CN106366517A - Badminton racket material with high bending strength - Google Patents
Badminton racket material with high bending strength Download PDFInfo
- Publication number
- CN106366517A CN106366517A CN201610766114.6A CN201610766114A CN106366517A CN 106366517 A CN106366517 A CN 106366517A CN 201610766114 A CN201610766114 A CN 201610766114A CN 106366517 A CN106366517 A CN 106366517A
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- oxide
- bending strength
- fibre
- high bending
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a badminton racket material with high bending strength. The material comprises the following materials: polychloro trifluoroethylene-Vinylidene Fluoride copolymer, carbon fiber, vinyon, Dodecyl Mercaptan, polyethylene glycol, hydroxy propyl cellulose, zirconia fiber, alumina zirconate fiber, alumina silicate fibre, Nanometer chromium trioxide, Nanometer Yttrium Oxide, Nano Zinc oxide, titanium carbide, niobium carbide, Vinyltriethoxysilane, EDTA tetrasodium salt, Benzene-1,3-disulphohydrazide, Octadecyl acrylate, Triethylene glycol isopropyl ether, Propylene glycol monomethyl ether acetate and performance additives. The badminton racket made of the material has the advantages of outstanding mechanical property, high bending strength, feather weight and endurability. The handle bar has good air permeation and anti-slippery features.
Description
Technical field
The present invention relates to a kind of racket high bending strength material, belong to Material Field.
Background technology
Racket is typically made up of the joint of racket head, dabber, handle and frame and dabber.Send out with scientific and technical
Exhibition, the development of racket towards weight increasingly lighter, frame is increasingly harder, dabber elasticity is become better and better, air drag is less and less
Direction develop.
Before the seventies, racket using timber and steel pipe manufacture, has begun with aluminium alloy substantially the seventies, with
Afterwards, start to use new material in a large number, such as carbon fiber, titanium alloy, high-strength carbon fiber etc..These new materials are lighter, higher, more resistant to
With absorbing more vibrations and concussion, allowing racket manufacturer have in the hardness of racket, the feel of the ball, the design of batting performance simultaneously
Bigger performance space.
Content of the invention
The invention reside in providing a kind of racket high bending strength material, this material makes exclusively for racket development
With.There is good mechanical performance simultaneously using the racket that this material is obtained, also there is high bending strength.
The solution of the present invention is as follows: racket high bending strength material, is obtained by following raw material:
Polychlorotrifluoroethylene-vinylidene fluoride copolymers 25-35 part, carbon fiber 75-100 part, vinyon 15-19 part, 12 sulfur
Alcohol 3-8 part, Polyethylene Glycol 3-8 part, hydroxypropyl cellulose 2-10 part, Zirconium oxide fibre 2-4 part, zirconic acid aluminum fiber 0.5-2 part, silicon
Sour aluminum fiber 0.5-2 part, Nanoscale Chromic Oxides 4-10 part, nano yttrium oxide 5-10 part, nano zine oxide 4-9 part, titanium carbide
2-5 part, niobium carbide 2-5 part, VTES 5-10 part, tetrasodium salt of EDTA 7-15 part, 1,3- benzene two
Sulfohydrazide 4-10 part, octadecyl acrylate 6-12 part, triethylene glycol one diisopropyl ether 4-8 part, propylene glycol methyl ether acetate 5-10
Part, modified additive 2-6 part；
Described modified additive is obtained by following methods:
By titanium dioxide 1-3g, Graphene 2-5g, positive octadecanol 5-8g, acetylbutyrylcellulose 0.4-0.8g, perfluoro butyl sulphur
Sour potassium 0.2-0.5 g, fatty alcohol-polyoxyethylene ether 1-4 g, dibutyl tin laurate 1-3 g, glycerin mono-fatty acid ester 2-6g,
γ-urea propyl-triethoxysilicane 2-5g, 5-sulphosalicylic acid two water 0.6-0.9g, sodium chromate 0.1-0.35g, barium stannate
0.21-0.45g, chromium carbide 0.12-0.33g, acetic acid amylene ester 0.6-1.8g uniformly mix closes；
Described Zirconium oxide fibre, zirconic acid aluminum fiber, alumina silicate fibre weight are than for 1:0.6:0.5.
