CN106335946A - Highly efficient environment friendly waste water treatment agent - Google Patents

Highly efficient environment friendly waste water treatment agent Download PDF

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Publication number
CN106335946A
CN106335946A CN201611019192.6A CN201611019192A CN106335946A CN 106335946 A CN106335946 A CN 106335946A CN 201611019192 A CN201611019192 A CN 201611019192A CN 106335946 A CN106335946 A CN 106335946A
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parts
environment friendly
straw
distilled water
acid
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不公告发明人
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Zhengzhou Zhengxian Pharmaceutical Technology Co Ltd
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Zhengzhou Zhengxian Pharmaceutical Technology Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00—Nature of the contaminant
    • C02F2101/10—Inorganic compounds
    • C02F2101/20—Heavy metals or heavy metal compounds

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Sludge (AREA)
  • Processing Of Solid Wastes (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The invention discloses a highly efficient environment friendly waste water treatment agent which comprises, by weight, 5 to 10 parts of carboxymethylcellulose, 5 to 15 parts of sodium polyacrylate, 0.1 to 0.3 part of Amino Trimethylene Phosphonic Acid, 0.5 to 2 portions of ethylene glycol diethylether diamine tetraacetic acid, 10 to 25 parts of fly ash, 5 to 10 parts of sodium carbonate, 5 to 7 parts of Ipomoea batatas, 3 to 5 parts of sunflower straw, 10 to 15 parts of activated sludge, 5 to 7 parts of shaddock peel, 5 to 10 parts of Firmiana simplex fallen leaves, 0.5 to 1 part of jasmine straw, 0.1 to 0.5 part of methyl acetate and 50 to 180 parts of distilled water. The highly efficient environment friendly waste water treatment agent provided by the invention has stark decontamination effects to the Zn2 +, Cu2 +, Pd2 +, Cd2 +, chromium and manganese in the waster water polluted by heavy metal. The agent can effectively reduces the content of COD ad SS in the waster water; the treatment results are optimal with easily acquirable and cheap raw materials. The waster water treatment agent is prone to decompose and poses no negative impacts to the environment which make it more economically feasible and environment friendly.

Description

A kind of high-efficiency environment friendly sewage-treating agent
Technical field
The present invention relates to technical field of sewage, specifically a kind of high-efficiency environment friendly sewage-treating agent.
Background technology
China is the country of a shortage of water resources, and water resource of per capita is only the 1/4 of the world, and the distribution of water resource Seriously uneven, how to alleviate that water resource doctor is weary and the problems such as pollution oneself through becoming an instant problem.Solve to lack Water problems, in addition to increasing income and decreasing expenditure, comprehensively utilizing, pollution treatment oneself be increasingly becoming the mesh of the basic principle that China must adhere to for a long time Before, countries in the world process for treating heavy-metal waste water mainly has three classes: the first kind is that heavy metal ions in wastewater is passed through chemistry The method that reaction removes, including neutralization precipitation method, sulphide precipitation, ferrite coprecipitation, chemical reduction method, electrochemistry also Former method and high molecular heavy metals trapping agent method etc..Equations of The Second Kind is to make the heavy metal in waste water in the condition not changing its chemical form Under carry out adsorbing, concentrate, detached method, including absorption, solvent extraction, evaporation and freezing method, ion exchange and membrance separation etc.. 3rd class is made by the method that the effects such as the flocculation of microorganism or plant, absorption, accumulation, enrichment remove heavy metal in waste water, its Include bioflocculation, biochemical process and plant ecological reparation etc..
But, existing heavy metal containing wastewater treatment agent haves the shortcomings that processing cost is higher, there is secondary pollution, processes effect Fruit has much room for improvement.
Chinese invention patent 201310726188.3 disclose in March, 2016 No. 2 a kind of heavy metal-polluted water treatment agent and Its preparation method, described heavy metal-polluted water treatment agent includes the raw material of following weight portion: amino three methene unicorn acid 0.5-2 part, second Glycol diethyl ether ethylenediamine tetraacetic acid (EDTA) 1-5 part, sodium polyacrylate 10-20 part, diethylene triamine pentacetic acid (DTPA) five sodium 5-15 part, poly- Radix Asparagi Propylhomoserin 10-20 part, starch xanthic acid cruel 20-30 part, graphene nano layer/mnoz complex 3-6 part, cross-linked rectorite 15-20 Part, aluminium polychlorid 10-30 part, shitosan-graphene composite material 5-10 part, balance of deionized water；The huge sum of money of the present invention Belong to sewage-treating agent purity high, avirulence, operator is no affected, after process the problems such as water non-secondary pollution.But its tool Have the shortcomings that raw material is not easy to obtain, cost of material is higher, production cost is high, and not degradable, environment is had an impact, inadequate ring Protect.
