CN106336635B - 一种聚乳酸和苯并噁嗪共混薄膜及其制备方法 - Google Patents
一种聚乳酸和苯并噁嗪共混薄膜及其制备方法 Download PDFInfo
- Publication number
- CN106336635B CN106336635B CN201610831305.6A CN201610831305A CN106336635B CN 106336635 B CN106336635 B CN 106336635B CN 201610831305 A CN201610831305 A CN 201610831305A CN 106336635 B CN106336635 B CN 106336635B
- Authority
- CN
- China
- Prior art keywords
- benzoxazine
- polylactic acid
- mixed solution
- blend film
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 229920000747 poly(lactic acid) Polymers 0.000 title claims abstract description 60
- 239000004626 polylactic acid Substances 0.000 title claims abstract description 60
- CMLFRMDBDNHMRA-UHFFFAOYSA-N 2h-1,2-benzoxazine Chemical compound C1=CC=C2C=CNOC2=C1 CMLFRMDBDNHMRA-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 239000011259 mixed solution Substances 0.000 claims abstract description 28
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000002904 solvent Substances 0.000 claims abstract description 5
- 239000000178 monomer Substances 0.000 claims abstract description 4
- 239000000758 substrate Substances 0.000 claims abstract description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 5
- 229920006267 polyester film Polymers 0.000 claims description 5
- BCHZICNRHXRCHY-UHFFFAOYSA-N 2h-oxazine Chemical compound N1OC=CC=C1 BCHZICNRHXRCHY-UHFFFAOYSA-N 0.000 claims description 4
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 4
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 claims description 4
- 125000005605 benzo group Chemical group 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- BYVSMDBDTBXASR-UHFFFAOYSA-N 5,6-dihydro-4h-oxazine Chemical compound C1CON=CC1 BYVSMDBDTBXASR-UHFFFAOYSA-N 0.000 claims 3
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims 2
- UFTHEDBYLPFRDP-UHFFFAOYSA-N 5,6-dihydro-2h-oxazine Chemical compound C1CC=CNO1 UFTHEDBYLPFRDP-UHFFFAOYSA-N 0.000 claims 1
- 235000014655 lactic acid Nutrition 0.000 claims 1
- 239000004310 lactic acid Substances 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 10
- 230000000903 blocking effect Effects 0.000 abstract description 10
- 239000001301 oxygen Substances 0.000 abstract description 10
- 229910052760 oxygen Inorganic materials 0.000 abstract description 10
- 239000011248 coating agent Substances 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 3
- 238000005538 encapsulation Methods 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 229920002521 macromolecule Polymers 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000004806 packaging method and process Methods 0.000 abstract description 2
- 229920001169 thermoplastic Polymers 0.000 abstract description 2
- 239000004416 thermosoftening plastic Substances 0.000 abstract description 2
