CN106745358A - A kind of heavy metal-polluted water treatment agent and preparation method thereof - Google Patents

A kind of heavy metal-polluted water treatment agent and preparation method thereof Download PDF

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Publication number
CN106745358A
CN106745358A CN201611048609.1A CN201611048609A CN106745358A CN 106745358 A CN106745358 A CN 106745358A CN 201611048609 A CN201611048609 A CN 201611048609A CN 106745358 A CN106745358 A CN 106745358A
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China
Prior art keywords
parts
heavy metal
treatment agent
water treatment
polluted water
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CN201611048609.1A
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Chinese (zh)
Inventor
张春花
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Nanning Heivr Information Technology Co Ltd
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Nanning Heivr Information Technology Co Ltd
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Priority to CN201611048609.1A priority Critical patent/CN106745358A/en
Publication of CN106745358A publication Critical patent/CN106745358A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds

Abstract

Component the invention discloses a kind of heavy metal-polluted water treatment agent and preparation method thereof, including following parts by weight is constituted:15 25 parts of Sodium Polyacrylate, 10 30 parts of aluminum sulfate, 10 15 parts of iron chloride, 20 25 parts of activated sludge, 5 10 parts of tealeaves, 5 10 parts of sodium alginate, 13 parts of plant ash, 70 200 parts of deionized water.Many kinds of metal ions in the heavy metal-polluted water treatment agent heavy metal sewage has good clearance, and governance efficiency is high;And stable performance, sedimentation effect is good, and effluent quality is good, and processing method is simple, and processing cost is low;It is non-toxic and the heavy metal-polluted water treatment agent purity is high, on operator without influence, do not result in biological pollution and secondary pollution problem.

