CN105906314A - Long quan celadon She nationality puppet and production method of same - Google Patents
Long quan celadon She nationality puppet and production method of same Download PDFInfo
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- CN105906314A CN105906314A CN201610246147.8A CN201610246147A CN105906314A CN 105906314 A CN105906314 A CN 105906314A CN 201610246147 A CN201610246147 A CN 201610246147A CN 105906314 A CN105906314 A CN 105906314A
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- celadon
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- longquan celadon
- glaze
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 75
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 43
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000000654 additive Substances 0.000 claims abstract description 20
- 230000000996 additive effect Effects 0.000 claims abstract description 19
- 239000010453 quartz Substances 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 235000019738 Limestone Nutrition 0.000 claims abstract description 17
- DLHONNLASJQAHX-UHFFFAOYSA-N aluminum;potassium;oxygen(2-);silicon(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Si+4].[Si+4].[Si+4].[K+] DLHONNLASJQAHX-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000006028 limestone Substances 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 11
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 9
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 239000002689 soil Substances 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 31
- 239000000758 substrate Substances 0.000 claims description 30
- 239000000126 substance Substances 0.000 claims description 23
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 22
- 229910052573 porcelain Inorganic materials 0.000 claims description 20
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 18
- 239000000377 silicon dioxide Substances 0.000 claims description 17
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 16
- 229910052681 coesite Inorganic materials 0.000 claims description 16
- 229910052593 corundum Inorganic materials 0.000 claims description 16
- 229910052906 cristobalite Inorganic materials 0.000 claims description 16
- 229910052682 stishovite Inorganic materials 0.000 claims description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 16
- 229910052905 tridymite Inorganic materials 0.000 claims description 16
- 229910001845 yogo sapphire Inorganic materials 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 10
- 244000025254 Cannabis sativa Species 0.000 claims description 8
- 238000007605 air drying Methods 0.000 claims description 8
- 239000012298 atmosphere Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 239000004744 fabric Substances 0.000 claims description 8
- 239000002270 dispersing agent Substances 0.000 claims description 7
- 239000012535 impurity Substances 0.000 claims description 7
- 238000007873 sieving Methods 0.000 claims description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- 238000000498 ball milling Methods 0.000 claims description 6
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 229940084030 carboxymethylcellulose calcium Drugs 0.000 claims description 5
- 238000002347 injection Methods 0.000 claims description 5
- 239000007924 injection Substances 0.000 claims description 5
- 238000000462 isostatic pressing Methods 0.000 claims description 5
- 239000003595 mist Substances 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 239000002002 slurry Substances 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 4
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 238000004040 coloring Methods 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 abstract description 5
- 230000002829 reductive effect Effects 0.000 abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 abstract description 2
- 239000006185 dispersion Substances 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 9
- 239000002932 luster Substances 0.000 description 7
- 244000178870 Lavandula angustifolia Species 0.000 description 6
- 235000010663 Lavandula angustifolia Nutrition 0.000 description 6
- 238000005452 bending Methods 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000001102 lavandula vera Substances 0.000 description 6
- 235000018219 lavender Nutrition 0.000 description 6
- 230000008901 benefit Effects 0.000 description 4
- 238000009413 insulation Methods 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- 238000010923 batch production Methods 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000003648 hair appearance Effects 0.000 description 1
- 239000000017 hydrogel Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000008447 perception Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000003746 solid phase reaction Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
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- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C04B33/00—Clay-wares
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- C04B33/13—Compounding ingredients
- C04B33/1305—Organic additives
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
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- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/63—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
- C04B35/632—Organic additives
- C04B35/634—Polymers
- C04B35/63448—Polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B35/63488—Polyethers, e.g. alkylphenol polyglycolether, polyethylene glycol [PEG], polyethylene oxide [PEO]
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- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3205—Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide
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- C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3217—Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
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- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
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- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3427—Silicates other than clay, e.g. water glass
- C04B2235/3463—Alumino-silicates other than clay, e.g. mullite
- C04B2235/3472—Alkali metal alumino-silicates other than clay, e.g. spodumene, alkali feldspars such as albite or orthoclase, micas such as muscovite, zeolites such as natrolite
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Abstract
The invention discloses a Long quan celadon She nationality puppet and a production method of same. The puppet includes a green body raw material for the Long quan celadon She nationality puppet, water and additives according to the weight percentage ratio of 45-55:35-45:1-5. The Long quan celadon She nationality puppet green body oxide includes the raw materials including, by weight, 20-35% of Long quan porcelain clay, 5-20% of quartz, 10-30% of calcined aluminum oxide powder, 30-45% of Long yan kaolin, 5-18% of potassium feldspar, 1-3% of limestone and 5-10% of violet golden earth. On the basis of the Long quan celadon She nationality puppet green body material, the additive includes: 2-7% of a binder, and 1-5% of a dispersion agent. In the invention, traditional Long quan celadon art is combined with traditional She nationality costume, so that application and development of Long quan celadon production technology and traditional She nationality costume culture are effectively promoted. Production cost of the Long quan celadon in large scale is greatly reduced.
