CN106883644A - A kind of inorganic nano combined shell powder paint of environmental protection and preparation method thereof - Google Patents

A kind of inorganic nano combined shell powder paint of environmental protection and preparation method thereof Download PDF

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CN106883644A
CN106883644A CN201710116182.2A CN201710116182A CN106883644A CN 106883644 A CN106883644 A CN 106883644A CN 201710116182 A CN201710116182 A CN 201710116182A CN 106883644 A CN106883644 A CN 106883644A
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parts
environmental protection
nano combined
shell powder
powder paint
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焦英华
胡松涛
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
    • C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/346—Clay
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/02—Fibres or whiskers
    • C08K7/04—Fibres or whiskers inorganic
    • C08K7/08—Oxygen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08—Cellulose derivatives
    • C08L1/26—Cellulose ethers
    • C08L1/28—Alkyl ethers
    • C08L1/284—Alkyl ethers with hydroxylated hydrocarbon radicals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/24—Homopolymers or copolymers of amides or imides
    • C08L33/26—Homopolymers or copolymers of acrylamide or methacrylamide

Abstract

The present invention relates to technical field of coatings, and in particular to a kind of inorganic nano combined shell powder paint of environmental protection and preparation method thereof；Raw material including following parts by weight：25 40 parts of film forming matter, 15 parts of coalescents, 18 parts of modified function composition, 38 parts of pigment, 10 30 parts of filler, 05 parts of surfactant；Take distilled water as the viscosity of solvent adjustment coating, distilled water is 2: 37 with the weight ratio of above-mentioned substance；The inorganic nano combined shell powder paint adhesive force of environmental protection that the present invention is provided is strong, and coating is hard, and drying time is short.

Description

A kind of inorganic nano combined shell powder paint of environmental protection and preparation method thereof
Technical field
The present invention relates to technical field of coatings, and in particular to a kind of inorganic nano combined shell powder paint of environmental protection and its Preparation method.
Background technology
In order to improve the corrosion resistance of building wall and other objects, weatherability and chemically resistant material, it is both needed in its table Face applies coats, and current coating film forming matter is main based on organic emulsion, but because its volatile component content is higher, deposits In substantial amounts of organic residue, environment is had a certain impact.Therefore, low stain or Environmentally friendly coatings are commercially subject to pole Big concern, aqueous inorganic paint arises at the historic moment as a kind of green coating of energy-saving and environmental protection, is also gradually suggested higher performance Requirement.Inorganic coating is primarily referred to as using silicate and phosphate compound as adhesive, is added various face, filler, is helped The coating that agent, curing agent are formulated.This coating using inorganic bond as film forming matter has film-forming temperature low, film Good, the low cost with excellent weatherability, highly stable, good heat resistance under action of ultraviolet radiation, the fiery non-ignitable, resistance to soiling of chance The series of advantages such as honest and clean, thus be widely used.However, current aqueous inorganic paint has adhesive force not strong, paint The problem that film difficulty is parched.
The content of the invention
The technical problem to be solved in the present invention is the defect for overcoming prior art, there is provided a kind of adhesive force is strong, and coating is hard, Drying time short inorganic nano combined shell powder paint of environmental protection and preparation method thereof.
A kind of inorganic nano combined shell powder paint of environmental protection, including following parts by weight raw material：Film forming matter 25- 40 parts, coalescents 1-5 parts, 1-8 parts, pigment 3-8 parts, filler 10-30 parts, surfactant 0-5 parts of modified function composition；With Distilled water is the viscosity of solvent adjustment coating, and distilled water is 2: 3-7 with the weight ratio of above-mentioned substance.
Further, the inorganic nano combined shell powder paint of described environmental protection, the film forming matter is selected from water solubility Inorganic Ludox resin, water-soluble inorganic Alumina gel resin, the one of which or any two in water-soluble inorganic silicic acid potassium resin Plant composition.
