CN106320080B - A kind of coating and coating paper - Google Patents
A kind of coating and coating paper Download PDFInfo
- Publication number
- CN106320080B CN106320080B CN201610873003.5A CN201610873003A CN106320080B CN 106320080 B CN106320080 B CN 106320080B CN 201610873003 A CN201610873003 A CN 201610873003A CN 106320080 B CN106320080 B CN 106320080B
- Authority
- CN
- China
- Prior art keywords
- coating
- paper
- parts
- nbr latex
- bentonite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/28—Colorants ; Pigments or opacifying agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/38—Coatings with pigments characterised by the pigments
- D21H19/40—Coatings with pigments characterised by the pigments siliceous, e.g. clays
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/56—Macromolecular organic compounds or oligomers thereof obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D21H19/60—Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters
Abstract
The present invention provides a kind of coating and coating paper, institute's coating includes polyvinyl alcohol, phenylethene modified NBR latex, coating starch, p-methyl benzenesulfonic acid and bentonite；The composition of the component by weight are as follows: 100 parts of polyvinyl alcohol, 10~15 parts of phenylethene modified NBR latex, 5~10 parts of coating starch, 5~10 parts of p-methyl benzenesulfonic acid and 10~20 parts of bentonite；Wherein, the bentonite is to be obtained by natural montmorillonite by cationic activation modification.The present invention is by adding phenylethene modified NBR latex, coating is made using the synergistic effect of phenylethene modified NBR latex and polyvinyl alcohol, make that not only there is good physical property using the coating paper of the coating, while it can still keep smooth under the conditions of 80~100 DEG C, fold do not occur.
Description
Technical field
The present invention relates to pulp technology for making paper, more particularly to a kind of coating and coating paper.
Background technique
Current numerial code spray drawing technology has occupied the main market in commercial printing field, with the continuous breakthrough of digital product technology,
Requirement to digital spray printed effect and printing rate is also higher and higher, thus to the quality requirement of spray printed paper product
Also increasingly harsh, the especially requirement to glossiness and rate of drying.
The pigment of the numerial code spray drawing coated paper for printing coating of current high rate of drying is mainly with silica or alumina silicate
Based on system, silica is that absorbency is strong with the advantages of silicic acid aluminized coating, but blotting amount is excessive when spray printed, and ink is big
It infiltrates into inside paper more, and coating surface ink fixation is few, imaged color saturation degree is low, and printing is coarse, glossiness is low.
CN 104389239A discloses a kind of coating and coating paper, and the coating includes polyvinyl alcohol, bentonite and water,
The bentonite is to be obtained by natural montmorillonite by cationic activation modification.Although using coating paper made from the coating
With preferable glossiness and pull-out capacity, but it easily occurs fold at 60 DEG C or more, and then paper is in spray printed process
In use.Summary of the invention
For first by technology the problem of, the present invention provides a kind of coating and coating paper, pass through addition benzene second
Alkene is modified NBR latex, and coating is made using the synergistic effect of phenylethene modified NBR latex and polyvinyl alcohol, makes using described
The coating paper of coating not only has good physical property, while it can still keep smooth under the conditions of 80~100 DEG C, not occur
Fold.
In order to solve the above technical problems, the present invention adopts the following technical scheme:
In a first aspect, the present invention provides a kind of coating, the coating include polyvinyl alcohol, phenylethene modified nitrile rubber
Cream, coating starch, p-methyl benzenesulfonic acid, bentonite and water；The composition of the component by weight are as follows:
Wherein, the parts by weight of phenylethene modified NBR latex can be 10 parts, 11 parts, 12 parts, 13 parts, 14 parts or 15 parts etc.；
The parts by weight of coating starch can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts or 10 parts etc.；The parts by weight of p-methyl benzenesulfonic acid can be 5 parts, 6
Part, 7 parts, 8 parts, 9 parts or 10 parts etc.；Bentonitic parts by weight can be 10 parts, 12 parts, 14 parts, 16 parts, 18 parts or 20 parts etc..
