CN106350798A - Road sign - Google Patents

Road sign Download PDF

Info

Publication number
CN106350798A
CN106350798A CN201610749681.0A CN201610749681A CN106350798A CN 106350798 A CN106350798 A CN 106350798A CN 201610749681 A CN201610749681 A CN 201610749681A CN 106350798 A CN106350798 A CN 106350798A
Authority
CN
China
Prior art keywords
weight
weight portion
parts
main body
metallic plate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610749681.0A
Other languages
Chinese (zh)
Inventor
姚金元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshou City Ancient Town Baimao Emerging Signs Printing Factory
Original Assignee
Changshou City Ancient Town Baimao Emerging Signs Printing Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changshou City Ancient Town Baimao Emerging Signs Printing Factory filed Critical Changshou City Ancient Town Baimao Emerging Signs Printing Factory
Priority to CN201610749681.0A priority Critical patent/CN106350798A/en
Publication of CN106350798A publication Critical patent/CN106350798A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/23—Condensed phosphates

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

The invention discloses a road sign. The main body of the metal plate of the road sign is passivated. The passivation comprises the steps of 1, adding, by weight, 1-2 parts of cerous nitrate, 3.6 parts of polyethylene glycol, 4.3 parts of amino trim ethylene phosphonic acid, 0.4 part of calcium chloride and 2.8 parts of ortho-phosphoric acid successively into 30 parts of deionized water and stirring evenly; 2, obtaining the passivation liquid by stirring evenly after adding, by weight, 1.2 parts of sodium tripolyphosphate, 1.7 parts of nonylphenol ethoxylate carboxyl ate, 2.3 parts of inositol hexaphosphate, 1.8 parts of polyoxyethylene alkyl ether and 3.3 parts of poval successively; 3, passivating the main body of the metal plate in the passivation liquid for 45 seconds at the temperature of 35 DEG C, and then cleaning with aqua pura and stoving. The main body of the metal plate of the road sign is passivated. The road sign has the advantages of good performance and good surface finish.

Description

Road sign
Technical field
The present invention relates to road sign.
Background technology
Existing road sign board, including metallic plate main body, but the antirust, abrasion-resistant of metallic plate main body, corrosion-resistant, heat-resisting, Cold-resistant, weather resistance has much room for improvement, and surface smoothness is also not ideal enough.
Content of the invention
It is an object of the invention to provide a kind of road sign, its metallic plate main body through Passivation Treatment, in metal watch Face forms uniform passivation protection film, has excellent antirust, abrasion-resistant, corrosion-resistant, heat-resisting, cold-resistant, weather resistance, and surface Fineness is good.
For achieving the above object, the technical scheme is that a kind of road sign of design, it includes metallic plate main body, Through Passivation Treatment, described Passivation Treatment comprises the steps: this metallic plate main body
1) by 1～2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight Amount part calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weights are put into again successively Amount part inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to abundant Mix homogeneously, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, Cleaned with pure water after taking-up and dry again.
Preferably, road sign, it includes metallic plate main body, this metallic plate main body through Passivation Treatment, described passivation Process comprises the steps:
1) by 1 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight portion Calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weights are put into again successively Amount part inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to abundant Mix homogeneously, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, Cleaned with pure water after taking-up and dry again.
Preferably, road sign, it includes metallic plate main body, this metallic plate main body through Passivation Treatment, described passivation Process comprises the steps:
1) by 2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight portion Calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weights are put into again successively Amount part inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to abundant Mix homogeneously, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, Cleaned with pure water after taking-up and dry again.
Preferably, road sign, it includes metallic plate main body, this metallic plate main body through Passivation Treatment, described passivation Process comprises the steps:
1) by 1.2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight Part calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weights are put into again successively Amount part inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to abundant Mix homogeneously, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, Cleaned with pure water after taking-up and dry again.
Advantages of the present invention and having the beneficial effects that: a kind of road sign is provided, its metallic plate main body through transpassivation at Reason, forms uniform passivation protection film in metal surface, has excellent antirust, abrasion-resistant, corrosion-resistant, heat-resisting, cold-resistant, weather-proof Performance, and surface smoothness is good.
The performance of " inactivating treatment liquid " and purposes are determined by its component and proportioning, and in " inactivating treatment liquid " not With group, branch influences each other, and component and its proportioning can determine the final performance of " inactivating treatment liquid ", such as fruit component and its proportioning not Mutually coordinated, the beneficial effect that single component is brought, even can be eliminated by other components abatement, when serious, different groups Split-phase is mutually conflicted, and does not have whole synthesis effect, produces negative interaction and substandard products.The present invention passes through a large amount of creative works, repeatedly Checking, obtain the optimal component of " inactivating treatment liquid " and proportioning so that multiple component combine, mutually coordinated and produce Positive comprehensive effect.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is further described.Following examples are only used for more Plus clearly demonstrate technical scheme, and can not be limited the scope of the invention with this.
The technical scheme that the present invention is embodied as is:
Embodiment 1
Road sign, it includes metallic plate main body, and through Passivation Treatment, described Passivation Treatment includes this metallic plate main body Following steps:
1) by 1～2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight Amount part calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weights are put into again successively Amount part inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to abundant Mix homogeneously, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, Cleaned with pure water after taking-up and dry again.
Embodiment 2
Road sign, it includes metallic plate main body, and through Passivation Treatment, described Passivation Treatment includes this metallic plate main body Following steps:
1) by 1 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight portion Calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weights are put into again successively Amount part inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to abundant Mix homogeneously, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, Cleaned with pure water after taking-up and dry again.
Embodiment 3
Road sign, it includes metallic plate main body, and through Passivation Treatment, described Passivation Treatment includes this metallic plate main body Following steps:
1) by 2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight portion Calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weights are put into again successively Amount part inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to abundant Mix homogeneously, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, Cleaned with pure water after taking-up and dry again.
Embodiment 4
Road sign, it includes metallic plate main body, and through Passivation Treatment, described Passivation Treatment includes this metallic plate main body Following steps:
1) by 1.2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight Part calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weights are put into again successively Amount part inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to abundant Mix homogeneously, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, Cleaned with pure water after taking-up and dry again.
Through, in the various embodiments described above, the metallic plate main body of road sign, through Passivation Treatment, is formed all in metal surface Even passivation protection film, has excellent antirust, abrasion-resistant, corrosion-resistant, heat-resisting, cold-resistant, weather resistance, and surface smoothness Good.
The above is only the preferred embodiment of the present invention it is noted that ordinary skill people for the art For member, on the premise of without departing from the technology of the present invention principle, some improvements and modifications can also be made, these improvements and modifications Also should be regarded as protection scope of the present invention.