Further, the inorganic nano combined shell powder paint of described environmental protection, the coalescents are selected from polyethylene Alcohol, polyacrylamide, polyvinylpyrrolidone, diethylene glycol phenyl ether, propane diols phenyl ether, two aklylene glycol phenyl ethers, At least two compositions in dipropylene.
Further, the inorganic nano combined shell powder paint of described environmental protection, described filler is selected from oyster shell whiting, silico-calcium At least one in powder, algae clay, volcanic ash, bauxite, Paris white, calcium sulfate crystal whiskers, organobentonite.
Further, the inorganic nano combined shell powder paint of described environmental protection, the modified function composition includes A groups Divide and B component, the component A is selected from mica, carborundum, boron oxide, tripolyphosphate aluminium powder, zirconia powder, the metal of yttrium stabilization One of which in tungsten powder, silica；The B component is selected from nano-graphene, TiO2/Cu2O nano composite materials, nanometer One of which in zinc powder.
Mica has good insulating properties, elasticity and toughness；The Graphene spy such as have softness, planar structure, intensity high Levy, when being dispersed in inorganic matter, the Graphene of planar structure can improve adsorption capacity, and the flexibility of Graphene can suppress Shrinkage of the inorganic matter under dry and external heat field action, so as to suppress cracking, Graphene is special along the high intensity of in-plane Property can increase the bulk strength after inorganic matter film forming.
Further, the inorganic nano combined shell powder paint of described environmental protection, the surfactant includes froth breaking Agent, thickener, stabilizer.
Further, the inorganic nano combined shell powder paint of described environmental protection, the thickener is by following weight portion Several raw material compositions：Methacrylic acid 25-35 parts, hydroxymethyl cellulose 15-25 parts, stearic acid 10-20 parts, detergent alkylate sulphur Sour sodium 5-10 parts, benzylidene sorbitol 5-10 parts, polyethylene glycol 10-30 parts, talcum powder 5-15 parts, OP-10 1-5 parts, to steam Distilled water is the viscosity of solvent adjustment thickener, and distilled water is 1: 4-8 with the weight ratio of above-mentioned substance.
Further, the inorganic nano combined shell powder paint of described environmental protection, the preparation method of the thickener, step It is rapid as follows：Stirred during methacrylic acid, neopelex, OP-10 and polyethylene glycol are put into emulsifying kettle；Then 60-70 DEG C is warming up to, remaining raw material is instilled in 2h, insulation, stirring reaction 20-40min, addition water, insulation reaction 1-2h, then Room temperature is cooled to, is obtained final product.
Further, the inorganic nano combined shell powder paint of described environmental protection, the defoamer is selected from isooctanol, different One of which in propyl alcohol；The stabilizer is selected from calcium-zinc composite stabilizing agent, the one of which in organic tin stabilizer.
A kind of preparation method of the inorganic nano combined shell powder paint of environmental protection, comprises the following steps：
(1) pigment, filler and modified function composition are mixed, mixing 15- is stirred under the rotating speed of 1500-2000r/min 30min；Then at 700-1000 DEG C, 60-90min is calcined, obtains clinker, clinker is placed on the carbon that mass concentration is 50-60% 10-20min is impregnated in sour hydrogen ammonium salt solution, clinker is taken out, the secondary clacining 20-40min at 200-300 DEG C finally crosses 100-200 Mesh sieve；
(2) at room temperature, obtained clinker in film forming matter and step (1) is mixed, 300-500r/min dispersed with stirring 15- 30min, enters in grinder and is ground, and the mixture granularity ground is less than 20 microns；Then to addition water, film forming in mixture Auxiliary agent and surfactant, adjust PH=7-9, and mechanical agitation 2-2.5h, is cooled to normal temperature at 60-80 DEG C, obtains final product.
The beneficial effect of protrusion that the present invention has compared with prior art is：
The present invention obtains inorganic coating using nano material and filler powder composition modification, effectively improves coating and prepared The bubbling phenomenon easily occurred in journey, the addition of mommy's material effectively increases the antioxygenic property and thermal shock performance of coating, by It is smaller in nano-powder, obtain effective dispersion in the thermal stress of cooling procedure floating coat, it is to avoid larger stress concentration occur, Obtained coating quality is hard, and antistrip performance is good, and the adhesive force with matrix is good, and drying time is short after brushing.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to Limit the present invention.
