CN106349629A - Anti-flaming wood-plastic composite - Google Patents
Anti-flaming wood-plastic composite Download PDFInfo
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- CN106349629A CN106349629A CN201610725192.1A CN201610725192A CN106349629A CN 106349629 A CN106349629 A CN 106349629A CN 201610725192 A CN201610725192 A CN 201610725192A CN 106349629 A CN106349629 A CN 106349629A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an anti-flaming wood-plastic composite which comprises the following materials in parts by weight: 40-65 parts of maleic anhydride grafted polypropylene, 35-45 parts of straw, 5-8 parts of polyethylene, 3.5-4.5 parts of polyphenyl ether, 2-3 parts of benzoin, 4-6 parts of methyl phenyl siloxane boron, 2.0-2.5 parts of zinc borate, 5.5-7.5 parts of asbestos, 5-7 parts of walnut shell flour, 8-10 parts of camphorwood powder, 6-8 parts of folium ginkgoes, 6-8 parts of aralia echinocaulis powder, 0.1-0.2 part of eaglewood powder, 4-6 parts of 3-hydroxybenzoic acid, 1-2 parts of laurinol sulfate, 4-6 parts of plant saponin, 0.1-0.2 part of terpilenol and 1-3 parts of white emulsion. The anti-flaming wood-plastic composite provided by the invention can continuously release delicate fragrance; the panel has the characteristics of higher strength, anti-flaming property, corrosion resistance and mold-proof property; and the anti-flaming wood-plastic composite can be used in both indoor and outdoor places, is anti-ageing and is free from cracking deformation.
Description
Technical field
The invention belongs to plastic-wood material production technical field, specifically a kind of flame-retardant wood-plastic composite material.
Background technology
Construction material refers to the general name of the various materials for building and field of civil engineering, referred to as " building materials ".In the narrow sense
The building materials material that refers to for civil engineering, such as steel, timber, glass, cement, coating etc., generally by cement, steel and timber
It is referred to as three big materials of common buildings engineering.Sensu lato building materials also include the material for Architectural Equipment, such as electric wire, water pipe
Deng." construction material " of discipline of architecture refers to the subject that physics and the chemical characteristic of different construction materials are studied.
Floor, i.e. the surface layer of house earth surface or flooring, is one kind of construction material.Made by timber or other materials.
The classification on floor has a lot, has by textural classification: solid wooden floor board, reinforced composite wooden floor, solid wooden compound floor, bamboo-wood floor,
Cork flooring and at present most popular multi-layer solid wood composite floor etc.;Classification by use has: domestic, commercially use, antistatic ground
Special floor, the special floor of track and field etc. in the special floor of plate, outdoor flooring, choreography, Stadium field;By environmental protection grade classification
Have: e0 level floor, the f4 star floor of jas star criteria etc..
At present plastic-wood composite floor is mainly with plastics, bamboo/wood fiber as raw material, it be by plastics and bamboo (wooden) consider to be worth doing according to
It is similar to what the ratio of 3:5 was made.Mould wood and have the Waterproof corrosion of plastics and two kinds of characteristics of texture of timber concurrently so that it becomes one
Plant function admirable and very durable outdoor building materials purposes is extremely wide.Existing wood products performance of moulding is still not ideal enough, also exists
The parameters such as the homogeneous degree of some defects, such as plastic wood sheet, density, water absorption still need to improve further.And existing mould
Wood material kind is more single, user according to oneself like selection space too little.
Content of the invention
It is an object of the invention to overcoming prior art defect, provide a kind of flame-retardant wood-plastic composite material.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of flame-retardant wood-plastic composite material, includes following component by weight: maleic anhydride inoculated polypropylene 40-65 part,
Straw 35-45 part, polyethylene 5-8 part, polyphenylene oxide 3.5-4.5 part, Benzoinum 2-3 part, aminomethyl phenyl polyborosiloxane 4-6 part,
Firebrake ZB 2.0-2.5 part, asbestos 5.5-7.5 part, walnut shell powder 5-7 part, camphorwood powder 8-10 part, Folium Ginkgo 6-8 part, spine stem wood
Powder 6-8 part, eaglewood powder 0.1-0.2 part, 3- hydroxy benzoic acid 4-6 part, sulfated lauryl alcohol 1-2 part, plant saponin 4-6
Part, terpineol 0.1-0.2 part, white glue with vinyl 1-3 part.