Description

A kind of heavy metal-polluted water treatment agent and preparation method thereof
Technical field
The present invention relates to technical field of sewage, specifically a kind of heavy metal-polluted water treatment agent and preparation method thereof.
Background technology
Heavy metal wastewater thereby refers to discharge in the industrial processes such as mining and metallurgy, machine-building, chemical industry, electronics, instrument containing weight The waste water of metal.Heavy metal wastewater thereby is arranged essentially from enterprises such as mine, smelting, electrolysis, plating, agricultural chemicals, medicine, paint, pigment The waste water for going out.The species of heavy metal in waste water, content and existing forms are different with different manufacturing enterprises.Heavy metal wastewater thereby is to one One of environmental pollution most serious and the industrial wastewater maximum to mankind's harm, its water quality and quantity is relevant with production technology.In waste water Heavy metal can not typically decompose destruction, can only shift its existence position and change its Material Form.Heavy metal pollution and other The pollution of organic compound is different.Many organic compounds can be by the net of nature physics, chemistry or biology in itself Change, make harmfulness reduction or release.And heavy metal has enriching, it is difficult to degrade in the environment.Current China is due in a huge sum of money In exploitation, smelting, the process of category, many heavy metals such as lead, mercury, cadmium, cobalt etc. is caused to cause sternly into big gas and water, soil The environmental pollution of weight.The heavy metal such as discharged with useless heavy metal mercury water, even if concentration is small, can also accumulate in algae and bed mud It is tired, adsorbed by fish and shellfish body surface, food chain concentration is produced, so as to cause public hazards.Metal is favourable in water body or harmful not only takes Depending on the species of metal, physicochemical property, but also concentration and the valence state of presence and form depending on metal, even if beneficial Metallic element concentration also has violent toxicity more than a certain numerical value, animals and plants is poisoned, or even dead.
At present, countries in the world process for treating heavy-metal waste water mainly has three classes:The first kind is that heavy metal ions in wastewater is led to Cross and the method that chemical reaction is removed occurs, including neutralization precipitation method, sulphide precipitation, ferrite coprecipitation, electronation Method, electrochemical reducing and high molecular heavy metals trapping agent method etc., but this method reaction time is more long, governance efficiency compared with It is low;Equations of The Second Kind is the side for making the heavy metal in waste water be adsorbed under conditions of its chemical form is not changed, concentrated, be separate Method, including absorption, solvent extraction, evaporation and freezing method, ion exchange and UF membrane etc., complex treatment process, treatment cost compared with It is high;3rd class is the method by the effect removal heavy metal in waste water such as flocculation, absorption, accumulation, enrichment of microorganism or plant, Including bioflocculation, biochemical process and plant ecological repair etc., this method exist high cost, technology it is immature, hold Easily cause the shortcoming of biological pollution.Therefore, in the urgent need to a kind of governance efficiency is high, low cost, administering method are simple, do not result in The heavy metal-polluted water treatment agent of biological pollution.
The content of the invention
It is an object of the invention to provide a kind of heavy metal-polluted water treatment agent and preparation method thereof, to solve above-mentioned background skill The problem proposed in art.
To achieve the above object, the present invention provides following technical scheme:
A kind of heavy metal-polluted water treatment agent, including the component of following parts by weight is constituted:Sodium Polyacrylate 15-25 parts, aluminum sulfate 10-30 parts, iron chloride 10-15 parts, activated sludge 20-25 parts, tealeaves 5-10 parts, sodium alginate 5-10 parts, plant ash 1-3 parts, Deionized water 70-200 parts.
As further scheme of the invention:Component composition including following parts by weight:22 parts of Sodium Polyacrylate, sulfuric acid 25 parts of aluminium, 13 parts of iron chloride, 22 parts of activated sludge, 9 parts of tealeaves, 6 parts of sodium alginate, 2 parts of plant ash, 90 parts of deionized water.
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs poly- third Olefin(e) acid sodium, aluminum sulfate, iron chloride, activated sludge, tealeaves, sodium alginate, plant ash, it is standby;(2)By activated sludge, tealeaves, grass Wood ash is added in pulverizer, and it is 80-110 mesh powder to crush, standby;(3)Sodium Polyacrylate, aluminum sulfate, iron chloride are added and gone In ionized water, using vibration of ultrasonic wave 15-20 minutes, mixed liquor I is obtained;(4)Sodium alginate, and side are added in mixed liquor I The stirring of addition side, obtains mixed liquor II;(5)Above-mentioned powder is added in mixed liquor II, is stirred 10-15 minutes, using ultrasound Ripple shakes 5-10 minutes, gets product.
