CN106349510A - Plastic masterbatch with high strength and hardness - Google Patents
Plastic masterbatch with high strength and hardness Download PDFInfo
- Publication number
- CN106349510A CN106349510A CN201610743805.4A CN201610743805A CN106349510A CN 106349510 A CN106349510 A CN 106349510A CN 201610743805 A CN201610743805 A CN 201610743805A CN 106349510 A CN106349510 A CN 106349510A
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- parts
- dispersant
- resin
- master batch
- plastic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
Abstract
The invention discloses plastic masterbatch with high strength and hardness, made from, by weight, 50-65 parts of cellulose, 8-15 parts of polyethylene, 1-5 parts of polyphenolic aldehyde, 0.1-5 parts of a coupling agent, 0.1-5 parts of a dispersant, 2-8 parts of polyethylene wax, 50-65 parts of nano titanium dioxide antibacterial agent, 20-40 parts of plastic resin, 20-70 parts of carrier resin, 15-40 parts of a pigment, 15-40 parts of filling material, 0.5-2 parts of an antioxidant, and 0.5-5 parts of a dispersant. The plastic masterbatch has the advantages such as environmental friendliness, zero pollution, high dispersibility, good thermal stability and good convenience of use, and can provide improved hardness and wear resistance for injection molding products.
Description
Technical field
The invention belongs to technical field of polymer materials, more particularly, to a kind of plastic master batch with high intensity and hardness.
Background technology
With expanding economy, the application of injecting products is also developed rapidly.The production of injecting products uses in a large number
Pp, the plastic raw materialss such as pe, abs, but light has these plastic raw materialss can't produce the product of super quality and competitive price well, also
Need to add master batch to improve the performance of injecting products.High performance master batch plays very big to the performance improving injecting products
Effect, including the hardness improving injecting products and abrasion resistance.
PTT (abbreviation ptt polyester) is by p-phthalic acid and 1,3- propylene glycol polycondensation
The new polyester macromolecular material of prepared a kind of great development prospect.Ptt polyester belongs to a kind of and has higher melting temperature
Degree and the hemicrystalline high polymer of vitrification point, have good wearability, thermostability and chemical proofing, extensively should
For fields such as synthetic fibers, thin film and engineering plastics.And, most of ptt polyester are required to coloring and use, in ptt
In the production of polyester course of processing, commonly used Masterbatch colours to it.Masterbatch coloring overcomes a variety of drawbacks of toner coloring,
But, how with ptt polyester as carrier, ptt polyester thermostability is bad, through multiple thermal history, color can occur for ptt Masterbatch
Deepen phenomenon, thus hindering the development of ptt Masterbatch.
Content of the invention
Goal of the invention: the present invention is directed to deficiency of the prior art, proposes a kind of environmental protection, pollution-free, high dispersive, thermally-stabilised
Effect is good, easy to use the features such as, simultaneously this master batch can improve the hardness of injecting products and abrasion resistance have high intensity and
The plastic master batch of hardness.
Technical scheme: a kind of plastic master batch with high intensity and hardness of the present invention, include following mass fraction
Component:
Cellulose 50-65 part, polyethylene 8-15 part, poly- methyl phenolic aldehyde 1-5 part, coupling agent 0.1-5 part, dispersant 0.1-
5 parts, Tissuemat E 2-8 part, nano titanium dioxide anti-bacterial agent 50-65 part, plastic resin 20-40 part, vector resin
20-70 part, pigment 15-40 part, filler 15-40 part, antioxidant 0.5-2 part, dispersant 0.5-5 part.
Further, including the component of following mass fraction:
Cellulose 55-65 part, polyethylene 10-15 part, poly- methyl phenolic aldehyde 3-5 part, coupling agent 3-5 part, dispersant 3-5
Part, Tissuemat E 4-8 part, nano titanium dioxide anti-bacterial agent 55-65 part, plastic resin 30-40 part, vector resin
40-70 part, pigment 25-40 part, filler 20-40 part, antioxidant 1-2 part, dispersant 3-5 part.
Further, including the component of following mass fraction:
60 parts of cellulose, 12 parts of polyethylene, 4 parts of poly- methyl phenolic aldehyde, 4 parts of coupling agent, 4 parts of dispersant, Tissuemat E 6
Part, 60 parts of nano titanium dioxide anti-bacterial agent, 35 parts of plastic resin, 55 parts of vector resin, 30 parts of pigment, 30 parts of filler,
2 parts of antioxidant, 4 parts of dispersant.
Further, described dispersant is grafting eba dispersant.
Further, described Tissuemat E molecular weight is 3000～5000.
Further, described nano titanium dioxide anti-bacterial agent is the sharp of 20 ± 10nm or 10 ± 5nm for mean diameter
Titanium-type nano titanium oxide.
Further, described plastic resin is polypropylene plastics resin, vinyon resin, polystyrene plastics tree
One of fat
Further, described vector resin is polyethylene terephthalate-Isosorbide-5-Nitrae-cyclohexanedimethanoester ester.
