, improve thermostability, intensity, antibiotic property and the stain resistance of composite；Red phosphorus, phosphorus
Dibutyl phthalate, TDE cooperate, and improve the anti-flammability of composite.
After in the present invention, said ratio compatibility pressed by each raw material, its performance is worked in coordination with and is promoted, and the composite material strength obtaining is high, resists
Bacterium dirt-resistant excellent performance, good flame resistance.
Specific embodiment
In order that the objects, technical solutions and advantages of the present invention become more apparent, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that specific embodiment described herein is only in order to explain the present invention, not
For limiting the present invention.
Embodiment 1
A kind of natural resin composite, its raw material includes following components: 25 parts of natural resin, organic siliconresin 25 by weight
Part, 1 part of Tissuemat E, 10 parts of nano titanium oxide, 1 part of hollow glass microbead, 8 parts of activated carbon, 3 parts of bamboo charcoal powder, trimethyl six
0.8 point of methylene diamine, 0.2 part of ethoxylation lauramide, 1 part of red phosphorus, 0.3 part of dibutylphosphoric acid ester, 1 part of epoxy soybean oil,
2.5 parts of TDE, 1 part of glucose, 5 parts of ethanol, 30 parts of water, 2 parts of corrosion inhibiter.
Embodiment 2
A kind of natural resin composite, its raw material includes following components: 40 parts of Pinus massoniana Lamb natural resin, organosilicon by weight
10 parts of resin, 8 parts of Tissuemat E, 2 parts of nano titanium oxide, 5 parts of hollow glass microbead, 2 parts of activated carbon, 10 parts of bamboo charcoal powder, three
0.1 point of methyl hexamethylene diamine, 1.5 parts of ethoxylation lauramide, 0.2 part of red phosphorus, 1 part of dibutylphosphoric acid ester, epoxy soybean
2.5 parts of oil, 1 part of TDE, 5 parts of glucose, 10 parts of ethanol, 5 parts of water, 3 parts of defoamer, 7 parts of corrosion inhibiter.
Embodiment 3
A kind of natural resin composite, its raw material includes following components: 36 parts of natural resin, organic siliconresin 20 by weight
Part, 5.6 parts of Tissuemat E, 7 parts of nano titanium oxide, 4 parts of hollow glass microbead, 7 parts of activated carbon, 8.6 parts of bamboo charcoal powder, trimethyl
0.55 point of hexamethylene diamine, 1 part of ethoxylation lauramide, 0.8 part of red phosphorus, 0.57 part of dibutylphosphoric acid ester, epoxy soybean oil 2
Part, 2 parts of TDE, 3.7 parts of glucose, 20 parts of ethanol, 8 parts of water, 2 parts of defoamer, 3 parts of corrosion inhibiter, 3 parts of dispersant.
Embodiment 4
A kind of natural resin composite, its raw material includes following components: 30 parts of natural resin, organic siliconresin 22 by weight
Part, 4 parts of Tissuemat E, 9 parts of nano titanium oxide, 3 parts of hollow glass microbead, 8 parts of activated carbon, 7 parts of bamboo charcoal powder, trimethyl six are sub-
0.7 point of methanediamine, 0.7 part of ethoxylation lauramide, 1 part of red phosphorus, 0.5 part of dibutylphosphoric acid ester, 2.1 parts of epoxy soybean oil,
1.7 parts of TDE, 4.5 parts of glucose, 22 parts of solvent, 9 parts of auxiliary agent.
A kind of preparation method of described natural resin composite proposed by the present invention, comprises the following steps: by natural tree
Fat, organic siliconresin, Tissuemat E add in solvent, are warming up to 75 DEG C of mix homogeneously, are subsequently adding nano titanium oxide, hollow
Glass microballoon, activated carbon and bamboo charcoal powder, are stirring evenly and then adding into trimethylhexamethylenediamine, ethoxylation lauramide, red
Phosphorus, dibutylphosphoric acid ester, epoxy soybean oil, TDE, glucose, are stirring evenly and then adding into auxiliary agent, cured after obtain
Described natural resin composite.
