CN106366661A - New energy-saving environment-friendly PVC (Polyvinyl Chloride) trough plate for shelf display - Google Patents
New energy-saving environment-friendly PVC (Polyvinyl Chloride) trough plate for shelf display Download PDFInfo
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- CN106366661A CN106366661A CN201610736347.1A CN201610736347A CN106366661A CN 106366661 A CN106366661 A CN 106366661A CN 201610736347 A CN201610736347 A CN 201610736347A CN 106366661 A CN106366661 A CN 106366661A
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- saving environment
- shelf display
- friendly pvc
- modified polypropene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a new energy-saving environment-friendly PVC (Polyvinyl Chloride) trough plate for shelf display, which is prepared from the following raw materials in parts by weight: 15 to 28 parts of polyvinyl chloride, 10 to 18 parts of modified polypropylene, 20 to 40 parts of silicone rubber, 1 to 2 parts of succinic acid peroxide, 1 to 2 parts of phthalic acid hydrogen tert-butyl ester, 0.1 to 0.6 part of tetramethyl thiuram disulfide, 0.5 to 1.2 parts of diazine triethylbenzene mercaptan, 40 to 60 parts of talcum powder, 5 to 12 parts of ceramic fiber, 10 to 20 parts of attapulgite, 20 to 40 parts of activated carbon, 0.5 to 1.5 parts of foaming agent, 1 to 2 parts of phthalic acid dimethyl, 1 to 2 parts of stearic acid, 1 to 2 parts of polyethylene wax, and 1 to 2 parts of epoxidized soybean oil. The new energy-saving environment-friendly PVC trough plate for shelf display provided by the invention is good in tenacity, tear resistant, high in hardness, and good in heat stability.
Description
Technical field
The present invention relates to pvc ventilation channel plate technical field, more particularly, to a kind of shelf display novel energy-saving environment-friendly pvc groove
Plate.
Background technology
The hardness of existing shelf display frid not, is easily worn and torn, and affects service life, and toughness is not, load-bearing
Not it is easy to rupture in use, there is certain potential safety hazard, and heat stability is not enough, leads in some high temperature rings
Cannot use in border, significantly limit to its application scenarios it would be highly desirable to improve.
Content of the invention
The technical problem being existed based on background technology, the present invention proposes a kind of shelf display novel energy-saving environment-friendly pvc
Frid, good toughness, tear-resistant, hardness is high, and heat stability is good.
A kind of shelf display proposed by the present invention novel energy-saving environment-friendly pvc frid, its raw material includes by weight: polychlorostyrene
15～28 parts of ethylene, 10～18 parts of modified polypropene, 20～40 parts of silicone rubber, 1～2 part of peroxysuccinic acid, phthalic acid
1～2 part of the hydrogen tert-butyl ester, 0.1～0.6 part of tetramethylthiuram disulfide, 0.5～1.2 part of iso-cyanuric acid triallyl ester is sliding
40～60 parts of stone powder, 5～12 parts of ceramic fibre, 10～20 parts of attapulgite, 20～40 parts of activated carbon, foaming agent 0.5～1.5
Part, 1～2 part of dimethyl phthalate, 1～2 part of stearic acid, 1～2 part of Tissuemat E, 1～2 part of epoxy soybean oil.
Preferably, modified polypropene adopts the preparation of following technique: by Egg Yolk Lecithin (PC-98T), 1，2-ethandithiol, benzophenone,
Ethanol mix homogeneously obtains prefabricated material；Polypropylene powder is placed at electric discharge in atmospheric dielectric barrier discharge plasma equipment
Reason, is then fed in prefabricated material, ultraviolet light, washing, is dried to obtain modified polypropene.
Preferably, modified polypropene adopts the preparation of following technique: by weight by 5～15 parts of Egg Yolk Lecithin (PC-98T), 1～5 part
1,2- dithioglycol, 0.1～0.8 part of benzophenone, 40～80 parts of ethanol mix homogeneously obtain prefabricated material；Polypropylene powder is placed
Discharge process in atmospheric dielectric barrier discharge plasma equipment, is then fed in prefabricated material, ultraviolet light, washing, does
Dry obtain modified polypropene.
