CN106348738A - Health-maintaining ceramics and preparing method thereof - Google Patents

Health-maintaining ceramics and preparing method thereof Download PDF

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Publication number
CN106348738A
CN106348738A CN201610764801.4A CN201610764801A CN106348738A CN 106348738 A CN106348738 A CN 106348738A CN 201610764801 A CN201610764801 A CN 201610764801A CN 106348738 A CN106348738 A CN 106348738A
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Prior art keywords
health preserving
tourmaline
maifanitum
health
preserving pottery
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CN201610764801.4A
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陈瑶武
邓东亮
徐端珍
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Jiedong Jieyang Heng Cheng Ceramic Industry Co Ltd
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Jiedong Jieyang Heng Cheng Ceramic Industry Co Ltd
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Priority to CN201610764801.4A priority Critical patent/CN106348738A/en
Publication of CN106348738A publication Critical patent/CN106348738A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/14Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on silica
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/08Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by adding porous substances
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • CCHEMISTRY; METALLURGY
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3205Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
    • C04B2235/3208Calcium oxide or oxide-forming salts thereof, e.g. lime
    • C04B2235/321Dolomites, i.e. mixed calcium magnesium carbonates
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3472Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3427Silicates other than clay, e.g. water glass
    • C04B2235/3463Alumino-silicates other than clay, e.g. mullite
    • C04B2235/3481Alkaline earth metal alumino-silicates other than clay, e.g. cordierite, beryl, micas such as margarite, plagioclase feldspars such as anorthite, zeolites such as chabazite
    • CCHEMISTRY; METALLURGY
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    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30Constituents and secondary phases not being of a fibrous nature
    • C04B2235/34Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/349Clays, e.g. bentonites, smectites such as montmorillonite, vermiculites or kaolines, e.g. illite, talc or sepiolite

Abstract

The invention relates to a ceramic material, and discloses health-maintaining ceramics and a preparing method thereof. The health-maintaining ceramics consist of the following raw materials in weight percentage: 20 -27% of clay, 30 -34% of quartz, 15 - 20% of feldspar, 14 -18% of dolomite, 1 -2% of calcite, 3 -5% of tourmaline and 6 - 8% of medical stone. The preparing process of the health-maintaining ceramics is simple. According to the a new process in which iron content in the tourmaline and the medical stone is reduced, and ceramics are formed via the formula of ceramic foundation blank and glaze, the aims of improving the whiteness and clarity of the health-maintaining ceramics and improving the pyroelectric property are fulfilled.

