CN106318289A - 一种利用黑水虻蛹制备标签胶的方法 - Google Patents
一种利用黑水虻蛹制备标签胶的方法 Download PDFInfo
- Publication number
- CN106318289A CN106318289A CN201610721522.XA CN201610721522A CN106318289A CN 106318289 A CN106318289 A CN 106318289A CN 201610721522 A CN201610721522 A CN 201610721522A CN 106318289 A CN106318289 A CN 106318289A
- Authority
- CN
- China
- Prior art keywords
- pupa
- reaction
- add
- juice
- stirring
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000853 adhesive Substances 0.000 title claims abstract description 39
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 39
- 241000382353 Pupa Species 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 10
- 241000709785 Hermetia illucens Species 0.000 title abstract 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 36
- 238000002156 mixing Methods 0.000 claims abstract description 33
- 238000006243 chemical reaction Methods 0.000 claims abstract description 31
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims abstract description 29
- 239000000843 powder Substances 0.000 claims abstract description 23
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 239000000376 reactant Substances 0.000 claims abstract description 16
- 239000001254 oxidized starch Substances 0.000 claims abstract description 12
- 235000013808 oxidized starch Nutrition 0.000 claims abstract description 12
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 8
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910021538 borax Inorganic materials 0.000 claims abstract description 8
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 8
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims abstract description 8
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims abstract description 8
- 235000010339 sodium tetraborate Nutrition 0.000 claims abstract description 8
- 229920002261 Corn starch Polymers 0.000 claims abstract description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 7
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004328 sodium tetraborate Substances 0.000 claims abstract description 7
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 43
- 239000008367 deionised water Substances 0.000 claims description 24
- 229910021641 deionized water Inorganic materials 0.000 claims description 24
- 238000007599 discharging Methods 0.000 claims description 13
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 12
- 230000001804 emulsifying effect Effects 0.000 claims description 12