Preferably, the discharge process concrete operations in modified polypropene preparation technology are as follows: polypropylene is placed in two electric discharges
Between electrode, adjusting distance between two sparking electrodes is 1.5cm, is passed through helium, gas flow 0.5l/min, discharge frequency during electric discharge
For 10khz, discharge power is 50w, and process time is 5s.
Preferably, the weight of polrvinyl chloride, modified polypropene, silicone rubber is than for 18～22:12～16:25～35.
Preferably, peroxysuccinic acid, the hydrogen phthalate tert-butyl ester, tetramethylthiuram disulfide, triallyl are different
The weight of cyanurate is than for 1.5～1.7:1.2～1.4:0.3～0.5:0.8～1.
Preferably, Pulvis Talci, ceramic fibre, attapulgite, activated carbon, dimethyl phthalate, stearic acid, polyethylene
Wax, the weight of epoxy soybean oil are than for 45～55:8～10:12～18:25～35:1.3～1.7:1.4～1.6:1.2～1.4:
1.6～1.8.
The present invention is obtained using conventional pvc preparation technology.
The present invention adopts polrvinyl chloride, modified polypropene, silicone rubber as major ingredient, and with peroxysuccinic acid, adjacent benzene two
The formic acid hydrogen tert-butyl ester, tetramethylthiuram disulfide, iso-cyanuric acid triallyl ester are vulcanizing system, make toughness of the present invention
Good, tear-resistant, and also heat stability is good；In the modified polypropene of the present invention, lecithin molecules chain containing unsaturated alkyl, is passing through
Polypropylene powder surface self-organization after process, the lecithin containing unsaturated long alkyl chain is carried out crosslinking by mercapto-alkene click-reaction,
Hydrophobic polypropylene powder surface formed uniformly, the lecithin layer of lasting stability, thus giving polypropylene powder excellent Combination, toughness
Preferably, thermal stability is excellent；And modified polypropene and dimethyl phthalate, stearic acid, Tissuemat E, epoxy soybean oil
Between compatibility good, with Pulvis Talci, ceramic fibre, attapulgite, activated carbon mating reaction, so that thermal stability of the present invention is torn with resistance to
Fragility can further enhance, and on the basis of ensureing toughness of the present invention, makes hardness of the present invention higher.
Specific embodiment
Below, by specific embodiment, technical scheme is described in detail.
Embodiment 1
A kind of shelf display proposed by the present invention novel energy-saving environment-friendly pvc frid, its raw material includes by weight: polychlorostyrene
15 parts of ethylene, 18 parts of modified polypropene, 20 parts of silicone rubber, 2 parts of peroxysuccinic acid, 1 part of the hydrogen phthalate tert-butyl ester, two sulfur
Change 0.6 part of tetra methylthiuram, 0.5 part of iso-cyanuric acid triallyl ester, 60 parts of Pulvis Talci, 5 parts of ceramic fibre, attapulgite
20 parts, 20 parts of activated carbon, 1.5 parts of foaming agent, 1 part of dimethyl phthalate, 2 parts of stearic acid, 1 part of Tissuemat E, epoxy is big
2 parts of Oleum Glycines.
Embodiment 2
A kind of shelf display proposed by the present invention novel energy-saving environment-friendly pvc frid, its raw material includes by weight: polychlorostyrene
28 parts of ethylene, 10 parts of modified polypropene, 40 parts of silicone rubber, 1 part of peroxysuccinic acid, 2 parts of the hydrogen phthalate tert-butyl ester, two sulfur
Change 0.1 part of tetra methylthiuram, 1.2 parts of iso-cyanuric acid triallyl ester, 40 parts of Pulvis Talci, 12 parts of ceramic fibre, attapulgite
10 parts of soil, 40 parts of activated carbon, 0.5 part of foaming agent, 2 parts of dimethyl phthalate, 1 part of stearic acid, 2 parts of Tissuemat E, epoxy
1 part of soybean oil.