Content of the invention
It is an object of the invention to provide a kind of high-efficiency environment friendly sewage-treating agent, to solve proposition in above-mentioned background technology Problem.
For achieving the above object, the following technical scheme of present invention offer:
A kind of high-efficiency environment friendly sewage-treating agent, including the raw material composition of following weight fraction: carboxymethyl cellulose 5-10 part, Sodium polyacrylate 5-15 part, amino three methene unicorn acid 0.1-0.3 part, ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA) 0.5-2 part, flyash 10-25 part, sodium carbonate 5-10 part, sweet potato vine 5-7 part, sunflower straw 3-5 part, activated sludge 10-15 part, pomelo peel 5-7 part, Phoenix tree fallen leaves 5-10 part, Flos Jasmini Sambac straw 0.5-1 part, methyl acetate 0.1-0.5 part, distilled water 50-180 part.
As the further scheme of the present invention: the raw material including following weight fraction forms: carboxymethyl cellulose 6-8 part, Sodium polyacrylate 6-12 part, amino three methene unicorn acid 0.1-0.2 part, ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA) 0.6-1.5 part, fine coal Grey 15-20 part, sodium carbonate 6-9 part, sweet potato vine 6-7 part, sunflower straw 3-4 part, activated sludge 11-13 part, pomelo peel 5-6 Part, phoenix tree fallen leaves 5-9 part, Flos Jasmini Sambac straw 0.6-0.8 part, methyl acetate 0.2-0.3 part, distilled water 70-160 part.
As the present invention further scheme: the raw material including following weight fraction forms: 7 parts of carboxymethyl cellulose, Sodium polyacrylate 10,0.15 part of amino three methene unicorn acid, 1 part of ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), 18 parts of flyash, sodium carbonate 7 parts, 6.5 parts of sweet potato vine, 3.5 parts of sunflower straw, 12 parts of activated sludge, 5.5 parts of pomelo peel, phoenix tree fall leaves 6 parts, Flos Jasmini Sambac 0.7 part of straw, 0.25 part of methyl acetate, 100 parts of distilled water.
As the present invention further scheme: the raw material including following weight fraction forms: 8 parts of carboxymethyl cellulose, 11 parts of sodium polyacrylate, amino three methene unicorn acid 0.18 part, 1.25 parts of ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), 19 parts of flyash, 8 parts of sodium carbonate, 6.8 parts of sweet potato vine, 3.6 parts of sunflower straw, 11.3 parts of activated sludge, 5.9 parts of pomelo peel, phoenix tree fallen leaves 8 Part, 0.75 part of Flos Jasmini Sambac straw, 0.27 part of methyl acetate, 150 parts of distilled water.
As the present invention further scheme: include the raw material composition of following weight fraction: carboxymethyl cellulose 6.5 Part, 7 parts of sodium polyacrylate, amino three methene unicorn acid 0.13 part, 0.9 part of ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), 17 parts of flyash, 6.2 parts of sodium carbonate, 6.1 parts of sweet potato vine, 3.4 parts of sunflower straw, 12.8 parts of activated sludge, 5.2 parts of pomelo peel, phoenix tree fallen leaves 7.2 parts, 0.68 part of Flos Jasmini Sambac straw, 0.24 part of methyl acetate, 85 parts of distilled water.