- 241001481656 Stratiomyidae Species 0.000 claims description 10
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 229940117958 vinyl acetate Drugs 0.000 claims description 7
- 239000005708 Sodium hypochlorite Substances 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 235000013877 carbamide Nutrition 0.000 claims description 6
- 239000011790 ferrous sulphate Substances 0.000 claims description 6
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 6
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 6
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 claims description 6
- GPRLSGONYQIRFK-MNYXATJNSA-N triton Chemical compound [3H+] GPRLSGONYQIRFK-MNYXATJNSA-N 0.000 claims description 6
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 238000007259 addition reaction Methods 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 abstract description 10
- 239000003292 glue Substances 0.000 abstract description 7
- 239000011787 zinc oxide Substances 0.000 abstract description 5
- 239000008120 corn starch Substances 0.000 abstract description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract 1
- 238000000265 homogenisation Methods 0.000 abstract 1
- 108010073771 Soybean Proteins Proteins 0.000 description 6
- 235000018102 proteins Nutrition 0.000 description 6
- 108090000623 proteins and genes Proteins 0.000 description 6
- 102000004169 proteins and genes Human genes 0.000 description 6
- 235000019710 soybean protein Nutrition 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920002799 BoPET Polymers 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 238000007711 solidification Methods 0.000 description 3
- 230000008023 solidification Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 2
- 235000010469 Glycine max Nutrition 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920001206 natural gum Polymers 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 210000000582 semen Anatomy 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 235000005637 Brassica campestris Nutrition 0.000 description 1
- 241001301148 Brassica rapa subsp. oleifera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 244000000231 Sesamum indicum Species 0.000 description 1
- 235000003434 Sesamum indicum Nutrition 0.000 description 1