Modified polypropene adopts following technique preparation: Egg Yolk Lecithin (PC-98T), 1,2- dithioglycol, benzophenone, ethanol are mixed
Close and uniformly obtain prefabricated material；Polypropylene powder is placed on discharge process in atmospheric dielectric barrier discharge plasma equipment, then
Send in prefabricated material, ultraviolet light, washing, it is dried to obtain modified polypropene.
Embodiment 3
A kind of shelf display proposed by the present invention novel energy-saving environment-friendly pvc frid, its raw material includes by weight: polychlorostyrene
18 parts of ethylene, 16 parts of modified polypropene, 25 parts of silicone rubber, 1.7 parts of peroxysuccinic acid, 1.2 parts of the hydrogen phthalate tert-butyl ester,
0.5 part of tetramethylthiuram disulfide, 0.8 part of iso-cyanuric acid triallyl ester, 55 parts of Pulvis Talci, 8 parts of ceramic fibre, concavo-convex
18 parts of rod soil, 25 parts of activated carbon, 1.2 parts of foaming agent, 1.3 parts of dimethyl phthalate, 1.6 parts of stearic acid, Tissuemat E 1.2
Part, 1.8 parts of epoxy soybean oil.
Modified polypropene adopts the preparation of following technique: by weight by 5 parts of Egg Yolk Lecithin (PC-98T), 5 parts of 1,2- dithioglycols,
80 parts of ethanol mix homogeneously of 0.1 part of benzophenone obtain prefabricated material；By polypropylene powder be placed on atmospheric dielectric barrier discharge etc. from
Discharge process in daughter equipment, is then fed in prefabricated material, ultraviolet light, washing, is dried to obtain modified polypropene.
Discharge process concrete operations in modified polypropene preparation technology are as follows: by polypropylene be placed in two sparking electrodes it
Between, adjusting distance between two sparking electrodes is 1.5cm, is passed through helium, gas flow 0.5l/min, discharge frequency is during electric discharge
10khz, discharge power is 50w, and process time is 5s.
Embodiment 4
A kind of shelf display proposed by the present invention novel energy-saving environment-friendly pvc frid, its raw material includes by weight: polychlorostyrene
22 parts of ethylene, 12 parts of modified polypropene, 35 parts of silicone rubber, 1.5 parts of peroxysuccinic acid, 1.4 parts of the hydrogen phthalate tert-butyl ester,
0.3 part of tetramethylthiuram disulfide, 1 part of iso-cyanuric acid triallyl ester, 45 parts of Pulvis Talci, 10 parts of ceramic fibre, concavo-convex
12 parts of rod soil, 35 parts of activated carbon, 1 part of foaming agent, 1.7 parts of dimethyl phthalate, 1.4 parts of stearic acid, Tissuemat E 1.4
Part, 1.6 parts of epoxy soybean oil.
Modified polypropene adopts the preparation of following technique: by weight by 15 parts of Egg Yolk Lecithin (PC-98T), 1 part of 1,2- dithioglycol,
0.8 part of benzophenone, 40 parts of ethanol mix homogeneously obtain prefabricated material；By polypropylene powder be placed on atmospheric dielectric barrier discharge etc. from
Discharge process in daughter equipment, is then fed in prefabricated material, ultraviolet light, washing, is dried to obtain modified polypropene.
Discharge process concrete operations in modified polypropene preparation technology are as follows: by polypropylene be placed in two sparking electrodes it
Between, adjusting distance between two sparking electrodes is 1.5cm, is passed through helium, gas flow 0.5l/min, discharge frequency is during electric discharge
10khz, discharge power is 50w, and process time is 5s.