Wherein, the bentonite is to be obtained by natural montmorillonite by cationic activation modification.
As the preferred technical solution of the present invention, the bentonite be by natural montmorillonite by sodium ion activation modification and
Obtain sodium bentonite.
Preferably, the composition of each component by weight in the coating are as follows:
As the preferred technical solution of the present invention, the coating further includes ethyl alcohol, and the ethyl alcohol is 15~50 mass parts.
As the preferred technical solution of the present invention, the coating further includes glyoxal, and the glyoxal is 0.1~2 mass
Part.
As the preferred technical solution of the present invention, the coating further includes defoaming agent, and the defoaming agent is 0.1~1 mass
Part.
As the preferred technical solution of the present invention, the degree of polymerization of the polyvinyl alcohol is 300~2500.
Preferably, the solid content of the coating is 15~18%, such as 15%, 16%, 17% or 18% etc..
As the preferred technical solution of the present invention, the phenylethene modified NBR latex the preparation method comprises the following steps: by styrene
First segment is carried out under 50~60 DEG C and 1~2Mpa of pressure with butadiene acrylonitrile rubber cream to react, the reaction time is 30~50min；It heats up again
Second segment reaction is carried out under to 100~120 DEG C and 1~2Mpa, reacts 60~80min, phenylethene modified NBR latex is made.
Wherein, the temperature of first segment reaction can be 50 DEG C, 52 DEG C, 54 DEG C, 56 DEG C, 58 DEG C or 60 DEG C etc.；First segment reaction
Pressure can be for 1Mpa, 1.2Mpa, 1.4Mpa, 1.6Mpa, 1.8Mpa or 2Mpa etc.；The first segment reaction time can for 30min,
35min, 40min, 45min or 50min etc.；Second segment reaction temperature can be 100 DEG C, 105 DEG C, 110 DEG C, 115 DEG C or 120 DEG C
Deng；Second segment reaction pressure can be 1Mpa, 1.2Mpa, 1.4Mpa, 1.6Mpa, 1.8Mpa or 2Mpa etc.；The second segment reaction time
It can be 60min, 65min, 70min, 75min or 80min etc..
Second aspect, the present invention provides a kind of coating paper, including base paper, there are two opposite appearances for the base paper tool
Face has at least one outer surface of the base paper and is formed by coating layer by above-mentioned coating.
Wherein, the coating weight of the coating paper is 2~15 grams every square metre.
The beneficial effects of the present invention are:
By adding phenylethene modified NBR latex, the synergistic effect of phenylethene modified NBR latex and polyvinyl alcohol is utilized
Coating is made, makes the coating paper using the coating that not only there is good physical property, glossiness is up to 96%, roughness
It is 1.5 μm reachable, burst index 7Kgf/cm2, out-of-flatness is kept in 80~100 DEG C, fold does not occur.
Specific embodiment
Below by specific embodiment, the present invention will be further described:
Embodiment 1: the preparation of phenylethene modified NBR latex
Styrene is carried out first segment with butadiene acrylonitrile rubber cream to react under 55 DEG C and pressure 1.5Mpa, reaction time 40min；
It is warming up under 110 DEG C and 1.5Mpa again and carries out second segment reaction, reacted 70min, phenylethene modified NBR latex is made.
Embodiment 2: the preparation of phenylethene modified NBR latex
Styrene is carried out first segment with butadiene acrylonitrile rubber cream to react under 50 DEG C and pressure 1Mpa, reaction time 30min；Again
It is warming up under 100 DEG C and 1Mpa and carries out second segment reaction, react 60min, phenylethene modified NBR latex is made.