- 241000255632 Tabanus atratus Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000013405 beer Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004832 casein glue Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000004833 fish glue Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229930014626 natural product Natural products 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/02—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to polysaccharides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B31/00—Preparation of derivatives of starch
- C08B31/18—Oxidised starch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
本发明涉及一种利用黑水虻蛹制备标签胶的方法，属于标签胶制备技术领域。本发明先对黑水虻蛹进行榨汁，收集蛹汁和残渣，将残渣晒干后研磨成粉末，将粉末和水混合后与氨水反应，反应后加入氧化锌混合得混合物，备用，将玉米淀粉和水混合匀浆后进行氧化反应得氧化淀粉液，并与蛹汁混合后与丙烯酸、丙烯酸丁酯和醋酸乙烯酯进行反应，反应后得反应物，将反应物和备用的混合物混合后加入反应釜中，加入羧甲基纤维素钠、纳米有机膨润土和四硼酸钠，搅拌混合后出料得标签胶。本发明将制备得到的标签胶粘结力好，防水性能好，不易脱落，固化后牢度大，韧性好，胶层不发脆，不脱落，并且安全环保，制备工艺简单，成本低廉。
Description
技术领域
本发明涉及一种利用黑水虻蛹制备标签胶的方法，属于标签胶制备技术领域。
背景技术
印刷业所称的标签，大部分是用来标识自己产品的相关说明的印刷品，并且大部分都是以背面自带胶的，但也有一些印刷时不带胶的，也可称为标签，举例：大部分的啤酒标签，印刷时都是无胶的，是厂商通过刷标签胶方式帖上去的，而这也叫标签，所以说，标签不一定是有胶的，有胶的标签就是通俗称的“不干胶标签”。
最初的标贴是以手工完成的，因而对粘合剂的要求并不高，一般是以天然胶，动物胶及其改性品种为主，例如淀粉胶、酪素胶、天然胶、鱼胶、骨胶等。其缺点是干燥慢，初粘力差，耐水性低，运输和贮存过程标签易脱落。随着科学的发展，很多产品的包装是在自动线上完成的，标签粘贴也是自动化的一部分：因而对标签胶提出了更高的要求。这些要求包括：①初粘力好，标签瞬间施压后不脱落，不滑移，不翘曲。②干燥速度快。适合高速自动化标贴。③固化后牢度大，韧性好，胶层不发脆，不脱落。④无毒，无污染。⑤有利于包装的回收。
目前，胶粘剂正在朝着环保节能的方向发展。以天然植物产物作主要原料生产胶粘剂也受到广泛关注。植物蛋白作为主要的天然产物之一，因其可再生性，多样性，生物环境相容性等优点而备受关注。在世界范围内，大宗的植物蛋白主要为大豆蛋白、小麦蛋白、花生蛋白、油菜蛋白、芝麻蛋白、向日葵蛋白和棉籽蛋白等。目前作为胶粘剂应用和研究最多的蛋白质是大豆蛋白，这是因为大豆种植量很大，蛋白含量很高可达40%，大豆蛋白制取工艺比较成熟且脱脂豆粉、大豆浓缩蛋白、大豆分离蛋白改性做胶粘剂的历史悠久，效果良好。
发明内容
本发明所要解决的技术问题：针对目前直接利用大豆蛋白制得的胶粘剂粘结强度不够，抗水性能差，尚不能很好地达到生产中需要的标准的问题，本发明提供一种利用黑水虻蛹制备标签胶的方法，本发明先对黑水虻蛹进行榨汁，收集蛹汁和残渣，将残渣晒干后研磨成粉末，将粉末和水混合后与氨水反应，反应后加入氧化锌混合得混合物，备用，将玉米淀粉和水混合匀浆后进行氧化反应得氧化淀粉液，并与蛹汁混合后与丙烯酸、丙烯酸丁酯和醋酸乙烯酯进行反应，反应后得反应物，将反应物和备用的混合物混合后加入反应釜中，加入羧甲基纤维素钠、纳米有机膨润土和四硼酸钠，搅拌混合后出料得标签胶。本发明将制备得到的标签胶粘结力好，防水性能好，不易脱落，固化后牢度大，韧性好，胶层不发脆，不脱落，并且安全环保，制备工艺简单，成本低廉。
为解决上述技术问题，本发明采用的技术方案是：
（1）称取200～300g黑水虻蛹，用去离子水清洗表面后加入榨汁机中榨汁，分别收集得蛹汁和残渣，将残渣放入太阳下暴晒3～5天后粉碎，过60～80目筛后得粉末，将粉末按质量比1:5与去离子水混合后加入粉末质量8～10%尿素，搅拌反应2～3h，反应后加入2～4g氧化锌，搅拌混合30～50min，得混合物，备用；
（2）称取60～80g玉米淀粉，按质量比1:5与去离子水混合，置于匀浆机中，在300～500r/min条件下搅拌混合20～30min后加入3～5g次氯酸钠和5～7g硫酸亚铁，加入后搅拌反应1～2h，反应结束后得氧化淀粉液，按质量比3:1将氧化淀粉液和上述蛹汁混合，得混合液；
（3）在500mL的三口烧瓶中加入15～20g丙烯酸、8～10g丙烯酸丁酯、5～8g醋酸乙烯酯、3～5g聚乙二醇辛基苯基醚、80～120mL去离子水和15～20g上述混合液，放入水浴中，在50～60℃温度下搅拌乳化20～30min，乳化后加入0.3～0.5g过硫酸铵，搅拌反应3～5h后冷却至室温出料，得反应物；
（4）将步骤（1）备用的混合物与上述反应物按质量比1:8混合后放入反应釜中，在45～55℃条件下依次加入1～3g羧甲基纤维素钠、2～4g纳米有机膨润土和0.2～0.4g四硼酸钠，搅拌混合1～2h后出料，即可得到标签胶。
本发明的应用方法：将本发明制备的标签胶按15～20g/m2均匀涂覆于PET膜标签基材上，将覆标签胶的标签基材粘贴在预先洗净干燥的玻璃瓶上，并按压平整后放入室温下自然干燥即可，标签胶的粘结强度为150～200N，抗水时间为10～15h，使用3～4年没有出现脱落、发脆现象。
本发明与其他方法相比，有益技术效果是：