Embodiment 5
A kind of shelf display proposed by the present invention novel energy-saving environment-friendly pvc frid, its raw material includes by weight: polychlorostyrene
20 parts of ethylene, 14 parts of modified polypropene, 30 parts of silicone rubber, 1.6 parts of peroxysuccinic acid, 1.3 parts of the hydrogen phthalate tert-butyl ester,
0.4 part of tetramethylthiuram disulfide, 0.9 part of iso-cyanuric acid triallyl ester, 50 parts of Pulvis Talci, 9 parts of ceramic fibre, concavo-convex
15 parts of rod soil, 30 parts of activated carbon, 1.1 parts of foaming agent, 1.5 parts of dimethyl phthalate, 1.5 parts of stearic acid, Tissuemat E 1.3
Part, 1.7 parts of epoxy soybean oil.
Modified polypropene adopts the preparation of following technique: by weight by 10 parts of Egg Yolk Lecithin (PC-98T), 3 parts of 1,2- dithioglycols,
0.5 part of benzophenone, 60 parts of ethanol mix homogeneously obtain prefabricated material；By polypropylene powder be placed on atmospheric dielectric barrier discharge etc. from
Discharge process in daughter equipment, is then fed in prefabricated material, ultraviolet light, washing, is dried to obtain modified polypropene.
Discharge process concrete operations in modified polypropene preparation technology are as follows: by polypropylene be placed in two sparking electrodes it
Between, adjusting distance between two sparking electrodes is 1.5cm, is passed through helium, gas flow 0.5l/min, discharge frequency is during electric discharge
10khz, discharge power is 50w, and process time is 5s.
The above, the only present invention preferably specific embodiment, but protection scope of the present invention is not limited thereto,
Any those familiar with the art the invention discloses technical scope in, technology according to the present invention scheme and its
Inventive concept equivalent or change in addition, all should be included within the scope of the present invention.
Claims (7)
1. a kind of shelf display novel energy-saving environment-friendly pvc frid is it is characterised in that its raw material includes by weight: polychlorostyrene second
15～28 parts of alkene, 10～18 parts of modified polypropene, 20～40 parts of silicone rubber, 1～2 part of peroxysuccinic acid, hydrogen phthalate
1～2 part of the tert-butyl ester, 0.1～0.6 part of tetramethylthiuram disulfide, 0.5～1.2 part of iso-cyanuric acid triallyl ester, Talcum
40～60 parts of powder, 5～12 parts of ceramic fibre, 10～20 parts of attapulgite, 20～40 parts of activated carbon, 0.5～1.5 part of foaming agent,
1～2 part of dimethyl phthalate, 1～2 part of stearic acid, 1～2 part of Tissuemat E, 1～2 part of epoxy soybean oil.
2. according to claim 1 shelf display novel energy-saving environment-friendly pvc frid it is characterised in that modified polypropene is adopted
With the preparation of following technique: Egg Yolk Lecithin (PC-98T), 1,2- dithioglycol, benzophenone, ethanol mix homogeneously are obtained prefabricated material；To gather
Propylene powder is placed on discharge process in atmospheric dielectric barrier discharge plasma equipment, is then fed in prefabricated material, ultraviolet lighting
Penetrate, washing, be dried to obtain modified polypropene.
3. shelf display according to claim 1 or claim 2 with novel energy-saving environment-friendly pvc frid it is characterised in that modified polypropene
Using the preparation of following technique: by weight by 5～15 parts of Egg Yolk Lecithin (PC-98T), 1～5 part of 1,2- dithioglycol, 0.1～0.8 part two
Benzophenone, 40～80 parts of ethanol mix homogeneously obtain prefabricated material；Polypropylene powder is placed on atmospheric dielectric barrier discharge plasma
Discharge process in body equipment, is then fed in prefabricated material, ultraviolet light, washing, is dried to obtain modified polypropene.
4. according to Claims 2 or 3 shelf display with novel energy-saving environment-friendly pvc frid it is characterised in that modified polypropene
Discharge process concrete operations in preparation technology are as follows: polypropylene is placed between two sparking electrodes, adjusts between two sparking electrodes
Distance is 1.5cm, is passed through helium, gas flow 0.5l/min during electric discharge, and discharge frequency is 10khz, and discharge power is 50w, place
The reason time is 5s.