Further, described pigment includes one of organic pigment, inorganic pigment and dyestuff, described organic pigment choosing
From one of AZOpigments, phthalocyanine color, Heterocyclics Pigments, described inorganic pigment is selected from titanium dioxide, white carbon black, lithopone, oxidation
One of iron oxide red, described dyestuff is selected from Threne brilliant pink or disperse orange.
Beneficial effect: the present invention have environmental protection, pollution-free, high dispersive, thermostable effect are good, easy to use the features such as, with
When this master batch can improve hardness and the abrasion resistance of injecting products.
Specific embodiment
With reference to specific embodiment, the invention will be further described:
Embodiment 1
A kind of antimicrobial form plastic color master grain formula, including the component of following mass fraction:
50 parts of cellulose, 8 parts of polyethylene, 1 part of poly- methyl phenolic aldehyde, 0.1 part of coupling agent, 0.1 part of dispersant, Tissuemat E 2
Part, 50 parts of nano titanium dioxide anti-bacterial agent, 20 parts of plastic resin, 20 parts of vector resin, 15 parts of pigment, 15 parts of filler, resist
0.5 part of oxygen agent, 0.5 part of dispersant.
Described coupling agent is efficient monoalkoxy fatty acid titanate coupling agent.
Described dispersant is grafting eba dispersant.
Described Tissuemat E molecular weight is 3000～5000.
Described nano titanium dioxide anti-bacterial agent is the dichloride in anatase type of 20 ± 10nm or 10 ± 5nm for mean diameter
Titanium dioxide.
Described plastic resin is one of polypropylene plastics resin, vinyon resin, polystyrene plastics resin
Described vector resin is polyethylene terephthalate-Isosorbide-5-Nitrae-cyclohexanedimethanoester ester.
Embodiment 2
A kind of antimicrobial form plastic color master grain formula, including the component of following mass fraction:
65 parts of cellulose, 15 parts of polyethylene, 5 parts of poly- methyl phenolic aldehyde, 5 parts of coupling agent, 5 parts of dispersant, Tissuemat E
8 parts, 65 parts of nano titanium dioxide anti-bacterial agent, 40 parts of plastic resin, 70 parts of vector resin, 40 parts of pigment, filler 40
Part, 2 parts of antioxidant, 5 parts of dispersant.
Described coupling agent is efficient monoalkoxy fatty acid titanate coupling agent.
Described dispersant is grafting eba dispersant.
Described Tissuemat E molecular weight is 3000～5000.
Described nano titanium dioxide anti-bacterial agent is the dichloride in anatase type of 20 ± 10nm or 10 ± 5nm for mean diameter
Titanium dioxide.
Described plastic resin is one of polypropylene plastics resin, vinyon resin, polystyrene plastics resin
Described vector resin is polyethylene terephthalate-Isosorbide-5-Nitrae-cyclohexanedimethanoester ester.
Embodiment 3
A kind of antimicrobial form plastic color master grain formula, including the component of following mass fraction:
60 parts of cellulose, 12 parts of polyethylene, 4 parts of poly- methyl phenolic aldehyde, 4 parts of coupling agent, 4 parts of dispersant, Tissuemat E 6
Part, 60 parts of nano titanium dioxide anti-bacterial agent, 35 parts of plastic resin, 55 parts of vector resin, 30 parts of pigment, 30 parts of filler,
2 parts of antioxidant, 4 parts of dispersant.
Described coupling agent is efficient monoalkoxy fatty acid titanate coupling agent.
Described dispersant is grafting eba dispersant.
Described Tissuemat E molecular weight is 3000～5000.
Described nano titanium dioxide anti-bacterial agent is the dichloride in anatase type of 20 ± 10nm or 10 ± 5nm for mean diameter
Titanium dioxide.
Described plastic resin is one of polypropylene plastics resin, vinyon resin, polystyrene plastics resin
Described vector resin is polyethylene terephthalate-Isosorbide-5-Nitrae-cyclohexanedimethanoester ester.
The above, be only presently preferred embodiments of the present invention, not the present invention is made with any pro forma restriction, though
So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any is familiar with this professional technology people
Member, in the range of without departing from technical solution of the present invention, when the technology contents of available the disclosure above make a little change or modification
For the Equivalent embodiments of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit of the foundation present invention
Any simple modification, equivalent variations and the modification that above example is made, all still falls within the range of technical solution of the present invention.
Claims (10)
1. a kind of plastic master batch with high intensity and hardness it is characterised in that: include the component of following mass fraction:
Cellulose 50-65 part, polyethylene 8-15 part, poly- methyl phenolic aldehyde 1-5 part, coupling agent 0.1-5 part, dispersant 0.1-
5 parts, Tissuemat E 2-8 part, nano titanium dioxide anti-bacterial agent 50-65 part, plastic resin 20-40 part, vector resin
20-70 part, pigment 15-40 part, filler 15-40 part, antioxidant 0.5-2 part, dispersant 0.5-5 part.
2. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: include following matter
The component of amount number:
Cellulose 55-65 part, polyethylene 10-15 part, poly- methyl phenolic aldehyde 3-5 part, coupling agent 3-5 part, dispersant 3-5
Part, Tissuemat E 4-8 part, nano titanium dioxide anti-bacterial agent 55-65 part, plastic resin 30-40 part, vector resin
40-70 part, pigment 25-40 part, filler 20-40 part, antioxidant 1-2 part, dispersant 3-5 part.
3. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: include following matter
The component of amount number:
60 parts of cellulose, 12 parts of polyethylene, 4 parts of poly- methyl phenolic aldehyde, 4 parts of coupling agent, 4 parts of dispersant, Tissuemat E 6
Part, 60 parts of nano titanium dioxide anti-bacterial agent, 35 parts of plastic resin, 55 parts of vector resin, 30 parts of pigment, 30 parts of filler,
2 parts of antioxidant, 4 parts of dispersant.
4. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: described coupling agent
For efficient monoalkoxy fatty acid titanate coupling agent.
5. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: described dispersant
For being grafted eba dispersant.
6. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: described polyethylene
Wax molecular weight is 3000～5000.
7. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: described nanometer two
Titanium oxide antibacterial is the nanometer anatase titania of 20 ± 10nm or 10 ± 5nm for mean diameter.
8. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: described plastic tree
Fat is one of polypropylene plastics resin, vinyon resin, polystyrene plastics resin.
9. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: described carrier tree
Fat is polyethylene terephthalate-Isosorbide-5-Nitrae-cyclohexanedimethanoester ester.
10. a kind of plastic master batch with high intensity and hardness according to claim 1 it is characterised in that: described pigment
Including one of organic pigment, inorganic pigment and dyestuff, described organic pigment is selected from AZOpigments, phthalocyanine color, heterocycle face
One of material, described inorganic pigment is selected from one of titanium dioxide, white carbon black, lithopone, iron oxide red, and described dyestuff is selected from
Threne brilliant pink or disperse orange.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610743805.4A CN106349510A (en) | 2016-08-29 | 2016-08-29 | Plastic masterbatch with high strength and hardness |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610743805.4A CN106349510A (en) | 2016-08-29 | 2016-08-29 | Plastic masterbatch with high strength and hardness |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106349510A true CN106349510A (en) | 2017-01-25 |
Family
ID=57855259
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610743805.4A Pending CN106349510A (en) | 2016-08-29 | 2016-08-29 | Plastic masterbatch with high strength and hardness |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106349510A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109398038A (en) * | 2018-10-10 | 2019-03-01 | 宁波科镭汽车零部件有限公司 | A kind of efficient automobile air outlet panel sectional production technology |
| CN110228159A (en) * | 2019-05-13 | 2019-09-13 | 福建新永发塑胶模具有限公司 | A kind of high abrasion anticorrosion three-dimensional decorative technique |
| CN112812377A (en) * | 2021-02-25 | 2021-05-18 | 绍兴上虞伟强包装有限公司 | High-strength medical plastic bag and preparation process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571055A (en) * | 2013-10-30 | 2014-02-12 | 芜湖纽麦特新材料有限公司 | Antibacterial plastic master batch, and preparation method and antibacterial plastic thereof |
| CN103834065A (en) * | 2014-03-26 | 2014-06-04 | 张家港市康旭聚合体有限公司 | Plastic master batch |
| CN104861543A (en) * | 2014-10-16 | 2015-08-26 | 青岛欣展塑胶有限公司 | PTT polyester plastic color master batch |
-
2016
- 2016-08-29 CN CN201610743805.4A patent/CN106349510A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103571055A (en) * | 2013-10-30 | 2014-02-12 | 芜湖纽麦特新材料有限公司 | Antibacterial plastic master batch, and preparation method and antibacterial plastic thereof |
| CN103834065A (en) * | 2014-03-26 | 2014-06-04 | 张家港市康旭聚合体有限公司 | Plastic master batch |
| CN104861543A (en) * | 2014-10-16 | 2015-08-26 | 青岛欣展塑胶有限公司 | PTT polyester plastic color master batch |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109398038A (en) * | 2018-10-10 | 2019-03-01 | 宁波科镭汽车零部件有限公司 | A kind of efficient automobile air outlet panel sectional production technology |
| CN110228159A (en) * | 2019-05-13 | 2019-09-13 | 福建新永发塑胶模具有限公司 | A kind of high abrasion anticorrosion three-dimensional decorative technique |
| CN112812377A (en) * | 2021-02-25 | 2021-05-18 | 绍兴上虞伟强包装有限公司 | High-strength medical plastic bag and preparation process thereof |
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| C06 | Publication | ||
| PB01 | Publication | ||
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| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170125 |