- 239000010408 film Substances 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000011056 performance test Methods 0.000 description 6
- 150000005130 benzoxazines Chemical class 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- 206010013786 Dry skin Diseases 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- NAEJIUKUFIHRKT-UHFFFAOYSA-N 3-phenyl-6-[2-(3-phenyl-2,4-dihydro-1,3-benzoxazin-6-yl)propan-2-yl]-2,4-dihydro-1,3-benzoxazine Chemical compound C=1C=C2OCN(C=3C=CC=CC=3)CC2=CC=1C(C)(C)C(C=C1C2)=CC=C1OCN2C1=CC=CC=C1 NAEJIUKUFIHRKT-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940106691 bisphenol a Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000004893 oxazines Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 229920000052 poly(p-xylylene) Polymers 0.000 description 1
- 229920006381 polylactic acid film Polymers 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
- C08K5/357—Six-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
本发明公开了一种聚乳酸和苯并噁嗪共混薄膜及其制备方法。包含作为基体材料聚乳酸和作为改性材料苯并噁嗪两种材料，苯并噁嗪在共混薄膜中的质量分数为5~30 wt%。其制备方法为：制备聚乳酸和苯并噁嗪的混合溶液；将聚乳酸和苯并噁嗪的混合溶液刮涂在基材的一侧表面上；干燥去除溶剂，从基材表面剥离，得到聚乳酸和苯并噁嗪共混薄膜。本发明的制备方法简单易行，适合工业化生产；充分利用了热固性苯并噁嗪树脂单体和热塑性高分子材料聚乳酸的性能特点，所得的共混薄膜同时具有较好的力学性能和阻隔氧气性能，在产品封装或包装领域有广阔的应用前景。
Description
技术领域
本发明涉及一种薄膜及其制备方法，尤其是涉及一种聚乳酸和苯并噁嗪共混薄膜及其制备方法。
背景技术
作为一种绿色高分子材料，聚乳酸在产品封装或包装薄膜领域有较好的应用价值。然而，聚乳酸本身的力学性能和阻隔氧气性能不太理想，从而影响了其应用。因此，如何提高聚乳酸的力学性能和阻隔氧气性能是备受业内关注的研究课题之一。目前，国内外研究者们在对其进行改性时，往往难于兼顾力学性能和阻隔性能；在提高阻隔性能时，力学性能提高幅度有限，甚至降低。因此，如何采用简单且有效的方法制备阻隔性能高且力学性能好的聚乳酸薄膜是一个亟待解决的问题。
发明内容
为了克服背景技术中存在的问题，本发明的目的在于提供一种聚乳酸和苯并噁嗪共混薄膜及其制备方法。
为达到上述目的，本发明解决其技术问题采用的技术方案是：
一、一种聚乳酸和苯并噁嗪共混薄膜：
包含聚乳酸和苯并噁嗪两种材料，聚乳酸为基体材料，苯并噁嗪为改性材料，苯并噁嗪在共混薄膜中的质量分数为5～30wt％。
所述苯并噁嗪为分子结构中含有3,4-二氢-3-取代基-2H-1,3-苯并噁嗪结构的苯并噁嗪树脂单体。
二、一种聚乳酸和苯并噁嗪共混薄膜的制备方法，包括以下步骤：
步骤1)制备聚乳酸和苯并噁嗪的混合溶液；
步骤2)将聚乳酸和苯并噁嗪的混合溶液刮涂在基材的一侧表面上；
步骤3)干燥去除溶剂，从基材表面剥离，得到所述的聚乳酸和苯并噁嗪共混薄膜。
步骤1)中所述混合溶液中聚乳酸和苯并噁嗪的质量含量为10～50wt％，聚乳酸和苯并噁嗪的质量比为19-7:1-3。
步骤1)中所述聚乳酸和苯并噁嗪的混合溶液的制备方法，是将干燥的聚乳酸和苯并噁嗪加入有机溶剂，搅拌至均匀透明。
步骤2)中所述将聚乳酸和苯并噁嗪的混合溶液刮涂在基材的一侧表面上的方法，是将聚乳酸和苯并噁嗪的混合溶液浇注在基材的一侧表面上，采用刮膜工具将该混合溶液刮涂在基材一侧表面上。
步骤2)中所述基材为玻璃板或聚酯薄膜。
步骤3)中所述干燥去除溶剂，其方法为：常温～40℃环境下，放置1～15天。
步骤3)中所述有机溶剂为三氯甲烷或二氯甲烷。
所述刮膜工具为玻璃棒或美工刀片。
与背景技术相比，本发明的有益效果是：
本发明的制备方法简单易行，适合工业化生产；本发明充分利用了热固性苯并噁嗪树脂单体和热塑性高分子材料聚乳酸的性能特点，所得的共混薄膜同时具有较好的力学性能和阻隔氧气性能，在产品封装或包装领域有广阔的应用前景。
具体实施方式
下面结合具体实施例对本发明作进一步详细说明。
实施例中的聚乳酸为市购材料，牌号为3051D；苯并噁嗪，化学名为6,6'-(propane-2,2-diyl)bis(3-phenyl-3,4-dihydro-2H-benzo[e][1,3]oxa-zine)，参考文献：(1)Ishida,H.；Rodriguez,Y.,Curing kinetics of a new benzoxazine-basedphenolic resin by differential scanning calorimetry.Polymer 1995,36(16),3151-3158.(2)Ning,X.；Ishida,H.,Phenolic materials via ring-opening polymerization:Synthesis and characterization of bisphenol-A based benzoxazines and theirpolymers.Journal of Polymer Science Part A:Polymer Chemistry 1994,32(6),1121-1129.。
实施例1：
(1)将9.5g干燥的聚乳酸和0.5g苯并噁嗪加入90mL三氯甲烷中，磁力搅拌至均匀透明，形成聚乳酸和苯并噁嗪的混合溶液；