Description

A kind of health preserving pottery and preparation method thereof
Technical field
The present invention relates to a kind of ceramic material and preparation method thereof is and in particular to a kind of health preserving pottery and preparation method thereof.
Background technology
Health preserving pottery is in recent years on the basis of the artistry of traditional ceramicses, the suitability, increasingly increases for improving Modern human populations Long quality of the life and the new porcelain kind researched and developed.Be different from traditional ceramicses is that it such as has health preserving, health care, gets rid of illness at the function.Using The beneficiating ingredient to human body in natural mineral raw, special physico-chemical effect, implant in traditional ceramicses preparation process above because Element, is a kind of novel ceramic craft, is also that human development utilizes mineral resources, good for health, life lengthening direction.
But, the dyeing element such as irony in natural mineral raw, whiteness, the transparency of pottery can be affected.And it is most Crowd is partial to white, saturating or more gorgeous tone, repels the dead color based on ferrum.
" female spy " test shows: the change of iron oxide content in tourmaline, and tourmaline pyroelectric effect is had a direct impact. Iron oxide content increases, and pyroelectric effect gradually weakens;Conversely, pyroelectric effect strengthens.And pyroelectricity characteristic directly affect negative Ionic effect and the power of far infrared effect.
Content of the invention
The present invention becomes in porcelain technique, the function raw mineral materials adding only is focused on its granularity, ignorance adjustment for prior art Its iron-holder, leads to into porcelain whiteness, thoroughly spends poor, the low defect of pyroelectric effect, can strengthen tourmaline, wheat according to reducing iron content The principle of meal stone pyroelectric effect, provide first by tourmaline, Maifanitum separating-purifying be concentrate, then participate in pottery basis base, glaze Formula becomes the new technology of porcelain, the high whiteness of output, the high strong health preserving ceramic of degree, health-preserving function thoroughly.
To achieve these goals, a kind of health preserving pottery that the present invention provides, by the percentage by weight group of following raw material Become: clay 20 ~ 27%;Quartz 30 ~ 34%;Anhydrite 15 ~ 20%;Dolomite 14 ~ 18%;Calcite 1 ~ 2%;Tourmaline 3 ~ 5%;Maifanitum 6~8%.
Further, the raw material composition of described health preserving pottery also includes the lithium porcelain stone that percentage by weight is 2 ~ 6%.
Preferably, described tourmaline and the separated purification of Maifanitum are so as to iron content is less than 0.3%.
The preparation method of described health preserving pottery comprises the following steps:
S1. carried out in small, broken bits to tourmaline and Maifanitum except ferrum by physics, chemical method to 200 mesh, make this two raw mineral materials Iron content be down to less than 0.3%;
S2. by clay 20 ~ 27%;Quartz 30 ~ 34%;Anhydrite 15 ~ 20%;Dolomite 14 ~ 18%;Calcite 1 ~ 2%;And divide through s1 From tourmaline 3 ~ 5% and the Maifanitum 6 ~ 8% of purification, mix in proportion, fed intake;
S3. press material: ball: the mass ratio of water is 1: 1.5: 0.8, is ground, milling time is 15 ~ 20 hours;
S4. the compound after grinding is carried out process of sieving, then is designed by purposes requirement, extrusion molding, and repair surface, Reject plug-hole pug;
S5. s4 gained base substrate is sintered in 1300 ~ 1330 DEG C of high temperature reduction flames, firing time is 8 ~ 10 hours, furnace cooling, Obtain final product described health preserving pottery.
Preferably, 250 eye mesh screens, screen over-size < 0.5% are adopted in described step s4 screening process.
Preferably, the sintering temperature of described step s5 base substrate is 1330 DEG C.
Beneficial effects of the present invention:
(1) in prior art the preparation technology of function ceramics need with 10% about tourmaline and 18% about Maifanitum, this Invention at most only need to become base, glaze porcelain making with the tourmaline 5% of separated purification and Maifanitum 8% respectively, can at least save tourmaline 5%th, save Maifanitum 10%, the production cost of health preserving pottery is greatly lowered.
(2) preparation process is simple of health preserving pottery of the present invention, is contained by first reducing the ferrum in tourmaline and Maifanitum raw material Amount, then participate in the new technology that pottery basis base, glaze formula become porcelain, improve health preserving pottery whiteness, thoroughly spend, and lifted its heat to reach Release the purpose of electrical property.
