CN106363734B - A kind of timber preservative containing compound AinsliadimerA - Google Patents
A kind of timber preservative containing compound AinsliadimerA Download PDFInfo
- Publication number
- CN106363734B CN106363734B CN201611022484.5A CN201611022484A CN106363734B CN 106363734 B CN106363734 B CN 106363734B CN 201611022484 A CN201611022484 A CN 201611022484A CN 106363734 B CN106363734 B CN 106363734B
- Authority
- CN
- China
- Prior art keywords
- ainsliadimera
- containing compound
- evocarpine
- timber preservative
- preservative containing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001875 compounds Chemical class 0.000 title claims abstract description 15
- 239000011864 timber preservative Substances 0.000 title claims abstract description 11
- HWFYWIVOYBPLQU-SREVYHEPSA-N Evocarpine Chemical compound C1=CC=C2N(C)C(CCCCCCC\C=C/CCCC)=CC(=O)C2=C1 HWFYWIVOYBPLQU-SREVYHEPSA-N 0.000 claims abstract description 37
- HWFYWIVOYBPLQU-UHFFFAOYSA-N Evocarpin Natural products C1=CC=C2N(C)C(CCCCCCCC=CCCCC)=CC(=O)C2=C1 HWFYWIVOYBPLQU-UHFFFAOYSA-N 0.000 claims abstract description 18
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 5
- 229920003169 water-soluble polymer Polymers 0.000 claims description 5
- 239000004480 active ingredient Substances 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 14
- 239000002023 wood Substances 0.000 abstract description 7
- 239000003755 preservative agent Substances 0.000 description 11
- 239000000523 sample Substances 0.000 description 10
- 230000002335 preservative effect Effects 0.000 description 9
- 238000004321 preservation Methods 0.000 description 5
- 241000124033 Salix Species 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- HATRDXDCPOXQJX-UHFFFAOYSA-N Thapsigargin Natural products CCCCCCCC(=O)OC1C(OC(O)C(=C/C)C)C(=C2C3OC(=O)C(C)(O)C3(O)C(CC(C)(OC(=O)C)C12)OC(=O)CCC)C HATRDXDCPOXQJX-UHFFFAOYSA-N 0.000 description 3
- 239000000539 dimer Substances 0.000 description 3
- 208000015181 infectious disease Diseases 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 229930009674 sesquiterpene lactone Natural products 0.000 description 3
- 150000002107 sesquiterpene lactone derivatives Chemical class 0.000 description 3
- 241001038615 Ainsliaea macrocephala Species 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- QYIHABZOQGFHJO-UHFFFAOYSA-N ainsliadimer A Natural products OC12CC(C(CCC3C(=C)C(=O)OC33)=C)C3C1(O)CCC21C(=O)CC2C(=C)CCC3C(=C)C(=O)OC3C21 QYIHABZOQGFHJO-UHFFFAOYSA-N 0.000 description 2
- QYIHABZOQGFHJO-RLKQMHIPSA-N ainsliadimer A Chemical compound C([C@@]12O)[C@@H](C(CC[C@H]3C(=C)C(=O)O[C@@H]33)=C)[C@@H]3[C@@]1(O)CC[C@]21C(=O)C[C@H]2C(=C)CC[C@H]3C(=C)C(=O)O[C@@H]3[C@H]21 QYIHABZOQGFHJO-RLKQMHIPSA-N 0.000 description 2
- -1 alkylammonium class compound Chemical class 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 description 1
- 241000132064 Ainsliaea Species 0.000 description 1
- 241000228245 Aspergillus niger Species 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 241000228153 Penicillium citrinum Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000003110 anti-inflammatory effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 230000000259 anti-tumor effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- MZGNSEAPZQGJRB-UHFFFAOYSA-N dimethyldithiocarbamic acid Chemical compound CN(C)C(S)=S MZGNSEAPZQGJRB-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 244000144992 flock Species 0.000 description 1
- 239000005452 food preservative Substances 0.000 description 1
- 235000019249 food preservative Nutrition 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 241000411851 herbal medicine Species 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/50—Mixtures of different organic impregnating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K2240/00—Purpose of the treatment
- B27K2240/20—Removing fungi, molds or insects
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of timber preservative containing compound AinsliadimerA, AinsliadimerA and evocarpine, the ratio between parts by weight of AinsliadimerA and evocarpine are 1:1‑30:1.The present invention is 25 28 particularly in the ratio between parts by weight of AinsliadimerA and evocarpine by the way that AinsliadimerA and evocarpine compatibility to be had found to have good wood mould effect under specific ratio:Between 1, it cooperates with anti-mold effect effect apparent.
Description
Technical field
The present invention relates to a kind of preservative, specifically a kind of timber preservative containing compound AinsliadimerA, category
In agricultural technology field.
Background technology
Up to the present, the most commonly used method for preventing foxiness is to use chemical agent anti-corrosion, preservative in production and
Leakage during use and ooze out, and the discarded and burning of preservative-treated timber can all adversely affect to environment, and
Endanger the health of the mankind.Because environmental problem has been to be concerned by more and more people, also turn into the key of selection preservative.