Embodiment 1：
A kind of inorganic nano combined shell powder paint of environmental protection, including following parts by weight raw material：Film forming matter：Water 30 parts of insoluble inorganic Ludox resin, coalescents：2 parts of polyvinyl alcohol, 1 part of polyacrylamide, modified function composition：Mica 2 Part, 4 parts of nano-graphene, 4 parts of pigment, filler：10 parts of oyster shell whiting, 10 parts of silicon calcium powder, 1 part of isooctanol, 0.5 part of thickener, calcium 1.5 parts of zinc composite stabilizer；Take distilled water as the viscosity of solvent adjustment coating, distilled water is 2: 5 with the weight ratio of above-mentioned substance.
In the present embodiment, the thickener is made up of the raw material of following parts by weight：30 parts of methacrylic acid, methylol is fine 20 parts of dimension element, 15 parts of stearic acid, 8 parts of neopelex, 6 parts of benzylidene sorbitol, 18 parts of polyethylene glycol, talcum powder 8 parts, 2 parts of OP-10 take distilled water as the viscosity of solvent adjustment thickener, and distilled water is 1: 5 with the weight ratio of above-mentioned substance, its Preparation method is as follows：Stirred during methacrylic acid, neopelex, OP-10 and polyethylene glycol are put into emulsifying kettle Mix；60-70 DEG C is then heated to, remaining raw material is instilled in 2h, insulation, stirring reaction 20-40min add water, insulation reaction 1-2h, is cooled to room temperature, obtains final product.
A kind of preparation method of the inorganic nano combined shell powder paint of environmental protection, comprises the following steps：
(1) pigment, filler and modified function composition are mixed, mixing 15- is stirred under the rotating speed of 1500-2000r/min 30min；Then at 700-1000 DEG C, 60-90min is calcined, obtains clinker, clinker is placed on the carbon that mass concentration is 50-60% 10-20min is impregnated in sour hydrogen ammonium salt solution, clinker is taken out, the secondary clacining 20-40min at 200-300 DEG C finally crosses 100-200 Mesh sieve；
(2) at room temperature, obtained clinker in film forming matter and step (1) is mixed, 300-500r/min dispersed with stirring 15- 30min, enters in grinder and is ground, and the mixture granularity ground is less than 20 microns；Then in mixture add distilled water, Coalescents and surfactant, adjust PH=7-9, and mechanical agitation 2-2.5h, is cooled to normal temperature at 60-80 DEG C, obtains final product.
Embodiment 2：
A kind of inorganic nano combined shell powder paint of environmental protection, including following parts by weight raw material：Film forming matter：Water 40 parts of insoluble inorganic Alumina gel resin, coalescents：0.5 part of polyvinylpyrrolidone, 0.5 part of diethylene glycol phenyl ether is modified Functional component：4 parts of carborundum, 4 parts of TiO2/Cu2O nano composite materials, 3 parts of pigment, filler：15 parts of algae clay, volcanic ash 10 Part, 5 parts of bauxite, take distilled water as the viscosity of solvent adjustment coating, and distilled water is 2: 7 with the weight ratio of above-mentioned substance.
In the present embodiment, the thickener is made up of the raw material of following parts by weight：35 parts of methacrylic acid, methylol is fine 15 parts of dimension element, 20 parts of stearic acid, neopelex 5,10 parts of benzylidene sorbitol, 10 parts of polyethylene glycol, talcum powder 15 parts, 1 part of OP-10 take distilled water as the viscosity of solvent adjustment thickener, and distilled water is 1: 8 with the weight ratio of above-mentioned substance, Its preparation method is as follows：It is subject to during methacrylic acid, neopelex, OP-10 and polyethylene glycol are put into emulsifying kettle Stirring；60-70 DEG C is then heated to, remaining raw material is instilled in 2h, insulation, stirring reaction 20-40min add water, and insulation is anti- 1-2h is answered, room temperature is cooled to, obtained final product.