Description
Technical field
Originally the present invention relates to a kind of Longquan celadon technical field, particularly relate to a kind of Longquan celadon She
Image and manufacture method thereof.
Background technology
Existing doll toy on market, profile and structure are all the low grades of similar batch production
Toy, it is impossible to meet people's tight demand to the culture of doll toy spirit, existing doll toy root
Manufacturing according to caricature or cartoon are humanoid etc., use the materials such as wooden or plastics, profile dullness is stiff
And aesthetical perception is the strongest.
Such as application publication number: the Chinese patent of CN102335509A Shen Qing Publication day: 2012.02.01 is public
Having opened the preparation method of a kind of artificial toy doll, the manufacture craft of this artificial toy doll includes: 1, by three-dimensional
Body scans image in one's power makes reference object specifying information and is stored in computer；2, by computer control
3 D stereo engraving machine processed carries out carving artificial toy doll position；3, the human body department carved is dismembered use
Filler injection molding, then assemble；4, hair quality is implanted in face's coloring and Silica hydrogel, and the most supporting
Corresponding clothes.From the preparation of above artificial toy doll it can be seen that existing artificial toy doll preparation technology wants
Ask harsh, need to carry out forming simulation image by particular device and software, moulding process complex and
Loaded down with trivial details and cost intensive.
Longquan celadon, color and luster simple and natural with moulding dignity always is pure bright-colored well-known, has bigger city
Field demand.But, cost of material is high, celadon intensity and the factor of the aspect such as not enough hinders in intensity of colour
The popularization and application of Longquan celadon.Can open up with the Longquan celadon She image that dragon's fountain china clay is raw material manufacture
Wide celadon product, and tradition Longquan celadon art is combined with culture of the She Nationality, with She's dress ornament
Dress Longquan celadon image, has significant Social benefit and economic benefit.To this end, a kind of Longquan celadon
She's image and manufacture method thereof are urgently researched and developed.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of Longquan celadon She image and manufacturer thereof
Method, with She's traditional clothes dressing and the Longquan celadon image product with flexible joint.
For solving above technical problem, the technical scheme is that a kind of Longquan celadon She image,
It includes Longquan celadon She image base raw material, water and additive, and percentage by weight is 45～55:
35～45:1～5.
Further, the base dragon's fountain china clay raw material of described Longquan celadon She image is Huang Tanni, Pu
One or more in city mud, precious Xi Nihezhu township mud.
Further, the raw material weight of blank oxide in described Longquan celadon She image base raw material
Percentage is respectively dragon's fountain china clay 20～35%, quartz 5～20%, calcined alumina 10～30%, Longyan
Kaolin 30～45%, potassium feldspar 5～18%, lime stone 1～3%, Zijin soil 5～10%；Described base
Material raw material components amounts to 100%.
Further, described dragon's fountain base substrate chemical composition contains SiO265～70%, Al2O320～28%,
Fe2O32.0～3.5%, K2O 2.3～3.5%, Na2O 0.2～0.5%, CaO 0.1～0.4%, MgO
0.1～0.5%, TiO20.6～1.2%.
Further, the additive in described Longquan celadon blank is binding agent and dispersant, wherein glues
Knot agent is one or more in carboxymethylcellulose calcium, polyvinyl alcohol, starch, glycerine；Dispersant is poly-
Methyl acrylamide (PMAA-NH4), ammonium chloride (NH4Cl), polyethylene glycol (mean molecule quantity is 10000),
One or more in olein (GTO), castor oil (CTO).
Further, described dragon's fountain base feed particles granularity D10 ＞ 0.06 μm, D90 is
0.35 ± 0.05 μm, D100 ＜ 3 μm, and use aperture≤1 μm；Slip during slip is old sieves
After tail over 0.3～0.6%；Slip moisture content 24～28%；Slip proportion 1.65～1.95%；Pulp flow
Speed 25～40 seconds.
Further, described Longquan celadon She image also includes Longquan celadon She image glaze raw material,
Wherein the raw material weight percentage of glaze oxide is respectively dragon's fountain china clay 10～30%, quartz 10～25%,
Ridge root glaze soil 8～20%, potassium feldspar 30～55%, lime stone 10～25%, Zijin soil 5～15%；Institute
State glaze raw material components and amount to 100%.
Further, described dragon's fountain glaze chemical composition contains SiO250～75%, Al2O35～20%,
Fe2O31.5～3.5%, K2O 0.6～2.5%, Na2O 0.2～2.0%, CaO 0.1～0.3%, MgO
0.1～1.0%, TiO20.1～0.5%.
Further, the grain graininess of described Longquan celadon glaze raw material is 10000-hole sieve surplus 0.02%, and
Glaze proportion is modulated at the mixing glaze slip that Baume concentration is 45～55 degree.