A kind of preparation method of high-efficiency environment friendly sewage-treating agent, concretely comprises the following steps: (1) weighs each raw material according to weight portion, Standby；(2) flyash, sodium carbonate and sweet potato vine are stirred, be then placed in crucible, in Muffle kiln roasting 1-2 hour, Roasting time 20-30 minute, 150-180 DEG C of sintering temperature, it is then passed through grinding, crosses 80-100 mesh sieve, obtain powder a, standby； (3) open container, add distilled water, distilled water is warming up to 80-105 DEG C, add carboxymethyl cellulose, sodium polyacrylate, ammonia The acid of base three methene unicorn and ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stir 5-15 minute, and every kind of raw material adds all interval 1-2 minutes, Stir in interpolation；(4) step (3) gains are cooled to 55-65 DEG C, add activated sludge and methyl acetate, stirring 1-3 divides Clock；(5) by sunflower straw, pomelo peel, phoenix tree fallen leaves, Flos Jasmini Sambac straw after over cleaning, drying, grinding, sieve, obtain Powder b；(6) by powder a and powder b mix homogeneously, it is subsequently adding in step (4) gains, vibration of ultrasonic wave 5-8 minute, that is, Obtain finished product.
As the present invention further scheme: flyash, sodium carbonate and sweet potato vine are stirred by described step (2), It is then placed in crucible, in Muffle kiln roasting 1.5 hours, roasting time 25 minutes, 160 DEG C of sintering temperature, be then passed through grinding Grind, cross 90 mesh sieves, obtain powder a, standby.
As the present invention further scheme: described step (3) opens container, add distilled water, distilled water is heated up To 95 DEG C, add carboxymethyl cellulose, sodium polyacrylate, the acid of amino three methene unicorn and ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stir Mix 8 minutes, every kind of raw material interpolation is all spaced 1.5 minutes, stirs in interpolation.
As the present invention further scheme: step (3) gains are cooled to 60 DEG C by described step (4), add and live Property mud and methyl acetate, stir 2 minutes.
Compared with prior art, the invention has the beneficial effects as follows:
The high-efficiency environment friendly sewage-treating agent of the present invention, is compounded by above-mentioned raw materials, plays synergism, can capture water body In many kinds of metal ions, the zn in heavy metal sewage2+、cu2+、pd2+、cd2+, chromium, manganese there is good place to go effect, energy Effectively reduce cod, ss content in sewage；The high-efficiency environment friendly sewage-treating agent treatment effect of the present invention is good, and raw material is easy to get, former Expect low cost, and this sewage treating machine easily decomposes, and environment will not be impacted, more economical environmental protection；Adding in sewage should After medicament, float is flocculated at once, and precipitation is quick；Sewage after process can reach discharge standard, and Floc strength is high, hydrophobicity Can be good；The high-efficiency environment friendly sewage-treating agent purity of the present invention is high, and avirulence no affects on operator, after process, water is no secondary The problems such as pollution.
Specific embodiment
With reference to specific embodiment, the technical scheme of this patent is described in more detail.
Embodiment 1
A kind of high-efficiency environment friendly sewage-treating agent, including the raw material composition of following weight fraction: 5 parts of carboxymethyl cellulose, poly- 5 parts of sodium acrylate, 0.1 part of amino three methene unicorn acid, 0.5 part of ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), 10 parts of flyash, sodium carbonate 5 parts, 5 parts of sweet potato vine, 3 parts of sunflower straw, 10 parts of activated sludge, 5 parts of pomelo peel, phoenix tree fall leaves 5 parts, Flos Jasmini Sambac straw 0.5 part, 0.1 part of methyl acetate, 50 parts of distilled water.
A kind of preparation method of high-efficiency environment friendly sewage-treating agent, concretely comprises the following steps: (1) weighs each raw material according to weight portion, Standby；(2) flyash, sodium carbonate and sweet potato vine are stirred, be then placed in crucible, in Muffle kiln roasting 1 hour, roasting 20 minutes burning time, 150 DEG C of sintering temperature, it is then passed through grinding, crosses 80 mesh sieves, obtain powder a, standby；(3) open container, Add distilled water, distilled water is warming up to 80 DEG C, add carboxymethyl cellulose, sodium polyacrylate, the acid of amino three methene unicorn and second Glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stirs 5 minutes, and every kind of raw material interpolation is all spaced 1 minute, stirs in interpolation；(4) by step (3) gains are cooled to 55 DEG C, add activated sludge and methyl acetate, stir 1 minute；(5) by sunflower straw, pomelo peel, Phoenix tree fallen leaves, Flos Jasmini Sambac straw, after over cleaning, drying, grinding, sieve, obtain powder b；(6) powder a and powder b is mixed Close uniformly, be subsequently adding in step (4) gains, vibration of ultrasonic wave 5 minutes, get product.