Its preparation method is with embodiment 1.
Embodiment 3：
A kind of inorganic nano combined shell powder paint of environmental protection, including following parts by weight raw material：
Film forming matter：28 parts of water-soluble inorganic silicic acid potassium resin, coalescents：1 part of propane diols phenyl ether, two alkylidenes two 3 parts of alcohol phenyl ether, modified function composition：2 parts of boron oxide, 2 parts of nano zinc powder, 4 parts of pigment, filler：5 parts of bauxite, calcium carbonate 10 parts of powder, 5 parts of calcium sulfate crystal whiskers, 0.5 part of isooctanol, 1 part of thickener, 0.5 part of calcium-zinc composite stabilizing agent；With distilled water as solvent The viscosity of adjusting coating, distilled water is 2: 6 with the weight ratio of above-mentioned substance.
In the present embodiment, the thickener is made up of the raw material of following parts by weight：32 parts of methacrylic acid, methylol is fine 22 parts of dimension element, 17 parts of stearic acid, 6 parts of neopelex, 8 parts of benzylidene sorbitol, 24 parts of polyethylene glycol, talcum powder 7 parts, 2 parts of OP-10 take distilled water as the viscosity of solvent adjustment thickener, and distilled water is 1: 7 with the weight ratio of above-mentioned substance, its Preparation method is as follows：Stirred during methacrylic acid, neopelex, OP-10 and polyethylene glycol are put into emulsifying kettle Mix；60-70 DEG C is then heated to, remaining raw material is instilled in 2h, insulation, stirring reaction 20-40min add water, insulation reaction 1-2h, is cooled to room temperature, obtains final product.
Its preparation method is with embodiment 1.
Embodiment 4：
A kind of inorganic nano combined shell powder paint of environmental protection, including following parts by weight raw material：Film forming matter：Water 10 parts of insoluble inorganic Ludox resin, 24 parts of water-soluble inorganic Alumina gel resin, coalescents：Two aklylene glycol phenyl ethers 2 Part, 3 parts of dipropylene, modified function composition：4 parts of tripolyphosphate aluminium powder, 1 part of nano-graphene, 4 parts of pigment, filler：Sulphur 15 parts of sour calcium pyroborate, 10 parts of organobentonite, 1 part of isooctanol, thickener part, 1 part of organic tin stabilizer；With distilled water as solvent The viscosity of adjusting coating, distilled water is 2: 7 with the weight ratio of above-mentioned substance.
In the present embodiment, the thickener is made up of the raw material of following parts by weight：29 parts of methacrylic acid, methylol is fine 17 parts of dimension element, 16 parts of stearic acid, 9 parts of neopelex, 5 parts of benzylidene sorbitol, 15 parts of polyethylene glycol, talcum powder 12 parts, 4 parts of OP-10 take distilled water as the viscosity of solvent adjustment thickener, and distilled water is 1: 4 with the weight ratio of above-mentioned substance, Its preparation method is as follows：It is subject to during methacrylic acid, neopelex, OP-10 and polyethylene glycol are put into emulsifying kettle Stirring；60-70 DEG C is then heated to, remaining raw material is instilled in 2h, insulation, stirring reaction 20-40min add water, and insulation is anti- 1-2h is answered, room temperature is cooled to, obtained final product.
Its preparation method is with embodiment 1.
Embodiment 5：
A kind of inorganic nano combined shell powder paint of environmental protection, including following parts by weight raw material：Film forming matter：Water 10 parts of insoluble inorganic Alumina gel resin, 15 parts of water-soluble inorganic silicic acid potassium resin, coalescents：3 parts of polyvinyl alcohol, two alkylidenes 2 parts of glycol phenyl ether, modified function composition：0.5 part of the zirconia powder of yttrium stabilization, 0.5 part of TiO2/Cu2O nano composite materials, 8 parts of pigment, filler：5 parts of oyster shell whiting, 5 parts of organobentonite, 2 parts of isopropanol, 2 parts of thickener, 1 part of organic tin stabilizer；To steam Distilled water is the viscosity of solvent adjustment coating, and distilled water is 2: 3 with the weight ratio of above-mentioned substance.