A kind of described flame-retardant wood-plastic composite material, includes following component by weight: 55 parts of maleic anhydride inoculated polypropylene,
40 parts of straw, 6 parts of polyethylene, 4 parts of polyphenylene oxide, 2 parts of Benzoinum, 5 parts of aminomethyl phenyl polyborosiloxane, 2 parts of Firebrake ZB, asbestos 6
Part, 6 parts of walnut shell powder, 9 parts of camphorwood powder, 7 parts of Folium Ginkgo, 7 parts of spine stem wood powder, 0.2 part of eaglewood powder, 3- hydroxy benzoic acid 4
Part, 1 part of sulfated lauryl alcohol, 6 parts of plant saponin, 0.1 part of terpineol, 1 part of white glue with vinyl.
A kind of described flame-retardant wood-plastic composite material, its preparation method comprises the following steps:
(1) successively by maleic anhydride inoculated polypropylene, straw, polyethylene, polyphenylene oxide, Benzoinum, the poly- borosilicate of aminomethyl phenyl
Oxygen alkane, Firebrake ZB, asbestos, walnut shell powder, camphorwood powder, Folium Ginkgo, spine stem wood powder, eaglewood powder, 3- hydroxy benzoic acid, Laurel
Alcohol sulfate, plant saponin, terpineol, white glue with vinyl add high-speed mixer to be sufficiently mixed uniformly;
(2) step of pelletize, is carried out in comminutor, through the process heating, mediate, bonding, after high pressure batch mixing
Material adds in comminutor, and prilling temperature is 180-300 DEG C, and the time in comminutor for the material is 20-30 minute, is finally obtained
Compound material grain;
(3) extrusion molding, the compound material grain stirring mixing obtaining in granulation step is subsequently adding extruder and is extruded into
Sheet material, the machine barrel of extruder includes five warm areas, from feed end to extruding end, the temperature of five warm areas be set as successively 150 DEG C,
260 DEG C, 200 DEG C, 220 DEG C, 185 DEG C, the machine barrel of extruder connects vaccum-pumping equipment, and the pressure in machine barrel is 0.05mpa.
Described aminomethyl phenyl polyborosiloxane granularity is 100-260 mesh.
Beneficial effects of the present invention: the wood plastic composite that the present invention provides, can persistently give out delicate fragrance, sheet material has
Preferably intensity, with more fire-retardant, anti-corrosion, mould proof feature, indoor, open air all can use, and aging resistance will not craze and transfiguration.
Specific embodiment
For the ease of it will be appreciated by those skilled in the art that the present invention is further illustrated with reference to specific embodiment.
Embodiment 1
A kind of flame-retardant wood-plastic composite material, includes following component: maleic anhydride inoculated polypropylene 40, straw 35 by weight
, polyethylene 5, polyphenylene oxide 3.5, Benzoinum 2, aminomethyl phenyl polyborosiloxane 4, Firebrake ZB 2, asbestos 5.5,
Walnut shell powder 5, camphorwood powder 8, Folium Ginkgo 6, spine stem wood powder 6, eaglewood powder 0.1,3- hydroxy benzoic acid 4,
Sulfated lauryl alcohol 1, plant saponin 4, terpineol 0.1, white glue with vinyl 1.
Its preparation method comprises the following steps:
(1) successively by maleic anhydride inoculated polypropylene 40, straw 35, polyethylene 5, polyphenylene oxide 3.5, Benzoinum
2nd, aminomethyl phenyl polyborosiloxane 4, Firebrake ZB 2, asbestos 5.5, walnut shell powder 5, camphorwood powder 8, Folium Ginkgo 6
, spine stem wood powder 6, eaglewood powder 0.1,3- hydroxy benzoic acid 4, sulfated lauryl alcohol 1, plant saponin 4,
Terpineol 0.1, white glue with vinyl 1 add high-speed mixer to be sufficiently mixed uniformly;
(2) step of pelletize, is carried out in comminutor, through the process heating, mediate, bonding, after high pressure batch mixing
Material adds in comminutor, and prilling temperature is 180-300 DEG C, and the time in comminutor for the material is 20-30 minute, is finally obtained
Compound material grain;
(3) extrusion molding, the compound material grain stirring mixing obtaining in granulation step is subsequently adding extruder and is extruded into
Sheet material, the machine barrel of extruder includes five warm areas, from feed end to extruding end, the temperature of five warm areas be set as successively 150 DEG C,
260 DEG C, 200 DEG C, 220 DEG C, 185 DEG C, the machine barrel of extruder connects vaccum-pumping equipment, and the pressure in machine barrel is 0.05mpa.
