CN106318227A - Organic-inorganic compound adhesive with elasticity and oxidization resistance and use method of organic-inorganic compound adhesive - Google Patents
Organic-inorganic compound adhesive with elasticity and oxidization resistance and use method of organic-inorganic compound adhesive Download PDFInfo
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- CN106318227A CN106318227A CN201610707739.5A CN201610707739A CN106318227A CN 106318227 A CN106318227 A CN 106318227A CN 201610707739 A CN201610707739 A CN 201610707739A CN 106318227 A CN106318227 A CN 106318227A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J1/00—Adhesives based on inorganic constituents
- C09J1/02—Adhesives based on inorganic constituents containing water-soluble alkali silicates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
Abstract
The invention belongs to the field of compound adhesives, and particularly relates to an organic-inorganic compound adhesive with elasticity and oxidization resistance and a use method of the organic-inorganic compound adhesive. The compound adhesive is prepared from a component A and a component B, wherein the mass ratio of the component A to the component B is (1 to 1.2) to 1. The component A and the component B are respectively prepared from the following raw materials in parts by weight: the component A: 90 to 110 parts of water glass with the Baume degree of 38 to 42, 20 to 35 parts of mixed rubber emulsion, 1.0 to 1.5 parts of a silane coupling agent, 1.0 to 2.0 parts of sodium carboxymethylcellulose and 25 to 40 parts of water; and the component B: 50 to 80 parts of silicon dioxide, 15 to 25 parts of sodium fluosilicate, 5 to 10 parts of sodium tripolyphosphate and 0.5 to 1 part of polyacrylamide. The component A and the component B are separately stored at ordinary times; during use, the uniformly mixed component B is slowly added into the component A and continuously stirred, and the adding of the component B is stopped until the component A and the component B reach the corresponding mass ratio; and then the component A and the component B are continuously stirred for 5 to 10 min for uniform mixing for construction work. The organic-inorganic compound adhesive with elasticity and oxidization resistance has the beneficial effects that the compound adhesive has certain elasticity and oxidization resistance, and is relatively high in water resistance and acid resistance.
Description
Technical field
The invention belongs to composite adhesive field, relate to a kind of Organic-inorganic composite glue with elasticity and non-oxidizability
Glutinous agent and using method thereof, this compound glutinous agent specially one utilizes mixed rubber emulsion modified sodium silicate adhesive.
Background technology
Sodium silicate is as a kind of traditional inorganic adhesive, and it not only has preferable adhesive property, acid resistance, and
And mechanical strength is high, fire resistance is good, so nearly its application in China's fireproof coating of more than ten years is relatively broad, (Cai builds
Female, Zheng Yifang, Qu Bo, etc. the composite bonding material impact [J] on fire-resistant coating for steel structure performance. fire science and technology,
2008,27(09):671-674.).But its shortcoming is the most prominent, not only poor water resistance, the moisture-sensitive accumulation of salt in the surface soil, and solidify
After adhesive linkage crisp, easily split, collapsibility is poor, the easy efflorescence in surface, poor flexibility, regenerating used and reclaim difficulty (Zhu Chunxi, Lu Chen,
Ji Dunsheng. water-glass sand rationale [M]. Shanghai: Shanghai science tech publishing house, 2000.).The most existing many scholars couple
The modification of sodium silicate is studied.The mechanism of modifying water glass is probed into by Zhu Chunxi etc., it is believed that the change of waterglass
Learn modifying agent and should possess certain hydrogen bond activity, intramolecular activity decrease time water solublity increases because hydroxyl increases, the degree of polymerization with
Activity increase and raise, modified compound molecule should be able to nm every with polysilicon acid molecule2Structure containing 5-8 silicone hydroxyl
Match (Zhu Chunxi, Lu Chen, Ji Dunsheng, etc. the classification of waterglass additive and selection principle [J]. casting, 1997 (09):
50-52.).Zhu Jun etc. use polyethylene glycol oxide that waterglass has been carried out study on the modification, and the modified waterglass finally given is being protected
On the premise of demonstrate,proving its bonding efficiency, improve the catabiosis of waterglass, enhance its sand bond, and easy after pouring into a mould
Shake out, it is simple to old sand is carried out Dry recovery (Zhu Jun, what has root, Zhou Lianshan. grinding of polyethylene oxide modified sodium silicate binder
Study carefully [J]. casting, 2006,55 (08): 839-841.).History is excellent etc. utilizes silicone acrylic emulsion that waterglass has carried out study on the modification,
Obtain the shop primer of a kind of aqueous.This priming paint not only has excellent rustless property, heat resistance, welding performance, and
And avoid producing substantial amounts of zinc oxide dust in work progress, greatly reduce its body harm (Shi You to workmen
Good. a kind of aqueous inorganic shop primer: China, 104987758A [P] .2015-10-21).
Summary of the invention
The poor water resistance existed for sodium silicate adhesive in prior art and some of modification composite adhesive, solidification
After adhesive linkage crisp, easily split, collapsibility is poor, the deficiency such as the easy efflorescence in surface and poor flexibility, the present invention provide a kind of cheap and
There is the certain elastic and Organic-inorganic composite adhesive of non-oxidizability.