In the present embodiment, the thickener is made up of the raw material of following parts by weight：25 parts of methacrylic acid, methylol is fine 25 parts of dimension element, 10 parts of stearic acid, 10 parts of neopelex, 5 parts of benzylidene sorbitol, 30 parts of polyethylene glycol, talcum 5 parts of powder, 5 parts of OP-10 take distilled water as the viscosity of solvent adjustment thickener, and distilled water is 1: 8 with the weight ratio of above-mentioned substance, Its preparation method is as follows：It is subject to during methacrylic acid, neopelex, OP-10 and polyethylene glycol are put into emulsifying kettle Stirring；60-70 DEG C is then heated to, remaining raw material is instilled in 2h, insulation, stirring reaction 20-40min add water, and insulation is anti- 1-2h is answered, room temperature is cooled to, obtained final product.
Its preparation method is with embodiment 1.
Presently preferred embodiments of the present invention is the foregoing is only, is not intended to limit the invention, it is all in essence of the invention Any modification, equivalent and improvement made within god and principle etc., should be included within the scope of the present invention.

Claims (10)

1. a kind of inorganic nano combined shell powder paint of environmental protection, it is characterised in that the raw material including following parts by weight：Into Membrane substance 25-40 parts, coalescents 1-5 parts, 1-8 parts of modified function composition, pigment 3-8 parts, filler 10-30 parts, surface-active Agent 0-5 parts；Take distilled water as the viscosity of solvent adjustment coating, distilled water is 2: 3-7 with the weight ratio of above-mentioned substance.
2. the inorganic nano combined shell powder paint of environmental protection according to claim 1, it is characterised in that the film forming matter Matter be selected from water-soluble inorganic Ludox resin, water-soluble inorganic Alumina gel resin, in water-soluble inorganic silicic acid potassium resin wherein A kind of or any two kinds of compositions.
3. the inorganic nano combined shell powder paint of environmental protection according to claim 1, it is characterised in that the film forming is helped Agent is selected from polyvinyl alcohol, polyacrylamide, polyvinylpyrrolidone, diethylene glycol phenyl ether, propane diols phenyl ether, two alkylidenes Glycol phenyl ether, at least two compositions in dipropylene.
4. the inorganic nano combined shell powder paint of environmental protection according to claim 1, it is characterised in that described filler is selected From in oyster shell whiting, silicon calcium powder, algae clay, volcanic ash, bauxite, Paris white, calcium sulfate crystal whiskers, organobentonite at least one Kind.
5. the inorganic nano combined shell powder paint of environmental protection according to claim 1, it is characterised in that the modified work( Can composition include component A and B component, the component A be selected from mica, carborundum, boron oxide, tripolyphosphate aluminium powder, yttrium stabilization One of which in zirconia powder, metal tungsten powder, silica；The B component is selected from nano-graphene, TiO2/Cu2O nanometers Composite, the one of which in nano zinc powder.
6. the inorganic nano combined shell powder paint of environmental protection according to claim 1, it is characterised in that live on the surface Property agent include defoamer, thickener, stabilizer.
7. the inorganic nano combined shell powder paint of environmental protection according to claim 1, it is characterised in that the thickener It is made up of the raw material of following parts by weight：Methacrylic acid 25-35 parts, hydroxymethyl cellulose 15-25 parts, stearic acid 10-20 parts, Neopelex 5-10 parts, benzylidene sorbitol 5-10 parts, polyethylene glycol 10-30 parts, talcum powder 5-15 parts, OP- 10 1-5 parts, take distilled water as the viscosity of solvent adjustment thickener, and distilled water is 1: 4-8 with the weight ratio of above-mentioned substance.