Embodiment 2
A kind of flame-retardant wood-plastic composite material, includes following component: maleic anhydride inoculated polypropylene 65, straw 45 by weight
, polyethylene 8, polyphenylene oxide 4.5, Benzoinum 3, aminomethyl phenyl polyborosiloxane 6, Firebrake ZB 2.5, asbestos 7.5
, walnut shell powder 7, camphorwood powder 10, Folium Ginkgo 8, spine stem wood powder 8, eaglewood powder 0.2,3- hydroxy benzoic acid 6
, sulfated lauryl alcohol 2, plant saponin 6, terpineol 0.2, white glue with vinyl 3.
Its preparation method comprises the following steps:
(1) successively by maleic anhydride inoculated polypropylene 65, straw 45, polyethylene 8, polyphenylene oxide 4.5, Benzoinum
3rd, aminomethyl phenyl polyborosiloxane 6, Firebrake ZB 2.5, asbestos 7.5, walnut shell powder 7, camphorwood powder 10, Folium Ginkgo
8, spine stem wood powder 8, eaglewood powder 0.2,3- hydroxy benzoic acid 6, sulfated lauryl alcohol 2, plant saponin 6
, terpineol 0.2, white glue with vinyl 3 add high-speed mixer be sufficiently mixed uniformly;
(2) step of pelletize, is carried out in comminutor, through the process heating, mediate, bonding, after high pressure batch mixing
Material adds in comminutor, and prilling temperature is 180-300 DEG C, and the time in comminutor for the material is 20-30 minute, is finally obtained
Compound material grain;
(3) extrusion molding, the compound material grain stirring mixing obtaining in granulation step is subsequently adding extruder and is extruded into
Sheet material, the machine barrel of extruder includes five warm areas, from feed end to extruding end, the temperature of five warm areas be set as successively 150 DEG C,
260 DEG C, 200 DEG C, 220 DEG C, 185 DEG C, the machine barrel of extruder connects vaccum-pumping equipment, and the pressure in machine barrel is 0.05mpa.
Embodiment 3
A kind of flame-retardant wood-plastic composite material, includes following component: maleic anhydride inoculated polypropylene 50, straw 40 by weight
, polyethylene 6, polyphenylene oxide 4, Benzoinum 3, aminomethyl phenyl polyborosiloxane 5, Firebrake ZB 2, asbestos 6, Semen Juglandiss
Shell powder 6, camphorwood powder 9, Folium Ginkgo 6, spine stem wood powder 6, eaglewood powder 0.1,3- hydroxy benzoic acid 6, Laurel
Alcohol sulfate 1, plant saponin 6, terpineol 0.2, white glue with vinyl 1.
Its preparation method comprises the following steps:
(1) successively by maleic anhydride inoculated polypropylene 50, straw 40, polyethylene 6, polyphenylene oxide 4, Benzoinum 3
, aminomethyl phenyl polyborosiloxane 5, Firebrake ZB 2, asbestos 6, walnut shell powder 6, camphorwood powder 9, Folium Ginkgo 6, spine
Stem wood powder 6, eaglewood powder 0.1,3- hydroxy benzoic acid 6, sulfated lauryl alcohol 1, plant saponin 6, Oleum Pini
Alcohol 0.2, white glue with vinyl 1 add high-speed mixer to be sufficiently mixed uniformly;
(2) step of pelletize, is carried out in comminutor, through the process heating, mediate, bonding, after high pressure batch mixing
Material adds in comminutor, and prilling temperature is 180-300 DEG C, and the time in comminutor for the material is 20-30 minute, is finally obtained
Compound material grain;
(3) extrusion molding, the compound material grain stirring mixing obtaining in granulation step is subsequently adding extruder and is extruded into
Sheet material, the machine barrel of extruder includes five warm areas, from feed end to extruding end, the temperature of five warm areas be set as successively 150 DEG C,
260 DEG C, 200 DEG C, 220 DEG C, 185 DEG C, the machine barrel of extruder connects vaccum-pumping equipment, and the pressure in machine barrel is 0.05mpa.