Specific embodiment
The invention will be further described below.Following examples are only used for the technical side of the present invention is clearly described Case, and can not be limited the scope of the invention with this.
Embodiment 1
A kind of health preserving pottery, the percentage by weight of its raw material is: clay 25%;Quartz 30%;Anhydrite 17%;Dolomite 14%;Fang Xie Stone 1%;Tourmaline 5%;Maifanitum 8%.Its product producing process step includes: (1) by small, broken bits to tourmaline and Maifanitum to 200 mesh, Carry out making the iron content of this two raw mineral materials be down to less than 0.3% except ferrum by physics, chemical method;(2) by raw material press than Example mix homogeneously, is fed intake;(3) press material: ball: the mass ratio of water is 1: 1.5: 0.8, is ground, milling time is little for 15 When;(4) compound after grinding is carried out process of sieving, adopt 250 eye mesh screens, screen over-size < 0.5% in screening process, then press Purposes requires to be designed, extrusion molding, and repairs surface, rejects plug-hole pug;(5) by gained base substrate in 1300 DEG C of oxidizing flames Middle sintering, firing time is 8 hours, and furnace cooling obtains final product described wheat meal porous ceramicss.
Embodiment 2
A kind of health preserving pottery, the percentage by weight of its raw material is: clay 20%;Quartz 34%;Anhydrite 19%;Dolomite 14%;Fang Xie Stone 2%;Tourmaline 4%;Maifanitum 7%.Its product producing process step includes: (1) by small, broken bits to tourmaline and Maifanitum to 200 mesh, Carry out making the iron content of this two raw mineral materials be down to less than 0.3% except ferrum by physics, chemical method;(2) by raw material press than Example mix homogeneously, is fed intake;(3) press material: ball: the mass ratio of water is 1: 1.5: 0.8, is ground, milling time is little for 20 When;(4) compound after grinding is carried out process of sieving, adopt 250 eye mesh screens, screen over-size < 0.5% in screening process, then press Purposes requires to be designed, extrusion molding, and repairs surface, rejects plug-hole pug;(5) by gained base substrate in 1330 DEG C of oxidizing flames Middle sintering, firing time is 10 hours, and furnace cooling obtains final product described wheat meal porous ceramicss.
Embodiment 3
A kind of health preserving pottery, the percentage by weight of its raw material is: clay 27%;Quartz 30%;Anhydrite 15%;Dolomite 18%;Fang Xie Stone 1%;Tourmaline 3%;Maifanitum 6%.Its product producing process step includes: (1) by small, broken bits to tourmaline and Maifanitum to 200 mesh, Carry out making the iron content of this two raw mineral materials be down to less than 0.3% except ferrum by physics, chemical method;(2) by raw material press than Example mix homogeneously, is fed intake;(3) press material: ball: the mass ratio of water is 1: 1.5: 0.8, is ground, milling time is little for 18 When;(4) compound after grinding is carried out process of sieving, adopt 250 eye mesh screens, screen over-size < 0.5% in screening process, then press Purposes requires to be designed, extrusion molding, and repairs surface, rejects plug-hole pug;(5) by gained base substrate in 1300 DEG C of oxidizing flames Middle sintering, firing time is 9 hours, and furnace cooling obtains final product described wheat meal porous ceramicss.
The health preserving pottery of present invention preparation is by the iron content in first minimizing tourmaline and Maifanitum raw material, then participates in pottery Basic base, glaze formula become the new technology of porcelain, improve health preserving pottery whiteness, thoroughly spend to reach, and the mesh lifting its pyroelectric property 's.Shown in the following contrast table of its excellent properties.
Unprocessed with the tourmaline after separating-purifying, Maifanitum participates in formula and becomes the whiteness after porcelain to compare:
Unprocessed with the tourmaline after separating-purifying, Maifanitum participates in formula and becomes anion releasing number after porcelain to compare
Finally it is noted that obviously, above-described embodiment is only intended to clearly illustrate example of the present invention, and not right The restriction of embodiment.For those of ordinary skill in the field, can also be made it on the basis of the above description The change of its multi-form or variation.There is no need to be exhaustive to all of embodiment.And thus amplified out Obvious change or change still in protection scope of the present invention among.