Further, a kind of Longquan celadon She image manufacture method, comprise the following steps:
S1 base raw material, water and additive, percentage by weight is 45～55:35～45:1～5 to carry out
Slurrying, stirring 3～4h mixing is finely ground to all form slip by 10000-hole sieve；Repeatedly vacuum takes off
The old injection forming that carries out after bubble, or old after mist projection granulating carry out isostatic pressing
It is 10000-hole sieve surplus 0.02% that Longquan celadon glaze raw material is finely ground to grain graininess by S2, and glaze
Proportion is modulated at the mixing glaze slip that Baume concentration is 45～55 degree；
The Longquan celadon base substrate of shaping is dried by S3, after microwave drying and heated-air drying,
Carry out biscuiting at a temperature of 500～700 DEG C, be incubated 1～2h；
S4 after cooling, then executes tradition Longquan celadon green grass or young crops glaze layer 1～2mm, uses and hangs firing technique, also
It is heat-treated under the conditions of Primordial Qi atmosphere.
Further, in described step S1: described celadon She image batch mixtures ball milling is to fineness
For D10 ＞ 0.06 μm, D90 is 0.35 ± 0.05 μm, D100 ＜ 3 μm, and uses aperture≤1 μm
Screen cloth carry out sieving removal of impurities, thus obtained Longquan celadon She image blank slip.Longquan celadon
After She's image blank slip reaches this micro/nano level fineness, Longquan celadon She image base substrate becomes porcelain strong
More preferably, compactness is more preferably for degree.
Further, in described step S2: slip fineness 325 mesh during slip is old；Tail over 0.3～
0.6%；Slip moisture content 24～28%；Slip proportion 1.65～1.95%；Slurry flow rate 25～40 seconds.
Further, in described step S4: described Longquan celadon She image green grass or young crops glaze coloring raw material is
Zijin soil, Fe2O3, one or more in FeO.
Further, in described step S4: the thermal coefficient of expansion of the base of described Longquan celadon She image
It is 7～15 × 10-6/ DEG C, glaze layer thermal coefficient of expansion is 8～13 × 10-6/℃。
Further, in described step S4: be heat-treated, specifically comprise the following steps that
Warm-up phase: kiln temperature rises to 550～650 DEG C from normal temperature, with the programming rate of 2～3 DEG C/min
It is heat-treated 2～3h；
Oxidation holding stage: with the programming rate of 3～4 DEG C/min be warming up to 950～980 DEG C insulation 1～
2h；
Strong reduction phase: with the programming rate of 2～3 DEG C/min be warming up to 1200～1250 DEG C of insulations 2～
3h, and kiln air pressure constant is 0.03～0.04Mpa；
Weak reduction holding stage: again kiln temperature is risen to 1280～1300 DEG C, the most fiery after insulation 1～1.5h；
Cooling stage: use natural cooling, kiln discharge after kiln temperature is cooled to 40～60 DEG C, be heat-treated
Complete, obtain Longquan celadon the Shes's body component, then carry out assembling and She's traditional clothes dressing, obtain
Obtain a kind of Longquan celadon She image with dragon's fountain china clay as primary raw material.
The present invention uses dragon's fountain china clay to replace or replaces the general common quartz used in part prior art
And bauxite, coordinate the celadon She image base material powder modification optimized, mainly by
Quartz and aluminum oxide in dragon's fountain china clay, it is possible to the characteristic fully reacted with celadon She image base raw material,
Make solid phase reaction carry out the most complete, be favorably improved celadon She image and become porcelain intensity and glaze colour-stable.
The present invention prepares Longquan celadon She image with dragon's fountain china clay for primary raw material, and its base slip has
Having good suspension and dispersiveness, chemical stability is high, rheological property is good, environment friendly and pollution-free.
And, again through reductive heat treatment after the base substrate glazing of biscuiting, the associativity of base glaze is good, become porcelain intensity
Height, third dimension are strong, glaze tone exquisiteness no color differnece.
It is simple that the present invention manufactures Longquan celadon She image manufacturing process, and can be greatly reduced and produce into
This, fully improve dragon's fountain china clay resource utilization.
Detailed description of the invention
Embodiment 1
By weight, preparation Longquan celadon She image blank oxide component is as follows: dragon's fountain porcelain for S1
Soil 20%, quartz 8%, calcined oxide aluminium powder 10%, Longyan kaolin 30%, potassium feldspar 8%, lime stone
1%, Zijin soil 5%.Wherein dragon's fountain base substrate chemical composition contains described dragon's fountain base substrate chemical composition and contains SiO2
65%, Al2O322%, Fe2O32.0%, K2O 2.3%, Na2O 0.2%, CaO 0.1%, MgO 0.1%,
TiO20.6%.