It is currently used it is most be waterborne-type preservation, account for preservative uses total amount 3/4.Because single preservative resists
Domestomycetes, the scope of worm are narrow, typically now mix two or more preservatives by a certain percentage, can not only overcome
Weak point when single preservative uses, but also some new characteristics can be produced.At present, compound preservative is each in the world
State has obtained widest application, and achieves good effect.Because traditional preservatives have many deficiencies, people are forced to grind
Study carefully and find to person poultry harmless, environmentally safe, only poisonous to microorganism new food preservative.More include is studied at present
Water miscible alkylammonium class compound (AAC), the molten alkylamine copper (ACQ) of ammonia, boride, cupric dimethyldithio carbamate
And oil-soluble Bravo (CTL), organic iodide (IPBC) etc. (CDDC).It is nontoxic, high for the essence of wood preservation, exploitation
Effect and practical wood preservation method, reduce environmental pollution, to protection human ecological environment and make full use of existing resource meaning
It is far-reaching.
AinsliadimerA is with very complicated and strange from flat one separated of conservative Chinese herbal medicine major part Ainsliaea
The sesquiterpene lactone dimer of special fresh layout.Meanwhile it also has main anti-inflammatory and antitumor activity, is published in first
Ainsliadimer A, A New Sesquiterpene Lactone Dimer with an Unusual Carbon
Skeleton from Ainsliaea macrocephala, Org.Lett., 2008,10 (12), 2397-2400.Apply for human hair
Existing AinsliadimerA coordinates the effect for wood preservation with synergy with evocarpine under certain proportion.
The content of the invention
In view of the above-mentioned problems of the prior art, it is an object of the invention to provide one kind to contain compound
AinsliadimerA timber preservative, it is to be compounded the composition of two kinds of different structures, the different mechanisms of action, to wood
Material plays corrosion-resistant effect.To realize the purpose of the present invention, inventor compounds AinsliadimerA and evocarpine, uses
In wood preservation.
To achieve these goals, the technical solution adopted by the present invention is:Timber containing compound AinsliadimerA
Preservative, include principle active component:AinsliadimerA.Structural formula is as follows：
The ratio between described AinsliadimerA and the parts by weight of evocarpine are 1:1-30:1.
The ratio between parts by weight of AinsliadimerA and evocarpine are 1:1-30:1, active ingredient accounts for gross weight
0.3%~10%..
Said composition also includes auxiliary formula：High molecular weight water soluble polymer, surfactant, organic solvent and water.
Described high molecular weight water soluble polymer is copolyvidone, polyvinylpyrrolidone, cinnamic acrylic ester are birdsed of the same feather flock together
Any one in compound.
Described organic solvent is normal propyl alcohol or n-butanol.
Active ingredient 0.1-5%, high molecular weight water soluble polymer 0.6-4%, organic solvent 3-7%, excess water.
The present invention is by the way that AinsliadimerA and evocarpine compatibility to be had found to have well under specific ratio
Anti-mold effect, it is 25-28 particularly in the ratio between parts by weight of AinsliadimerA and evocarpine:Between 1, it is cooperateed with
Anti-mold effect is apparent, and small toxicity, health environment-friendly.
Embodiment
Evocarpine, No. CAS:15266-38-3, Chengdu Zhi Biaohuachun Bioisystech Co., Ltd etc. is on sale.
Compound AinsliadimerA involved in the present invention preparation method is referring to document：(Ainsliadimer A,A
New Sesquiterpene Lactone Dimer with an Unusual Carbon Skeleton from
Ainsliaea macrocephala, Org.Lett., 2008,10 (12), 2397-2400).Effect test:
Material willow is tried, originates from Jiangsu Province, life in 5~10 years, zero defect.Adjustable cast iron planes willow bar is processed into peeling, and in natural ring
Gas is done to moisture content 12%~15% under border.Willow is all processed into 40mm × 30mm × 6mm (length × width x thickness) in this experiment
Sample
Mould:Aspergillus niger (AspergillusnigerV.Tiegh), Penicillium citrinum (Penicilliumcitrintim
Thom), strain is provided by INST OF WOOD INDUDTRY CHINESE.
Experimental facilities
MJX-8503 Intelligent culture casees, BCL-1360-B type superclean benches etc..
Every group has 22 willow samples in different decoctions during normal temperature dipping processing, according to processing time 3min according to normal
Press infusion process.Same group of sample is placed on into groined type in beaker to put, weight bears down on one to prevent from floating, and is subsequently poured into decoction simultaneously
Its liquid level is set to be higher by sample material top 2cm.After taking-up, the raffinate of specimen surface is wiped.Blank control group sample is soaked with sterilized water,
Sample after processing is placed in ventilation, and gas is dry 21 days.