Embodiment 2
A kind of high-efficiency environment friendly sewage-treating agent, including the raw material composition of following weight fraction: 10 parts of carboxymethyl cellulose, poly- 15 parts of sodium acrylate, 0.3 part of amino three methene unicorn acid, 2 parts of ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), 25 parts of flyash, sodium carbonate 10 parts, 7 parts of sweet potato vine, 5 parts of sunflower straw, 15 parts of activated sludge, 7 parts of pomelo peel, phoenix tree fall leaves 10 parts, Flos Jasmini Sambac straw 1 part, 0.5 part of methyl acetate, 180 parts of distilled water.
A kind of preparation method of high-efficiency environment friendly sewage-treating agent, concretely comprises the following steps: (1) weighs each raw material according to weight portion, Standby；(2) flyash, sodium carbonate and sweet potato vine are stirred, be then placed in crucible, in Muffle kiln roasting 2 hours, roasting 30 minutes burning time, 180 DEG C of sintering temperature, it is then passed through grinding, crosses 100 mesh sieves, obtain powder a, standby；(3) open container, Add distilled water, distilled water is warming up to 105 DEG C, add carboxymethyl cellulose, sodium polyacrylate, the acid of amino three methene unicorn and second Glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stirs 15 minutes, and every kind of raw material interpolation is all spaced 2 minutes, stirs in interpolation；(4) will walk Suddenly (3) gains are cooled to 65 DEG C, add activated sludge and methyl acetate, stir 3 minutes；(5) by sunflower straw, Fructus Citri grandiss Skin, phoenix tree fallen leaves, Flos Jasmini Sambac straw, after over cleaning, drying, grinding, sieve, obtain powder b；(6) by powder a and powder b Mix homogeneously, is subsequently adding in step (4) gains, vibration of ultrasonic wave 8 minutes, gets product.
Embodiment 3
A kind of high-efficiency environment friendly sewage-treating agent, including the raw material composition of following weight fraction: 7 parts of carboxymethyl cellulose, poly- Sodium acrylate 10,0.15 part of amino three methene unicorn acid, 1 part of ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), 18 parts of flyash, sodium carbonate 7 Part, 6.5 parts of sweet potato vine, 3.5 parts of sunflower straw, 12 parts of activated sludge, 5.5 parts of pomelo peel, phoenix tree fallen leaves 6 parts, Flos Jasmini Sambac 0.7 part of straw, 0.25 part of methyl acetate, 100 parts of distilled water.
A kind of preparation method of high-efficiency environment friendly sewage-treating agent, concretely comprises the following steps: (1) weighs each raw material according to weight portion, Standby；(2) flyash, sodium carbonate and sweet potato vine are stirred, be then placed in crucible, in Muffle kiln roasting 1.5 hours, Roasting time 25 minutes, 160 DEG C of sintering temperature, it is then passed through grinding, crosses 90 mesh sieves, obtain powder a, standby；(3) open appearance Device, add distilled water, distilled water is warming up to 95 DEG C, add carboxymethyl cellulose, sodium polyacrylate, amino three methene unicorn acid and Ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stirs 8 minutes, and every kind of raw material interpolation is all spaced 1.5 minutes, stirs in interpolation；(4) will Step (3) gains are cooled to 60 DEG C, add activated sludge and methyl acetate, stir 2 minutes；(5) by sunflower straw, Fructus Citri grandiss Skin, phoenix tree fallen leaves, Flos Jasmini Sambac straw, after over cleaning, drying, grinding, sieve, obtain powder b；(6) by powder a and powder b Mix homogeneously, is subsequently adding in step (4) gains, vibration of ultrasonic wave 5-8 minute, gets product.
Comparative example 1
A kind of high-efficiency environment friendly sewage-treating agent, including the raw material composition of following weight fraction: 7 parts of carboxymethyl cellulose, poly- Sodium acrylate 10,0.15 part of amino three methene unicorn acid, 1 part of ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), 18 parts of flyash, sodium carbonate 7 Part, 6.5 parts of sweet potato vine, 3.5 parts of sunflower straw, 12 parts of activated sludge, 5.5 parts of pomelo peel, phoenix tree fallen leaves 6 parts, Flos Jasmini Sambac 0.7 part of straw, 100 parts of distilled water.