S2 by weight percentage, Longquan celadon She image base raw material, water and the weight hundred of additive
Proportion by subtraction is 45:35:2.Wherein, in terms of base substrate blank formulation, described binding agent carboxymethylcellulose calcium is
2%, dispersant PMAA-NH4It is 1%, after base raw material, water and additive being mixed, is placed in ball
Being milled to D10 ＞ 0.06 μm in grinding machine, D90 is 0.35 ± 0.05 μm, the fineness of D100 ＜ 3 μm
After, use the screen cloth of aperture 325 mesh to carry out sieving removal of impurities, old, the slip during slip is old sieves,
Form high-performance Longquan celadon base slip.
S3 is by the injection forming that carries out old after slip repeatedly vacuum defoamation, then the dragon's fountain green grass or young crops that will be molded
Porcelain She image base substrate is dried, and after microwave drying and heated-air drying, carries out at a temperature of 650 DEG C
Biscuiting, is incubated 1h.
S4 is by the raw material weight percentage score of glaze oxide in Longquan celadon She image glaze raw material
Not Wei dragon's fountain china clay 10%, quartz 13%, ridge root glaze soil 8%, potassium feldspar 30%, lime stone 15%, purple
Gold soil 5%；Dragon's fountain green grass or young crops glaze chemical composition contains SiO250%, Al2O310%, Fe2O31.5%, K2O 0.8%,
Na2O 0.2%, CaO 0.1%, MgO 0.3%, TiO20.1%.Glaze raw material, He Shui are placed in ball milling
The grain graininess being milled to Longquan celadon glaze raw material in machine is 10000-hole sieve surplus 0.02%, and glaze proportion
It is modulated at the mixing glaze slip that Baume concentration is 45 degree.
S5 after cooling, then executes S4 tradition Longquan celadon lavender grey glaze, in 1200 DEG C of temperature of reducing atmosphere
Under burn till, be incubated 2h, it is thus achieved that become that porcelain intensity is high, bending and compressive strength is good, bright in luster, texture from
So, texture is soft, third dimension is strong, have natural pale blue texture and color, and surface is more smooth and smooth,
With She's traditional clothes dressing and the imperial celadon image product of flexible joint.
Embodiment 2
By weight, preparation Longquan celadon She image blank oxide component is as follows: dragon's fountain porcelain for S1
Soil 25%, quartz 15%, calcined alumina 20%, Longyan kaolin 35%, potassium feldspar 15%, lime stone
2%, Zijin soil 6%.Wherein dragon's fountain base substrate chemical composition contains described dragon's fountain base substrate chemical composition and contains SiO2
67%, Al2O322%, Fe2O32.0%, K2O 2.5%, Na2O 0.3%, CaO 0.2%, MgO 0.1%,
TiO20.65%.
S2 by weight percentage, Longquan celadon She image base raw material, water and the weight hundred of additive
Proportion by subtraction is 48:36:3.Wherein, in terms of base substrate blank formulation, described binding agent is carboxymethylcellulose calcium
It is 2%；Dispersant be polyethylene glycol (mean molecule quantity is 10000) be 3%, by base raw material, water and
After additive mixes, being placed in ball mill and be milled to D10 ＞ 0.06 μm, D90 is
0.35 ± 0.05 μm, after the fineness of D100 ＜ 3 μm, uses the screen cloth of aperture 325 mesh to screen out
Miscellaneous, old, the slip during slip is old sieves, and forms high-performance Longquan celadon base slip.
S3 is by the injection forming that carries out old after slip repeatedly vacuum defoamation, then the dragon's fountain green grass or young crops that will be molded
Porcelain She image base substrate is dried, and after microwave drying and heated-air drying, carries out at a temperature of 600 DEG C
Biscuiting, is incubated 2h.
S4 is by the raw material weight percentage score of glaze oxide in Longquan celadon She image glaze raw material
Wei the raw material weight percentage of glaze oxide be respectively in described Longquan celadon She image glaze raw material
For dragon's fountain china clay 15%, quartz 25%, ridge root glaze soil 10%, potassium feldspar 35%, lime stone 18%, Zijin
Soil 8%.Described dragon's fountain glaze chemical composition contains SiO265%, Al2O315%, Fe2O31.5%, K2O 1.0%,
Na2O 0.8%, CaO 0.1%, MgO 0.3%, TiO20.1%.Glaze raw material, He Shui are placed in ball milling
The grain graininess being milled to Longquan celadon glaze raw material in machine is 10000-hole sieve surplus 0.02%, and glaze proportion
It is modulated at the mixing glaze slip that Baume concentration is 50 degree.
S5 after cooling, then executes S4 tradition Longquan celadon lavender grey glaze, in 1280 DEG C of temperature of reducing atmosphere
Under burn till, it is thus achieved that become that porcelain intensity is high, bending and compressive strength is good, bright in luster, texture is natural, texture
Soft, third dimension is strong, have pale blue texture and color, and surface is more smooth and smooth, traditional with the She
Dress ornament dressing and the imperial celadon image product of flexible joint.
