CN105037653A - Titanium reinforced carbon fiber composite material for badminton racket, and preparation method for titanium reinforced carbon fiber composite material - Google Patents
Titanium reinforced carbon fiber composite material for badminton racket, and preparation method for titanium reinforced carbon fiber composite material Download PDFInfo
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- CN105037653A CN105037653A CN201510455348.4A CN201510455348A CN105037653A CN 105037653 A CN105037653 A CN 105037653A CN 201510455348 A CN201510455348 A CN 201510455348A CN 105037653 A CN105037653 A CN 105037653A
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Abstract
The invention discloses a titanium reinforced carbon fiber composite material for a badminton racket. The titanium reinforced carbon fiber composite material comprises the following components in parts by weight: 30-40 parts of carbon fiber, 10-20 parts of polyacrylonitrile-based carbon fiber, 4-8 parts of nanometer titanium dioxide, 5-8 parts of acrylate resin, 3-8 parts of perchloroethylene resin, 3-6 parts of ethyl cellulose, 10-18 parts of polyamide fiber, 5-8 parts of acrylonitrile, 1.6-2.4 parts of nanometer aluminium oxide, 0.8-1.6 parts of tri-hydroxyethylmethyl ammnium methosulfate, 1-3 parts of a foaming agent, 2-5 parts of a coupling agent and 0.5-1.3 parts of a stabilizing agent. The titanium reinforced carbon fiber composite material adopts carbon fiber as a main body, and titanium dioxide and resin materials are added, so that not only is excellent property maintained, but also the cost of the composite material is reduced; the composite material is light in weight, high in rigidity and elasticity, and low in cost, and can be popularized and used.
Description
Technical field
The invention belongs to sports equipment technical field of composite materials, be specifically related to a kind of titanium metal enhanced carbon fiber racket matrix material and preparation method thereof.
Background technology
Carbon fiber is the inorganic polymer filamentary material that carbon content is very high, it " soft outside but hard inside ", quality is lighter than metallic aluminium, and intensity is higher than iron and steel.It has four kinds of product forms: fiber, cloth, prepreg and chopped fibres.Cloth refers to the fabric be made up of carbon fiber; Prepreg is unanimously arranged according to a direction by carbon fiber, and make it change into sheet through resin impregnation on carbon fiber or cloth; Chopped fibres refers to short silk.According to different proportionings, these products are applied and will be formed carbon fibre reinforced composite together with resin.Current, be used for manufacturing the novel material mainly matrix material of athletic sports appliance, and carbon-fibre composite is outstanding person wherein.From certain meaning, modern competitive sport is a motion to human physical extremes challenge, and the raising that any project world record is small often needs and relies on the promotion of science and technology.Utilize novel material to promote the performance of sport equipment, thus the case improving sports achievement is of common occurrence.Carbon-fibre composite is used for sports equipment and has the advantages such as quality is light, high specific strength, high ratio modulus, fatigue strength are large, thermal expansivity is little, fail safety performance is good.
Shuttlecock is national physical training first chosen sport, along with the development of society, growth in the living standard, the people more and more recognize importance that is healthy and motion, shuttlecock fan is more and more fastidious to the science of equipment, reasonableness, continuous demand high-performance, diversified racket.Exactly because these demands, badminton needs to introduce novel material, new technology, novel process.Before the seventies, the material of racket is almost the world of timber and steel pipe entirely, now that the world of novel material is as carbon fiber, titanium alloy, high-strength carbon fiber etc. completely, therefore these materials gentlier, more by force, more durable, also can absorb more vibration and concussion, thus make this motion of shuttlecock more healthy.Current China racket standard is low, with international presence a certain distance, most enterprises mainly relies on the process for processing task imitating or bear foreign brand name, earn a profit, scientific and technological content is low, and profit is limited, is therefore badly in need of the racket material of developing one's own intellectual property, to occupy the wider market space, seek larger development.
Summary of the invention
The object of this invention is to provide a kind of titanium metal enhanced carbon fiber racket matrix material and preparation method thereof, this matrix material is based on carbon fiber, add titanium dioxide and resin material, the cost of matrix material is reduced while keeping excellent properties, matrix material light weight, rigidity is high, and elasticity is strong, cost is low, can promote the use of.