（1）本发明将制备得到的标签胶粘结力好，不易脱落，防水性能好；
（2）本发明将制备得到的标签胶固化后牢度大，韧性好，胶层不发脆，不脱落；
（3）并且安全环保，制备工艺简单，成本低廉。
具体实施方式
称取200～300g黑水虻蛹，用去离子水清洗表面后加入榨汁机中榨汁，分别收集得蛹汁和残渣，将残渣放入太阳下暴晒3～5天后粉碎，过60～80目筛后得粉末，将粉末按质量比1:5与去离子水混合，加入粉末质量8～10%尿素，搅拌反应2～3h，反应后加入2～4g氧化锌，搅拌混合30～50min，得混合物，备用；称取60～80g玉米淀粉，按质量比1:5与去离子水混合，置于匀浆机中，在300～500r/min条件下搅拌混合20～30min后加入3～5g次氯酸钠和5～7g硫酸亚铁，加入后搅拌反应1～2h，反应结束后得氧化淀粉液，按质量比3:1将氧化淀粉液和上述蛹汁混合，得混合液；在500mL的三口烧瓶中加入15～20g丙烯酸、8～10g丙烯酸丁酯、5～8g醋酸乙烯酯、3～5g聚乙二醇辛基苯基醚、80～120mL去离子水和15～20g上述混合液，放入水浴中，在50～60℃温度下搅拌乳化20～30min，乳化后加入0.3～0.5g过硫酸铵，搅拌反应3～5h后冷却至室温出料，得反应物；将备用的混合物与上述反应物按质量比1:8混合后放入反应釜中，在45～55℃条件下依次加入1～3g羧甲基纤维素钠、2～4g纳米有机膨润土和0.2～0.4g四硼酸钠，搅拌混合1～2h后出料，即可得到标签胶。
实例1
称取200g黑水虻蛹，用去离子水清洗表面后加入榨汁机中榨汁，分别收集得蛹汁和残渣，将残渣放入太阳下暴晒3天后粉碎，过60目筛后得粉末，将粉末按质量比1:5与去离子水混合，加入粉末质量8%尿素，搅拌反应2h，反应后加入2g氧化锌，搅拌混合30min，得混合物，备用；称取60g玉米淀粉，按质量比1:5与去离子水混合，置于匀浆机中，在300r/min条件下搅拌混合20min后加入3g次氯酸钠和5g硫酸亚铁，加入后搅拌反应1h，反应结束后得氧化淀粉液，按质量比3:1将氧化淀粉液和上述蛹汁混合，得混合液；在500mL的三口烧瓶中加入15g丙烯酸、8g丙烯酸丁酯、5g醋酸乙烯酯、3g聚乙二醇辛基苯基醚、80mL去离子水和15g上述混合液，放入水浴中，在50℃温度下搅拌乳化20min，乳化后加入0.3g过硫酸铵，搅拌反应3h后冷却至室温出料，得反应物；将备用的混合物与上述反应物按质量比1:8混合后放入反应釜中，在45℃条件下依次加入1g羧甲基纤维素钠、2g纳米有机膨润土和0.2g四硼酸钠，搅拌混合1h后出料，即可得到标签胶。
将本发明制备的标签胶按15g/m2均匀涂覆于PET膜标签基材上，将覆标签胶的标签基材粘贴在预先洗净干燥的玻璃瓶上，并按压平整后放入室温下自然干燥即可，标签胶的粘结强度为150N，抗水时间为10h，使用3年没有出现脱落、发脆现象。
实例2
称取250g黑水虻蛹，用去离子水清洗表面后加入榨汁机中榨汁，分别收集得蛹汁和残渣，将残渣放入太阳下暴晒4天后粉碎，过70目筛后得粉末，将粉末按质量比1:5与去离子水混合，加入粉末质量9%尿素，搅拌反应2.5h，反应后加入3g氧化锌，搅拌混合40min，得混合物，备用；称取70g玉米淀粉，按质量比1:5与去离子水混合，置于匀浆机中，在400r/min条件下搅拌混合25min后加入4g次氯酸钠和6g硫酸亚铁，加入后搅拌反应1.5h，反应结束后得氧化淀粉液，按质量比3:1将氧化淀粉液和上述蛹汁混合，得混合液；在500mL的三口烧瓶中加入17g丙烯酸、9g丙烯酸丁酯、6g醋酸乙烯酯、4g聚乙二醇辛基苯基醚、100mL去离子水和17g上述混合液，放入水浴中，在55℃温度下搅拌乳化25min，乳化后加入0.4g过硫酸铵，搅拌反应4h后冷却至室温出料，得反应物；将备用的混合物与上述反应物按质量比1:8混合后放入反应釜中，在50℃条件下依次加入2g羧甲基纤维素钠、3g纳米有机膨润土和0.3g四硼酸钠，搅拌混合1.5h后出料，即可得到标签胶。
将本发明制备的标签胶按17g/m2均匀涂覆于PET膜标签基材上，将覆标签胶的标签基材粘贴在预先洗净干燥的玻璃瓶上，并按压平整后放入室温下自然干燥即可，标签胶的粘结强度为175N，抗水时间为13h，使用3.5年没有出现脱落、发脆现象。
实例3
称取300g黑水虻蛹，用去离子水清洗表面后加入榨汁机中榨汁，分别收集得蛹汁和残渣，将残渣放入太阳下暴晒5天后粉碎，过80目筛后得粉末，将粉末按质量比1:5与去离子水混合，加入粉末质量8～10%尿素，搅拌反应3h，反应后加入4g氧化锌，搅拌混合50min，得混合物，备用；称取80g玉米淀粉，按质量比1:5与去离子水混合，置于匀浆机中，在500r/min条件下搅拌混合30min后加入5g次氯酸钠和5～7g硫酸亚铁，加入后搅拌反应2h，反应结束后得氧化淀粉液，按质量比3:1将氧化淀粉液和上述蛹汁混合，得混合液；在500mL的三口烧瓶中加入20g丙烯酸、10g丙烯酸丁酯、8g醋酸乙烯酯、5g聚乙二醇辛基苯基醚、120mL去离子水和20g上述混合液，放入水浴中，在60℃温度下搅拌乳化30min，乳化后加入0.5g过硫酸铵，搅拌反应5h后冷却至室温出料，得反应物；将备用的混合物与上述反应物按质量比1:8混合后放入反应釜中，在55℃条件下依次加入3g羧甲基纤维素钠、4g纳米有机膨润土和0.4g四硼酸钠，搅拌混合2h后出料，即可得到标签胶。
将本发明制备的标签胶按20g/m2均匀涂覆于PET膜标签基材上，将覆标签胶的标签基材粘贴在预先洗净干燥的玻璃瓶上，并按压平整后放入室温下自然干燥即可，标签胶的粘结强度为200N，抗水时间为15h，使用4年没有出现脱落、发脆现象。
Claims (1)
1.一种利用黑水虻蛹制备标签胶的方法，其特征在于具体制备步骤为：