Further, it is obtained by following raw material: 30 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, carbon fiber 86
Part, 17 parts of vinyon, 4 parts of lauryl mercaptan, 6 parts of Polyethylene Glycol, 6 parts of hydroxypropyl cellulose, 2.4 parts of Zirconium oxide fibre, zirconic acid
1.44 parts of aluminum fiber, 1.2 parts of alumina silicate fibre, 5 parts of Nanoscale Chromic Oxides, 8 parts of nano yttrium oxide, 5 parts of nano zine oxide, carbon
Change 3 parts of titanium, 4 parts of niobium carbide, 9 parts of VTES, 11 parts of tetrasodium salt of EDTA, 1,3- benzene disulfohydrazide
6 parts, 8 parts of octadecyl acrylate, 5 parts of triethylene glycol one diisopropyl ether, 7 parts of propylene glycol methyl ether acetate, 5 parts of modified additive.
Further, it is obtained by following raw material: 33 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, carbon fiber 90
Part, 18 parts of vinyon, 6 parts of lauryl mercaptan, 5 parts of Polyethylene Glycol, 6 parts of hydroxypropyl cellulose, 3 parts of Zirconium oxide fibre, zirconic acid aluminum
1.8 parts of fiber, 1.5 parts of alumina silicate fibre, 7 parts of Nanoscale Chromic Oxides, 5 parts of nano yttrium oxide, 4 parts of nano zine oxide, carbonization
5 parts of titanium, 3 parts of niobium carbide, 8 parts of VTES, 9 parts of tetrasodium salt of EDTA, 1,3- benzene disulfohydrazide 6
Part, 8 parts of octadecyl acrylate, 6 parts of triethylene glycol one diisopropyl ether, 9 parts of propylene glycol methyl ether acetate, 4 parts of modified additive.
Further, it is obtained by following raw material: 25 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, carbon fiber 85
Part, 17 parts of vinyon, 7 parts of lauryl mercaptan, 3 parts of Polyethylene Glycol, 8 parts of hydroxypropyl cellulose, 1.8 parts of Zirconium oxide fibre, zirconic acid
1.08 parts of aluminum fiber, 0.9 part of alumina silicate fibre, 6 parts of Nanoscale Chromic Oxides, 8 parts of nano yttrium oxide, 8 parts of nano zine oxide, carbon
Change 3 parts of titanium, 4 parts of niobium carbide, 6 parts of VTES, 12 parts of tetrasodium salt of EDTA, 1,3- benzene disulfohydrazide
8 parts, 7 parts of octadecyl acrylate, 5 parts of triethylene glycol one diisopropyl ether, 5 parts of propylene glycol methyl ether acetate, 3 parts of modified additive.
The racket that material of the present invention is obtained has the advantages that good mechanical performance and has high bending strength, gently
Just, durable, and at handle ventilative be difficult wet and slippery.
By increasing Zirconium oxide fibre, zirconic acid aluminum fiber, aluminium silicate fiber and modified additive cooperation, greatly enhance material
Bending strength, improve pliability so that racket user swing laborsaving, easily hold direction.
Specific embodiment
With reference to embodiment, the present invention will be further described.
The preparation of modified additive:
By titanium dioxide 2g, Graphene 3g, positive octadecanol 6g, acetylbutyrylcellulose 0.56g, perfluorobutyl potassium sulfonate 0.33g,
Fatty alcohol-polyoxyethylene ether 2g, dibutyl tin laurate 2.5g, glycerin mono-fatty acid ester 4g, γ-urea propyl-triethoxysilicane
3g, 5-sulphosalicylic acid two water 0.8g, sodium chromate 0.27g, barium stannate 0.34g, chromium carbide 0.21g, acetic acid amylene ester 0.9g are equal
Even mix.