Embodiment 3
By weight, preparation Longquan celadon She image blank oxide component is as follows: dragon's fountain porcelain for S1
Soil 27%, quartz 16%, calcined alumina 15%, Longyan kaolin 33%, potassium feldspar 14%, lime stone
2%, Zijin soil 7%.Wherein dragon's fountain base substrate chemical composition contains described dragon's fountain base substrate chemical composition and contains SiO2
66%, Al2O323%, Fe2O32.2%, K2O 2.4%, Na2O 0.3%, CaO 0.2%, MgO 0.3%,
TiO20.8%.
S2 by weight percentage, Longquan celadon She image base raw material, water and the weight hundred of additive
Proportion by subtraction is 50:38:3.Wherein, in terms of base substrate blank formulation, described binding agent glycerine is 4%；Point
Powder is poly-methyl acrylamide (PMAA-NH4) 3%, base raw material, water and additive are mixed
After, it being placed in ball mill and be milled to D10 ＞ 0.06 μm, D90 is 0.35 ± 0.05 μm, D100 ＜ 3 μm
Fineness after, use the screen cloth of aperture 325 mesh to carry out sieving removal of impurities, old, the material during slip is old
Slurry sieves, and forms high-performance Longquan celadon base slip.
S3 is by the injection forming that carries out old after slip repeatedly vacuum defoamation, then the dragon's fountain green grass or young crops that will be molded
Porcelain She image base substrate is dried, and after microwave drying and heated-air drying, carries out at a temperature of 700 DEG C
Biscuiting, is incubated 1h.
S4 is by the raw material weight percentage score of glaze oxide in Longquan celadon She image glaze raw material
Wei the raw material weight percentage of glaze oxide be respectively in described Longquan celadon She image glaze raw material
For dragon's fountain china clay 15%, quartz 20%, ridge root glaze soil 15%, potassium feldspar 40%, lime stone 15%, Zijin
Soil 10%.Described dragon's fountain glaze chemical composition contains SiO264%, Al2O316%, Fe2O33%, K2O 0.6～
2.5%, Na2O 0.2%, CaO 0.1%, MgO 0.3%, TiO20.1%.Glaze raw material and water are placed in
The grain graininess being milled to Longquan celadon glaze raw material in ball mill is 10000-hole sieve surplus 0.02%, and glaze
Proportion is modulated at the mixing glaze slip that Baume concentration is 50 degree.
S5 after cooling, then executes S4 tradition Longquan celadon lavender grey glaze, in 1280 DEG C of temperature of reducing atmosphere
Under burn till, it is thus achieved that become that porcelain intensity is high, bending and compressive strength is good, bright in luster, texture is natural, texture
Soft, third dimension is strong, have pea green texture and color, and surface is more smooth and smooth, traditional with the She
Dress ornament dressing and the imperial celadon image product of flexible joint.
Embodiment 4
By weight, preparation Longquan celadon She image blank oxide component is as follows: dragon's fountain porcelain for S1
Soil 27%, quartz 18%, calcined alumina 23%, Longyan kaolin 35%, potassium feldspar 14%, lime stone
2%, Zijin soil 9%.Wherein dragon's fountain base substrate chemical composition contains described dragon's fountain base substrate chemical composition and contains SiO2
68%, Al2O324%, Fe2O32.5%, K2O 3%, Na2O 0.4%, CaO 0.3%, MgO 0.1%,
TiO20.7%.
S2 by weight percentage, Longquan celadon She image base raw material, water and the weight hundred of additive
Proportion by subtraction is 48:39:2.Wherein, in terms of base substrate blank formulation, described binding agent carboxymethylcellulose calcium is
2%；Dispersant olein (GTO) is 1%, after base raw material, water and additive are mixed,
Being placed in ball mill and be milled to D10 ＞ 0.06 μm, D90 is 0.35 ± 0.05 μm, D100 ＜ 3 μm
Fineness after, use the screen cloth of aperture 325 mesh to carry out sieving removal of impurities, old, the material during slip is old
Slurry sieves, and forms high-performance Longquan celadon base slip.
S3 by after slip repeatedly vacuum defoamation after mist projection granulating the old isostatic pressing that carries out, then
The Longquan celadon She image base substrate of shaping is dried, after microwave drying and heated-air drying,
Carry out biscuiting at a temperature of 650 DEG C, be incubated 1h.
S4 is by the raw material weight percentage score of glaze oxide in Longquan celadon She image glaze raw material
Wei the raw material weight percentage of glaze oxide be respectively in described Longquan celadon She image glaze raw material
For dragon's fountain china clay 18%, quartz 22%, ridge root glaze soil 14%, potassium feldspar 45%, lime stone 15%, Zijin
Soil 8%.Described dragon's fountain glaze chemical composition contains SiO265%, Al2O318%, Fe2O32.6%, K2O 1.2%,
Na2O 0.8%, CaO 0.2%, MgO 0.5%, TiO20.2%.Glaze raw material, He Shui are placed in ball milling
The grain graininess being milled to Longquan celadon glaze raw material in machine is 10000-hole sieve surplus 0.02%, and glaze proportion
It is modulated at the mixing glaze slip that Baume concentration is 45 degree.