To achieve these goals, the technique means that the present invention adopts is:
Titanium metal enhanced carbon fiber racket matrix material, component and and the massfraction of each component as follows: 30 ~ 40 parts, carbon fiber, carbon fibre 10 ~ 20 parts, nano titanium oxide 4 ~ 8 parts, acrylate resin 5 ~ 8 parts, supervinyi chloride resin 3 ~ 8 parts, ethyl cellulose 3 ~ 6 parts, poly-phthalein amine fiber 10 ~ 18 parts, vinyl cyanide 5 ~ 8 parts, nano aluminium oxide 1.6 ~ 2.4 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 0.8 ~ 1.6 part, whipping agent 1 ~ 3 part, coupling agent 2 ~ 5 parts, stablizer 0.5 ~ 1.3 part.
Described whipping agent is dichloro one fluoroethane or chlorodifluoroethane.
Described coupling agent is silane coupling agent; Silane coupling agent can be any one in KH550, KH560, KH570, KH792, DL602, DL171.
Described stablizer is quadrol or xylidine.
Described titanium metal enhanced carbon fiber racket matrix material, component and and the massfraction of each component be preferably as follows: 32 ~ 38 parts, carbon fiber, carbon fibre 13 ~ 18 parts, nano titanium oxide 5 ~ 7 parts, acrylate resin 5.6 ~ 7.1 parts, supervinyi chloride resin 4 ~ 6.7 parts, ethyl cellulose 4.6 ~ 5.5 parts, poly-phthalein amine fiber 13 ~ 16 parts, vinyl cyanide 6 ~ 7 parts, nano aluminium oxide 1.9 ~ 2.1 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 1.2 ~ 1.4 parts, whipping agent 1.6 ~ 2.4 parts, coupling agent 3 ~ 4 parts, stablizer 0.7 ~ 1.1 part.
Described titanium metal enhanced carbon fiber racket matrix material, component and and the massfraction of each component be preferably as follows further: 35 parts, carbon fiber, carbon fibre 15 parts, nano titanium oxide 6 parts, acrylate resin 6.2 parts, supervinyi chloride resin 5.4 parts, ethyl cellulose 5 parts, poly-phthalein amine fiber 14.8 parts, vinyl cyanide 6.5 parts, nano aluminium oxide 2 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 1.3 parts, whipping agent 2 parts, coupling agent 3.7 parts, stablizer 0.9 part.
The preparation method of described titanium metal enhanced carbon fiber racket matrix material, comprises the steps:
1) each component is joined in high speed mixing machine in proportion mix, rotating speed 800 ~ 900rpm, mixing 1 ~ 2h;
2) join in forcing machine by the mixture that step 1) obtains, at 300 ~ 330 DEG C, melting mixing is extruded, and cooling granulation obtains titanium metal enhanced carbon fiber racket matrix material.
Step 1) medium speed is 850rpm, mixing 1.5h.
Beneficial effect: the invention provides a kind of titanium metal enhanced carbon fiber racket matrix material and preparation method thereof, this matrix material is based on carbon fiber, add titanium dioxide and resin material, the cost of matrix material is reduced while keeping excellent properties, matrix material light weight, rigidity is high, and elasticity is strong, cost is low, can promote the use of.
Embodiment
In following examples adopt component all to obtain by commercial sources.
Embodiment 1
Titanium metal enhanced carbon fiber racket matrix material, component and and the massfraction of each component as follows: 30 parts, carbon fiber, carbon fibre 10 parts, nano titanium oxide 4 parts, acrylate resin 5 parts, supervinyi chloride resin 3 parts, ethyl cellulose 3 parts, poly-phthalein amine fiber 10 parts, vinyl cyanide 5 parts, nano aluminium oxide 1.6 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 0.8 part, whipping agent dichloro one fluoroethane 1 part, coupling agent KH5502 part, stablizer xylidine 0.5 part.
Preparation method, comprises the steps:
1) each component is joined in high speed mixing machine in proportion mix, rotating speed 850rpm, mixing 1.5h;
2) join in forcing machine by the mixture that step 1) obtains, at 320 DEG C, melting mixing is extruded, and cooling granulation obtains titanium metal enhanced carbon fiber racket matrix material.
Embodiment 2
Titanium metal enhanced carbon fiber racket matrix material, component and and the massfraction of each component as follows: 40 parts, carbon fiber, carbon fibre 20 parts, nano titanium oxide 8 parts, acrylate resin 8 parts, supervinyi chloride resin 8 parts, ethyl cellulose 6 parts, poly-phthalein amine fiber 18 parts, vinyl cyanide 8 parts, nano aluminium oxide 2.4 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 1.6 parts, whipping agent dichloro one fluoroethane 3 parts, coupling agent KH5505 part, stablizer xylidine 1.3 parts.