Embodiment 3: the preparation of phenylethene modified NBR latex
Styrene is carried out first segment with butadiene acrylonitrile rubber cream to react under 60 DEG C and pressure 2Mpa, reaction time 50min；Again
It is warming up under 120 DEG C and 2Mpa and carries out second segment reaction, react 80min, phenylethene modified NBR latex is made.
Embodiment 4: the preparation of coating and coated paper
Coating in the present embodiment includes that the 100 mass parts degree of polymerization change for 700 polyvinyl alcohol, the styrene of 13 mass parts
Property NBR latex (in embodiment 1 be made), the coating starch of 6 mass parts, the p-methyl benzenesulfonic acid of 7 mass parts, 15 mass parts sodium matter
Bentonite, 15 mass parts ethyl alcohol, 0.5 mass parts glyoxal and 0.5 mass parts defoaming agent, the solid content of the coating is
17%；
Coating paper coating weight is 2g/m in the present embodiment2, coating is coated on base paper surface by way of wire rod, is passed through
120 DEG C infrared to add 125 DEG C of heated-air dryings and obtain, the base weight of base paper is 120g/m2。
The glossiness of coating paper made from the present embodiment is 97%, and roughness is up to 1.3 μm, burst index 7Kgf/
cm2, out-of-flatness is kept in 80~100 DEG C, fold does not occur.
Embodiment 5: the preparation of coating and coated paper
Coating in the present embodiment includes that the 100 mass parts degree of polymerization change for 700 polyvinyl alcohol, the styrene of 15 mass parts
Property NBR latex (in embodiment 2 be made), the coating starch of 10 mass parts, the p-methyl benzenesulfonic acid of 10 mass parts, 20 mass parts sodium
Matter bentonite, 30 mass parts ethyl alcohol, 0.5 mass parts glyoxal and 0.5 mass parts defoaming agent, the solid content of the coating is
15%；
Coating paper coating weight is 2g/m in the present embodiment2, coating is coated on base paper surface by way of wire rod, is passed through
120 DEG C infrared to add 125 DEG C of heated-air dryings and obtain, the base weight of base paper is 120g/m2。
The glossiness of coating paper made from the present embodiment is 96%, and roughness is up to 1.5 μm, burst index 8Kgf/
cm2, out-of-flatness is kept in 80~100 DEG C, fold does not occur.
Embodiment 6: the preparation of coating and coated paper
Coating in the present embodiment includes that the 100 mass parts degree of polymerization change for 700 polyvinyl alcohol, the styrene of 10 mass parts
Property NBR latex (in embodiment 3 be made), the coating starch of 5 mass parts, the p-methyl benzenesulfonic acid of 5 mass parts, 10 mass parts sodium matter
Bentonite, 30 mass parts ethyl alcohol, 0.5 mass parts glyoxal and 0.5 mass parts defoaming agent, the solid content of the coating is
18%；
Coating paper coating weight is 2g/m in the present embodiment2, coating is coated on base paper surface by way of wire rod, is passed through
120 DEG C infrared to add 125 DEG C of heated-air dryings and obtain, the base weight of base paper is 120g/m2。
The glossiness of coating paper made from the present embodiment is 96%, and roughness is up to 1.4 μm, burst index 7Kgf/
cm2, out-of-flatness is kept in 80~100 DEG C, fold does not occur.
Comparative example 1:
Embodiment 1 in CN 104389239A, the glossiness of coating paper obtained are 96%, pleat occur when in 70 DEG C
Wrinkle.
Comparative example 2:
In this comparison other than not adding phenylethene modified NBR latex in coating, unclassified stores dosage and preparation method are equal
In the same manner as in Example 4, the glossiness of coating paper obtained is 93%, and roughness is 1.7 μm, burst index 3Kgf/cm2,
There is fold at 70 DEG C.
Comparative example 3:
In this comparison other than not adding coating starch in coating, unclassified stores dosage and preparation method with embodiment 4
In it is identical, the glossiness of coating paper obtained is 91%, and roughness is up to 1.9 μm, burst index 3Kgf/cm2, at 70 DEG C
There is fold.