Claims (6)

1. a kind of health preserving pottery is it is characterised in that be made up of the percentage by weight of following raw material: clay 20 ~ 27%;Quartzy 30 ~ 34%;Anhydrite 15 ~ 20%;Dolomite 14 ~ 18%;Calcite 1 ~ 2%;Tourmaline 3 ~ 5%;Maifanitum 6 ~ 8%.
2. a kind of health preserving pottery according to claim 1 is it is characterised in that the raw material composition of described health preserving pottery also includes Percentage by weight is 2 ~ 6% lithium porcelain stone.
3. a kind of health preserving pottery according to claim 1 is it is characterised in that described tourmaline and Maifanitum is separated carries Pure so as to iron content be less than 0.3%.
4. a kind of preparation method of the health preserving pottery described in claim 1 is it is characterised in that the method comprising the steps of:
S1. carried out in small, broken bits to tourmaline and Maifanitum except ferrum by physics, chemical method to 200 mesh, make this two raw mineral materials Iron content be down to less than 0.3%;
S2. by clay 20 ~ 27%;Quartz 30 ~ 34%;Anhydrite 15 ~ 20%;Dolomite 14 ~ 18%;Calcite 1 ~ 2%;And divide through s1 From tourmaline 3 ~ 5% and the Maifanitum 6 ~ 8% of purification, mix in proportion, fed intake;
S3. press material: ball: the mass ratio of water is 1: 1.5: 0.8, is ground, milling time is 15 ~ 20 hours;
S4. the compound after grinding is carried out process of sieving, then is designed by purposes requirement, extrusion molding, and repair surface, Reject plug-hole pug;
S5. s4 gained base substrate is sintered in 1300 ~ 1330 DEG C of high temperature reduction flames, firing time is 8 ~ 10 hours, furnace cooling, Obtain final product described health preserving pottery.
5. a kind of preparation method of health preserving pottery according to claim 4 is it is characterised in that described step s4 screening process In adopt 250 eye mesh screens, screen over-size < 0.5%.
6. a kind of preparation method of health preserving pottery according to claim 4 is it is characterised in that the burning of described step s5 base substrate Junction temperature is 1330 DEG C.
CN201610764801.4A 2016-08-31 2016-08-31 Health-maintaining ceramics and preparing method thereof Pending CN106348738A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108383493A (en) * 2018-04-04 2018-08-10 佛山市润辉合化工有限公司 It is a kind of to have magnetic ceramics and preparation method thereof
CN110240474A (en) * 2019-07-10 2019-09-17 揭阳恒成陶瓷科技有限公司 A kind of near-infrared ceramics and preparation method thereof
CN111548119A (en) * 2020-05-13 2020-08-18 郑州普利飞尔环保科技有限公司 Anion ceramic applied to electric appliance product and preparation method thereof
CN113416056A (en) * 2021-02-02 2021-09-21 国启艾福佳健康科技(山东)有限公司 Ceramic energy storage tube and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102617124A (en) * 2012-03-27 2012-08-01 林俊生 Active crystal ceramic production process
CN105016708A (en) * 2015-08-11 2015-11-04 林俊生 Functional live crystal porcelain and preparation method and application thereof
CN105669162A (en) * 2016-02-18 2016-06-15 金日光 Preparation method of active ceramic and device where active ceramic acts to cause low-temperature nucleus melting reaction in water

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102617124A (en) * 2012-03-27 2012-08-01 林俊生 Active crystal ceramic production process
CN105016708A (en) * 2015-08-11 2015-11-04 林俊生 Functional live crystal porcelain and preparation method and application thereof
CN105669162A (en) * 2016-02-18 2016-06-15 金日光 Preparation method of active ceramic and device where active ceramic acts to cause low-temperature nucleus melting reaction in water

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108383493A (en) * 2018-04-04 2018-08-10 佛山市润辉合化工有限公司 It is a kind of to have magnetic ceramics and preparation method thereof
CN110240474A (en) * 2019-07-10 2019-09-17 揭阳恒成陶瓷科技有限公司 A kind of near-infrared ceramics and preparation method thereof
CN111548119A (en) * 2020-05-13 2020-08-18 郑州普利飞尔环保科技有限公司 Anion ceramic applied to electric appliance product and preparation method thereof
CN113416056A (en) * 2021-02-02 2021-09-21 国启艾福佳健康科技(山东)有限公司 Ceramic energy storage tube and preparation method thereof
CN113416056B (en) * 2021-02-02 2022-12-13 国启艾福佳健康科技(山东)有限公司 Ceramic energy storage tube and preparation method thereof

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