CN106349912A - 一种单组份纳米离子水性生态涂料及其制备方法 - Google Patents
一种单组份纳米离子水性生态涂料及其制备方法 Download PDFInfo
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Abstract
本发明涉及一种单组份纳米离子水性生态涂料，配方包括成膜物质50‑80％，水性溶剂1‑10％，去离子水5‑15％，分散剂0.1‑3％，成膜助剂0.3‑3％，钛白粉0‑20％，润湿助剂0.1‑1％，流平助剂0.1‑1％，消泡助剂0.1‑1％，防缩孔助剂0.1‑3％，增稠剂0.1‑5％，植物防腐剂0.1‑2％，果蔬熟化抑制剂0.1‑10％，艾草萃取液0.1‑10％，酵母0.1‑10％，银离子0.1‑10％，钙离子0.1‑10％，钛离子0.1‑10％，填充料0‑10％，颜料0‑10％。涂料的制备方法是原料搅拌后加入研磨机进行研磨，低恒温研磨1至5遍，用300目纱网过滤后包装。本发明主要起到防腐、抑菌和保洁的功效。
Description
技术领域
本发明涉及印刷和饰面涂料领域，尤其是涉及一种适用于纳米离子食品保鲜抑菌的包装纸张制品、卫生抑菌保洁制品、及竹木制品抑菌保洁饰面的水性生态涂料，并提供了其制备方法。
背景技术
“民以食为天，食以安为先”，食品安全问题更是我们所关注的焦点。粮食、茶叶、中药等农产品及其它食品，包装、贮藏稍有不慎，就会发霉变质，产生黄曲霉菌等致癌的高危有害微生物，引起食品安全的极大问题。
其中，果蔬类农产品最大的特点是含水量相当高，极易变质腐败，导致其保存期较短。在欧美日韩等经济发达国家，其果蔬类农产品因水分损失在5％以上时，就被认为其失去了鲜销的价值，他们拥有较高的果蔬类农产品贮藏质量的技术，控制变质腐败的损失在5％以內。目前我国的果蔬贮运设施、技术较落后，采后损失高达20％～30％，果蔬类农产品的年经济损失率近2000亿元，因此，研究提高果蔬贮藏质量的技术势在必行。
水果和蔬菜中的化学成分主要有水分和干物质两大类，干物质一般又分为水溶性物质和非水溶性物质。水果和蔬菜中的水溶性物质主要是糖类、果胶、有机酸、多元醇、酶、水溶性维生素、单宁及部分无机盐类；非水溶性物质主要有纤维素、半纤维素、原果胶、淀粉、脂肪、色素、维生素、矿物质和有机盐等。这些物质具有各自的特性，而这些特性则是决定水果和蔬菜本身品质的重要因素。水果和蔬菜的这些组成成分无论在营养还是品质上都是非常重要的。在贮藏中，这些物质共同维持着水果和蔬菜的基本生理活性，他们之问相互作用发生化学变化，而组成的变化又决定着水果和蔬菜的保藏品质及商品价值。
在水果和蔬菜中，水分是主要成分，可以说水分是影响水果和蔬菜嫩度、鲜度和味道的极其重要的成分。但含水量高，又是导致水果和蔬菜耐贮藏性能差、容易腐烂和变质的主要原因，这是因为水分的存在是水果和蔬菜完成全部生命活动的必要条件，同时也给微生物和酶的活动创造了有利的条件，因此应根据不同种类的水果和蔬菜的特性严格控制其水分含量。
针对上述的技术问题，出现了许多新的保鲜技术方法，如：通风库贮藏保鲜、冷库贮藏保鲜、气调库和塑料薄膜小包装气调贮藏保鲜、减压保鲜法、新型薄膜保鲜法、微生物抗菌保鲜法、基因工程技术保鲜法、电子技术保鲜法、陶瓷保鲜袋保鲜法等。但是，这些技术方法实用性低，缺泛统一性，也不能从根本上提高果蔬类农产品的贮藏质量。
发明内容
本发明为了克服现有技术的不足，提供了一种适用于食品保鲜防腐抑菌保洁的包装纸张制品、卫生抑菌保洁纸张制品印刷及竹木制品抑菌保洁饰面的纳米离子单组份水性涂料，并提供了其制备方法，其目的是为了彻底改变以往食品、农产品易腐、易烂、易发霉、易变质、农药残留等纷繁复杂的情况。