(2)将聚乳酸和苯并噁嗪的混合溶液浇注在玻璃板的一侧表面上，采用玻璃棒将该混合溶液刮涂在玻璃板一侧表面上；
(3)室温下，放置15天，从玻璃板表面剥离，得到所述的聚乳酸和苯并噁嗪共混薄膜。
力学性能测试结果见表1，阻隔氧气性能测试结果见表1。
实施例2：
(1)将9.0g干燥的聚乳酸和1.0g苯并噁嗪加入20mL二氯甲烷中，磁力搅拌至均匀透明，形成聚乳酸和苯并噁嗪的混合溶液；
(2)将聚乳酸和苯并噁嗪的混合溶液浇注在聚酯膜的一侧表面上，采用玻璃棒将该混合溶液刮涂在聚酯膜一侧表面上；
(3)30℃下，放置10天，从聚酯膜表面剥离，得到所述的聚乳酸和苯并噁嗪共混薄膜。
力学性能测试结果见表1，阻隔氧气性能测试结果见表1。
实施例3：
(1)将7.0g干燥的聚乳酸和3.0g苯并噁嗪加入10mL二氯甲烷中，磁力搅拌至均匀透明，形成聚乳酸和苯并噁嗪的混合溶液；
(2)将聚乳酸和苯并噁嗪的混合溶液浇注在玻璃板的一侧表面上，采用美工刀片将该混合溶液刮涂在玻璃板一侧表面上；
(3)40℃下，放置1天，从玻璃板表面剥离，得到所述的聚乳酸和苯并噁嗪共混薄膜。
力学性能测试结果见表1，阻隔氧气性能测试结果见表1。
本发明各个实施例均进行了力学性能测试和阻隔氧气性能测试，力学性能测试结果如表1所示，阻隔氧气性能测试结果如表1所示。力学性能测试方法：万能试验机(Instron5943，传感器100N，美国)，样品(3×30mm，每组至少五次)，速度10mm/min，标距10mm。阻隔氧气性能测试方法：气体渗透仪(兰光VAC-V1，中国)，温度23℃，相对湿度50％，每组样品至少三次。
表1
分析表1中数据可知，本发明的苯并噁嗪在其质量含量为5～10wt％时对聚乳酸起到了良好的改性作用，同时提高了力学性能和阻隔氧气性能。
上述实施例仅用来解释本发明，而不是限制本发明的保护范围。在本发明的精神实质和权利要求保护范围内做出的任何等效变化或修饰，都视为在本发明的保护范围内。
Claims (6)
1.一种聚乳酸和苯并噁嗪共混薄膜，其特征在于：包含聚乳酸和苯并噁嗪两种材料，聚乳酸为基体材料，苯并噁嗪为改性材料，苯并噁嗪在共混薄膜中的质量分数为5~30 wt%；
所述苯并噁嗪为分子结构中含有3,4-二氢-3-取代基-2H-1,3-苯并噁嗪结构的苯并噁嗪树脂单体；该薄膜的制备方法包括以下步骤：
步骤1)制备聚乳酸和苯并噁嗪的混合溶液；所述混合溶液中聚乳酸和苯并噁嗪的质量含量为10~50 wt%，聚乳酸和苯并噁嗪的质量比为19-7:1-3；
步骤2)将聚乳酸和苯并噁嗪的混合溶液刮涂在基材的一侧表面上；是将聚乳酸和苯并噁嗪的混合溶液浇注在基材的一侧表面上，采用刮膜工具将该混合溶液刮涂在基材一侧表面上；
步骤3)干燥去除溶剂，其方法为：常温～40℃环境下，放置1~15天；从基材表面剥离，得到所述的聚乳酸和苯并噁嗪共混薄膜。
2.一种用于权利要求1所述的聚乳酸和苯并噁嗪共混薄膜的制备方法，其特征在于，该方法包括以下步骤：
步骤1)制备聚乳酸和苯并噁嗪的混合溶液；
步骤2)将聚乳酸和苯并噁嗪的混合溶液刮涂在基材的一侧表面上；是将聚乳酸和苯并噁嗪的混合溶液浇注在基材的一侧表面上，采用刮膜工具将该混合溶液刮涂在基材一侧表面上；
步骤3)干燥去除溶剂，从基材表面剥离，得到所述的聚乳酸和苯并噁嗪共混薄膜。
3.根据权利要求2所述的一种聚乳酸和苯并噁嗪共混薄膜的制备方法，其特征在于：步骤1)中所述聚乳酸和苯并噁嗪的混合溶液的制备方法，是将干燥的聚乳酸和苯并噁嗪加入有机溶剂，搅拌至均匀透明。
4.根据权利要求2所述的一种聚乳酸和苯并噁嗪共混薄膜的制备方法，其特征在于：步骤2)中所述基材为玻璃板或聚酯薄膜。
5.根据权利要求3所述的一种聚乳酸和苯并噁嗪共混薄膜的制备方法，其特征在于：步骤1)中所述有机溶剂为三氯甲烷或二氯甲烷。
6.根据权利要求2所述的一种聚乳酸和苯并噁嗪共混薄膜的制备方法，其特征在于：所述刮膜工具为玻璃棒或美工刀片。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610831305.6A CN106336635B (zh) | 2016-09-19 | 2016-09-19 | 一种聚乳酸和苯并噁嗪共混薄膜及其制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610831305.6A CN106336635B (zh) | 2016-09-19 | 2016-09-19 | 一种聚乳酸和苯并噁嗪共混薄膜及其制备方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106336635A CN106336635A (zh) | 2017-01-18 |
| CN106336635B true CN106336635B (zh) | 2018-04-17 |
Family
ID=57840232
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610831305.6A Active CN106336635B (zh) | 2016-09-19 | 2016-09-19 | 一种聚乳酸和苯并噁嗪共混薄膜及其制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106336635B (zh) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111361245A (zh) * | 2020-03-11 | 2020-07-03 | 宁波东旭成新材料科技有限公司 | 一种阻隔膜 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008266470A (ja) * | 2007-04-20 | 2008-11-06 | Unitika Ltd | ポリ乳酸系樹脂組成物、およびそれを成形してなる成形体 |
| CN102677193A (zh) * | 2012-05-03 | 2012-09-19 | 东华大学 | 一种酚醛树脂基纳米活性碳纤维材料的制备方法 |
| CN102653891A (zh) * | 2012-05-03 | 2012-09-05 | 东华大学 | 一种具有磁性的苯并噁嗪基碳纳米纤维材料的制备方法 |
| CN103225132A (zh) * | 2013-02-28 | 2013-07-31 | 江苏竹溪活性炭有限公司 | 一种生物活性碳纤维的制备方法 |
