CN101967283A - Lacquer-wax silicone resin and preparation method thereof - Google Patents
Lacquer-wax silicone resin and preparation method thereof Download PDFInfo
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- CN101967283A CN101967283A CN 201010514665 CN201010514665A CN101967283A CN 101967283 A CN101967283 A CN 101967283A CN 201010514665 CN201010514665 CN 201010514665 CN 201010514665 A CN201010514665 A CN 201010514665A CN 101967283 A CN101967283 A CN 101967283A
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- lacquer
- lacquer tree
- tree fat
- organosilicon
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Abstract
The invention provides a lacquer-wax silicone resin product. The prepared lacquer-wax silicone resin product comprises the following raw materials in percentage by mass: 25 to 35 percent of lacquer wax or paints, 25 to 35 percent of organic silicon, 1 to 6 percent of catalyst, 5 to 10 percent of emulsifier and 25 to 35 percent of solvent, wherein the mass percentages of the raw materials above add up to 100 percent. The lacquer-wax silicone resin is a novel fine chemical product with excellent performances. After simple processing, the lacquer-wax silicone resin product can widely be used in the industries such as polishing agent, furniture, automobile beauty and commodity, and the like, and most of the objects after adopting the lacquer-wax silicone resin of the invention are shiny, satiny, soft, moisturizing, hydrophobic, dustproof, heat-resistant, corrosion-resistance, and the like.
Description
Technical field
The invention belongs to the application chemical technology field, relate to a kind of fine chemistry industry early-products, particularly a kind of lacquer tree fat organosilicon goods that silicone based substance modification lacquer tree fat makes and preparation method thereof that utilize.
Background technology
Organosilicon has purposes widely with its particular performances.As the special tensio-active agent of a class, organic silicon surfactant is the tensio-active agent that parent, end group or side chain connect one or more functional functional groups often with the siloxanes.It has the capillary ability of good reduction, good wetting, froth breaking, surely bubble and characteristics such as anti-aging, high temperature resistant, and also its biological degradability is good, environmental pollution is little.In field such as daily chemical products such as articles for washing and textile printing and dyeing, plating be anticorrosion, be widely used as tensio-active agent always.
The lacquer seed is the fruit of lacquer tree, mesocarp is light yellow or greyish-green, be wax layer, can extract lacquer tree fat, kernel can squeeze urushoil for kind of a nuclear, lacquer tree fat and urushoil are referred to as lacquer tree fat, account for about 35%～50% of lacquer seed total amount, contain the glycerin fatty acid ester more than 90% in the lacquer tree fat, wherein palmitic acid content reaches about 70%; Contain the linolic acid more than 60% in the urushoil, have the blood fat of adjustment and arteriosclerosis effect, can reduce evidence of coronary heart diseases and mortality ratio, have very high nourishing function.The a large amount of high-grade aliphatic esters, higher fatty acid free acid and the high fatty alcohol that contain in the lacquer seed, and glucides such as glucose, lactose, sucrose and maltose, can prepare novel and effective higher polyol ester compound, gentle non-stimulated, be the main raw material of present daily necessities, superior cosmetics and healthcare products, application prospect is very wide.
Summary of the invention
On the basis that keeps lacquer tree fat and the original premium properties of organosilicon, the objective of the invention is to, a kind of lacquer tree fat organosilicon goods are provided, these lacquer tree fat organosilicon goods are excellent fine chemistry industry early-products, after simple processing, just can be applied to the R and D of polishing material, furniture, car detailing and daily product aspect.
In order to realize above-mentioned task, the present invention adopts following technical scheme:
A kind of lacquer tree fat organosilicon goods, these lacquer tree fat organosilicon goods that make are made by mass percentage by following raw materials according: lacquer tree fat or urushoil: 25%～35%, organosilicon: 25%～35%, catalyzer: 1%～6%, emulsifying agent: 5%～10%, solvent: 25%～45%, the per-cent sum of above-mentioned raw materials is 100%.
Above-mentioned lacquer tree fat or urushoil are that the traditional mode of employing is squeezed or lixiviate forms from Ankang, Hanzhong, entrance of the city, Mao Ba, the Qinling Mountains or other blocky lacquer seeds of area plantation lacquer trees institute.
Above-mentioned organosilicon is organosilane monomer, performed polymer or silicone resin one or more mixtures wherein.
Above-mentioned catalyzer is the acid-base class compound;
Above-mentioned emulsifying agent is a sodium alkyl benzene sulfonate salt anionic emulsifier;
Above-mentioned solvent is an aliphatic compound.
The invention provides the preparation method of these lacquer tree fat organosilicon goods in addition, it is characterized in that, comprise the steps:
Step 1, to plucking the lacquer seed, after fully airing was chosen, it was oily or produce urushoil in traditional lixiviate mode to utilize traditional way to squeeze lacquer tree fat;
Step 2 takes by weighing lacquer tree fat or urushoil after the removal of impurities system by formula ratio, is fed in the reactor, the organosilicon, catalyzer, emulsifying agent and the solvent that add formula ratio after the heat fused again, be heated to 80 ℃～85 ℃, be incubated 3～5 hours, reaction finishes to obtain lacquer tree fat organosilicon crude product;
Step 3 through dehydration, removal of impurities, cooling, promptly gets lacquer tree fat organosilicon goods with lacquer tree fat organosilicon crude product.
The lacquer tree fat that the present invention makes with the processing of lacquer tree fruit lacquer seed is as raw material, pure natural, and safety non-toxic, raw materials for production are abundant, are the significant agricultural resource of a kind of health function by products.Lacquer tree fat organosilicon goods according to the present invention preparation can be widely used in industries such as polishing material, furniture, car detailing and daily necessities, have after the use light, satiny, softness is preserved moisture, hydrophobic dustproof, premium properties such as corrosion resistant is heat-resisting, development prospect is very wide.Be that simultaneously vast lacquer farming provides the channel of a long-term good supply lacquer tree resource, the excellent popularization exemplary role that plays for " serving the agriculture-countryside-farmer ".
Embodiment
Lacquer tree fat of the present invention is to be made by the processing of lacquer tree fruit lacquer seed, because of its main effective constituent includes a large amount of high-grade aliphatic esters, higher fatty acid, saturated and the unsaturated acid and the high fatty alcohol of part, can be by the further modification of organosilicon, be characterized in pure natural, safety non-toxic is the significant agricultural resource of an a kind of health function by product.
The lacquer tree fat organosilicon goods that the present invention makes, make by mass percentage by following raw materials according: lacquer tree fat or urushoil: 20%～30%, organosilicon: 25%～40%, catalyzer: 1%～6%, emulsifying agent: 5%～10%, solvent: 25%～45%, the per-cent sum of above-mentioned raw materials is 100%.
Its preparation method is, at first, with the lacquer seed of plucking select, fully airing, utilize traditional way to squeeze lacquer tree fat or urushoil or produce lacquer tree fat or urushoil in traditional lixiviate mode, then, with lacquer tree fat or the removal of impurities of urushoil crude extract; Lacquer tree fat after the removal of impurities or urushoil are fed in the reactor, add organosilicon, catalyzer, emulsifying agent and the solvent of formula ratio after the heat fused again, be heated to 80 ℃～85 ℃, be incubated 3～5 hours, reaction finishes, and obtains lacquer tree fat organosilicon crude product.At last, lacquer tree fat organosilicon crude product through dehydration, removal of impurities, cooling, is promptly got lacquer tree fat organosilicon goods.
In the above-mentioned raw materials of the present invention, wherein organosilicon is organosilane monomer, is organosilicon performed polymer and the silicone resin that parent, end group or side chain connect one or more functional functional groups with the siloxanes.Its organosilicon performance characteristics is to have good wetting, froth breaking, surely bubble and characteristics such as anti-aging, high temperature resistant, and its biological degradability is good, environmental pollution is little.
Described catalyzer is the acid-base class compound; Described emulsifying agent is a sodium alkyl benzene sulfonate salt anionic emulsifier; Described solvent is an aliphatic compound.
The embodiment that provides below in conjunction with the contriver is described in further detail the present invention, need to prove that the present invention is not limited to following examples.
Embodiment 1:
Its mass percent prescription of the lacquer tree fat organosilicon goods raw material of present embodiment is as follows:
Above-mentioned lacquer tree fat or urushoil select Ankang, Hanzhong, entrance of the city, Mao Ba, the Qinling Mountains and other areas to produce to coat with lacquer that the traditional mode of seed employing is squeezed or lixiviate forms for use.
By above-mentioned mass ratio prescription, lacquer tree fat or urushoil are fed in the reactor, add organosilane monomer, potassium hydroxide, sodium alkyl benzene sulfonate and No. 200 solvent oils after the heat fused again, be heated to 80 ℃, be incubated 3 hours, reaction obtains lacquer tree fat organosilicon crude product after finishing, again method routinely to the organosilicon crude product dewater, removal of impurities, cooling, pour out and can obtain lacquer tree fat organosilicon goods.
Embodiment 2:
The mass percent prescription of the lacquer tree fat organosilicon goods raw material of present embodiment is as follows:
Above-mentioned lacquer tree fat or urushoil select Ankang, Hanzhong, entrance of the city, Mao Ba, the Qinling Mountains and other areas to produce to coat with lacquer that the traditional mode of seed employing is squeezed or lixiviate forms for use.