为了解决上述的技术问题，本发明提出的技术方案为：一种单组份纳米离子水性生态涂料，其特征在于，按照质量百分比计算包括如下组分：成膜物质50-80％，水性溶剂1-10％，去离子水5-15％，分散剂0.1-3％，成膜助剂0.3-3％，钛白粉0-20％，润湿助剂0.1-1％，流平助剂0.1-1％，消泡助剂0.1-1％，防缩孔助剂0.1-3％，增稠剂0.1-5％，植物防腐剂0.1-2％，果蔬熟化抑制剂0.1-10％，艾草萃取液0.1-10％，酵母0.1-10％，银离子0.1-10％，钙离子0.1-10％，钛离子0.1-10％，填充料0-10％，颜料0-10％。
进一步的，所述制备方法包括如下步骤：
步骤一：将成膜树脂、水溶性溶剂、去离子水、成膜助剂、润湿助剂、流平助剂、消泡助剂、防缩孔助剂、按照比例依次加入分散机的容器内，启动分散机搅拌均匀；
步骤二：将植物防腐剂、果蔬熟化抑制剂、真菌抑制剂、艾草萃取液、酵母、银离子、钙离子、钛离子、按照比例依次添加到分散机的容器内，搅拌均匀；
步骤三：将上述搅拌好的原料加入研磨机进行研磨，低恒温研磨1至5遍，直至颗粒粒径达到200纳米的均匀度；
步骤四：用300目纱网过滤后包装。
优选的，所述步骤一和步骤二中的分散机的搅拌速度为800-1000转/分钟，搅拌时间为30分钟。
优选的，所述水性溶剂为乙二醇单丁醚、二乙二醇丁醚、丙二醇甲醚醋酸酯和乙醇中的一种。
优选的，所述成膜物质为水性树脂乳液，且该水性树脂乳液为单组份聚氨酯乳液、丙烯酸乳液、聚氨酯-丙烯酸共聚乳液和环氧改性苯丙乳液中的一种。
优选的，所述成膜助剂为醇酯十二成膜助剂。
优选的，所述植物防腐剂为曲酸。
优选的，所述果蔬熟化抑制剂为乙烯抑制剂。
优选的，所述钙离子为高活性纳米二氧化钙离子，所述钛离子为高活性纳米二氧化钛离子，所述银离子为高活性纳米银离子。
为了进一步实现本发明的技术方案，所述黑色颜料为炭黑，所述白色颜料为钛白粉。
本发明的有益效果如下：本发明是一种单组份纳米离子水性生态涂料，适用于食品保鲜防腐抑菌保洁的包装纸张制品、卫生抑菌保洁纸张制品印刷及竹木制品抑菌保洁饰面，具有无毒无害，不燃不爆，无甲醛，零排放，符合人类健康要求的高度环保、节能的特性，并且在使用过程无须专用设备、工具、专业人员。
使用本发明的食品保鲜防抑菌包装纸张制品印刷的纳米离子(单组份)水性生态涂料，克服以往各种改变以往食品、农产品易腐、易烂、易发霉、易变质等纷繁复的问题；
本发明所使用于食品保鲜抑菌包装纸张制品印刷的纳米离子(单组份)水性生态涂料(油墨、光油)，具有很广的使用范围，如食品包装纸张印刷、家居竹木藤植物制品家具、书刊印刷、一次性抑菌灭菌卫生用品及包装。
具体实施方式
为了能够更好的理解本发明的技术方案，以下将列举具体实施例来进行说明，但这些具体实施例不应限制本发明的保护范围。
实施例一：
一种单组份纳米离子水性生态涂料，按照质量百分比计算包括如下组分：成膜物质60％，水性溶剂1％，去离子水5％，分散剂0.8％，成膜助剂1％，钛白粉17％，润湿助剂0.2％，，流平助剂0.2％，消泡助剂0.4％，防缩孔助剂0.2％，增稠剂0.5％，植物防腐剂0.2％，果蔬熟化抑制剂1％，艾草萃取液5％，酵母1％，银离子3％，钙离子3.5％，钛离子0％，填充料0％，颜料0％；该方案中，使用的颜料为白色颜料。
本实施例中，使用的颜料为白色颜料，但在具体的使用情况下，不仅仅限于白色颜料，还可以是红色颜料、黄色颜料、蓝色颜料、黑色颜料、金色颜料和银色颜料中的一种。
实施例二：
一种单组份纳米离子水性生态涂料，按照质量百分比计算包括如下组分：成膜物质68％，水性溶剂1％，去离子水5％，分散剂0.3％，成膜助剂0.5％，钛白粉0％，润湿助剂0.2％，流平助剂0.2％，消泡助剂0.4％，防缩孔助剂0.2％，增稠剂0.5％，植物防腐剂0.2％，果蔬熟化抑制剂1％，艾草萃取液5％，酵母1％，银离子3％，钙离子3.5％，钛离子2％，填充料3％，颜料5％；该方案中，使用的颜料为红色颜料。
本实施例中，使用的颜料为红色颜料，但在具体的使用情况下，不仅仅限于白色颜料，还可以是白色颜料、黄色颜料、蓝色颜料、黑色颜料、金色颜料和银色颜料中的一种。
