CN105039822A - Composite material for badminton racket and preparation method thereof - Google Patents
Composite material for badminton racket and preparation method thereof Download PDFInfo
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- CN105039822A CN105039822A CN201510446004.7A CN201510446004A CN105039822A CN 105039822 A CN105039822 A CN 105039822A CN 201510446004 A CN201510446004 A CN 201510446004A CN 105039822 A CN105039822 A CN 105039822A
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- parts
- racket
- matrix material
- preparation
- zinc oxide
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- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000002131 composite material Substances 0.000 title abstract description 8
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 34
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 18
- 239000011787 zinc oxide Substances 0.000 claims abstract description 17
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 14
- 239000004917 carbon fiber Substances 0.000 claims abstract description 14
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000835 fiber Substances 0.000 claims abstract description 13
- 229910052582 BN Inorganic materials 0.000 claims abstract description 10
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 10
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 10
- 241001330002 Bambuseae Species 0.000 claims abstract description 10
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims abstract description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 10
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 10
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 10
- 239000011425 bamboo Substances 0.000 claims abstract description 10
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 10
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 10
- 239000010941 cobalt Substances 0.000 claims abstract description 10
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 10
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052802 copper Inorganic materials 0.000 claims abstract description 10
- 239000010949 copper Substances 0.000 claims abstract description 10
- 239000003822 epoxy resin Substances 0.000 claims abstract description 10
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 10
- 239000011733 molybdenum Substances 0.000 claims abstract description 10
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 10
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 10
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 10
- 239000010703 silicon Substances 0.000 claims abstract description 10
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 10
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000011159 matrix material Substances 0.000 claims description 30
- -1 3 parts Chemical compound 0.000 claims description 14
- 238000001816 cooling Methods 0.000 claims description 14
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000012299 nitrogen atmosphere Substances 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- 229910052748 manganese Inorganic materials 0.000 claims description 2
- 239000011572 manganese Substances 0.000 claims description 2
- 238000005245 sintering Methods 0.000 claims description 2
- 238000009776 industrial production Methods 0.000 abstract description 2
- 238000011161 development Methods 0.000 description 3
- 238000011056 performance test Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920000433 Lyocell Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000007770 graphite material Substances 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention belongs to the technical field of sports equipment, and particularly relates to a composite material for a badminton racket and a preparation method thereof. The composite material for the badminton racket comprises the following raw materials in parts by weight: 20-22 parts of cobalt, 5-12 parts of carbon fiber, 1-4 parts of epoxy resin, 1-3 parts of bamboo fiber, 3-6 parts of nickel, 1-2 parts of copper, 1-2 parts of silicon, 2-4 parts of molybdenum, 0.5-1 part of manganese, 1-3 parts of zinc oxide, 1-5 parts of silicon carbide, 1-2 parts of calcium fluoride and 1-4 parts of boron nitride. The composite material has high strength and good toughness, and the badminton racket made of the composite material is portable and durable, and the handle is breathable and is not easy to wet and slide; the preparation method is simple and convenient and is suitable for industrial production.
Description
Technical field
The invention belongs to technical field of sports apparatus, be specifically related to the matrix material and preparation method thereof for racket.
Background technology
Along with the raising of people's living standard, sport and body-building also becomes more and more concerned, and wherein shuttlecock is exactly instantly very popular motion.Shuttlecock is the motion that indoor, an outdoor are taken into account, and can be divided into singles and doubles according to the number participated in.Badminton requires also not bery high to the physique of player, be but relatively particular about endurance, and extremely suitable racket is generally made up of the joint of racket head, dabber, handle and frame and dabber.The length of a racket is no more than 68 centimetres, and wherein racket handle and ball rapping bar length are no more than 41 centimetres, and frame length is 28 centimetres, and wide is 23 centimetres.Along with the development of science and technology, the future development that the development of racket is more and more lighter towards weight, frame is more and more harder, dabber elasticity is become better and better.
Carbon fiber (carbonfiber is called for short CF) is the tencel material of the high strength of a kind of carbon content more than 95%, high modulus fibre.It to be piled up along fiber axial direction due by organic fibres such as flake graphite crystallites to form, the micro crystal graphite material obtained through carbonization and graphitization processing.Carbon fiber " soft outside but hard inside ", quality is lighter than metallic aluminium, but intensity is higher than iron and steel, and has characteristic that is corrosion-resistant, high-modulus, defence and military and civilian in be all important materials.It not only has the intrinsic intrinsic property of carbon material, has both again the soft workability of textile fibres, is fortifying fibre of new generation.
The present invention studies the matrix material of preparation containing carbon fiber for racket, to meet the requirement of people's sport and body-building.
Summary of the invention
The object of the invention is to provide a kind of matrix material for racket and preparation method thereof, this composite material strength is high, good toughness, utilize its obtained racket light, durable, and handle place is ventilative not easily wet and slippery.
The technical solution used in the present invention is as follows:
For the matrix material of racket, comprise the following raw material according to mass fraction meter: cobalt 20-22 part, carbon fiber 5-12 part, epoxy resin 1-4 part, bamboo fibers 1-3 part, nickel 3-6 part, copper 1-2 part, silicon 1-2 part, molybdenum 2-4 part, manganese 0.5-1 part, zinc oxide 1-3 part, silicon carbide 1-5 part, Calcium Fluoride (Fluorspan) 1-2 part, boron nitride 1-4 part.
The above-described matrix material for racket, comprises the following raw material according to mass fraction meter: cobalt 21 parts, 8.5 parts, carbon fiber, epoxy resin 2.5 parts, bamboo fibers 2 parts, 4.5 parts, nickel, copper 1.5 parts, silicon 1.6 parts, molybdenum 3 parts, 0.7 part, manganese, 2 parts, zinc oxide, 3 parts, silicon carbide, 1.5 parts, Calcium Fluoride (Fluorspan), boron nitride 2.5 parts.
Further, described zinc oxide particle diameter is less than 80nm.
The preparation method of the above-described matrix material for racket, comprise the steps: according to quality proportioning, each raw material to be mixed, suppress under 300-500MPa, after in nitrogen atmosphere, at 1200-1320 DEG C, sinter 20-40min, be cooled to 400-500 DEG C, keep 1-2h, rear continuation cooling, to naturally cooling, obtains the described matrix material for racket.
Further, described compacting pressure is 400MPa.
Further, described sintering temperature is 1240-1280 DEG C.
Beneficial effect of the present invention is: composite material strength of the present invention is high, good toughness, utilize its obtained racket light, durable, and handle place is ventilative not easily wet and slippery; Preparation method of the present invention is easy, is suitable for industrial production.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, the raw material used in the present invention unless otherwise noted, all by commercial acquisition.
Embodiment 1
For the matrix material of racket, comprise the following raw material according to mass fraction meter: cobalt 20 parts, 5 parts, carbon fiber, epoxy resin 1 part, bamboo fibers 1 part, 3 parts, nickel, copper 1 part, silicon 1 part, molybdenum 2 parts, 0.5 part, manganese, 1 part, zinc oxide, 1 part, silicon carbide, 1 part, Calcium Fluoride (Fluorspan), boron nitride 1 part, wherein said zinc oxide particle diameter is less than 80nm.
The preparation method of the matrix material for racket of the present embodiment, comprise the steps: according to quality proportioning, each raw material to be mixed, suppress under 300MPa, after in nitrogen atmosphere, at 1200 DEG C, sinter 20-40min, be cooled to 400-500 DEG C, keep 1-2h, rear continuation cooling, to naturally cooling, obtains the described matrix material for racket.
Embodiment 2
For the matrix material of racket, comprise the following raw material according to mass fraction meter: cobalt 20 parts, 7 parts, carbon fiber, epoxy resin 1.2 parts, bamboo fibers 1.5 parts, 4 parts, nickel, copper 1.2 parts, silicon 1.3 parts, molybdenum 2.5 parts, 0.6 part, manganese, 1.4 parts, zinc oxide, 2 parts, silicon carbide, 1.2 parts, Calcium Fluoride (Fluorspan), boron nitride 2 parts, wherein said zinc oxide particle diameter is less than 80nm.
The preparation method of the matrix material for racket of the present embodiment, comprise the steps: according to quality proportioning, each raw material to be mixed, suppress under 350MPa, after in nitrogen atmosphere, at 1240 DEG C, sinter 20-40min, be cooled to 400-500 DEG C, keep 1-2h, rear continuation cooling, to naturally cooling, obtains the described matrix material for racket.
Embodiment 3
For the matrix material of racket, comprise the following raw material according to mass fraction meter: cobalt 21 parts, 8.5 parts, carbon fiber, epoxy resin 2.5 parts, bamboo fibers 2 parts, 4.5 parts, nickel, copper 1.5 parts, silicon 1.6 parts, molybdenum 3 parts, 0.7 part, manganese, 2 parts, zinc oxide, 3 parts, silicon carbide, 1.5 parts, Calcium Fluoride (Fluorspan), boron nitride 2.5 parts, wherein said zinc oxide particle diameter is less than 80nm.
The preparation method of the matrix material for racket of the present embodiment, comprise the steps: according to quality proportioning, each raw material to be mixed, suppress under 400MPa, after in nitrogen atmosphere, at 1260 DEG C, sinter 20-40min, be cooled to 400-500 DEG C, keep 1-2h, rear continuation cooling, to naturally cooling, obtains the described matrix material for racket.
Embodiment 4
For the matrix material of racket, comprise the following raw material according to mass fraction meter: cobalt 21 parts, 10 parts, carbon fiber, epoxy resin 3 parts, bamboo fibers 2 parts, 5 parts, nickel, copper 2 parts, silicon 2 parts, molybdenum 3 parts, 0.8 part, manganese, 2.4 parts, zinc oxide, 4 parts, silicon carbide, 1.8 parts, Calcium Fluoride (Fluorspan), boron nitride 3 parts, wherein said zinc oxide particle diameter is less than 80nm.
The preparation method of the matrix material for racket of the present embodiment, comprise the steps: according to quality proportioning, each raw material to be mixed, suppress under 450MPa, after in nitrogen atmosphere, at 1280 DEG C, sinter 20-40min, be cooled to 400-500 DEG C, keep 1-2h, rear continuation cooling, to naturally cooling, obtains the described matrix material for racket.
Embodiment 5
For the matrix material of racket, comprise the following raw material according to mass fraction meter: cobalt 22 parts, 12 parts, carbon fiber, epoxy resin 4 parts, bamboo fibers 3 parts, 6 parts, nickel, copper 2 parts, silicon 2 parts, molybdenum 4 parts, 1 part, manganese, 3 parts, zinc oxide, 5 parts, silicon carbide, 2 parts, Calcium Fluoride (Fluorspan), boron nitride 4 parts, wherein said zinc oxide particle diameter is less than 80nm.
The preparation method of the matrix material for racket of the present embodiment, comprise the steps: according to quality proportioning, each raw material to be mixed, suppress under 500MPa, after in nitrogen atmosphere, at 1320 DEG C, sinter 20-40min, be cooled to 400-500 DEG C, keep 1-2h, rear continuation cooling, to naturally cooling, obtains the described matrix material for racket.
Performance test
Carry out performance test to embodiment of the present invention 1-5 products obtained therefrom, result is as following table:
Table 1 product performance test data
| Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Commercially available common racket |
| Wear-resisting amount, mg/1000 time | 0.5 | 0.4 | 0.3 | 0.4 | 0.4 | 1.0 |
| Tensile strength, MPa | 705 | 712 | 720 | 710 | 706 | 450 |
| Tension set, % | 43 | 46 | 49 | 48 | 44 | 20 |
| Obtained racket quality | 3U-4U | 3U-4U | 3U-4U | 3U-4U | 3U-4U | U-2U |
| Wet and slippery rate after motion 4h, % | 2％ | 2％ | 1％ | 1％ | 2％ | 6％ |
As seen from the above table, composite material strength of the present invention is high, good toughness, utilize its obtained racket light, durable, and handle place is ventilative not easily wet and slippery, wherein embodiment 3 best results.
Claims (6)
1. for the matrix material of racket, it is characterized in that, comprise the following raw material according to mass fraction meter: cobalt 20-22 part, carbon fiber 5-12 part, epoxy resin 1-4 part, bamboo fibers 1-3 part, nickel 3-6 part, copper 1-2 part, silicon 1-2 part, molybdenum 2-4 part, manganese 0.5-1 part, zinc oxide 1-3 part, silicon carbide 1-5 part, Calcium Fluoride (Fluorspan) 1-2 part, boron nitride 1-4 part.