Comparative example 4:
In this comparison other than not adding p-methyl benzenesulfonic acid in coating, unclassified stores dosage and preparation method are and embodiment
Identical in 4, the glossiness of coating paper obtained is 94%, and roughness is up to 1.9 μm, burst index 3Kgf/cm2, at 60 DEG C
Under there is fold.
The result of integrated embodiment 1-6 and comparative example 1-4 can be seen that the present invention by adding phenylethene modified nitrile rubber
Cream is made coating using the synergistic effect of phenylethene modified NBR latex and polyvinyl alcohol, makes the coating paper using the coating
Not only there is good physical property, glossiness is up to 96%, and roughness is up to 1.5 μm, burst index 7Kgf/cm2,
Out-of-flatness is kept in 80~100 DEG C, fold does not occur.
Mode the above is only the implementation of the present invention is not intended to limit the scope of the invention, all to utilize this
Equivalent structure or equivalent flow shift made by description of the invention content is applied directly or indirectly in other relevant technology necks
Domain is included within the scope of the present invention.
Claims (9)
1. a kind of coating, which is characterized in that the coating by polyvinyl alcohol, phenylethene modified NBR latex, coating starch, to first
Benzene sulfonic acid and bentonite composition；The composition of the component by weight are as follows:
Wherein, the bentonite is to be obtained by natural montmorillonite by cationic activation modification；
The solid content of the coating is 15~18%；
The phenylethene modified NBR latex the preparation method comprises the following steps: by styrene and NBR latex in 50~60 DEG C and pressure 1~
First segment reaction is carried out under 2Mpa, the reaction time is 30~50min；It is warming up under 100~120 DEG C and 1~2Mpa again and carries out
Second-stage reaction reacts 60~80min, phenylethene modified NBR latex is made.
2. coating according to claim 1, which is characterized in that the bentonite is living by sodium ion by natural montmorillonite
Change modification and obtains sodium bentonite.
3. coating according to claim 1, which is characterized in that the composition of each component by weight in the coating are as follows:
4. coating according to claim 1 or 2, which is characterized in that the coating further includes ethyl alcohol, the ethyl alcohol be 15~
50 mass parts.
5. coating according to claim 1 or 2, which is characterized in that the coating further includes glyoxal, and the glyoxal is
0.1~2 mass parts.
6. coating according to claim 1 or 2, which is characterized in that the coating further includes defoaming agent, and the defoaming agent is
0.1~1 mass parts.
7. coating according to claim 1 or 2, which is characterized in that the degree of polymerization of the polyvinyl alcohol is 300~2500.
8. a kind of coating paper, including base paper, there are two opposite outer surfaces for the base paper tool, which is characterized in that the base paper
Have at least one outer surface and coating layer is formed by by coating of any of claims 1 or 2.