实施例三：
一种单组份纳米离子水性生态涂料，按照质量百分比计算包括如下组分：成膜物质75％，水性溶剂1％，去离子水5％，分散剂0.3％，成膜助剂1％，钛白粉0％，润湿助剂0.2％，流平助剂0.2％，消泡助剂0.4％，防缩孔助剂0.2％，增稠剂0.5％，植物防腐剂0.2％，果蔬熟化抑制剂1％，艾草萃取液5％，酵母1％，银离子5％，钙离子4％，钛离子5％；填充料0％，颜料0％；该方案中，不使用颜料。
本实施例中，不使用颜料，为透明涂层；其可做最表层的透明涂层，但在具体的使用情况下，亦可用于调整白色、红色、黄色、蓝色、黑色、金色银色中的任何一种。
以上三个具体实施例的制备方法如下：
步骤一：将成膜树脂、水溶性溶剂、去离子水、成膜助剂、润湿助剂、流平助剂、消泡助剂、防缩孔助剂、按照比例依次加入分散机的容器内，启动分散机搅拌均匀，搅拌速度为600-1000转/分钟，搅拌时间为30分钟。
步骤二：将植物防腐剂、果蔬熟化抑制剂、真菌抑制剂、艾草萃取液、酵母、银离子、钙离子、钛离子、按照比例依次添加到分散机的容器内，搅拌速度为600-1000转/分钟，搅拌时间为30分钟。搅拌均匀；
步骤三：将上述搅拌好的原料加入研磨机进行研磨，低恒温研磨1至5遍，直至颗粒粒径达到200纳米的均匀度。
步骤四：用300目纱网过滤后包装。
本发明所述的技术方案，能够符合国际环保标准和人类健康标准的食品保鲜抑菌包装纸张制品印刷的单组份纳米离子水性生态涂料(油墨、光油)，根据微生物检测结果，涂层针对大肠杆菌的抑菌率为：99.99％，致病菌(金黄色葡萄球菌、沙门氏菌、志贺氏菌、副溶血性弧菌、溶血性链球菌)抑菌率为：99.88％，本发明不含甲醛与TVOC。
以上显示和描述了本发明的基本原理和主要特征和本发明的优点。本行业的技术人员应该了解，本发明不受上述实施例的限制，上述实施例和说明书中描述的只是说明本发明的原理，在不脱离本发明精神和范围的前提下，本发明还会有各种变化和改进，这些变化和改进都落入要求保护的本发明范围内。
Claims (9)
1.一种单组份纳米离子水性生态涂料，其特征在于，按照质量百分比计算包括如下组分：成膜物质50-80％，水性溶剂1-10％，去离子水5-15％，分散剂0.1-3％，成膜助剂0.3-3％，钛白粉0-20％，润湿助剂0.1-1％，流平助剂0.1-1％，消泡助剂0.1-1％，防缩孔助剂0.1-3％，增稠剂0.1-5％，植物防腐剂0.1-2％，果蔬熟化抑制剂0.1-10％，艾草萃取液0.1-10％，酵母0.1-10％，银离子0.1-10％，钙离子0.1-10％，钛离子0.1-10％，填充料0-10％，颜料0-10％。
2.根据权利要求1所述的一种单组份纳米离子水性生态涂料，其特征在于，所述制备方法包括如下步骤：
步骤一：将成膜树脂、水溶性溶剂、去离子水、成膜助剂、润湿助剂、流平助剂、消泡助剂、防缩孔助剂、按照比例依次加入分散机的容器内，启动分散机搅拌均匀；
步骤二：将植物防腐剂、果蔬熟化抑制剂、真菌抑制剂、艾草萃取液、酵母、银离子、钙离子、钛离子、按照比例依次添加到分散机的容器内，搅拌均匀；
步骤三：将上述搅拌好的原料加入研磨机进行研磨，低恒温研磨1至5遍，直至颗粒粒径达到200纳米的均匀度；
步骤四：用300目纱网过滤后包装。
3.根据权利要求1所述的一种纳米离子抑菌生肌护理液，其特征在于，所述水性溶剂为乙二醇单丁醚、二乙二醇丁醚、丙二醇甲醚醋酸酯和乙醇中的一种。
4.根据权利要求1所述的一种纳米离子抑菌生肌护理液，其特征在于，所述成膜物质为水性树脂乳液，且该水性树脂乳液为单组份聚氨酯乳液、丙烯酸乳液、聚氨酯-丙烯酸共聚乳液和环氧改性苯丙乳液中的一种。
5.根据权利要求1所述的一种纳米离子抑菌生肌护理液，其特征在于，所述成膜助剂为醇酯十二成膜助剂。
6.根据权利要求1所述的一种纳米离子抑菌生肌护理液，其特征在于，所述植物防腐剂为曲酸。