As further scheme of the invention:The step(2)Activated sludge, tealeaves, plant ash are added into pulverizer In, it is 90 mesh powder to crush.
As further scheme of the invention:The step(3)Sodium Polyacrylate, aluminum sulfate, iron chloride are added and gone In ionized water, using vibration of ultrasonic wave 16 minutes, mixed liquor I is obtained.
As further scheme of the invention:The step(5)Above-mentioned powder is added in mixed liquor II, stirring 12 Minute, using vibration of ultrasonic wave 8 minutes.
Compared with prior art, the beneficial effects of the invention are as follows:
The heavy metal-polluted water treatment agent is compounded by above-mentioned raw materials, plays synergy, can capture the various metals in water body Many kinds of metal ions in ion, and heavy metal sewage has good clearance, and governance efficiency is high;Heavy metal of the invention Sewage-treating agent treatment effect is good, and stable performance, sedimentation effect is good, and effluent quality is good;And processing method is simple, is using When, only need to be by the dirty inorganic agent input water, processing cost is low;Sewage after treatment can reach discharge standard, floc sedimentation Intensity is high, and hydrophobic performance is good;Heavy metal-polluted water treatment agent purity of the invention is high, non-toxic, on operator without influence, will not Cause biological pollution and secondary pollution problem.
Specific embodiment
The technical scheme of this patent is described in more detail with reference to specific embodiment.
Embodiment 1
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs polyacrylic acid 15 parts of sodium, 10 parts of aluminum sulfate, 10 parts of iron chloride, 20 parts of activated sludge, 5 parts of tealeaves, 5 parts of sodium alginate, 1 part of plant ash, go from 70 parts of sub- water, it is standby;(2)By in activated sludge, tealeaves, plant ash addition pulverizer, it is 80 mesh powder to crush, standby;(3)Will Sodium Polyacrylate, aluminum sulfate, iron chloride are added in deionized water, using vibration of ultrasonic wave 15 minutes, obtain mixed liquor I;(4) Sodium alginate is added in mixed liquor I, and is stirred in addition, obtain mixed liquor II;(5)Above-mentioned powder is added to mixed liquor II In, stir 10 minutes, using vibration of ultrasonic wave 5 minutes, get product.
Embodiment 2
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs polyacrylic acid 25 parts of sodium, 30 parts of aluminum sulfate, 15 parts of iron chloride, 25 parts of activated sludge, 10 parts of tealeaves, 10 parts of sodium alginate, 3 parts of plant ash, go 200 parts of ionized water, it is standby;(2)By in activated sludge, tealeaves, plant ash addition pulverizer, it is 110 mesh powder to crush, standby; (3)During Sodium Polyacrylate, aluminum sulfate, iron chloride added into deionized water, using vibration of ultrasonic wave 20 minutes, mixed liquor I is obtained; (4)Sodium alginate is added in mixed liquor I, and is stirred in addition, obtain mixed liquor II;(5)Above-mentioned powder is added to mixed Close in liquid II, stir 15 minutes, using vibration of ultrasonic wave 10 minutes, get product.
Embodiment 3
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs polyacrylic acid 22 parts of sodium, 25 parts of aluminum sulfate, 13 parts of iron chloride, 22 parts of activated sludge, 9 parts of tealeaves, 6 parts of sodium alginate, 2 parts of plant ash, go from 90 parts of sub- water, it is standby;(2)By in activated sludge, tealeaves, plant ash addition pulverizer, it is 90 mesh powder to crush, standby;(3)Will Sodium Polyacrylate, aluminum sulfate, iron chloride are added in deionized water, using vibration of ultrasonic wave 16 minutes, obtain mixed liquor I;(4) Sodium alginate is added in mixed liquor I, and is stirred in addition, obtain mixed liquor II;(5)Above-mentioned powder is added to mixed liquor II In, stir 12 minutes, using vibration of ultrasonic wave 8 minutes, get product.
Embodiment 4
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs polyacrylic acid 18 parts of sodium, 19 parts of aluminum sulfate, 14 parts of iron chloride, 24 parts of activated sludge, 7 parts of tealeaves, 8 parts of sodium alginate, 2 parts of plant ash, go from 180 parts of sub- water, it is standby;(2)By in activated sludge, tealeaves, plant ash addition pulverizer, it is 100 mesh powder to crush, standby;(3) During Sodium Polyacrylate, aluminum sulfate, iron chloride added into deionized water, using vibration of ultrasonic wave 16 minutes, mixed liquor I is obtained;(4) Sodium alginate is added in mixed liquor I, and is stirred in addition, obtain mixed liquor II;(5)Above-mentioned powder is added to mixed liquor In II, stir 12 minutes, using vibration of ultrasonic wave 9 minutes, get product.
Embodiment 5