Embodiment 4
A kind of flame-retardant wood-plastic composite material, includes following component: maleic anhydride inoculated polypropylene 60, straw 40 by weight
, polyethylene 8, polyphenylene oxide 4.5, Benzoinum 2, aminomethyl phenyl polyborosiloxane 4, Firebrake ZB 2, asbestos 7.5,
Walnut shell powder 6, camphorwood powder 9, Folium Ginkgo 7, spine stem wood powder 7, eaglewood powder 0.2,3- hydroxy benzoic acid 5,
Sulfated lauryl alcohol 1, plant saponin 5, terpineol 0.2, white glue with vinyl 2.
Its preparation method comprises the following steps:
(1) successively by maleic anhydride inoculated polypropylene 60, straw 40, polyethylene 8, polyphenylene oxide 4.5, Benzoinum
2nd, aminomethyl phenyl polyborosiloxane 4, Firebrake ZB 2, asbestos 7.5, walnut shell powder 6, camphorwood powder 9, Folium Ginkgo 7
, spine stem wood powder 7, eaglewood powder 0.2,3- hydroxy benzoic acid 5, sulfated lauryl alcohol 1, plant saponin 5,
Terpineol 0.2, white glue with vinyl 2 add high-speed mixer to be sufficiently mixed uniformly;
(2) step of pelletize, is carried out in comminutor, through the process heating, mediate, bonding, after high pressure batch mixing
Material adds in comminutor, and prilling temperature is 180-300 DEG C, and the time in comminutor for the material is 20-30 minute, is finally obtained
Compound material grain;
(3) extrusion molding, the compound material grain stirring mixing obtaining in granulation step is subsequently adding extruder and is extruded into
Sheet material, the machine barrel of extruder includes five warm areas, from feed end to extruding end, the temperature of five warm areas be set as successively 150 DEG C,
260 DEG C, 200 DEG C, 220 DEG C, 185 DEG C, the machine barrel of extruder connects vaccum-pumping equipment, and the pressure in machine barrel is 0.05mpa.
Embodiment 5
A kind of flame-retardant wood-plastic composite material, includes following component: maleic anhydride inoculated polypropylene 60, straw 40 by weight
, polyethylene 6, polyphenylene oxide 4, Benzoinum 2, aminomethyl phenyl polyborosiloxane 5, Firebrake ZB 2, asbestos 7, Semen Juglandiss
Shell powder 6, camphorwood powder 8, Folium Ginkgo 8, spine stem wood powder 6, eaglewood powder 0.2,3- hydroxy benzoic acid 4, Laurel
Alcohol sulfate 1, plant saponin 6, terpineol 0.2, white glue with vinyl 2.
Its preparation method comprises the following steps:
(1) successively by maleic anhydride inoculated polypropylene 60, straw 40, polyethylene 6, polyphenylene oxide 4, Benzoinum 2
, aminomethyl phenyl polyborosiloxane 5, Firebrake ZB 2, asbestos 7, walnut shell powder 6, camphorwood powder 8, Folium Ginkgo 8, spine
Stem wood powder 6, eaglewood powder 0.2,3- hydroxy benzoic acid 4, sulfated lauryl alcohol 1, plant saponin 6, Oleum Pini
Alcohol 0.2, white glue with vinyl 2 add high-speed mixer to be sufficiently mixed uniformly;
(2) step of pelletize, is carried out in comminutor, through the process heating, mediate, bonding, after high pressure batch mixing
Material adds in comminutor, and prilling temperature is 180-300 DEG C, and the time in comminutor for the material is 20-30 minute, is finally obtained
Compound material grain;
(3) extrusion molding, the compound material grain stirring mixing obtaining in granulation step is subsequently adding extruder and is extruded into
Sheet material, the machine barrel of extruder includes five warm areas, from feed end to extruding end, the temperature of five warm areas be set as successively 150 DEG C,
260 DEG C, 200 DEG C, 220 DEG C, 185 DEG C, the machine barrel of extruder connects vaccum-pumping equipment, and the pressure in machine barrel is 0.05mpa.