S5 after cooling, then executes S4 tradition Longquan celadon lavender grey glaze, in 1200 DEG C of temperature of reducing atmosphere
Under burn till, it is thus achieved that become that porcelain intensity is high, bending and compressive strength is good, bright in luster, texture is natural, texture
Soft, third dimension is strong, have pale blue texture and color, and surface is more smooth and smooth, traditional with the She
Dress ornament dressing and the imperial celadon image product of flexible joint.
Embodiment 5
By weight, preparation Longquan celadon She image blank oxide component is as follows: dragon's fountain porcelain for S1
Soil 30%, quartz 18%, calcined alumina 25%, Longyan kaolin 40%, potassium feldspar 15%, lime stone
2%, Zijin soil 8%.Wherein dragon's fountain base substrate chemical composition contains described dragon's fountain base substrate chemical composition and contains SiO2
67%, Al2O325%, Fe2O32%, K2O 3%, Na2O 0.3%, CaO 0.2%, MgO 0.3%,
TiO20.6%.
S2 by weight percentage, Longquan celadon She image base raw material, water and the weight hundred of additive
Proportion by subtraction is 50:38:3.Wherein, in terms of base substrate blank formulation, described adhesive starch is 3%；Point
Powder poly-methyl acrylamide (PMAA-NH4) it is 3%, base raw material, water and additive are mixed
After, it being placed in ball mill and be milled to D10 ＞ 0.06 μm, D90 is 0.35 ± 0.05 μm, D100 ＜ 3 μm
Fineness after, use the screen cloth of aperture 325 mesh to carry out sieving removal of impurities, old, the material during slip is old
Slurry sieves, and forms high-performance Longquan celadon base slip.
S3 by after slip repeatedly vacuum defoamation after mist projection granulating the old isostatic pressing that carries out, then
The Longquan celadon She image base substrate of shaping is dried, after microwave drying and heated-air drying,
Carry out biscuiting at a temperature of 600 DEG C, be incubated 1h.
S4 is by the raw material weight percentage score of glaze oxide in Longquan celadon She image glaze raw material
Wei the raw material weight percentage of glaze oxide be respectively in described Longquan celadon She image glaze raw material
For dragon's fountain china clay 28%, quartz 17%, ridge root glaze soil 16%, potassium feldspar 35%, lime stone 18%, Zijin
Soil 12%.Described dragon's fountain glaze chemical composition contains SiO265%, Al2O315%, Fe2O33%, K2O 0.8%,
Na2O 0.5%, CaO 0.2%, MgO 0.1%, TiO20.1%.Glaze raw material, He Shui are placed in ball milling
The grain graininess being milled to Longquan celadon glaze raw material in machine is 10000-hole sieve surplus 0.02%, and glaze proportion
It is modulated at the mixing glaze slip that Baume concentration is 48 degree.
S5 after cooling, then executes S4 tradition Longquan celadon lavender grey glaze, in 1200 DEG C of temperature of reducing atmosphere
Under burn till, it is thus achieved that become that porcelain intensity is high, bending and compressive strength is good, bright in luster, texture is natural, texture
Soft, third dimension is strong, have pea green texture and color, and surface is more smooth and smooth, traditional with the She
Dress ornament dressing and the imperial celadon image product of flexible joint.
Embodiment 6
By weight, preparation Longquan celadon She image blank oxide component is as follows: dragon's fountain porcelain for S1
Soil 35%, quartz 19%, calcined alumina 28%, Longyan kaolin 45%, potassium feldspar 15%, lime stone
2.5%, Zijin soil 8%.Wherein dragon's fountain base substrate chemical composition contains described dragon's fountain base substrate chemical composition and contains
SiO268%, Al2O324%, Fe2O32.8%, K2O 2.9%, Na2O 0.4%, CaO 0.2%, MgO 0.1%,
TiO20.6%.
S2 by weight percentage, Longquan celadon She image base raw material, water and the weight hundred of additive
Proportion by subtraction is 48:37:4.Wherein, in terms of base substrate blank formulation, described adhesive starch is 5%；Point
Powder castor oil (CTO) is 6%, after base raw material, water and additive being mixed, is placed in ball mill
In be milled to D10 ＞ 0.06 μm, D90 is 0.35 ± 0.05 μm, after the fineness of D100 ＜ 3 μm,
The screen cloth using aperture 325 mesh is carried out sieving removal of impurities, old, and the slip during slip is old sieves, shape
Become high-performance Longquan celadon base slip.
S3 by after slip repeatedly vacuum defoamation after mist projection granulating the old isostatic pressing that carries out, then
The Longquan celadon She image base substrate of shaping is dried, after microwave drying and heated-air drying,
Carry out biscuiting at a temperature of 600 DEG C, be incubated 1h.