5. according to any one of claim 1-4 shelf display with novel energy-saving environment-friendly pvc frid it is characterised in that polychlorostyrene
Ethylene, modified polypropene, the weight of silicone rubber are than for 18～22:12～16:25～35.
6. according to any one of claim 1-5 shelf display with novel energy-saving environment-friendly pvc frid it is characterised in that peroxide
Change succinic acid, the hydrogen phthalate tert-butyl ester, tetramethylthiuram disulfide, the weight ratio of iso-cyanuric acid triallyl ester are
1.5～1.7:1.2～1.4:0.3～0.5:0.8～1.
7. according to any one of claim 1-6 shelf display with novel energy-saving environment-friendly pvc frid it is characterised in that Talcum
Powder, ceramic fibre, attapulgite, activated carbon, dimethyl phthalate, stearic acid, Tissuemat E, the weight of epoxy soybean oil
Than for 45～55:8～10:12～18:25～35:1.3～1.7:1.4～1.6:1.2～1.4:1.6～1.8.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610736347.1A CN106366661A (en) | 2016-08-28 | 2016-08-28 | New energy-saving environment-friendly PVC (Polyvinyl Chloride) trough plate for shelf display |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610736347.1A CN106366661A (en) | 2016-08-28 | 2016-08-28 | New energy-saving environment-friendly PVC (Polyvinyl Chloride) trough plate for shelf display |
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| Publication Number | Publication Date |
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| CN106366661A true CN106366661A (en) | 2017-02-01 |
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|---|---|---|---|
| CN201610736347.1A Withdrawn CN106366661A (en) | 2016-08-28 | 2016-08-28 | New energy-saving environment-friendly PVC (Polyvinyl Chloride) trough plate for shelf display |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107964087A (en) * | 2017-12-19 | 2018-04-27 | 滁州环球聚氨酯科技有限公司 | A kind of fork truck wheel abrasion resistant polyurethane material |
| CN108164986A (en) * | 2017-12-19 | 2018-06-15 | 滁州环球聚氨酯科技有限公司 | A kind of high load-bearing abrasion resistant polyurethane fork truck wheel |
| CN109354798A (en) * | 2018-09-28 | 2019-02-19 | 安徽优丽普科技有限公司 | A kind of furred ceiling PVC foam frid |
| CN109517291A (en) * | 2018-09-28 | 2019-03-26 | 安徽优丽普科技有限公司 | A kind of flame-proof heat-resistant aging PVC foam frid |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102258947A (en) * | 2011-05-23 | 2011-11-30 | 苏州市新能膜材料科技有限公司 | Lecithin self-assembly cross-linking bionic modified polymer membrane material and preparation method thereof |
| CN103665636A (en) * | 2013-11-27 | 2014-03-26 | 江阴匡时建材有限公司 | PVC (polyvinyl chloride) plastic building template |
-
2016
- 2016-08-28 CN CN201610736347.1A patent/CN106366661A/en not_active Withdrawn
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102258947A (en) * | 2011-05-23 | 2011-11-30 | 苏州市新能膜材料科技有限公司 | Lecithin self-assembly cross-linking bionic modified polymer membrane material and preparation method thereof |
| CN103665636A (en) * | 2013-11-27 | 2014-03-26 | 江阴匡时建材有限公司 | PVC (polyvinyl chloride) plastic building template |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107964087A (en) * | 2017-12-19 | 2018-04-27 | 滁州环球聚氨酯科技有限公司 | A kind of fork truck wheel abrasion resistant polyurethane material |
| CN108164986A (en) * | 2017-12-19 | 2018-06-15 | 滁州环球聚氨酯科技有限公司 | A kind of high load-bearing abrasion resistant polyurethane fork truck wheel |
| CN109354798A (en) * | 2018-09-28 | 2019-02-19 | 安徽优丽普科技有限公司 | A kind of furred ceiling PVC foam frid |
| CN109517291A (en) * | 2018-09-28 | 2019-03-26 | 安徽优丽普科技有限公司 | A kind of flame-proof heat-resistant aging PVC foam frid |
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Application publication date: 20170201 |