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs polyacrylic acid 16 parts of sodium, 29 parts of aluminum sulfate, 12 parts of iron chloride, 24 parts of activated sludge, 9 parts of tealeaves, 6 parts of sodium alginate, 2 parts of plant ash, go from 155 parts of sub- water, it is standby;(2)By in activated sludge, tealeaves, plant ash addition pulverizer, it is 90 mesh powder to crush, standby;(3) During Sodium Polyacrylate, aluminum sulfate, iron chloride added into deionized water, using vibration of ultrasonic wave 19 minutes, mixed liquor I is obtained;(4) Sodium alginate is added in mixed liquor I, and is stirred in addition, obtain mixed liquor II;(5)Above-mentioned powder is added to mixed liquor In II, stir 13 minutes, using vibration of ultrasonic wave 6 minutes, get product.
Comparative example 1
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs polyacrylic acid 22 parts of sodium, 25 parts of aluminum sulfate, 13 parts of iron chloride, 22 parts of activated sludge, 2 parts of plant ash, 90 parts of deionized water, it is standby;(2)Will be living Property sludge, plant ash add pulverizer in, it is 90 mesh powder to crush, standby;(3)Sodium Polyacrylate, aluminum sulfate, iron chloride are added In entering deionized water, using vibration of ultrasonic wave 16 minutes, mixed liquor is obtained;(4)Above-mentioned powder is added in mixed liquor, is stirred 12 minutes, using vibration of ultrasonic wave 8 minutes, get product.
Comparative example 2
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs polyacrylic acid 22 parts of sodium, 25 parts of aluminum sulfate, 13 parts of iron chloride, 22 parts of activated sludge, 6 parts of sodium alginate, 2 parts of plant ash, 90 parts of deionized water, It is standby;(2)By in activated sludge, plant ash addition pulverizer, it is 90 mesh powder to crush, standby;(3)By Sodium Polyacrylate, sulphur Sour aluminium, iron chloride are added in deionized water, using vibration of ultrasonic wave 16 minutes, obtain mixed liquor I;(4)Added in mixed liquor I Sodium alginate, and stirred in addition, obtain mixed liquor II;(5)Above-mentioned powder is added in mixed liquor II, 12 points are stirred Clock, using vibration of ultrasonic wave 8 minutes, gets product.
Comparative example 3
A kind of preparation method of heavy metal-polluted water treatment agent, concretely comprises the following steps:(1)It is first according to parts by weight and weighs polyacrylic acid 22 parts of sodium, 25 parts of aluminum sulfate, 13 parts of iron chloride, 22 parts of activated sludge, 9 parts of tealeaves, 2 parts of plant ash, 90 parts of deionized water, it is standby With;(2)By in activated sludge, tealeaves, plant ash addition pulverizer, it is 90 mesh powder to crush, standby;(3)By Sodium Polyacrylate, Aluminum sulfate, iron chloride are added in deionized water, using vibration of ultrasonic wave 16 minutes, obtain mixed liquor;(4)By the addition of above-mentioned powder To in mixed liquor, stir 12 minutes, using vibration of ultrasonic wave 8 minutes, get product.
First, test method
The finished product being made of embodiment 1-5 and comparative example 1-3 carries out heavy metal-polluted water process, and water quality situation is such as after sewage disposal Shown in following table:(Unit:mg/L)
Project COD SS CU2+ Cd2+ Chromium
Embodiment 1 25 6 0.12 0.05 0.04
Embodiment 2 26 5 0.15 0.07 0.02
Embodiment 3 23 5 0.11 0.04 0.03
Embodiment 4 27 7 0.16 0.05 0.05
Embodiment 5 28 6 0.13 0.06 0.04
Comparative example 1 213 53 13.5 7.2 1.2
Comparative example 2 176 42 10.5 5.4 0.68
Comparative example 3 165 39 7.6 2.5 0.54
Wherein:Tealeaves and sodium alginate are not added with comparative example 1, tealeaves is not added with comparative example 2, sea is not added with comparative example 3 Mosanom.
2nd, experimental result
As can be seen from the above table:Embodiment 1-5 can capture many in many kinds of metal ions in water body, and heavy metal sewage Metal ion species have good clearance, and governance efficiency is high, and many kinds of metal ions in comparative example 1-3 heavy metal sewage Clearance substantially clearance than embodiment 1-5 is low, governance efficiency is relatively low.May certify that only addition tealeaves and sodium alginate are not The many kinds of metal ions in heavy metal containing sewage can be preferably removed, and the synergy for passing through tealeaves and sodium alginate can be notable Improve the clearance of many kinds of metal ions in the heavy metal-polluted water treatment agent heavy metal sewage, and stable performance.
The heavy metal-polluted water treatment agent is compounded by above-mentioned raw materials, plays synergy, can capture various in water body Many kinds of metal ions in metal ion, and heavy metal sewage has good clearance, and governance efficiency is high;It is of the invention heavy Metal sewage-treating agent treatment effect is good, and stable performance, sedimentation effect is good, and effluent quality is good;And processing method is simple, When using, only need to be by the dirty inorganic agent input water, processing cost is low;Sewage after treatment can reach discharge standard, Floc strength is high, and hydrophobic performance is good;Heavy metal-polluted water treatment agent purity of the invention is high, non-toxic, on operator without influence, Biological pollution and secondary pollution problem are not resulted in.
The better embodiment to this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party Formula, in the ken that one skilled in the relevant art possesses, can also be on the premise of this patent objective not be departed from Make a variety of changes.