S4 is by the raw material weight percentage score of glaze oxide in Longquan celadon She image glaze raw material
Wei the raw material weight percentage of glaze oxide be respectively in described Longquan celadon She image glaze raw material
For dragon's fountain china clay 22%, quartz 24%, ridge root glaze soil 16%, potassium feldspar 20%, lime stone 10%, Zijin
Soil 8%.Described dragon's fountain glaze chemical composition contains SiO275%, Al2O319%, Fe2O32%, K2O 1%,
Na2O 0.6%, CaO 0.25%, MgO 0.1%, TiO20.15%.Glaze raw material, He Shui are placed in ball
The grain graininess being milled to Longquan celadon glaze raw material in grinding machine is 10000-hole sieve surplus 0.02%, and glaze ratio
Remodulates is at the mixing glaze slip that Baume concentration is 50 degree.
S5 after cooling, then executes S4 tradition Longquan celadon lavender grey glaze, in 1230 DEG C of temperature of reducing atmosphere
Under burn till, it is thus achieved that become that porcelain intensity is high, bending and compressive strength is good, bright in luster, texture is natural, texture
Soft, third dimension is strong, have plum green texture and color, and surface is more smooth and smooth, passes with the She
System dress ornament dressing and the imperial celadon image product of flexible joint.
The technology of the present invention advantage:
1, the present invention manufactures Longquan celadon She image with dragon's fountain china clay for primary raw material, the most significantly drops
The production cost of low Longquan celadon, and make full use of resource, widen Longquan celadon product and develop the She
Culture, passes on rapidly the culture of the world's " non-something lost " Longquan celadon and tradition culture of the She Nationality, propagates national literary composition
Change spirit, there is great economic and social benefit.Not only conform with the strategy of china natural resources regeneration
Demand, and meet the demand for development that following China construction of energy is intensive, environmental protection is social.
2, the Longquan celadon She image that prepared by the present invention becomes porcelain intensity height, (shock resistance is strong for consistency height
Degree reaches 4.00KJ/m2, rupture strength reaches more than 120Mpa, heat endurance can ensure 200～
20 DEG C of water-cooled exchanges are not split), various model Longquan celadon the Shes's couple material can be met
Can requirement.
3, manufacturing process of the present invention is simple, and cost of material low (can save more than 35%) is the most energy-conservation
Reduce discharging and the production of industrialization.
It is obvious to a person skilled in the art that the invention is not restricted to the thin of above-mentioned one exemplary embodiment
Joint, and without departing from the spirit or essential characteristics of the present invention, it is possible to concrete with other
Form realizes the present invention.Therefore, no matter from the point of view of which point, embodiment all should be regarded as exemplary
, and be nonrestrictive, the scope of the present invention is limited by claims rather than described above
It is fixed, it is intended that all changes in claim equivalency implication and scope are included in the present invention
In.
Moreover, it will be appreciated that although this specification is been described by according to embodiment, but the most each
Embodiment only comprises an independent technical scheme, and this narrating mode of specification is only is clear
Chu Qijian, those skilled in the art should be using specification as an entirety, the technology in each embodiment
Scheme can also form, through appropriately combined, other embodiments that it will be appreciated by those skilled in the art that.
Claims (10)
1. a Longquan celadon She image, it is characterised in that include that Longquan celadon She image base is used
Raw material, water and additive, percentage by weight is 45～55:35～45:1～5.
A kind of Longquan celadon She image, it is characterised in that described dragon
The dragon's fountain china clay raw material of spring celadon She image is Huang Tanni, in Pucheng mud, precious Xi Nihezhu township mud
One or more.
A kind of Longquan celadon She image, it is characterised in that described dragon
In spring celadon image base raw material the raw material weight percentage of blank oxide be respectively dragon's fountain china clay 20～
35%, quartz 5～20%, calcined oxide aluminium powder 10～30%, Longyan kaolin 30～45%, potassium feldspar
5～18%, lime stone 1～3%, Zijin soil 5～10%；Described dragon's fountain base substrate chemical composition contains SiO2
65～70%, Al2O320～28%, Fe2O32.0～3.5%, K2O 2.3～3.5%, Na2O 0.2～0.5%,
CaO 0.1～0.4%, MgO 0.1～0.5%, TiO20.6～1.2%；With Longquan celadon She image base
Material meter, additive consist of binding agent 2～7%, dispersant 1～5%.
A kind of Longquan celadon She image, it is characterised in that also include
Longquan celadon image glaze raw material, wherein the raw material weight percentage of glaze oxide is respectively dragon's fountain porcelain
Soil 10～30%, quartz 10～25%, ridge root glaze soil 8～20%, potassium feldspar 30～55%, lime stone 10～
25%, Zijin soil 5～15%；Described dragon's fountain glaze chemical composition contains SiO250～75%, Al2O35～
20%, Fe2O31.5～3.5%, K2O 0.6～2.5%, Na2O 0.2～2.0%, CaO 0.1～0.3%,
MgO 0.1～1.0%, TiO20.1～0.5%.