Embodiment 1
Racket high bending strength material, is obtained by following raw material:
30 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, 86 parts of carbon fiber, 17 parts of vinyon, 4 parts of lauryl mercaptan, poly- second
6 parts of glycol, 6 parts of hydroxypropyl cellulose, 2.4 parts of Zirconium oxide fibre, 1.44 parts of zirconic acid aluminum fiber, alumina silicate fibre 1.2 part, nanometer
5 parts of chromic oxide, 8 parts of nano yttrium oxide, 5 parts of nano zine oxide, 3 parts of titanium carbide, 4 parts of niobium carbide, vinyl triethoxyl
9 parts of silane, 11 parts of tetrasodium salt of EDTA, 6 parts of 1,3- benzene disulfohydrazide, 8 parts of octadecyl acrylate, triethylene glycol one are different
5 parts of propyl ether, 7 parts of propylene glycol methyl ether acetate, 5 parts of modified additive.
Routinely production method is obtained this material, and each raw material is uniformly mixed, and is then fed into the melting of extruder high temperature
Extruding pelletization, obtains racket high bending strength material material grain.
Embodiment 2
Racket high bending strength material, is obtained by following raw material:
33 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, 90 parts of carbon fiber, 18 parts of vinyon, 6 parts of lauryl mercaptan, poly- second
5 parts of glycol, 6 parts of hydroxypropyl cellulose, 3 parts of Zirconium oxide fibre, 1.8 parts of zirconic acid aluminum fiber, alumina silicate fibre 1.5 part, nanometer three
Aoxidize 7 parts of two chromium, 5 parts of nano yttrium oxide, 4 parts of nano zine oxide, 5 parts of titanium carbide, 3 parts of niobium carbide, vinyl triethoxyl silicon
8 parts of alkane, 9 parts of tetrasodium salt of EDTA, 6 parts of 1,3- benzene disulfohydrazide, 8 parts of octadecyl acrylate, triethylene glycol one isopropyl
6 parts of ether, 9 parts of propylene glycol methyl ether acetate, 4 parts of modified additive.
Routinely production method is obtained, with embodiment 1 this material.
Embodiment 3
Racket high bending strength material, is obtained by following raw material:
25 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, 85 parts of carbon fiber, 17 parts of vinyon, 7 parts of lauryl mercaptan, poly- second
3 parts of glycol, 8 parts of hydroxypropyl cellulose, 1.8 parts of Zirconium oxide fibre, 1.08 parts of zirconic acid aluminum fiber, alumina silicate fibre 0.9 part, nanometer
6 parts of chromic oxide, 8 parts of nano yttrium oxide, 8 parts of nano zine oxide, 3 parts of titanium carbide, 4 parts of niobium carbide, vinyl triethoxyl
6 parts of silane, 12 parts of tetrasodium salt of EDTA, 8 parts of 1,3- benzene disulfohydrazide, 7 parts of octadecyl acrylate, triethylene glycol one are different
5 parts of propyl ether, 5 parts of propylene glycol methyl ether acetate, 3 parts of modified additive.
Routinely production method is obtained, with embodiment 1 this material.
Comparative example 1
It is with embodiment 1 difference, without Zirconium oxide fibre, zirconic acid aluminum fiber, alumina silicate fibre.
Comparative example 2
It is with embodiment 1 difference, without modified additive.
Comparative example 3
It is with embodiment 1 difference, without Zirconium oxide fibre, zirconic acid aluminum fiber, aluminium silicate fiber peacekeeping modified additive.