A kind of preparation method of high-efficiency environment friendly sewage-treating agent, concretely comprises the following steps: (1) weighs each raw material according to weight portion, Standby；(2) flyash, sodium carbonate and sweet potato vine are stirred, be then placed in crucible, in Muffle kiln roasting 1.5 hours, Roasting time 25 minutes, 160 DEG C of sintering temperature, it is then passed through grinding, crosses 90 mesh sieves, obtain powder a, standby；(3) open appearance Device, add distilled water, distilled water is warming up to 95 DEG C, add carboxymethyl cellulose, sodium polyacrylate, amino three methene unicorn acid and Ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stirs 8 minutes, and every kind of raw material interpolation is all spaced 1.5 minutes, stirs in interpolation；(4) will Step (3) gains are cooled to 60 DEG C, add activated sludge, stir 2 minutes；(5) by sunflower straw, pomelo peel, phoenix tree Fallen leaves, Flos Jasmini Sambac straw, after over cleaning, drying, grinding, sieve, obtain powder b；(6) by powder a and powder b mix homogeneously, It is subsequently adding in step (4) gains, vibration of ultrasonic wave 5-8 minute, get product.
Comparative example 2
A kind of high-efficiency environment friendly sewage-treating agent, including the raw material composition of following weight fraction: 7 parts of carboxymethyl cellulose, poly- Sodium acrylate 10,0.15 part of amino three methene unicorn acid, 1 part of ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), 18 parts of flyash, sodium carbonate 7 Part, 6.5 parts of sweet potato vine, 3.5 parts of sunflower straw, 12 parts of activated sludge, 5.5 parts of pomelo peel, phoenix tree fallen leaves 6 parts, acetic acid first 0.25 part of ester, 100 parts of distilled water.
A kind of preparation method of high-efficiency environment friendly sewage-treating agent, concretely comprises the following steps: (1) weighs each raw material according to weight portion, Standby；(2) flyash, sodium carbonate and sweet potato vine are stirred, be then placed in crucible, in Muffle kiln roasting 1.5 hours, Roasting time 25 minutes, 160 DEG C of sintering temperature, it is then passed through grinding, crosses 90 mesh sieves, obtain powder a, standby；(3) open appearance Device, add distilled water, distilled water is warming up to 95 DEG C, add carboxymethyl cellulose, sodium polyacrylate, amino three methene unicorn acid and Ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stirs 8 minutes, and every kind of raw material interpolation is all spaced 1.5 minutes, stirs in interpolation；(4) will Step (3) gains are cooled to 60 DEG C, add activated sludge and methyl acetate, stir 2 minutes；(5) by sunflower straw, Fructus Citri grandiss Skin, phoenix tree fallen leaves, after over cleaning, drying, grinding, sieve, obtain powder b；(6) by powder a and powder b mix homogeneously, so Add afterwards in step (4) gains, vibration of ultrasonic wave 5-8 minute, get product.
The high-efficiency environment friendly sewage-treating agent finished product 100mg/l of Application Example 1-3 and the preparation of comparative example 1-2 carries out heavy metal Wastewater treatment, treatment effect is as follows, unit (mg/l):
Project cod ss zn2+ cu2+ pd2+ cd2+ Chromium Manganese ph
Water sample 284 202 85 101 5.1 62 9 8 5.1
Embodiment 1 26 5.3 0.54 0.11 0.01 0.03 0.035 0.0007 7.1
Embodiment 2 24 5.5 0.61 0.10 0.02 0.05 0.029 0.0006 7.0
Embodiment 3 19 4.6 0.49 0.10 0.01 0.02 0.021 0.0005 7.0
Comparative example 1 88 54 1.38 5.28 0.65 0.19 0.18 0.019 6.2
Comparative example 2 76 49 2.54 5.98 0.58 0.37 0.098 0.018 6.0
As can be known from the above table, the zn in the high-efficiency environment friendly sewage-treating agent heavy metal sewage of the present invention2+、cu2+、pd2+、cd2 +, chromium, manganese there is good place to go effect.And Flos Jasmini Sambac straw be can be seen that by the contrast of embodiment 1-3 and comparative example 1-2 The effect of this sewage-treating agent can be greatly increased with methyl acetate.