A kind of Longquan celadon She image, it is characterised in that described viscous
Knot agent is one or more in carboxymethylcellulose calcium, polyvinyl alcohol, starch, glycerine；Dispersant is poly-
Methyl acrylamide (PMAA-NH4), ammonium chloride (NH4Cl), polyethylene glycol (mean molecule quantity is 10000),
One or more in olein (GTO), castor oil (CTO).
6. a kind of Longquan celadon She image manufacture method as described in one of claim 1 to 5, it is special
Levy and be, comprise the following steps:
S1 base raw material, water and additive, percentage by weight is 45～55:35～45:1～5 to carry out
Slurrying, stirring 3～4h mixing is finely ground to all form slip by 10000-hole sieve；Repeatedly vacuum takes off
The old injection forming that carries out after bubble, or old after mist projection granulating carry out isostatic pressing；
It is 10000-hole sieve surplus 0.02% that Longquan celadon glaze raw material is finely ground to grain graininess by S2, and glaze
Proportion is modulated at the mixing glaze slip that Baume concentration is 45～55 degree；
The Longquan celadon base substrate of shaping is dried by S3, after microwave drying and heated-air drying,
Carry out biscuiting at a temperature of 500～700 DEG C, be incubated 1～2h；
S4 after cooling, then executes tradition Longquan celadon green grass or young crops glaze layer 1～2mm, hangs under reducing atmosphere condition
Burning, heat treatment temperature is 1150～1300 DEG C, and programming rate is 2～5 DEG C/min, is incubated 2～3h,
Obtain a kind of Longquan celadon She image with dragon's fountain china clay as primary raw material.
A kind of Longquan celadon She image and manufacture method, its feature
It is, in step S1: the addition of dragon's fountain china clay is 1～3 times of celadon She image blank；Add
Add addition is celadon blank 1～5 times of agent.
A kind of Longquan celadon She image and manufacture method, its feature
It is, in step S1: described celadon batch mixtures ball milling to fineness is D10 ＞ 0.06 μm, D90
It is 0.35 ± 0.05 μm, D100 ＜ 3 μm, and use the screen cloth of aperture≤1 μm to carry out sieving removal of impurities,
Thus obtained Longquan celadon blank slip.
A kind of Longquan celadon She image and manufacture method, its feature
It is, in step S1: grain fineness 325 mesh in slip；Tail over 0.3～0.6%；Slip is aqueous
Rate 24～28%；Slip proportion 1.65～1.95%；Slurry flow rate 25～40 seconds.
The most according to claim 6, a kind of Longquan celadon She image and manufacture method thereof, it is special
Levy and be, in step S2: described Longquan celadon She image green grass or young crops glaze coloring raw material is Zijin soil, Fe2O3、
One or more in FeO.
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| CN110950650A (en) * | 2018-09-26 | 2020-04-03 | 辽宁省龙呈文化创意产业园有限公司 | Liaodai green glaze ceramic and preparation method thereof |
| CN112028606A (en) * | 2020-09-08 | 2020-12-04 | 赵卫洪 | Longquan Ge kiln garbage broken glaze and firing process thereof |
| CN114409373A (en) * | 2022-01-05 | 2022-04-29 | 丽水学院 | She-family-element-containing celadon and preparation method thereof |
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| CN105906314B (en) | 2020-11-17 |
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Application publication date: 20160831 Assignee: SUICHANG WENCHANG CELADON FACTORY Assignor: LISHUI University Contract record no.: X2024980014957 Denomination of invention: A Longquan celadon She ethnic puppet and its manufacturing method Granted publication date: 20201117 License type: Common License Record date: 20240912 Application publication date: 20160831 Assignee: SUICHANG CHUZHOU KILN CELADON CO.,LTD. Assignor: LISHUI University Contract record no.: X2024980014953 Denomination of invention: A Longquan celadon She ethnic puppet and its manufacturing method Granted publication date: 20201117 License type: Common License Record date: 20240912 |
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Application publication date: 20160831 Assignee: LONGQUAN JINHONG PORCELAIN CO.,LTD. Assignor: LISHUI University Contract record no.: X2024980015394 Denomination of invention: A Longquan celadon She ethnic puppet and its manufacturing method Granted publication date: 20201117 License type: Common License Record date: 20240918 Application publication date: 20160831 Assignee: LONGQUAN OUJIANG CELADON Co.,Ltd. Assignor: LISHUI University Contract record no.: X2024980015392 Denomination of invention: A Longquan celadon She ethnic puppet and its manufacturing method Granted publication date: 20201117 License type: Common License Record date: 20240918 Application publication date: 20160831 Assignee: LONGQUAN YUDE CELADON Co.,Ltd. Assignor: LISHUI University Contract record no.: X2024980015391 Denomination of invention: A Longquan celadon She ethnic puppet and its manufacturing method Granted publication date: 20201117 License type: Common License Record date: 20240918 |