Preparation method, comprises the steps:
1) each component is joined in high speed mixing machine in proportion mix, rotating speed 850rpm, mixing 1.5h;
2) join in forcing machine by the mixture that step 1) obtains, at 320 DEG C, melting mixing is extruded, and cooling granulation obtains titanium metal enhanced carbon fiber racket matrix material.
Embodiment 3
Titanium metal enhanced carbon fiber racket matrix material, component and and the massfraction of each component as follows: 32 parts, carbon fiber, carbon fibre 13 parts, nano titanium oxide 5 parts, acrylate resin 5.6 parts, supervinyi chloride resin 4 parts, ethyl cellulose 4.6 parts, poly-phthalein amine fiber 13 parts, vinyl cyanide 6 parts, nano aluminium oxide 1.9 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 1.2 parts, whipping agent chlorodifluoroethane 1.6 parts, coupling agent DL1713 part, stablizer xylidine 0.7 part.
Preparation method, comprises the steps:
1) each component is joined in high speed mixing machine in proportion mix, rotating speed 850rpm, mixing 1.5h;
2) join in forcing machine by the mixture that step 1) obtains, at 320 DEG C, melting mixing is extruded, and cooling granulation obtains titanium metal enhanced carbon fiber racket matrix material.
Embodiment 4
Titanium metal enhanced carbon fiber racket matrix material, component and and the massfraction of each component as follows: 38 parts, carbon fiber, carbon fibre 18 parts, nano titanium oxide 7 parts, acrylate resin 7.1 parts, supervinyi chloride resin 6.7 parts, ethyl cellulose 5.5 parts, poly-phthalein amine fiber 16 parts, vinyl cyanide 7 parts, nano aluminium oxide 2.1 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 1.4 parts, whipping agent chlorodifluoroethane 2.4 parts, coupling agent DL1714 part, stablizer xylidine 1.1 parts.
Preparation method, comprises the steps:
1) each component is joined in high speed mixing machine in proportion mix, rotating speed 850rpm, mixing 1.5h;
2) join in forcing machine by the mixture that step 1) obtains, at 310 DEG C, melting mixing is extruded, and cooling granulation obtains titanium metal enhanced carbon fiber racket matrix material.
Embodiment 5
Titanium metal enhanced carbon fiber racket matrix material, component and and the massfraction of each component as follows: 35 parts, carbon fiber, carbon fibre 15 parts, nano titanium oxide 6 parts, acrylate resin 6.2 parts, supervinyi chloride resin 5.4 parts, ethyl cellulose 5 parts, poly-phthalein amine fiber 14.8 parts, vinyl cyanide 6.5 parts, nano aluminium oxide 2 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 1.3 parts, whipping agent dichloro one fluoroethane 2 parts, coupling agent KH7923.7 part, stablizer xylidine 0.9 part.
Preparation method, comprises the steps:
1) each component is joined in high speed mixing machine in proportion mix, rotating speed 850rpm, mixing 1.5h;
2) join in forcing machine by the mixture that step 1) obtains, at 320 DEG C, melting mixing is extruded, and cooling granulation obtains titanium metal enhanced carbon fiber racket matrix material.
The performance test results of titanium metal enhanced carbon fiber racket matrix material prepared by embodiment 1 ~ 5 is in table 1.Testing method is respectively: density GB/T1033-1986, tensile strength GB/T1040-1992, elongation GB/T1040-1992, flexural strength GB/T9341-2000, notched Izod impact strength GB/T1843-1996.
Table 1:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | |
| Density/(g/cm3) | 1..97 | 1.88 | 1.69 | 1.72 | 1.47 |
| Tensile strength/MPa | 52.7 | 55.9 | 59.1 | 61.2 | 82.3 |
| Elongation/% | 431 | 441 | 483 | 491 | 527 |
| Flexural strength/MPa | 66.1 | 64.2 | 69.8 | 71.4 | 84.8 |
| Notched Izod impact strength/(J/m, 23 DEG C) | 619 | 629 | 683 | 690 | 771 |
Claims (8)
1. titanium metal enhanced carbon fiber racket matrix material, it is characterized in that component and and the massfraction of each component as follows: 30 ~ 40 parts, carbon fiber, carbon fibre 10 ~ 20 parts, nano titanium oxide 4 ~ 8 parts, acrylate resin 5 ~ 8 parts, supervinyi chloride resin 3 ~ 8 parts, ethyl cellulose 3 ~ 6 parts, poly-phthalein amine fiber 10 ~ 18 parts, vinyl cyanide 5 ~ 8 parts, nano aluminium oxide 1.6 ~ 2.4 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 0.8 ~ 1.6 part, whipping agent 1 ~ 3 part, coupling agent 2 ~ 5 parts, stablizer 0.5 ~ 1.3 part.