The high-efficiency environment friendly sewage-treating agent of the present invention, is compounded by above-mentioned raw materials, plays synergism, can capture water body In many kinds of metal ions, the zn in heavy metal sewage2+、cu2+、pd2+、cd2+, chromium, manganese there is good place to go effect, energy Effectively reduce cod, ss content in sewage；The high-efficiency environment friendly sewage-treating agent treatment effect of the present invention is good, and raw material is easy to get, former Expect low cost, and this sewage treating machine easily decomposes, and environment will not be impacted, more economical environmental protection；Adding in sewage should After medicament, float is flocculated at once, and precipitation is quick；Sewage after process can reach discharge standard, and Floc strength is high, hydrophobicity Can be good；The high-efficiency environment friendly sewage-treating agent purity of the present invention is high, and avirulence no affects on operator, after process, water is no secondary The problems such as pollution.
Above the better embodiment of this patent is explained in detail, but this patent is not limited to above-mentioned embodiment party Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of without departing from this patent objective Make a variety of changes.

Claims (9)

1. a kind of high-efficiency environment friendly sewage-treating agent is it is characterised in that include the raw material composition of following weight fraction: carboxymethyl cellulose Plain 5-10 part, sodium polyacrylate 5-15 part, amino three methene unicorn acid 0.1-0.3 part, ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA) 0.5-2 Part, flyash 10-25 part, sodium carbonate 5-10 part, sweet potato vine 5-7 part, sunflower straw 3-5 part, activated sludge 10-15 part, Fructus Citri grandiss Sub- skin 5-7 part, phoenix tree fallen leaves 5-10 part, Flos Jasmini Sambac straw 0.5-1 part, methyl acetate 0.1-0.5 part, distilled water 50-180 Part.
2. high-efficiency environment friendly sewage-treating agent according to claim 1 is it is characterised in that include the raw material of following weight fraction Composition: carboxymethyl cellulose 6-8 part, sodium polyacrylate 6-12 part, amino three methene unicorn acid 0.1-0.2 part, ethylene glycol diethyl ether Ethylenediamine tetraacetic acid (EDTA) 0.6-1.5 part, flyash 15-20 part, sodium carbonate 6-9 part, sweet potato vine 6-7 part, sunflower straw 3-4 part, work Property mud 11-13 part, pomelo peel 5-6 part, phoenix tree fallen leaves 5-9 part, Flos Jasmini Sambac straw 0.6-0.8 part, methyl acetate 0.2-0.3 Part, distilled water 70-160 part.
3. high-efficiency environment friendly sewage-treating agent according to claim 1 and 2 is it is characterised in that include following weight fraction Raw material forms: 7 parts of carboxymethyl cellulose, sodium polyacrylate 10, amino three methene unicorn acid 0.15 part, ethylene glycol diethyl ether diamidogen four 1 part of acetic acid, 18 parts of flyash, 7 parts of sodium carbonate, 6.5 parts of sweet potato vine, 3.5 parts of sunflower straw, 12 parts of activated sludge, pomelo peel 5.5 parts, phoenix tree fall leaves 6 parts, 0.7 part of Flos Jasmini Sambac straw, 0.25 part of methyl acetate, 100 parts of distilled water.
4. high-efficiency environment friendly sewage-treating agent according to claim 1 and 2 is it is characterised in that include following weight fraction Raw material forms: 8 parts of carboxymethyl cellulose, 11 parts of sodium polyacrylate, amino three methene unicorn acid 0.18 part, ethylene glycol diethyl ether diamidogen 1.25 parts of tetraacethyl, 19 parts of flyash, 8 parts of sodium carbonate, 6.8 parts of sweet potato vine, 3.6 parts of sunflower straw, 11.3 parts of activated sludge, 5.9 parts of pomelo peel, 8 parts of phoenix tree fallen leaves, 0.75 part of Flos Jasmini Sambac straw, 0.27 part of methyl acetate, 150 parts of distilled water.
5. high-efficiency environment friendly sewage-treating agent according to claim 1 and 2 is it is characterised in that include following weight fraction Raw material forms: 6.5 parts of carboxymethyl cellulose, 7 parts of sodium polyacrylate, amino three methene unicorn acid 0.13 part, ethylene glycol diethyl ether two 0.9 part of amine tetraacethyl, 17 parts of flyash, 6.2 parts of sodium carbonate, 6.1 parts of sweet potato vine, 3.4 parts of sunflower straw, activated sludge 12.8 Part, 7.2 parts of 5.2 parts of pomelo peel, phoenix tree fallen leaves, 0.68 part of Flos Jasmini Sambac straw, 0.24 part of methyl acetate, 85 parts of distilled water.