By above-mentioned mass ratio prescription, lacquer tree fat or urushoil are fed in the reactor, add the vitriol oil, organosilicon performed polymer, sodium alkyl benzene sulfonate and No. 200 solvent oils after the heat fused again, be heated to 83 ℃, be incubated 4 hours, reaction obtains the organosilicon crude product after finishing, then method routinely to the organosilicon crude product dewater, removal of impurities, cooling, pour out and promptly obtain lacquer tree fat organosilicon goods.
Embodiment 3:
Present embodiment the mass percent prescription of lacquer tree fat organosilicon product raw material as follows:
Above-mentioned lacquer tree fat or urushoil select Ankang, Hanzhong, entrance of the city, Mao Ba, the Qinling Mountains and other areas to produce to coat with lacquer that the traditional mode of seed employing is squeezed or lixiviate forms for use.
By above-mentioned mass ratio prescription, lacquer tree fat or urushoil are fed in the reactor, add sodium hydroxide, silicone resin, sodium alkyl benzene sulfonate and No. 200 solvent oils after the heat fused again, be heated to 85 ℃, be incubated 5 hours, reaction obtains the organosilicon crude product after finishing, the organosilicon crude product dewaters method routinely to obtaining, removal of impurities, cooling, pours out and can obtain lacquer tree fat organosilicon goods.
Need to prove that the foregoing description is wherein preferable example just, the invention is not restricted to these examples,, all can make the good silicone paint wax work of character as long as in the formula range that the present invention provides.
The technical feature of the lacquer tree fat organosilicon goods of the foregoing description preparation is referring to table 1.
Table 1
Claims (4)
1. lacquer tree fat organosilicon goods, it is characterized in that, these lacquer tree fat organosilicon goods that make are made by mass percentage by following raw materials according: lacquer tree fat: 20%～30%, silicone based: 25%～40%, catalyzer: 1%～6%, emulsifying agent: 5%～10%, solvent: 25%～45%, the per-cent sum of above-mentioned raw materials is 100%.
2. lacquer tree fat organosilicon goods as claimed in claim 1 is characterized in that, described lacquer tree fat is to extract from Ankang, Hanzhong, entrance of the city, Mao Ba, the Qinling Mountains or other blocky lacquer seeds of area plantation lacquer tree institute.
3. lacquer tree fat organosilicon goods as claimed in claim 1 is characterized in that, described silicone based be organosilane monomer, performed polymer or silicone resin one or more mixtures wherein;
Described catalyzer is the acid-base class compound; Described emulsifying agent is a sodium alkyl benzene sulfonate salt anionic emulsifier; Described solvent is an aliphatic compound.
4. the preparation method of the described lacquer tree fat organosilicon of claim 1 goods is characterized in that, comprises the steps:
Step 1 by plucking the lacquer seed on the sophisticated lacquer tree, is selected colory lacquer seed through abundant airing, and the processing removal of impurities makes lacquer tree fat;
Step 2, the lacquer tree fat that removal of impurities is made is fed in the reactor, add again after the heat fused prescription silicone based,, catalyzer, emulsifying agent and solvent, be heated to 80 ℃～85 ℃, be incubated 3～5 hours, the reaction end;
Step 3 promptly obtains lacquer tree fat organosilicon goods with the reacted product of step 3 through dehydration, removal of impurities, cooling.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010514665A CN101967283B (en) | 2010-10-21 | 2010-10-21 | Lacquer-wax silicone resin and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010514665A CN101967283B (en) | 2010-10-21 | 2010-10-21 | Lacquer-wax silicone resin and preparation method thereof |
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| CN101967283A true CN101967283A (en) | 2011-02-09 |
| CN101967283B CN101967283B (en) | 2012-10-10 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102732148A (en) * | 2012-06-15 | 2012-10-17 | 武汉市国漆有限公司 | Urushiol silicon high temperature resistant liquid anti-corrosion paint |
| CN106366673A (en) * | 2016-08-31 | 2017-02-01 | 李健 | Natural resin composite and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205505A (en) * | 2007-12-11 | 2008-06-25 | 中国林业科学研究院林产化学工业研究所 | Extraction method of japan wax, japan wax composite nano material and preparation method |
-
2010
- 2010-10-21 CN CN201010514665A patent/CN101967283B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205505A (en) * | 2007-12-11 | 2008-06-25 | 中国林业科学研究院林产化学工业研究所 | Extraction method of japan wax, japan wax composite nano material and preparation method |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102732148A (en) * | 2012-06-15 | 2012-10-17 | 武汉市国漆有限公司 | Urushiol silicon high temperature resistant liquid anti-corrosion paint |
| CN102732148B (en) * | 2012-06-15 | 2014-07-30 | 武汉市国漆有限公司 | Urushiol silicon high temperature resistant liquid anti-corrosion paint |
| CN106366673A (en) * | 2016-08-31 | 2017-02-01 | 李健 | Natural resin composite and preparation method thereof |
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| Publication number | Publication date |
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| CN101967283B (en) | 2012-10-10 |
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