2. titanium metal enhanced carbon fiber racket matrix material according to claim 1, is characterized in that: described whipping agent is dichloro one fluoroethane or chlorodifluoroethane.
3. titanium metal enhanced carbon fiber racket matrix material according to claim 1, is characterized in that: described coupling agent is silane coupling agent.
4. titanium metal enhanced carbon fiber racket matrix material according to claim 1, is characterized in that: described stablizer is quadrol or xylidine.
5. titanium metal enhanced carbon fiber racket matrix material according to claim 1, it is characterized in that component and and the massfraction of each component as follows: 32 ~ 38 parts, carbon fiber, carbon fibre 13 ~ 18 parts, nano titanium oxide 5 ~ 7 parts, acrylate resin 5.6 ~ 7.1 parts, supervinyi chloride resin 4 ~ 6.7 parts, ethyl cellulose 4.6 ~ 5.5 parts, poly-phthalein amine fiber 13 ~ 16 parts, vinyl cyanide 6 ~ 7 parts, nano aluminium oxide 1.9 ~ 2.1 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 1.2 ~ 1.4 parts, whipping agent 1.6 ~ 2.4 parts, coupling agent 3 ~ 4 parts, stablizer 0.7 ~ 1.1 part.
6. titanium metal enhanced carbon fiber racket matrix material according to claim 1, it is characterized in that component and and the massfraction of each component as follows: 35 parts, carbon fiber, carbon fibre 15 parts, nano titanium oxide 6 parts, acrylate resin 6.2 parts, supervinyi chloride resin 5.4 parts, ethyl cellulose 5 parts, poly-phthalein amine fiber 14.8 parts, vinyl cyanide 6.5 parts, nano aluminium oxide 2 parts, trihydroxyethyl methyl quaternary ammonium methyl sulfate salt 1.3 parts, whipping agent 2 parts, coupling agent 3.7 parts, stablizer 0.9 part.
7. the preparation method of titanium metal enhanced carbon fiber racket matrix material described in any one in claim 1 ~ 6, is characterized in that comprising the steps:
1) each component is joined in high speed mixing machine in proportion mix, rotating speed 800 ~ 900rpm, mixing 1 ~ 2h;
2) join in forcing machine by the mixture that step 1) obtains, at 300 ~ 330 DEG C, melting mixing is extruded, and cooling granulation obtains titanium metal enhanced carbon fiber racket matrix material.
8. the preparation method of titanium metal enhanced carbon fiber racket matrix material according to claim 7, is characterized in that: step 1) medium speed is 850rpm, mixing 1.5h.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106366526A (en) * | 2016-08-30 | 2017-02-01 | 安徽翰文运动用品股份有限公司 | Carbon fiber composite material for badminton rackets |
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| JP2003253094A (en) * | 2002-03-04 | 2003-09-10 | Toho Tenax Co Ltd | Epoxy resin composition for fiber reinforced composite material, prepreg and fiber reinforced composite material |
| JP2004269861A (en) * | 2003-02-18 | 2004-09-30 | Toray Ind Inc | Prepreg, fiber reinforced composite material and tubular product made from the fiber reinforced composite material |
| CN101629010A (en) * | 2009-08-07 | 2010-01-20 | 厦门大学 | Epoxy/POSS/carbon fiber nanometer composite material for light sports equipment and preparation method thereof |
| CN104448729A (en) * | 2014-11-24 | 2015-03-25 | 天津市大城工贸有限公司 | Carbon fiber composite material for bicycle and preparation method thereof |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003253094A (en) * | 2002-03-04 | 2003-09-10 | Toho Tenax Co Ltd | Epoxy resin composition for fiber reinforced composite material, prepreg and fiber reinforced composite material |
| JP2004269861A (en) * | 2003-02-18 | 2004-09-30 | Toray Ind Inc | Prepreg, fiber reinforced composite material and tubular product made from the fiber reinforced composite material |
| CN101629010A (en) * | 2009-08-07 | 2010-01-20 | 厦门大学 | Epoxy/POSS/carbon fiber nanometer composite material for light sports equipment and preparation method thereof |
| CN104448729A (en) * | 2014-11-24 | 2015-03-25 | 天津市大城工贸有限公司 | Carbon fiber composite material for bicycle and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106366526A (en) * | 2016-08-30 | 2017-02-01 | 安徽翰文运动用品股份有限公司 | Carbon fiber composite material for badminton rackets |
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Application publication date: 20151111 |