Performance test is carried out to the carbon fibre composite of above-described embodiment 1-3, the racket of comparative example 1-3 gained,
Result is as shown in the table.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 | Common racket | |
| Tensile strength (mpa) | 561 | 548 | 530 | 468 | 472 | 420 | 250-350 |
| Bending strength (mpa) | 653 | 640 | 642 | 522 | 502 | 480 | 260-380 |
| Heat distortion temperature (DEG C) | 382 | 386 | 388 | 320 | 341 | 303 | 200-250 |
| Wet and slippery rate (%) after motion 4h | 1 | 1 | 1 | 3 | 3 | 4 | 6-10 |
Although above the specific embodiment of the present invention being given with detailed description and illustrating, it should be noted that
We can carry out various equivalent changes according to the conception of the present invention and change to above-mentioned embodiment, and function produced by it is made
With still without departing from description covered spiritual when, all should be within protection scope of the present invention.
Claims (4)
1. racket high bending strength material is it is characterised in that be obtained by following raw material:
Polychlorotrifluoroethylene-vinylidene fluoride copolymers 25-35 part, carbon fiber 75-100 part, vinyon 15-19 part, 12 sulfur
Alcohol 3-8 part, Polyethylene Glycol 3-8 part, hydroxypropyl cellulose 2-10 part, Zirconium oxide fibre 2-4 part, zirconic acid aluminum fiber 0.5-2 part, silicon
Sour aluminum fiber 0.5-2 part, Nanoscale Chromic Oxides 4-10 part, nano yttrium oxide 5-10 part, nano zine oxide 4-9 part, titanium carbide
2-5 part, niobium carbide 2-5 part, VTES 5-10 part, tetrasodium salt of EDTA 7-15 part, 1,3- benzene two
Sulfohydrazide 4-10 part, octadecyl acrylate 6-12 part, triethylene glycol one diisopropyl ether 4-8 part, propylene glycol methyl ether acetate 5-10
Part, modified additive 2-6 part；
Described modified additive is obtained by following methods:
By titanium dioxide 1-3g, Graphene 2-5g, positive octadecanol 5-8g, acetylbutyrylcellulose 0.4-0.8g, perfluoro butyl sulphur
Sour potassium 0.2-0.5 g, fatty alcohol-polyoxyethylene ether 1-4 g, dibutyl tin laurate 1-3 g, glycerin mono-fatty acid ester 2-6g,
γ-urea propyl-triethoxysilicane 2-5g, 5-sulphosalicylic acid two water 0.6-0.9g, sodium chromate 0.1-0.35g, barium stannate
0.21-0.45g, chromium carbide 0.12-0.33g, acetic acid amylene ester 0.6-1.8g uniformly mix closes；
Described Zirconium oxide fibre, zirconic acid aluminum fiber, alumina silicate fibre weight are than for 1:0.6:0.5.
2. racket according to claim 1 with high bending strength material it is characterised in that by following raw material
It is obtained:
30 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, 86 parts of carbon fiber, 17 parts of vinyon, 4 parts of lauryl mercaptan, poly- second
6 parts of glycol, 6 parts of hydroxypropyl cellulose, 2.4 parts of Zirconium oxide fibre, 1.44 parts of zirconic acid aluminum fiber, alumina silicate fibre 1.2 part, nanometer
5 parts of chromic oxide, 8 parts of nano yttrium oxide, 5 parts of nano zine oxide, 3 parts of titanium carbide, 4 parts of niobium carbide, vinyl triethoxyl
9 parts of silane, 11 parts of tetrasodium salt of EDTA, 6 parts of 1,3- benzene disulfohydrazide, 8 parts of octadecyl acrylate, triethylene glycol one are different
5 parts of propyl ether, 7 parts of propylene glycol methyl ether acetate, 5 parts of modified additive.
3. racket according to claim 1 with high bending strength material it is characterised in that by following raw material
It is obtained:
33 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, 90 parts of carbon fiber, 18 parts of vinyon, 6 parts of lauryl mercaptan, poly- second
5 parts of glycol, 6 parts of hydroxypropyl cellulose, 3 parts of Zirconium oxide fibre, 1.8 parts of zirconic acid aluminum fiber, alumina silicate fibre 1.5 part, nanometer three
Aoxidize 7 parts of two chromium, 5 parts of nano yttrium oxide, 4 parts of nano zine oxide, 5 parts of titanium carbide, 3 parts of niobium carbide, vinyl triethoxyl silicon
8 parts of alkane, 9 parts of tetrasodium salt of EDTA, 6 parts of 1,3- benzene disulfohydrazide, 8 parts of octadecyl acrylate, triethylene glycol one isopropyl
6 parts of ether, 9 parts of propylene glycol methyl ether acetate, 4 parts of modified additive.