Claims (4)

1., it is characterised in that it includes metallic plate main body, this metallic plate main body is through Passivation Treatment, described blunt for road sign Change processes and comprises the steps:
1) by 1～2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight portion Calcium chloride, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weight portions are put into again successively Inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to being sufficiently mixed Uniformly, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, take out Cleaned with pure water afterwards and dry again.
2. road sign according to claim 1 is it is characterised in that it includes metallic plate main body, this metallic plate main body Through Passivation Treatment, described Passivation Treatment comprises the steps:
1) by 1 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight portion chlorination Calcium, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weight portions are put into again successively Inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to being sufficiently mixed Uniformly, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, take out Cleaned with pure water afterwards and dry again.
3. road sign according to claim 1 is it is characterised in that it includes metallic plate main body, this metallic plate main body Through Passivation Treatment, described Passivation Treatment comprises the steps:
1) by 2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight portion chlorination Calcium, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weight portions are put into again successively Inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to being sufficiently mixed Uniformly, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, take out Cleaned with pure water afterwards and dry again.
4. road sign according to claim 1 is it is characterised in that it includes metallic plate main body, this metallic plate main body Through Passivation Treatment, described Passivation Treatment comprises the steps:
1) by 1.2 parts by weight of cerium nitrate, 3.6 weight portion Polyethylene Glycol, 4.3 weight portion ATMPs, 0.4 weight portion chlorine Change calcium, 2.8 parts by weight of phosphoric acid put in 30 parts by weight of deionized water successively, stir；
2) 1.2 weight portion sodium tripolyphosphates, 1.7 weight portion nonylphenol ethylene oxide carboxylics, 2.3 weight portions are put into again successively Inositol hexaphosphate, 1.8 weight portion isomeric alcohol polyethenoxy ether, 3.3 weight account polyethylene alcohol, continue stirring, to being sufficiently mixed Uniformly, prepared inactivating treatment liquid；
3) metallic plate main body is inserted and be passivated in inactivating treatment liquid processing, 35 DEG C for the treatment of temperature, process time 45 seconds, take out Cleaned with pure water afterwards and dry again.
CN201610749681.0A 2016-08-29 2016-08-29 Road sign Pending CN106350798A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610749681.0A CN106350798A (en) 2016-08-29 2016-08-29 Road sign

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610749681.0A CN106350798A (en) 2016-08-29 2016-08-29 Road sign

Publications (1)

Publication Number Publication Date
CN106350798A true CN106350798A (en) 2017-01-25

Family

ID=57855463

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610749681.0A Pending CN106350798A (en) 2016-08-29 2016-08-29 Road sign

Country Status (1)

Country Link
CN (1) CN106350798A (en)

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104018148A (en) * 2014-06-25 2014-09-03 钱宏彬 Batch hot-dip galvanizing chromium-free passivator and application method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104018148A (en) * 2014-06-25 2014-09-03 钱宏彬 Batch hot-dip galvanizing chromium-free passivator and application method thereof

Similar Documents

Publication Publication Date Title
CN106282985A (en) Radiation electric heat pipe
CN106381487A (en) Straight electrical heating tube
CN102352188B (en) Precision cerium-zirconium-based solid solution rare earth polishing powder and preparation method thereof
CN106862042A (en) A kind of high-velocity spray aluminium section bar fluorine carbon dust powder formulation and spraying method
CN106191838A (en) Passivation for stainless steel agent
WO2017071024A1 (en) Method for preparing wet-type dedusting agent for reducing coal dust
CN105925985B (en) A kind of stainless iron room temperature chemical polishing solution and preparation method thereof and application method
CN106280613A (en) Automobile emission gas analyzer equipment
CN102559064B (en) Cerium-zirconium praseodymium sosoloid and preparation method thereof
CN106280630A (en) Heating high-resistance electrothermic alloy silk
CN106350798A (en) Road sign
CN106319507A (en) Metal signboard for electric cabinet
CN106119824A (en) Matal deactivator
CN106167898A (en) Industrial cinder ladle car
CN106167900A (en) industrial electric flatcar
CN106297555A (en) warning sign board
CN106119823A (en) Scenic spot signpost
CN106283000A (en) Industrial hot-metal ladle and carriage
CN106283003A (en) Road indicator
CN106350795A (en) High-temperature electric heating tube
CN106319496A (en) Industrial crossing vehicle
CN103320804B (en) A kind of acid cleaning process of zirconium material pickle solution
CN106282998A (en) Electric power sign board
CN106282993A (en) Synchrodrive rotor
CN106283010A (en) Industrial electric flat car

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170125