-
2016
- 2016-09-19 CN CN201610831305.6A patent/CN106336635B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106336635A (zh) | 2017-01-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Ocando et al. | Nanostructured thermoplastic elastomers based on SBS triblock copolymer stiffening with low contents of epoxy system. Morphological behavior and mechanical properties | |
| Jia et al. | Synthesis of a novel polyester plasticizer based on glyceryl monooleate and its application in poly (vinyl chloride) | |
| CN105585827A (zh) | 一种可生物降解聚酯组合物 | |
| Yuan et al. | Poly (lactic acid) plasticized by biodegradable glyceryl lactate | |
| Lv et al. | The morphology, rheological, and mechanical properties of wood flour/starch/poly (lactic acid) blends | |
| CN106336635B (zh) | 一种聚乳酸和苯并噁嗪共混薄膜及其制备方法 | |
| Soman et al. | FTIR studies of doped PMMA‐PVC blend system | |
| CN104327493B (zh) | 纳米二氧化硅改性pva-ep-pu互穿聚合物网络复合材料的制备方法 | |
| Jin et al. | Simultaneously reinforcing and toughening of poly (propylene carbonate) by epoxy-terminated hyperbranched polymer (EHBP) through micro-crosslinking | |
| JP4235697B2 (ja) | 漆系塗料、その製造方法及び漆塗装材 | |
| Rosen‐Kligvasser et al. | LLDPE films containing monoester of oleic acid grafted to silica particles as durable antifog additives | |
| Mouffok et al. | Artificial weathering effect on the structure and properties of polypropylene/polyamide‐6 blends compatibilized with PP‐g‐MA | |
| Song et al. | A one‐step strategy for aliphatic poly (carbonate‐ester) s with high performance derived from CO2, propylene oxide and l‐lactide | |
| CN115418085A (zh) | 一种生物可降解pbat/pla共混薄膜 | |
| Sangroniz et al. | Improving the barrier character of polylactide/phenoxy immiscible blend using poly (lactide‐co‐ɛ‐caprolactone) block copolymer as a compatibilizer | |
| Guo et al. | Preparation and properties of core [poly (styrene‐n‐butyl acrylate)]–shell [poly (styrene–methyl methacrylate–vinyl triethoxide silane)] structured latex particles with self‐crosslinking characteristics | |
| CN106336634B (zh) | 一种改进的生物降解购物袋及其制备方法 | |
| Kong et al. | Tannic acid as a natural crosslinker for catalyst-free silicone elastomers from hydrogen bonding to covalent bonding | |
| CN114573965A (zh) | 一种高阻隔生物可降解材料及其制备方法和应用 | |
| CN103881336A (zh) | 一种己二酸-对苯二甲酸-丁二醇三元共聚酯/氧化石墨烯复合材料及其制备方法 | |
| CN106674970B (zh) | 一种聚碳酸亚丙酯/ppc型聚氨酯弹性体高强度复合材料及其制备方法 | |
| Nakamura et al. | Glass transition behaviour of PMMA/PVA incompatible blend | |
| CN108165134A (zh) | 耐核辐射的纳米碳增强高分子涂料及其制备方法 | |
| Mehtiö et al. | Crosslinkable poly (lactic acid)‐based materials: Biomass‐derived solution for barrier coatings | |
| Tsujimoto et al. | Laccase‐Catalyzed Curing of Natural Phenolic Lipids and Product Properties |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |