KR20130048744A - Liquid curable composition - Google Patents
Liquid curable composition Download PDFInfo
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- KR20130048744A KR20130048744A KR1020130038009A KR20130038009A KR20130048744A KR 20130048744 A KR20130048744 A KR 20130048744A KR 1020130038009 A KR1020130038009 A KR 1020130038009A KR 20130038009 A KR20130038009 A KR 20130038009A KR 20130048744 A KR20130048744 A KR 20130048744A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/0008—Materials specified by a shape not covered by C04B20/0016 - C04B20/0056, e.g. nanotubes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B24/00—Use of organic materials as active ingredients for mortars, concrete or artificial stone, e.g. plasticisers
- C04B24/24—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
- C04B2111/00508—Cement paints
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- Engineering & Computer Science (AREA)
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Abstract
Description
The present invention relates to a liquid curable composition having improved physical properties with improved insulation and exothermic properties and greatly increased strength, bearing capacity, adhesion, and the like.
In the case of the airgel application composites used up to now, the strength and the supporting force are insufficient, so that the solid body is poor, the peeling and the flying property are severe, and the performance is low and the characteristics cannot be expected.
Complementing this has been developed applications for various manufacturing methods and performance.
However, the practical use of the application of silica airgel in nanomaterials has been made practical because of technical problems that are not differentiated due to lack of dispersion technology, bonding technology, compression technology, etc., compared to existing products for insulation. There was a problem of difficulty.
In addition, the peeling and separation of nanomaterials and other bonding materials is severe, causing a problem of inferior product stability.
An object of the present invention is to provide a multi-purpose liquid curable composition having excellent properties such as excellent insulation, exothermic properties, and very strong support of nanomaterials and solids, without peeling, cracking and scattering.
In order to achieve the above object,
According to one aspect of the invention,
Silica Aerogel, Carbon Aerogel, Alumina Aerogel, Titania Aerogel, Polyimide Aerogel, Silica-Titania Aerogel, Vanadia Aerogel, Zirconia Aerogel, Acetate Cellulose Organic Aerogel, Carbon Nanotube Aerogel, Silysene, Nanowire, Carbon Nanowire, Aerographite , Graphene, fullerene, graphene oxide, carbon nanotube, boron nitride nanotube, nickel oxide nanotube, tungsten oxide nanotube, copper oxide-tungsten oxide nanotube, cerium oxide nanotube, manganese oxide nanotube, titanate nano 0.01 to 96% by weight of one or two or more of the tubes, boron nitride nanotubes and copper oxide-titanium oxide nanotubes,
Titanium dioxide, zinc oxide, zeolite antibacterial agent, gypsum, lime, silicate metal oxide, silica fume, diatomaceous earth, calcium carbonate, potassium carbonate, magnesium carbonate, sodium carbonate, sodium aluminate, aluminum hydroxide, magnesium hydroxide, aluminum sulfate, aluminum chloride, ammonium 0.2-15 wt% of one or two or more of alum, potassium alum, potassium aluminum sulfate, borate, phosphate, polyacrylamide,
Talc 0.5-5% by weight,
0.03-15 weight% of 1 type, or 2 or more types of mixtures of a sodium laurate, an anneal resin hydrochloride, polysorbate, a chlorinated corpus,
Water, water glass, silica sol, alumina sol, titania sol, zirconia sol, ethanol, butyl alcohol, alkoxysilane, isopropyl alcohol, acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, butyl acetate, butyl cellosolve, Toluene, xylene, acetone, ethyl cellosolve, butyl paraben, phenyl glyoxylate, isopropyl palmanate, fluorinated ketone compound, polyether ether ketone, epoxy, acrylic, polyurethane, phenol, melamine, urea, furan , Silane, siloxane, silicon-alkyd, silicone, butyl titanate, aminoketone, varnish, amino, polyvinyl chloride, furfural alcohol, melamine modified acrylic, alkyd, aminoalkyd, polycarbonate, phosphine oxide, fluorine, hydroxy Ketones, halogenated compounds, phthalic acid, enamel, acrylic silicone, vinyl acetate, methacryl, polyvinyl butylene, benzoguanamine, polyacet Decarboxylate, unsaturated polyester, furfural, styrene-butadiene rubber, steel rubber, butyl rubber, nitrile rubber, polychloroprene rubber, butadiene rubber, ethylene-propylene rubber, silicone rubber, fluorine rubber, hyparon rubber, isoprene rubber, polyethylene, 0.5 to 70% by weight of one or two or more mixtures consisting of an aqueous dispersion or its own powder or its own liquid or resinous phase in polypropylene, polyimide, polycarbosilane, polybenzimidazole, silane siloxane polymer, and octaphenylcyclotetrasiloxane A liquid curable composition consisting of a mixture of can be presented.
According to another aspect of the present invention,
Here
After stirring at 500 ～ 2,000rpm for 1 ~ 30 minutes at 1 ～ 550 ℃, liquid compound
Here
A liquid curable composition consisting of drying and curing can be presented by selecting at least one of room temperature drying, steam drying, heating drying, hot air drying, microwave irradiation, and ultraviolet irradiation drying under conditions of 1 to 550 degrees Celsius and 1 to 180 minutes. have.
The component which comprises the liquid curable composition of this invention is demonstrated. The unit is weight percent.
Silica Aerogel, Carbon Aerogel, Alumina Aerogel, Titania Aerogel, Polyimide Aerogel, Silica-Titania Aerogel, Vanadia Aerogel, Zirconia Aerogel, Acetate Cellulose Organic Aerogel, Carbon Nanotube Aerogel, Silysene, Nanowire, Carbon Nanowire, Aerographite , Graphene, fullerene, graphene oxide, carbon nanotube, boron nitride nanotube, nickel oxide nanotube, tungsten oxide nanotube, copper oxide-tungsten oxide nanotube, cerium oxide nanotube, manganese oxide nanotube, titanate nano 0.01 ~ 96% by weight of one or two or more mixtures of tubes, boron nitride nanotubes, and copper oxide-titanium oxide nanotubes, which have superhydrophobicity, low density, high specific surface area, etc. Applied as the main functional material. The content is preferably in the range of composition, if the content is less than 0.01% by weight can not play the functional role, if the content exceeds 96% by weight is poor in the support force and strength and the formation of a solid body in the absence of bonding force. Hereinafter, referred to as nanomaterials.
Titanium dioxide, zinc oxide, zeolite antibacterial agent, gypsum, lime, silicate metal oxide, silica fume, diatomaceous earth, calcium carbonate, potassium carbonate, magnesium carbonate, sodium carbonate, sodium aluminate, aluminum hydroxide, magnesium hydroxide, aluminum sulfate, aluminum chloride, ammonium 0.2-15% by weight of one or two or more mixtures of alum, potassium alum, potassium aluminum sulfate, borate, phosphate, and polyacrylamide, provide cohesiveness by providing UV protection, antibacterial function, adhesiveness and reinforcement It prevents cracks. The content is preferably within the composition range, and if the content is less than 0.2% by weight, the function may not be performed. If the content is more than 15% by weight, the function may be partially increased, but it is not recommended in terms of economy.
Talc 0.5 ~ 5% by weight prevents the separation of layers due to precipitation by increasing adhesion between light weight nano material with low precipitation and other materials with high specific gravity and adhesion. Acts to make it higher. The degree of bonding with low-density nanomaterials is one of the key challenges as strength degradation due to volume expansion and layer separation is a major challenge. If the composition range is within the preferred range of less than 0.5% by weight, layer separation may be generated. If the content is more than 5% by weight, the viscosity may be excessively increased due to the increase of adhesion with organics, resulting in poor agitation and spaces between materials, resulting in cracking. Mixing with nanomaterials is very sensitive to nanomaterials, so physical adhesion and mixing are not easy.
0.03 to 15% by weight of one or two or more of sodium laurate, annealed resin hydrochloride, polysorbate, and chlorinated corpus cellulose increases the adhesion between materials by forming nonionic anionic and water-soluble cationic colloids. Star alone or in parallel. Increases cohesion and improves cohesion and adhesion and prevents cracks. The composition range is preferably less than 0.03% by weight, resulting in insufficient cohesion and cracking of solids. This happens.
Water, water glass, silica sol, alumina sol, titania sol, zirconia sol, ethanol, butyl alcohol, alkoxysilane, isopropyl alcohol, acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, butyl acetate, butyl cellosolve, Toluene, xylene, acetone, ethyl cellosolve, butyl paraben, phenyl glyoxylate, isopropyl palmanito, fluorinated ketone compound, polyether ether ketone, epoxy, acrylic, polyurethane, phenol, melamine, urea, Furan, silane, siloxane, silicon-alkyd, silicone, butyl titanate, aminoketone, varnish, amino, polyvinyl chloride, fururfural alcohol, melamine modified acrylic, alkyd, aminoalkyd, polycarbonate, phosphine oxide, fluorine, hydride Oxyketones, halogenated compounds, phthalic acid, enamel, acrylic silicone, vinyl acetate, methacryl, polyvinylbutylene, benzoguanamine, polyacet Decarboxylate, unsaturated polyester, furfural, styrene-butadiene rubber, steel rubber, butyl rubber, nitrile rubber, polychloroprene rubber, butadiene rubber, ethylene-propylene rubber, silicone rubber, fluorine rubber, hyparon rubber, isoprene rubber, polyethylene, 0.5 to 70% by weight of one or two or more mixtures consisting of an aqueous dispersion or its own powder or its own liquid or resinous phase in polypropylene, polyimide, polycarbosilane, polybenzimidazole, silane siloxane polymer, and octaphenylcyclotetrasiloxane Has the functions of dispersibility, rust resistance, cold resistance, mechanical strength, water resistance, adhesion, tear strength and elongation, flexural strength, impact strength, anti-foaming property, release property, compressibility, insulation property, and the content is preferably in the composition range. If it is less than 0.5% by weight, the above function may be lost. If it exceeds 70% by weight, the adhesion with the nanomaterial is also reduced. The viscosity rises with respect rather it can be a clumping phenomenon.
In addition, according to another aspect of the present invention,
The mixture
After stirring at 500 ～ 2,000rpm for 1 ~ 30 minutes at 1 ～ 550 ° C, liquid compound.
Liquid compounds
A liquid curable composition consisting of drying and curing can be presented by selecting at least one of room temperature drying, steam drying, heating drying, hot air drying, microwave irradiation, and ultraviolet irradiation drying under conditions of 1 to 550 degrees Celsius and 1 to 180 minutes. have.
In conclusion, the mixture was liquefied by stirring at 1-550 degrees Celsius and 500 to 2,000 rpm for 1 to 30 minutes in the state of mixing nanomaterial and other additive materials, and the liquid was dried at room temperature at 1 to 550 degrees Celsius for 1 to 180 minutes. It is possible to present a liquid curable composition consisting of drying and curing by selecting at least one of steam drying, heating drying, hot air drying, microwave irradiation and ultraviolet irradiation drying. Thermal drying and curing can be performed in parallel to increase productivity.
The shape is made of a liquid compound is properly balanced, and is formed into a paint and soft sheet-like sheet or a hard single-plate board, realizing a stable product properly and maximizes the difference in performance with existing products, such as energy saving Practical and popularized as an applied product.
This liquid curable composition is excellent in supporting capacity, strength, adhesiveness, etc., which maximizes thermal insulation, exothermicity, and conductor formation, which are characteristics of nanomaterials, has a wide range of versatility and application range, greatly increases durability and performance, and does not have peeling and scattering phenomenon. The performance of the material is maintained and the product stability is improved by preventing layer separation and precipitation. It is molded into paint or sheet-like flexible sheet and single-plate board in general residential and industrial facilities requiring insulation and sound insulation, heat generation, conductor formation, etc. and can be applied in various forms throughout the industry.
Hereinafter, the configuration and operation of the present invention through the preferred embodiments will be described in more detail. It is to be understood, however, that the same is by way of illustration and example only and is not to be construed in a limiting sense. Details that are not described herein will be omitted since those skilled in the art will be able to sufficiently infer technically.
Example 1
Application examples of silica airgels in the applied nanomaterials are described.
It carried out by applying the silica airgel of US Cabot Corporation (brand name: ENOVA AEROGEL IC 3100, formerly brand name Nanogel TLD 201).
Average particle distribution: 40 micrometers or less
Pore size: 20 nanometers or less
Superhydrophobic
Density: 120 ~ 140kg / m 3
Thermal Conductivity: 0.012W / m.k at 20 ℃
Specific surface area: 600 to 800 m 2 / g
CAS RN: 126877-03-0
A: 15 weight% of said silica airgels were mixed with 85 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold and molded to a thickness of 5 mm, and left to dry for 2 days at 20 degrees Celsius and 40% relative humidity to dry and cure.
B: 15 weight% of said silica airgels were mixed with 85 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold, molded to a thickness of 5 mm, and cured by drying for 20 minutes with steam at 100 degrees Celsius.
EXAMPLE 2
It was carried out by applying silica airgel of US Cabot Corporation (trade name: ENOVA AEROGEL IC 3110, (formerly, Nanogel TLD 101)).
Average particle distribution: 0.1 to 0.7 micrometers or less
Pore size: 20 nanometers or less
Superhydrophobic
Density: 120 ~ 140kg / m 3
Thermal Conductivity: 0.012W / m.k at 20 ℃
CAS RN: 126877-03-0
A: 15 weight% of said silica airgels were mixed with 85 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold and molded to a thickness of 5 mm, and left to dry for 2 days at 20 degrees Celsius and 40% relative humidity to dry and cure.
B: 15 weight% of said silica airgels were mixed with 85 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold, molded to a thickness of 5 mm, and cured by drying for 20 minutes with steam at 100 degrees Celsius.
EXAMPLE 3
It was carried out by applying silica airgel of US Cabot Corporation (trade name: ENOVA AEROGEL IC 3120, (formerly, Nanogel TLD 302)).
Average particle distribution: 0.1 to 1.2 micrometers or less
Pore size: 20 nanometers or less
Superhydrophobic
Density: 120 ~ 140kg / m 3
Thermal Conductivity: 0.012W / m.k at 20 ℃
CAS RN: 126877-03-0
A: 15 weight% of said silica airgels were mixed with 85 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. The product was injected into a square mold and molded to a thickness of 5 mm, and left to dry for 2 days at 20 degrees Celsius and 40% relative humidity, and dried and cured.
B: 15 weight% of said silica airgels were mixed with 85 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold, molded to a thickness of 5 mm, and cured by drying for 20 minutes with steam at 100 degrees Celsius.
[Comparative Example] 1
It carried out by applying the silica airgel of US Cabot Corporation (brand name: ENOVA AEROGEL IC 3100, formerly brand name Nanogel TLD 201).
Average particle distribution: 40 micrometers or less
Pore size: 20 nanometers or less
Superhydrophobic
Density: 120 ~ 140kg / m 3
Thermal Conductivity: 0.012W / m.k at 20 ℃
Specific surface area: 600 to 800 m 2 / g
CAS RN: 126877-03-0
A: 20 weight% of said silica airgels were mixed with 80 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold and molded to a thickness of 5 mm, and left to dry for 2 days at 20 degrees Celsius and 40% relative humidity to dry and cure.
B: 20 weight% of said silica airgels were mixed with 80 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold, molded to a thickness of 5 mm, and cured by drying for 20 minutes with steam at 100 degrees Celsius.
[Comparative Example] 2
It was carried out by applying silica airgel of US Cabot Corporation (trade name: ENOVA AEROGEL IC 3110, (formerly, Nanogel TLD 101)).
Average particle distribution: 0.1 to 0.7 micrometers or less
Pore size: 20 nanometers or less
Superhydrophobic
Density: 120 ~ 140kg / m 3
Thermal Conductivity: 0.012W / m.k at 20 ℃
CAS RN: 126877-03-0
A: 20 weight% of said silica airgels were mixed with 80 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold and molded to a thickness of 5 mm, and left to dry for 2 days at 20 degrees Celsius and 40% relative humidity to dry and cure.
B: 20 weight% of said silica airgels were mixed with 80 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold, molded to a thickness of 5 mm, and cured by drying for 20 minutes with steam at 100 degrees Celsius.
[Comparative Example] 3
It was carried out by applying silica airgel of US Cabot Corporation (trade name: ENOVA AEROGEL IC 3120, (formerly, Nanogel TLD 302)).
Average particle distribution: 0.1 to 1.2 micrometers or less
Pore size: 20 nanometers or less
Superhydrophobic
Density: 120 ~ 140kg / m 3
Thermal Conductivity: 0.012W / m.k at 20 ℃
CAS RN: 126877-03-0
A: 20 weight% of said silica airgels were mixed with 80 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. It was injected into a square mold and molded to a thickness of 5 mm, and left to dry for 2 days at 20 degrees Celsius and 40% relative humidity to dry and cure.
B: 20 weight% of said silica airgels were mixed with 80 weight% of all other materials, and it stirred for 3 minutes at 1,200 rpm at 20 degreeC. Injected into a square mold was molded to a thickness of 5mm and dried for 20 minutes with steam at 100 degrees Celsius to cure.