7.根据权利要求1所述的一种纳米离子抑菌生肌护理液，其特征在于，所述果蔬熟化抑制剂为乙烯抑制剂。
8.根据权利要求1所述的一种纳米离子抑菌生肌护理液，其特征在于，所述钙离子为高活性纳米二氧化钙离子，所述钛离子为高活性纳米二氧化钛离子，所述银离子为高活性纳米银离子。
9.根据权利要求2所述的一种纳米离子抑菌生肌护理液，其特征在于，所述制备方法步骤一和步骤二中的分散机的搅拌速度为800-1000转/分钟，搅拌时间为30分钟。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286787A (zh) * | 2017-07-24 | 2017-10-24 | 常德金德新材料科技股份有限公司 | 防霉保鲜涂层材料及其制备方法和应用 |
| CN108727913A (zh) * | 2018-04-27 | 2018-11-02 | 广西师范大学 | 一种生态环保水性石英涂料及制备方法 |
| CN110628262A (zh) * | 2019-10-17 | 2019-12-31 | 杭州美多乐环保新材料有限公司 | 一种生态纳米离子无机矿物涂料及其制备方法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130687A (zh) * | 2014-08-14 | 2014-11-05 | 深圳市能驭科技有限公司 | 食品级水性金属烤漆及其制备方法 |
| CN105153908A (zh) * | 2015-09-14 | 2015-12-16 | 南阳百草堂天然艾草制品有限公司 | 一种艾草涂料制备方法 |
| CN105238103A (zh) * | 2015-10-30 | 2016-01-13 | 江门四方英特宝涂料有限公司 | 一种节能抗菌纳米陶瓷涂料 |
-
2016
- 2016-09-28 CN CN201610855597.7A patent/CN106349912A/zh active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104130687A (zh) * | 2014-08-14 | 2014-11-05 | 深圳市能驭科技有限公司 | 食品级水性金属烤漆及其制备方法 |
| CN105153908A (zh) * | 2015-09-14 | 2015-12-16 | 南阳百草堂天然艾草制品有限公司 | 一种艾草涂料制备方法 |
| CN105238103A (zh) * | 2015-10-30 | 2016-01-13 | 江门四方英特宝涂料有限公司 | 一种节能抗菌纳米陶瓷涂料 |
Non-Patent Citations (2)
| Title |
|---|
| 丁浩等: "《纳米抗菌技术》", 31 January 2008, 化学工业出版社 * |
| 沈立荣等: "《公共食品安全知识解读（第二版）》", 31 August 2016, 中国轻工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286787A (zh) * | 2017-07-24 | 2017-10-24 | 常德金德新材料科技股份有限公司 | 防霉保鲜涂层材料及其制备方法和应用 |
| CN108727913A (zh) * | 2018-04-27 | 2018-11-02 | 广西师范大学 | 一种生态环保水性石英涂料及制备方法 |
| CN110628262A (zh) * | 2019-10-17 | 2019-12-31 | 杭州美多乐环保新材料有限公司 | 一种生态纳米离子无机矿物涂料及其制备方法 |
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