4. racket according to claim 1 with high bending strength material it is characterised in that by following raw material
It is obtained:
25 parts of polychlorotrifluoroethylene-vinylidene fluoride copolymers, 85 parts of carbon fiber, 17 parts of vinyon, 7 parts of lauryl mercaptan, poly- second
3 parts of glycol, 8 parts of hydroxypropyl cellulose, 1.8 parts of Zirconium oxide fibre, 1.08 parts of zirconic acid aluminum fiber, alumina silicate fibre 0.9 part, nanometer
6 parts of chromic oxide, 8 parts of nano yttrium oxide, 8 parts of nano zine oxide, 3 parts of titanium carbide, 4 parts of niobium carbide, vinyl triethoxyl
6 parts of silane, 12 parts of tetrasodium salt of EDTA, 8 parts of 1,3- benzene disulfohydrazide, 7 parts of octadecyl acrylate, triethylene glycol one are different
5 parts of propyl ether, 5 parts of propylene glycol methyl ether acetate, 3 parts of modified additive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610766114.6A CN106366517A (en) | 2016-08-30 | 2016-08-30 | Badminton racket material with high bending strength |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610766114.6A CN106366517A (en) | 2016-08-30 | 2016-08-30 | Badminton racket material with high bending strength |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106366517A true CN106366517A (en) | 2017-02-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610766114.6A Pending CN106366517A (en) | 2016-08-30 | 2016-08-30 | Badminton racket material with high bending strength |
Country Status (1)
| Country | Link |
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| CN (1) | CN106366517A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110511537A (en) * | 2019-07-22 | 2019-11-29 | 石狮市鸿兴文体器材有限公司 | A kind of racket and its manufacture craft |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183932A (en) * | 2011-12-29 | 2013-07-03 | 邓禄普体育用品株式会社 | Tubular body made of fiber-reinforced epoxy resin material |
| CN103272374A (en) * | 2013-06-07 | 2013-09-04 | 南京胜利体育用品实业有限公司 | Method for manufacturing badminton racket |
| CN103706089A (en) * | 2014-01-09 | 2014-04-09 | 宿迁傲达康复合材料有限公司 | Badminton racket and manufacturing method thereof |
| CN105039822A (en) * | 2015-07-27 | 2015-11-11 | 苏州天健竹业科技有限公司 | Composite material for badminton racket and preparation method thereof |
-
2016
- 2016-08-30 CN CN201610766114.6A patent/CN106366517A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183932A (en) * | 2011-12-29 | 2013-07-03 | 邓禄普体育用品株式会社 | Tubular body made of fiber-reinforced epoxy resin material |
| CN103272374A (en) * | 2013-06-07 | 2013-09-04 | 南京胜利体育用品实业有限公司 | Method for manufacturing badminton racket |
| CN103706089A (en) * | 2014-01-09 | 2014-04-09 | 宿迁傲达康复合材料有限公司 | Badminton racket and manufacturing method thereof |
| CN105039822A (en) * | 2015-07-27 | 2015-11-11 | 苏州天健竹业科技有限公司 | Composite material for badminton racket and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 卓昌明，等: "《塑料应用技术手册》", 31 May 2013, 机械工业出版社 * |
| 温变英，等: "《高分子材料加工》", 30 June 2016, 中国轻工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110511537A (en) * | 2019-07-22 | 2019-11-29 | 石狮市鸿兴文体器材有限公司 | A kind of racket and its manufacture craft |
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Application publication date: 20170201 |