Anti-mold effect is evaluated
With reference to national standard《Mould inhibitor prevents and treats the experimental method of timber mould and Stain fungi》, the interior of detection process sample
Fungicidal properties.Sample is connect in 4 weeks after bacterium, and the killed value and specimen surface for observing and recording sample for every 3 days are gone mouldy
Degree, and the killed value of reference sample.
| The degree that specimen surface goes mouldy | Try the killed value of bacterium infection area |
| Specimen surface is without mycelia | 0 |
| Specimen surface infection area ＜ 1/4 | 1 |
| Specimen surface infects area 1/4~1/2 | 2 |
| Specimen surface infects area 1/2~3/4 | 3 |
| Specimen surface infection area ＞ 3/4 | 4 |
Medicament is to the preventing efficiency calculation formula of mould:
In E=(1-Dt/D0) × 100% formula:E is preventing efficiency (%)；Dt is the average killed value of chemicals treatment sample；
D0 is the average killed value of untreated control sample,
After indoor mould proof experiment in 4 weeks, various concentrations processing sample is shown in Table to the preventing efficiency of mould.
The auxiliary formula of medicament is：Polyvinylpyrrolidone 2%, n-butanol 5%, excess water.
A is AinsliadimerA, and B is evocarpine.
By experimental result it can be seen that single AinsliadimerA and evocarpine has certain anti-mold effect,
But effect is not notable, substantial amounts of experiment shows only AinsliadimerA and evocarpine 25-28:1) ratio for
The prevention effect of mould is good, and other ratio groups are not notable, it is seen that AinsliadimerA is with evocarpine in 25-28:1
Shi Xietong antiseptic effects are obvious, have significant progressive.
Claims (5)
1. a kind of timber preservative containing compound AinsliadimerA, it is characterised in that principle active component is:
AinsliadimerA, its structural formula are as follows：
,
Described active ingredient also includes the parts by weight of evocarpine, described AinsliadimerA and evocarpine
The ratio between be 25:1.
A kind of 2. timber preservative containing compound AinsliadimerA according to claim 1, it is characterised in that
The weight of AinsliadimerA and evocarpine accounts for the 0.3%~5% of gross weight.
A kind of 3. timber preservative containing compound AinsliadimerA according to claim 1, it is characterised in that institute
The timber preservative stated also includes high molecular weight water soluble polymer, surfactant, organic solvent and water.
A kind of 4. timber preservative containing compound AinsliadimerA according to claim 3, it is characterised in that institute
The high molecular weight water soluble polymer stated is appointing in copolyvidone, polyvinylpyrrolidone, phenylethene-ACR polymer
Meaning is a kind of.
A kind of 5. timber preservative containing compound AinsliadimerA according to claim 4, it is characterised in that institute
The organic solvent stated is normal propyl alcohol or n-butanol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611022484.5A CN106363734B (en) | 2016-11-16 | 2016-11-16 | A kind of timber preservative containing compound AinsliadimerA |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611022484.5A CN106363734B (en) | 2016-11-16 | 2016-11-16 | A kind of timber preservative containing compound AinsliadimerA |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106363734A CN106363734A (en) | 2017-02-01 |
| CN106363734B true CN106363734B (en) | 2018-02-09 |
Family
ID=57891779
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611022484.5A Expired - Fee Related CN106363734B (en) | 2016-11-16 | 2016-11-16 | A kind of timber preservative containing compound AinsliadimerA |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106363734B (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102246827B (en) * | 2011-08-15 | 2014-06-25 | 高海利 | Compound pesticide |
| CN106459078B (en) * | 2014-04-24 | 2019-02-05 | 北京生命科学研究所 | Sesquiterpenoids |
| CN104210001A (en) * | 2014-07-24 | 2014-12-17 | 株洲市长缨有害生物防治有限责任公司 | Insect and mould inhibitor and application thereof |
| CN105660726B (en) * | 2016-03-09 | 2020-06-09 | 江苏省中国科学院植物研究所 | Preparation method and application of fructus evodiae as agricultural bactericide |
-
2016
- 2016-11-16 CN CN201611022484.5A patent/CN106363734B/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN106363734A (en) | 2017-02-01 |
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Effective date of registration: 20180112 Address after: No. 8 East 226600 Avenue Hyosung Haian County town of Jiangsu city of Nantong Province Applicant after: NANTONG HAIXIN INFORMATION TECHNOLOGY Co.,Ltd. Address before: 221116 Xuzhou province high tech Industrial Development Zone, Xuzhou, Pearl River Road, No. 231, No. Applicant before: XUZHOU DEZHU BIOTECHNOLOGY Co.,Ltd. |
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Effective date of registration: 20221227 Address after: 276000 413, block B, Chuangxin building, high tech Industrial Development Zone, Linyi City, Shandong Province Patentee after: Linyi Gaoxin Cultural Tourism Development Co.,Ltd. Address before: 226600 No. 8, Xiao Xing Avenue, Chengdong Town, Haian County, Nantong, Jiangsu Patentee before: NANTONG HAIXIN INFORMATION TECHNOLOGY Co.,Ltd. |
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Granted publication date: 20180209 |