2. the matrix material for racket according to claim 1, it is characterized in that, comprise the following raw material according to mass fraction meter: cobalt 21 parts, 8.5 parts, carbon fiber, epoxy resin 2.5 parts, bamboo fibers 2 parts, 4.5 parts, nickel, copper 1.5 parts, silicon 1.6 parts, molybdenum 3 parts, 0.7 part, manganese, 2 parts, zinc oxide, 3 parts, silicon carbide, 1.5 parts, Calcium Fluoride (Fluorspan), boron nitride 2.5 parts.
3. the matrix material for racket according to claim 1 and 2, is characterized in that, described zinc oxide particle diameter is less than 80nm.
4. the preparation method of the matrix material for racket according to claim 1, it is characterized in that, comprise the steps: according to quality proportioning, each raw material to be mixed, suppress under 300-500MPa, after in nitrogen atmosphere, 20-40min is sintered at 1200-1320 DEG C, be cooled to 400-500 DEG C, keep 1-2h, rear continuation cooling, to naturally cooling, obtain the described matrix material for racket.
5. the preparation method of the matrix material for racket according to claim 4, is characterized in that, described compacting pressure is 400MPa.
6. the preparation method of the matrix material for racket according to claim 4, is characterized in that, described sintering temperature is 1240-1280 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510446004.7A CN105039822B (en) | 2015-07-27 | 2015-07-27 | Composite material for badminton racket and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510446004.7A CN105039822B (en) | 2015-07-27 | 2015-07-27 | Composite material for badminton racket and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN105039822A true CN105039822A (en) | 2015-11-11 |
| CN105039822B CN105039822B (en) | 2017-06-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201510446004.7A Active CN105039822B (en) | 2015-07-27 | 2015-07-27 | Composite material for badminton racket and preparation method thereof |
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| Country | Link |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105774180A (en) * | 2016-03-01 | 2016-07-20 | 苏州莱特复合材料有限公司 | Carbon fiber composite for golf clubs and preparation method of carbon fiber composition |
| CN106366526A (en) * | 2016-08-30 | 2017-02-01 | 安徽翰文运动用品股份有限公司 | Carbon fiber composite material for badminton rackets |
| CN106366517A (en) * | 2016-08-30 | 2017-02-01 | 安徽翰文运动用品股份有限公司 | Badminton racket material with high bending strength |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101563487A (en) * | 2006-12-21 | 2009-10-21 | 昭和电工株式会社 | Carbon fiber and catalyst for carbon fiber production |
| US20110241057A1 (en) * | 2008-03-04 | 2011-10-06 | Chien-Fu Shen | High-efficiency light-emitting device and manufacturing method thereof |
| CN102574362A (en) * | 2009-06-02 | 2012-07-11 | 英特格兰科技公司 | Metal-clad polymer article |
-
2015
- 2015-07-27 CN CN201510446004.7A patent/CN105039822B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101563487A (en) * | 2006-12-21 | 2009-10-21 | 昭和电工株式会社 | Carbon fiber and catalyst for carbon fiber production |
| US20110241057A1 (en) * | 2008-03-04 | 2011-10-06 | Chien-Fu Shen | High-efficiency light-emitting device and manufacturing method thereof |
| CN102574362A (en) * | 2009-06-02 | 2012-07-11 | 英特格兰科技公司 | Metal-clad polymer article |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105774180A (en) * | 2016-03-01 | 2016-07-20 | 苏州莱特复合材料有限公司 | Carbon fiber composite for golf clubs and preparation method of carbon fiber composition |
| CN106366526A (en) * | 2016-08-30 | 2017-02-01 | 安徽翰文运动用品股份有限公司 | Carbon fiber composite material for badminton rackets |
| CN106366517A (en) * | 2016-08-30 | 2017-02-01 | 安徽翰文运动用品股份有限公司 | Badminton racket material with high bending strength |
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| Publication number | Publication date |
|---|---|
| CN105039822B (en) | 2017-06-13 |
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