[Test Example] 1. Insulation Evaluation
[Example] 3, [Example] 2, [Example] 1, the heat insulation was increased. The reason for this was determined that the silica airgels with small size formed tightly tight pores with each other and blocked the heat passage as much as possible. In each section, no scattering or cracking of nanomaterials occurred and it was determined that the warpage was good.
EXAMPLES Insulation property was favorable toward 3.2.1, and Comparative example. It was determined that heat insulation is good toward 3.2.1. The reason for this was that the smaller the outer diameter particle size of the silica airgel was, the better the thermal bridge and the air passage were.
[Test Example] 2. Strength Evaluation
[Example] 1, [Example] 2, [Example] 3, the strength was increased. The reason for this was that the larger the outer diameter was, the more the adhesive surface with other materials increased, the higher the strength, and the faster the stirring mixing time was.
[Test Example] 3. When comparing [Example] and {Comparative Example]
Example 1 and Comparative Example 1
Example 2 and Comparative Example 2
Example 3 and Comparative Example 3
In each section, the thermal conductivity remains low as the added amount of silica airgel increases in the 1: 1 comparison between [Example] and [Comparative Example], but the strength, bearing capacity, and binding strength are weak. As the input content increased, the thermal conductivity was kept low, but the strength was weakened. Therefore, it was determined that the application of quantitative application of silica airgel and other additive materials was required to ensure insulation and durability.
In addition, the evaluation of the warpage is to form a solid solid body, the nanomaterial is well adhered to the state of no flying phenomenon, and it was determined that the warpage is good at about 160 degrees. It was determined that the warpage was somewhat better. The reason was determined that the flexibility increased because the content of the solid hardened material was reduced and the hardness was weakened.
[Examples] and [Comparative Examples] In each case, it was determined that the air permeability was good due to the formation of smooth air passages by applying a large number of inorganic materials.
[Test Example] 4. Water repellency rating
EXAMPLE The water repellency of 1.2.3 was evaluated to be somewhat lower than the water repellency of 1.2.3. The reason was determined that the higher the content of the silica airgel, the higher the water repellency. Excessive application of silica airgel, however, can lead to the collapse of solids due to the weakening of the overall bearing capacity. It was determined that the ratio of quantitative application that retains the maximum bearing capacity and strength and maintains the characteristics such as heat insulation is maximum is very important.
Claims (1)
Titanium dioxide, zinc oxide, zeolite antibacterial agent, gypsum, lime, silicate metal oxide, silica fume, diatomaceous earth, calcium carbonate, potassium carbonate, magnesium carbonate, sodium carbonate, sodium aluminate, aluminum hydroxide, magnesium hydroxide, aluminum sulfate, aluminum chloride, ammonium 0.2-15 wt% of one or two or more of alum, potassium alum, potassium aluminum sulfate, borate, phosphate, polyacrylamide,
Talc 0.5-5% by weight,
0.03-15 weight% of 1 type, or 2 or more types of mixtures of a sodium laurate, an anneal resin hydrochloride, polysorbate, a chlorinated corpus,
Water, water glass, silica sol, alumina sol, titania sol, zirconia sol, ethanol, butyl alcohol, alkoxysilane, isopropyl alcohol, acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, butyl acetate, butyl cellosolve, Toluene, xylene, acetone, ethyl cellosolve, butyl paraben, phenyl glyoxylate, isopropyl palmanate, fluorinated ketone compound, polyether ether ketone, epoxy, acrylic, polyurethane, phenol, melamine, urea, furan , Silane, siloxane, silicon-alkyd, silicone, butyl titanate, aminoketone, varnish, amino, polyvinyl chloride, furfural alcohol, melamine modified acrylic, alkyd, aminoalkyd, polycarbonate, phosphine oxide, fluorine, hydroxy Ketones, halogenated compounds, phthalic acid, enamel, acrylic silicone, vinyl acetate, methacryl, polyvinyl butylene, benzoguanamine, polyacet Decarboxylate, unsaturated polyester, furfural, styrene-butadiene rubber, steel rubber, butyl rubber, nitrile rubber, polychloroprene rubber, butadiene rubber, ethylene-propylene rubber, silicone rubber, fluorine rubber, hyparon rubber, isoprene rubber, polyethylene, 0.5 to 70% by weight of one or two or more mixtures consisting of an aqueous dispersion or its own powder or its own liquid or resinous phase in polypropylene, polyimide, polycarbosilane, polybenzimidazole, silane siloxane polymer, and octaphenylcyclotetrasiloxane Mixture of
Here
After stirring at 500 ～ 2,000rpm for 1 ~ 30 minutes at 1 ～ 550 ℃, liquid compound
Here
Liquid curable composition which consists of drying and hardening by selecting at least 1 type from room temperature drying, steam drying, heat drying, hot air drying, microwave irradiation, and ultraviolet irradiation drying in the conditions of 1-550 degreeC and 1-180 minutes.