Claims (6)

1. a kind of heavy metal-polluted water treatment agent, it is characterised in that the component composition including following parts by weight:Sodium Polyacrylate 15-25 parts, aluminum sulfate 10-30 parts, iron chloride 10-15 parts, activated sludge 20-25 parts, tealeaves 5-10 parts, sodium alginate 5-10 Part, plant ash 1-3 parts, deionized water 70-200 parts.
2. heavy metal-polluted water treatment agent according to claim 1, it is characterised in that the component group including following parts by weight Into:22 parts of Sodium Polyacrylate, 25 parts of aluminum sulfate, 13 parts of iron chloride, 22 parts of activated sludge, 9 parts of tealeaves, 6 parts of sodium alginate, vegetation 2 parts of ash, 90 parts of deionized water.
3. a kind of preparation method of heavy metal-polluted water treatment agent as described in claim 1-2 is any, it is characterised in that specific step Suddenly it is:(1)Be first according to parts by weight weigh Sodium Polyacrylate, aluminum sulfate, iron chloride, activated sludge, tealeaves, sodium alginate, Plant ash, it is standby;(2)By in activated sludge, tealeaves, plant ash addition pulverizer, it is 80-110 mesh powder to crush, standby;(3) By in Sodium Polyacrylate, aluminum sulfate, iron chloride addition deionized water, using vibration of ultrasonic wave 15-20 minutes, mixed liquor I is obtained; (4)Sodium alginate is added in mixed liquor I, and is stirred in addition, obtain mixed liquor II;(5)Above-mentioned powder is added to mixed Close in liquid II, stir 10-15 minutes, using vibration of ultrasonic wave 5-10 minutes, get product.
4. the preparation method of heavy metal-polluted water treatment agent according to claim 3, it is characterised in that the step(2)Will Activated sludge, tealeaves, plant ash are added in pulverizer, and it is 90 mesh powder to crush.
5. the preparation method of heavy metal-polluted water treatment agent according to claim 3, it is characterised in that the step(3)Will Sodium Polyacrylate, aluminum sulfate, iron chloride are added in deionized water, using vibration of ultrasonic wave 16 minutes, obtain mixed liquor I.
6. the preparation method of heavy metal-polluted water treatment agent according to claim 3, it is characterised in that the step(5)Will Above-mentioned powder was added in mixed liquor II, stirs 12 minutes, using vibration of ultrasonic wave 8 minutes.
CN201611048609.1A 2016-11-25 2016-11-25 A kind of heavy metal-polluted water treatment agent and preparation method thereof Withdrawn CN106745358A (en)

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CN107324415A (en) * 2017-08-01 2017-11-07 天津中瑞水处理剂有限公司 A kind of heavy metal-polluted water treatment agent
CN108910983A (en) * 2018-08-06 2018-11-30 邹泽深 A kind of sewage-treating agent and preparation method thereof for purifying domestic sewage
CN111875450A (en) * 2020-08-17 2020-11-03 鄂尔多斯市蒙康元生物科技研究有限公司 Soil repairing agent and repairing method for backfill area of coal mining pit

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CN107324415A (en) * 2017-08-01 2017-11-07 天津中瑞水处理剂有限公司 A kind of heavy metal-polluted water treatment agent
CN108910983A (en) * 2018-08-06 2018-11-30 邹泽深 A kind of sewage-treating agent and preparation method thereof for purifying domestic sewage
CN111875450A (en) * 2020-08-17 2020-11-03 鄂尔多斯市蒙康元生物科技研究有限公司 Soil repairing agent and repairing method for backfill area of coal mining pit

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