Embodiment 5
A kind of natural resin composite, its raw material includes following components: 37 parts of natural resin, organic siliconresin 16 by weight
Part, 7 parts of Tissuemat E, 5 parts of nano titanium oxide, 4.5 parts of hollow glass microbead, 6 parts of activated carbon, 9 parts of bamboo charcoal powder, trimethyl six
0.4 point of methylene diamine, 1.2 parts of ethoxylation lauramide, 0.6 part of red phosphorus, 0.8 part of dibutylphosphoric acid ester, epoxy soybean oil 1.6
Part, 2.2 parts of TDE, 3 parts of glucose, 30 parts of solvent, 7 parts of auxiliary agent.
A kind of preparation method of described natural resin composite proposed by the present invention, comprises the following steps: by natural tree
Fat, organic siliconresin, Tissuemat E add in solvent, are warming up to 55 DEG C of mix homogeneously, are subsequently adding nano titanium oxide, hollow
Glass microballoon, activated carbon and bamboo charcoal powder, are stirring evenly and then adding into trimethylhexamethylenediamine, ethoxylation lauramide, red
Phosphorus, dibutylphosphoric acid ester, epoxy soybean oil, TDE, glucose, are stirring evenly and then adding into auxiliary agent, cured after obtain
Described natural resin composite.
With natural resin, organic siliconresin and Tissuemat E as main matter in the present invention, three's performance is mutually collaborative, carries
The high thermostability of composite and anti-stain characteristic；The nano titanium oxide of interpolation, hollow glass microbead, activated carbon, bamboo charcoal powder
Cooperate, by controlling match ratio, improve thermostability, intensity, antibiotic property and the stain resistance of composite；Red phosphorus, phosphorus
Dibutyl phthalate, TDE cooperate, and improve the anti-flammability of composite.In the present invention, said ratio pressed by each raw material
After compatibility, its performance is worked in coordination with and is promoted, and the composite material strength obtaining is high, antibacterial dirt-resistant excellent performance, good flame resistance.
Claims (9)
1. a kind of natural resin composite is it is characterised in that its raw material includes following components: natural resin 25- by weight
40 parts, organic siliconresin 10-25 part, Tissuemat E 1-8 part, nano titanium oxide 2-10 part, hollow glass microbead 1-5 part, work
Property charcoal 2-8 part, bamboo charcoal powder 3-10 part, trimethylhexamethylenediamine 0.1-0.8 are divided, ethoxylation lauramide 0.2-1.5 part,
Red phosphorus 0.2-1 part, dibutylphosphoric acid ester 0.3-1 part, epoxy soybean oil 1-2.5 part, TDE 1-2.5 part, glucose 1-5
Part, solvent 15-35 part, auxiliary agent 2-10 part.
2. according to claim 1 natural resin composite it is characterised in that nano titanium oxide, hollow glass microbead,
Activated carbon, the weight of bamboo charcoal powder are than for 3-8:3-4.5:4-7:6-9.
3. according to claim 1 natural resin composite it is characterised in that red phosphorus, dibutylphosphoric acid ester, decabrominated dipheny second
The weight of alkane is than for 0.6-0.9:0.5-0.8:1.6-2.2.
4. according to claim 1 natural resin composite it is characterised in that its raw material is included by weight with the following group
Point: natural resin 30-37 part, organic siliconresin 16-22 part, Tissuemat E 4-7 part, nano titanium oxide 5-9 part, double glazing
Microballon 3-4.5 part, activated carbon 6-8 part, bamboo charcoal powder 7-9 part, trimethylhexamethylenediamine 0.4-0.7 are divided, ethoxylation Laurel
Amide 0.7-1.2 part, red phosphorus 0.6-1 part, dibutylphosphoric acid ester 0.5-0.8 part, epoxy soybean oil 1.6-2.1 part, decabrominated dipheny second
Alkane 1.7-2.2 part, glucose 3-4.5 part, solvent 22-30 part, auxiliary agent 7-9 part.