6. a kind of preparation method of described high-efficiency environment friendly sewage-treating agent as arbitrary in claim 1-5 is it is characterised in that concrete Step is: (1) weighs each raw material according to weight portion, standby；(2) flyash, sodium carbonate and sweet potato vine are stirred, Ran Houfang Enter in crucible, in Muffle kiln roasting 1-2 hour, roasting time 20-30 minute, 150-180 DEG C of sintering temperature, be then passed through grinding Grind, cross 80-100 mesh sieve, obtain powder a, standby；(3) open container, add distilled water, distilled water is warming up to 80-105 DEG C, Add carboxymethyl cellulose, sodium polyacrylate, the acid of amino three methene unicorn and ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stirring 5-15 divides Clock, every kind of raw material adds all interval 1-2 minutes, stirs in interpolation；(4) step (3) gains are cooled to 55-65 DEG C, plus Enter activated sludge and methyl acetate, stir 1-3 minute；(5) by sunflower straw, pomelo peel, phoenix tree fallen leaves, Flos Jasmini Sambac straw After over cleaning, drying, grinding, sieve, obtain powder b；(6) by powder a and powder b mix homogeneously, it is subsequently adding step (4) In gains, vibration of ultrasonic wave 5-8 minute, get product.
7. the preparation method of high-efficiency environment friendly sewage-treating agent according to claim 6 is it is characterised in that described step (2) Flyash, sodium carbonate and sweet potato vine are stirred, is then placed in crucible, in Muffle kiln roasting 1.5 hours, roasting time 25 minutes, 160 DEG C of sintering temperature, it is then passed through grinding, crosses 90 mesh sieves, obtain powder a, standby.
8. the preparation method of high-efficiency environment friendly sewage-treating agent according to claim 6 is it is characterised in that described step (3) Open container, add distilled water, distilled water is warming up to 95 DEG C, add carboxymethyl cellulose, sodium polyacrylate, amino three methene Unicorn acid and ethylene glycol diethyl ether ethylenediamine tetraacetic acid (EDTA), stir 8 minutes, and every kind of raw material interpolation is all spaced 1.5 minutes, stirs in interpolation Mix.
9. the preparation method of high-efficiency environment friendly sewage-treating agent according to claim 6 is it is characterised in that described step (4) Step (3) gains are cooled to 60 DEG C, add activated sludge and methyl acetate, stir 2 minutes.
CN201611019192.6A 2016-11-17 2016-11-17 Highly efficient environment friendly waste water treatment agent Pending CN106335946A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107365042A (en) * 2017-09-01 2017-11-21 郑州大学 A kind of inorganic agent for benzopyrene pollution sludge and preparation method thereof
CN108751294A (en) * 2018-09-07 2018-11-06 滨州学院 Sewage-treating agent
CN113289584A (en) * 2021-07-05 2021-08-24 黑龙江省科学院高技术研究院 Preparation method and application of sunflower straw charcoal adsorbent

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CN103641226A (en) * 2013-12-26 2014-03-19 张�成 Heavy metal sewage treating agent and preparation method thereof
CN104163552A (en) * 2014-09-05 2014-11-26 郭云征 Organic wastewater treatment method
CN105565403A (en) * 2015-12-21 2016-05-11 天津欧盼科技开发有限公司 Preparation method of environment-friendly sewage treatment agent

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN103641226A (en) * 2013-12-26 2014-03-19 张�成 Heavy metal sewage treating agent and preparation method thereof
CN104163552A (en) * 2014-09-05 2014-11-26 郭云征 Organic wastewater treatment method
CN105565403A (en) * 2015-12-21 2016-05-11 天津欧盼科技开发有限公司 Preparation method of environment-friendly sewage treatment agent

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107365042A (en) * 2017-09-01 2017-11-21 郑州大学 A kind of inorganic agent for benzopyrene pollution sludge and preparation method thereof
CN108751294A (en) * 2018-09-07 2018-11-06 滨州学院 Sewage-treating agent
CN113289584A (en) * 2021-07-05 2021-08-24 黑龙江省科学院高技术研究院 Preparation method and application of sunflower straw charcoal adsorbent

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Application publication date: 20170118