(1)称取200～300g黑水虻蛹，用去离子水清洗表面后加入榨汁机中榨汁，分别收集得蛹汁和残渣，将残渣放入太阳下暴晒3～5天后粉碎，过60～80目筛后得粉末，将粉末按质量比1:5与去离子水混合后加入粉末质量8～10%尿素，搅拌反应2～3h，反应后加入2～4g氧化锌，搅拌混合30～50min，得混合物，备用；
(2)称取60～80g玉米淀粉，按质量比1:5与去离子水混合，置于匀浆机中，在300～500r/min条件下搅拌混合20～30min后加入3～5g次氯酸钠和5～7g硫酸亚铁，加入后搅拌反应1～2h，反应结束后得氧化淀粉液，按质量比3:1将氧化淀粉液和上述蛹汁混合，得混合液；
(3)在500mL的三口烧瓶中加入15～20g丙烯酸、8～10g丙烯酸丁酯、5～8g醋酸乙烯酯、3～5g聚乙二醇辛基苯基醚、80～120mL去离子水和15～20g上述混合液，放入水浴中，在50～60℃温度下搅拌乳化20～30min，乳化后加入0.3～0.5g过硫酸铵，搅拌反应3～5h后冷却至室温出料，得反应物；
(4)将步骤（1）备用的混合物与上述反应物按质量比1:8混合后放入反应釜中，在45～55℃条件下依次加入1～3g羧甲基纤维素钠、2～4g纳米有机膨润土和0.2～0.4g四硼酸钠，搅拌混合1～2h后出料，即可得到标签胶。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610721522.XA CN106318289B (zh) | 2016-08-25 | 2016-08-25 | 一种利用黑水虻蛹制备标签胶的方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610721522.XA CN106318289B (zh) | 2016-08-25 | 2016-08-25 | 一种利用黑水虻蛹制备标签胶的方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106318289A true CN106318289A (zh) | 2017-01-11 |
| CN106318289B CN106318289B (zh) | 2018-06-08 |
Family
ID=57792005
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610721522.XA Active CN106318289B (zh) | 2016-08-25 | 2016-08-25 | 一种利用黑水虻蛹制备标签胶的方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106318289B (zh) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440269A (zh) * | 2007-11-22 | 2009-05-27 | 国家淀粉及化学投资控股公司 | 粘合剂、其制备方法和应用 |
| CN102559108A (zh) * | 2012-01-17 | 2012-07-11 | 合肥工业大学 | 一种高初粘力耐水的淀粉胶粘剂的制备方法 |
| CN102719217A (zh) * | 2012-06-20 | 2012-10-10 | 马晓平 | 一种蛋白基木材胶粘剂及其制备方法 |
| CN105153998A (zh) * | 2015-08-28 | 2015-12-16 | 北京林业大学 | 人造板用胶粘剂及其制备方法 |
| CN105400454A (zh) * | 2015-12-23 | 2016-03-16 | 青岛拓联信息技术有限公司 | 一种高粘性固体胶棒 |
-
2016
- 2016-08-25 CN CN201610721522.XA patent/CN106318289B/zh active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101440269A (zh) * | 2007-11-22 | 2009-05-27 | 国家淀粉及化学投资控股公司 | 粘合剂、其制备方法和应用 |
| CN102559108A (zh) * | 2012-01-17 | 2012-07-11 | 合肥工业大学 | 一种高初粘力耐水的淀粉胶粘剂的制备方法 |
| CN102719217A (zh) * | 2012-06-20 | 2012-10-10 | 马晓平 | 一种蛋白基木材胶粘剂及其制备方法 |
| CN105153998A (zh) * | 2015-08-28 | 2015-12-16 | 北京林业大学 | 人造板用胶粘剂及其制备方法 |
| CN105400454A (zh) * | 2015-12-23 | 2016-03-16 | 青岛拓联信息技术有限公司 | 一种高粘性固体胶棒 |
Non-Patent Citations (1)
| Title |
|---|
| 李海旺等: "淀粉改性大豆蛋白标签胶制备", 《粮食与油脂》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106318289B (zh) | 2018-06-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101921381B (zh) | 应用于水基真空吸塑胶用胶黏剂的聚氨酯乳液的制备方法 | |
| CN102719217A (zh) | 一种蛋白基木材胶粘剂及其制备方法 | |
| CN104974696B (zh) | 一种生物质环保水性胶 | |
| CN104861892A (zh) | 一种氧化淀粉胶粘剂及其制备方法 | |