5. according to claim 4 natural resin composite it is characterised in that its raw material is included by weight with the following group
Point: 36 parts of natural resin, 20 parts of organic siliconresin, 5.6 parts of Tissuemat E, 7 parts of nano titanium oxide, 4 parts of hollow glass microbead,
7 parts of activated carbon, 8.6 parts of bamboo charcoal powder, 0.55 point of trimethylhexamethylenediamine, 1 part of ethoxylation lauramide, 0.8 part of red phosphorus,
0.57 part of dibutylphosphoric acid ester, 2 parts of epoxy soybean oil, 2 parts of TDE, 3.7 parts of glucose, 28 parts of solvent, 8 parts of auxiliary agent.
6. according to claim 1 natural resin composite it is characterised in that described solvent is the mixing of ethanol and water
Thing.
7. according to claim 1 natural resin composite it is characterised in that described auxiliary agent be defoamer, corrosion inhibiter, point
One of powder or multiple combinations.
8. according to claim 1 natural resin composite it is characterised in that described natural resin be the natural tree of Pinus massoniana Lamb
Fat.
9. a kind of preparation method of natural resin composite according to any one of claim 1-8 is it is characterised in that wrap
Include following steps: natural resin, organic siliconresin, Tissuemat E are added in solvent, is warming up to 55-75 DEG C of mix homogeneously, so
Add nano titanium oxide, hollow glass microbead, activated carbon and bamboo charcoal powder afterwards, be stirring evenly and then adding into tri-methyl hexamethylene two
Amine, ethoxylation lauramide, red phosphorus, dibutylphosphoric acid ester, epoxy soybean oil, TDE, glucose, after stirring
Add auxiliary agent, cured after obtain described natural resin composite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610767227.8A CN106366673A (en) | 2016-08-31 | 2016-08-31 | Natural resin composite and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610767227.8A CN106366673A (en) | 2016-08-31 | 2016-08-31 | Natural resin composite and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106366673A true CN106366673A (en) | 2017-02-01 |
Family
ID=57901688
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610767227.8A Pending CN106366673A (en) | 2016-08-31 | 2016-08-31 | Natural resin composite and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN106366673A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113652094A (en) * | 2021-07-26 | 2021-11-16 | 广州鸿绵合成材料有限公司 | Modified luminous color asphalt and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3542714A (en) * | 1965-10-06 | 1970-11-24 | Dow Corning | Paintable methylsiloxane elastomers |
| JPH0565418A (en) * | 1991-09-06 | 1993-03-19 | Agency Of Ind Science & Technol | Production of shellac resin-silica glass hybrid material |
| EP0540040A1 (en) * | 1991-10-31 | 1993-05-05 | Dow Corning Toray Silicone Company, Limited | Room-temperature-curable organopolysiloxane composition |
| US5530040A (en) * | 1995-04-14 | 1996-06-25 | Ross; Donald B. | Traction composition for rubber |
| CN101967283A (en) * | 2010-10-21 | 2011-02-09 | 中华全国供销合作总社西安生漆涂料研究所 | Lacquer-wax silicone resin and preparation method thereof |
-
2016
- 2016-08-31 CN CN201610767227.8A patent/CN106366673A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3542714A (en) * | 1965-10-06 | 1970-11-24 | Dow Corning | Paintable methylsiloxane elastomers |
| JPH0565418A (en) * | 1991-09-06 | 1993-03-19 | Agency Of Ind Science & Technol | Production of shellac resin-silica glass hybrid material |
| EP0540040A1 (en) * | 1991-10-31 | 1993-05-05 | Dow Corning Toray Silicone Company, Limited | Room-temperature-curable organopolysiloxane composition |
| US5530040A (en) * | 1995-04-14 | 1996-06-25 | Ross; Donald B. | Traction composition for rubber |
| CN101967283A (en) * | 2010-10-21 | 2011-02-09 | 中华全国供销合作总社西安生漆涂料研究所 | Lacquer-wax silicone resin and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113652094A (en) * | 2021-07-26 | 2021-11-16 | 广州鸿绵合成材料有限公司 | Modified luminous color asphalt and preparation method thereof |
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