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| KR1020130038009A KR20130048744A (en) | 2013-04-08 | 2013-04-08 | Liquid curable composition |
| PCT/KR2014/002859 WO2014163403A1 (en) | 2013-04-02 | 2014-04-02 | Coating composition containing composite aerogel and method for manufacturing same |
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| KR1020130038009A KR20130048744A (en) | 2013-04-08 | 2013-04-08 | Liquid curable composition |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105694036A (en) * | 2016-03-18 | 2016-06-22 | 江苏亚宝绝缘材料股份有限公司 | Polyimide resin doped with alumina oxide |
| WO2018008872A1 (en) * | 2016-07-04 | 2018-01-11 | 한미르 주식회사 | Thermally conductive composition and method for preparing same |
| CN109319761A (en) * | 2018-11-13 | 2019-02-12 | 河北省科学院能源研究所 | A kind of microwave heating hydrazine hydrate reduction carbon aerogels and preparation method thereof |
| KR20190027436A (en) | 2017-09-07 | 2019-03-15 | 한경대학교 산학협력단 | Organic -inorganic hybrid coating composition including nano-cellulose particle |
| CN110607008A (en) * | 2019-10-16 | 2019-12-24 | 侯强 | High-temperature-resistant anticorrosive cable material |
| CN111560162A (en) * | 2020-07-06 | 2020-08-21 | 华北电力大学 | Preparation method of enhanced PC/ABS alloy flame-retardant plate |
| CN115155470A (en) * | 2022-08-16 | 2022-10-11 | 南京信息工程大学 | Ordered carbon-polysiloxane composite aerogel and preparation method and application thereof |
| CN117806114A (en) * | 2024-02-29 | 2024-04-02 | 中国空气动力研究与发展中心低速空气动力研究所 | Ice-shaped developer and preparation method and application method thereof |
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2013
- 2013-04-08 KR KR1020130038009A patent/KR20130048744A/en not_active Application Discontinuation
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105694036A (en) * | 2016-03-18 | 2016-06-22 | 江苏亚宝绝缘材料股份有限公司 | Polyimide resin doped with alumina oxide |
| WO2018008872A1 (en) * | 2016-07-04 | 2018-01-11 | 한미르 주식회사 | Thermally conductive composition and method for preparing same |
| CN107573903A (en) * | 2016-07-04 | 2018-01-12 | 韩美尔株式会社 | Heat-conductive composition and its manufacture method |
| US10266740B2 (en) * | 2016-07-04 | 2019-04-23 | Hanmir Co., Ltd. | Thermally-conductive composition and method for manufacturing the same |
| KR20190027436A (en) | 2017-09-07 | 2019-03-15 | 한경대학교 산학협력단 | Organic -inorganic hybrid coating composition including nano-cellulose particle |
| CN109319761A (en) * | 2018-11-13 | 2019-02-12 | 河北省科学院能源研究所 | A kind of microwave heating hydrazine hydrate reduction carbon aerogels and preparation method thereof |
| CN110607008A (en) * | 2019-10-16 | 2019-12-24 | 侯强 | High-temperature-resistant anticorrosive cable material |
| CN111560162A (en) * | 2020-07-06 | 2020-08-21 | 华北电力大学 | Preparation method of enhanced PC/ABS alloy flame-retardant plate |
| CN115155470A (en) * | 2022-08-16 | 2022-10-11 | 南京信息工程大学 | Ordered carbon-polysiloxane composite aerogel and preparation method and application thereof |
| CN115155470B (en) * | 2022-08-16 | 2023-05-16 | 南京信息工程大学 | Ordered carbon-polysiloxane composite aerogel and preparation method and application thereof |
| CN117806114A (en) * | 2024-02-29 | 2024-04-02 | 中国空气动力研究与发展中心低速空气动力研究所 | Ice-shaped developer and preparation method and application method thereof |
| CN117806114B (en) * | 2024-02-29 | 2024-04-26 | 中国空气动力研究与发展中心低速空气动力研究所 | Ice-shaped developer and preparation method and application method thereof |
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