8. the inorganic nano combined shell powder paint of environmental protection according to claim 7, it is characterised in that the thickener Preparation method, step is as follows：By in methacrylic acid, neopelex, OP-10 and polyethylene glycol input emulsifying kettle Stirred；60-70 DEG C is then heated to, remaining raw material is instilled in 2h, insulation, stirring reaction 20-40min add water, protect Temperature reaction 1-2h, is cooled to room temperature, obtains final product.
9. the inorganic nano combined shell powder paint of environmental protection according to claim 7, it is characterised in that the defoamer Selected from the one of which in isooctanol, isopropanol；The stabilizer is selected from calcium-zinc composite stabilizing agent, its in organic tin stabilizer Middle one kind.
10. a kind of preparation side of the inorganic nano combined shell powder paint of environmental protection as claimed in any one of claims 1-9 wherein Method, it is characterised in that：Comprise the following steps：
(1) pigment, filler and modified function composition are mixed, mixing 15- is stirred under the rotating speed of 1500-2000r/min 30min；Then at 700-1000 DEG C, 60-90min is calcined, obtains clinker, clinker is placed on the carbon that mass concentration is 50-60% 10-20min is impregnated in sour hydrogen ammonium salt solution, clinker is taken out, the secondary clacining 20-40min at 200-300 DEG C finally crosses 100-200 Mesh sieve；
(2) at room temperature, obtained clinker in film forming matter and step (1) is mixed, 300-500r/min dispersed with stirring 15- 30min, enters in grinder and is ground, and the mixture granularity ground is less than 20 microns；Then to addition water, film forming in mixture Auxiliary agent and surfactant, adjust PH=7-9, and mechanical agitation 2-2.5h, is cooled to normal temperature at 60-80 DEG C, obtains final product.
CN201710116182.2A 2017-02-24 2017-02-24 A kind of inorganic nano combined shell powder paint of environmental protection and preparation method thereof Pending CN106883644A (en)

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CN109021628A (en) * 2018-07-12 2018-12-18 商丘师范学院 It is a kind of can low temperature bonding applied at elevated temperature aqueous boron nitride coating
CN110835475A (en) * 2019-11-29 2020-02-25 广东贝爱佳环保科技有限公司 Environment-friendly coating and preparation method thereof
CN111423750A (en) * 2020-05-16 2020-07-17 李宗奇 Inorganic ecological environment-friendly stain-resistant self-cleaning artistic seaweed paint and preparation method thereof
CN114192121A (en) * 2021-10-25 2022-03-18 北京航天计量测试技术研究所 Acidic solid hydrazine removal adsorbent and granulation method thereof
CN114479763A (en) * 2020-10-27 2022-05-13 山东润澜新材料科技有限责任公司 Novel environment-friendly efficient composite dust suppressant and preparation method thereof
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108610673A (en) * 2018-04-18 2018-10-02 刘勤 A kind of graphene is modified high-temperature anticorrosion paint and preparation method thereof
US11920059B2 (en) 2018-07-02 2024-03-05 Nippon Telegraph And Telephone Corporation Coating material
CN109021628A (en) * 2018-07-12 2018-12-18 商丘师范学院 It is a kind of can low temperature bonding applied at elevated temperature aqueous boron nitride coating
CN109021628B (en) * 2018-07-12 2020-09-04 商丘师范学院 Water-based boron nitride coating capable of being bonded at low temperature and used at high temperature
CN110835475A (en) * 2019-11-29 2020-02-25 广东贝爱佳环保科技有限公司 Environment-friendly coating and preparation method thereof
CN111423750A (en) * 2020-05-16 2020-07-17 李宗奇 Inorganic ecological environment-friendly stain-resistant self-cleaning artistic seaweed paint and preparation method thereof
CN114479763A (en) * 2020-10-27 2022-05-13 山东润澜新材料科技有限责任公司 Novel environment-friendly efficient composite dust suppressant and preparation method thereof
CN114192121A (en) * 2021-10-25 2022-03-18 北京航天计量测试技术研究所 Acidic solid hydrazine removal adsorbent and granulation method thereof

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Application publication date: 20170623