| CN101343513A (zh) | 玉米淀粉粘合剂 | |
| CN104946162B (zh) | 一种炭基缓释复混肥造粒用淀粉胶黏剂的制备方法 | |
| CN104629647B (zh) | 一种环保型淀粉胶黏剂 | |
| CN105348396A (zh) | 一种环保型壁纸胶粉用改性淀粉及其制备方法 | |
| CN102977799A (zh) | 一种高强度木工粘合剂的制备方法 | |
| CN110079239A (zh) | 一种接触式智能卡基与芯片封装用导电热熔胶带 | |
| CN101967355B (zh) | 一种纸品淀粉粘合剂及其制备方法 | |
| CN105315933B (zh) | 一种抗剥离瞬干胶及其制备方法 | |
| CN102618117A (zh) | 单液型环保通用复合油墨及其制备方法 | |
| CN104861894B (zh) | 书刊装订用的热熔胶及其生产方法 | |
| CN106318289A (zh) | 一种利用黑水虻蛹制备标签胶的方法 | |
| CN101967356B (zh) | 一种环保型喷胶的制备方法 | |
| CN109096951A (zh) | 一种家具封边胶及其制备方法 | |
| CN103122050A (zh) | 一种水溶性油墨用合成树脂及其制备方法 | |
| CN103360985A (zh) | 一种天然橡胶包装胶粘剂及其制备方法 | |
| CN103627366B (zh) | 一种明胶基胶粘剂的制备方法 | |
| CN104877063A (zh) | 一种聚醋酸乙烯乳液及其制备方法 | |
| CN101979452B (zh) | 一种瓦楞纸生产用的抗水胶粘剂的制备方法 | |
| CN103790316A (zh) | 一种环保型装饰板生产工艺 | |
| CN105440979A (zh) | 一种具有优异初粘性及终粘性的环保水性粘合剂 | |
| CN104449487A (zh) | 一种彩色复膜胶及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180510 Address after: 362141 Xu Shan Tou village, Dongling Town, Huian County, Quanzhou, Fujian, China Applicant after: Huian Tong boulder Co., Ltd. Address before: 213164 Changzhou, Jiangsu, Xinbei District, Phoenix City 24 buildings 703 rooms Applicant before: Dong Xiao |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190618 Address after: 215300 Room No. 568 Jinjin Road, Zhangpu Town, Kunshan City, Suzhou City, Jiangsu Province Patentee after: Kunshan Pride Electronics Co., Ltd. Address before: 362141 Xu Shan Tou village, Dongling Town, Huian County, Quanzhou, Fujian, China Patentee before: Huian Tong boulder Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| CP02 | Change in the address of a patent holder |
Address after: No.3, group 30, Erqiao village, Sixiang Town, medical high tech Zone, Taizhou City, Jiangsu Province Patentee after: Kunshan Pride Electronics Co.,Ltd. Address before: 215300 Room No. 568 Jinjin Road, Zhangpu Town, Kunshan City, Suzhou City, Jiangsu Province Patentee before: Kunshan Pride Electronics Co.,Ltd. |
|
| CP02 | Change in the address of a patent holder | ||
| CP02 | Change in the address of a patent holder |
Address after: No.32, group 27, Shangqiao village, yong'anzhou Town, Gaogang District, Taizhou City, Jiangsu Province 225300 Patentee after: Kunshan Pride Electronics Co.,Ltd. Address before: No.3, group 30, Erqiao village, Sixiang Town, medical high tech Zone, Taizhou City, Jiangsu Province Patentee before: Kunshan Pride Electronics Co.,Ltd. |
|
| CP02 | Change in the address of a patent holder |