Above content is only citing made for the present invention and illustrates, affiliated those skilled in the art are to being retouched
The specific embodiment stated is made various modifications or supplements or substituted using similar mode, without departing from invention or super
More scope defined in the claims, all should belong to protection scope of the present invention.
Claims (4)
1. a kind of flame-retardant wood-plastic composite material is it is characterised in that include following component: maleic anhydride inoculated polypropylene by weight
40-65 part, straw 35-45 part, polyethylene 5-8 part, polyphenylene oxide 3.5-4.5 part, Benzoinum 2-3 part, aminomethyl phenyl poly- borosilicate oxygen
Alkane 4-6 part, Firebrake ZB 2.0-2.5 part, asbestos 5.5-7.5 part, walnut shell powder 5-7 part, camphorwood powder 8-10 part, Folium Ginkgo 6-8 part,
Spine stem wood powder 6-8 part, eaglewood powder 0.1-0.2 part, 3- hydroxy benzoic acid 4-6 part, sulfated lauryl alcohol 1-2 part, plant soap
Angle glycosides 4-6 part, terpineol 0.1-0.2 part, white glue with vinyl 1-3 part.
2. as claimed in claim 1 a kind of flame-retardant wood-plastic composite material it is characterised in that including following component: horse by weight
55 parts of maleic anhydride grafted polypropylene, 40 parts of straw, 6 parts of polyethylene, 4 parts of polyphenylene oxide, 2 parts of Benzoinum, aminomethyl phenyl poly- borosilicate oxygen
5 parts of alkane, 2 parts of Firebrake ZB, 6 parts of asbestos, 6 parts of walnut shell powder, 9 parts of camphorwood powder, 7 parts of Folium Ginkgo, 7 parts of spine stem wood powder, Lignum Aquilariae Resinatum
0.2 part of powder, 4 parts of 3- hydroxy benzoic acid, 1 part of sulfated lauryl alcohol, 6 parts of plant saponin, 0.1 part of terpineol, 1 part of white glue with vinyl.
3. as claimed in claim 1 a kind of flame-retardant wood-plastic composite material it is characterised in that its preparation method comprises the following steps:
(1) successively by maleic anhydride inoculated polypropylene, straw, polyethylene, polyphenylene oxide, Benzoinum, aminomethyl phenyl polyborosiloxane,
Firebrake ZB, asbestos, walnut shell powder, camphorwood powder, Folium Ginkgo, spine stem wood powder, eaglewood powder, 3- hydroxy benzoic acid, lauryl alcohol sulfur
Hydrochlorate, plant saponin, terpineol, white glue with vinyl add high-speed mixer to be sufficiently mixed uniformly;
(2) step of pelletize, is carried out in comminutor, through the process heating, mediate, bonding, by the material after high pressure batch mixing
Add in comminutor, prilling temperature is 180-300 DEG C, the time in comminutor for the material is 20-30 minute, be finally obtained compound
Material grain;
(3) extrusion molding, the compound material grain stirring mixing obtaining in granulation step is subsequently adding extruder and is extruded into plate
Material, the machine barrel of extruder includes five warm areas, from feed end to extruding end, the temperature of five warm areas be set as successively 150 DEG C,
260 DEG C, 200 DEG C, 220 DEG C, 185 DEG C, the machine barrel of extruder connects vaccum-pumping equipment, and the pressure in machine barrel is 0.05mpa.
4. a kind of flame-retardant wood-plastic composite material according to claim 1 is it is characterised in that described aminomethyl phenyl poly- borosilicate oxygen
Alkane granularity is 100-260 mesh.
Priority Applications (1)
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CN201610725192.1A CN106349629A (en) | 2016-08-26 | 2016-08-26 | Anti-flaming wood-plastic composite |
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CN201610725192.1A CN106349629A (en) | 2016-08-26 | 2016-08-26 | Anti-flaming wood-plastic composite |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114524985A (en) * | 2022-03-23 | 2022-05-24 | 安徽森泰木塑集团股份有限公司 | Biomass flame-retardant floor |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN114524985A (en) * | 2022-03-23 | 2022-05-24 | 安徽森泰木塑集团股份有限公司 | Biomass flame-retardant floor |
CN114524985B (en) * | 2022-03-23 | 2023-09-29 | 安徽森泰木塑集团股份有限公司 | Biomass flame-retardant floor |
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