9. coating paper according to claim 8, which is characterized in that the coating weight of the coating paper is 2~15 grams every square
Rice.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610873003.5A CN106320080B (en) | 2016-09-30 | 2016-09-30 | A kind of coating and coating paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610873003.5A CN106320080B (en) | 2016-09-30 | 2016-09-30 | A kind of coating and coating paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106320080A CN106320080A (en) | 2017-01-11 |
| CN106320080B true CN106320080B (en) | 2019-01-25 |
Family
ID=57820714
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610873003.5A Active CN106320080B (en) | 2016-09-30 | 2016-09-30 | A kind of coating and coating paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106320080B (en) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080187691A1 (en) * | 2007-02-07 | 2008-08-07 | S.D. Warren Company | Rapid Ink Drying Papers |
| EP1964969B1 (en) * | 2007-02-27 | 2018-07-11 | Cargill, Incorporated | Coating compositions |
| EA017396B1 (en) * | 2007-07-09 | 2012-12-28 | Саппи Нидерландс Сервисез Б.В. | Paper for offset printing |
| KR101666005B1 (en) * | 2009-08-12 | 2016-10-13 | 뉴페이지 코포레이션 | Inkjet recording medium |
| CN104389239A (en) * | 2014-09-28 | 2015-03-04 | 金东纸业（江苏）股份有限公司 | Paint and coated paper |
| CN105274897B (en) * | 2015-10-27 | 2017-12-12 | 广西大学 | A kind of preparation method of ink-jet measurements of Digital Printing Papers coating |
-
2016
- 2016-09-30 CN CN201610873003.5A patent/CN106320080B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN106320080A (en) | 2017-01-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102107127B (en) | Technology for granulating powder | |
| JP2009506149A5 (en) | ||
| CN104553431B (en) | Self-adhesive quick-drying thermal sublimation transfer printing digital cloth | |
| CN106320080B (en) | A kind of coating and coating paper | |
| JP2009511409A5 (en) | ||
| CN104371115A (en) | Polymer-grafted graphene oxide master batch and preparation method thereof | |
| KR20130048744A (en) | Liquid curable composition | |
| CN108409177A (en) | A method of purified with diatomaceous shale and prepares diatom ooze functional stuffing | |
| CN107804839A (en) | A kind of high resiliency graphene aerogel and preparation method thereof | |
| CN105348983A (en) | Environmental friendly water-borne coating | |
| CN105327683A (en) | Carbon nanotube printing and dyeing wastewater treatment complexing agent based on SiO<2>/TiO<2> mesoporous composite microsphere carrier and preparation method | |
| CN103805015A (en) | Environmentally-friendly composite high polymer material | |
| CN105665698A (en) | Method for modifying surfaces of metal aluminum powder with nanometer magnesia-alumina spinel precursor-resin | |
| CN111439943A (en) | Environment-friendly building material and preparation method of nano pore water solution additive | |
| CN103409022A (en) | Environmentally-friendly polymer material | |
| CN107629536A (en) | A kind of production method of concave-convex stick suspending agent | |
| CN108191375A (en) | A kind of organically-modified inorganic mineral coating material of aqueous diatom and preparation method thereof | |
| CN107663398B (en) | Bio-based quick-drying thermal sublimation transfer paper, preparation method thereof, coating composition and fine-microporous coating cooperatively constructed by coating composition | |
| CN105602300B (en) | A kind of porous health coating of ecology | |
| CN104389239A (en) | Paint and coated paper | |
| CN106621574A (en) | Expanded graphite filter material and preparation method thereof | |
| CN107936804A (en) | A kind of cold lead ingot granulator surface coating | |
| CN107794049A (en) | Composite of used in soil remediation and preparation method thereof | |
| RU2004122418A (en) | WATER SILICA-CONTAINING COMPOSITION AND METHOD FOR PAPER MANUFACTURE | |
| CN104511296B (en) | A kind of porous molecular screen composite and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190329 Address after: 528226 No. 3, No. 4 Road, Luocun Lianhe and West District, Shishan Town, Nanhai District, Foshan City, Guangdong Province Patentee after: Foshan Lizheng Paper Co.,Ltd. Address before: 214177 Huishan District, Wuxi, Jiangsu Province, Yan Bridge Street, Changan community friendship Street 88. Patentee before: WUXI CHANG'AN SHUGUANG GLOVES FACTORY |
|
| TR01 | Transfer of patent right | ||
| CP03 | Change of name, title or address |
Address after: 528000 No. 6, Shuikeng Street, Middle Third Ring Road, Shishan Town, Nanhai District, Foshan City, Guangdong Province Patentee after: Foshan Lizheng New Materials Co.,Ltd. Address before: 528226 No. 3, No. 4 Road, Luocun Lianhe and West District, Shishan Town, Nanhai District, Foshan City, Guangdong Province Patentee before: Foshan Lizheng Paper Co.,Ltd. |
|
| CP03 | Change of name, title or address |