The technical scheme is that a kind of organic-nothing with elasticity and non-oxidizability
Machine composite adhesive, it is made up of two kinds of components of A, B, and component A is 1-1.2:1 with the mass ratio of B component, and component A is divided with B component
It is not made up of the raw material of following parts by weight:
Component A: waterglass 90-110 part of Baume degrees 38-42, mixed rubber emulsion 20-35 part, silane coupler 1.0-
1.5 parts, sodium carboxymethyl cellulose 1.0-2.0 part, water 25-40 part；
B component: silicon dioxide 50-80 part, prodan 15-25 part, sodium tripolyphosphate 5-10 part, polyacrylamide 0.5-
1 part.
It is wherein the emulsion of stable homogeneous under component A room temperature, is pulverulent solids under B component room temperature.
Concrete, described mixed rubber emulsion by carboxylic acrylonitrile butadiene rubber latex and silicone acrylic emulsion according to the mass ratio of 5.5-6.5:1
Mix.Carboxy terminated nitrile rubber breast is that one routinizes chemical product, and it is a kind of anionic emulsion polymerization, for
The latex of the Third monomer terpolymer of acrylonitrile, butadiene and hydroxyl, total solid content more than 45%, pH value 7.5-10.
Silicone acrylic emulsion is that with acrylic monomer, the organic silicon monomer containing unsaturated bond is added suitable auxiliary agent, is coated with by nucleocapsid
The emulsion that polymerization technique is polymerized.Combine organosilicon fire-resistant, weatherability, chemical-resistant, hydrophobic, surface can low not
V ulnerability and the high colour retention of acrylic resin, pliability, tack.It is a kind of high durable, high ring water-fast, resistant to pollution
Guarantor's type emulsion for building and coating, solid content is about 46%.
Preferably, described mixed rubber emulsion mixed according to the mass ratio of 6:1 by carboxylic acrylonitrile butadiene rubber latex and silicone acrylic emulsion and
Become.
Preferably, described silane coupler is KH-550.
Present invention also offers the above-mentioned user with the elastic Organic-inorganic composite adhesive with non-oxidizability
Method: component A and B component are separately deposited, is slowly added into the B component after mixing in component A and is stirred continuously during use, until
Component A reach with B component corresponding quality than time stop add B component, continuously stirred 5-10min, can enter after mix homogeneously
Row construction operation.
Compared with prior art, the invention has the beneficial effects as follows:
The composite adhesive that the present invention provides is based on waterglass, and it is cheap and easy to get, and itself just has preferably
Acid resistance；Modifying agent with mixed rubber emulsion as waterglass, it can not only significantly increase the resistance to water of waterglass, also
Can be obviously improved that waterglass adhesive linkage is crisp, easily split the problems such as poor with collapsibility, have after the composite adhesive finally given solidification
Certain elasticity and non-oxidizability；Additionally, mixed rubber emulsion is based on hydroxybutyronitrile latex, silicone acrylic emulsion is cosolvent, silicon
Acrylic emulsion can increase the compatibility of organic principle hydroxybutyronitrile latex and inorganic constituents waterglass；And, using silicon dioxide as
Acid resistance filler, can make composite adhesive have more preferable acid resistance；Its using method is simple, and the suitability is good, especially can be wide
The general consersion unit acid-proof ceramic tile lining for chemical industry corrosive materials bonding.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in further detail, and example is served only for explaining this
Bright, it is not intended to limit the scope of the present invention.
The medicine used in the present invention is commercially available prod, wherein silicon dioxide, prodan, Sodium triphosphate, poly-third
Acrylamide is commercial powder shape product.
Embodiment 1
A kind of have the elastic and Organic-inorganic composite adhesive of non-oxidizability, and it is made up of, wherein two kinds of components of A, B
The weight ratio of two kinds of components of A, B is 1:1, and by weight, the composition of two kinds of components of A, B is as follows:
The composition of component A and content: the waterglass of Baume degrees 38-42 98 parts, mixed rubber emulsion 22 parts, silane coupler
1 part, sodium carboxymethyl cellulose 1.2 parts, 30 parts of water.Wherein mixed rubber emulsion by carboxylic acrylonitrile butadiene rubber latex and silicone acrylic emulsion according to 6:
The mass ratio of 1 mixes.Silane coupler is KH-550.
The composition of B component and content: silicon dioxide 60 parts, prodan 18 parts, sodium tripolyphosphate 5 parts, polyacrylamide
0.6 part.
The B component of Organic-inorganic composite adhesive embodiment 1 prepared is added slowly to component A, and constantly stirs
Mix, until it reaches stopping during required proportioning adding B component, stirring and evenly mixing, then with a block plate and one piece of acid-proof ceramic tile
Test its adhesive property.Result shows, bonding force is relatively strong, and tack coat has certain elasticity, and fragility will not be occurred during stress to open
Split, use requirement can be met.Then remaining sample is divided into two parts at the beginning of standing solidification, 30min and solidifies, after drying being fully cured
Sample weigh respectively after be placed in water and 60% sulphuric acid in be placed in the calorstat of 60 DEG C in order to measure its resistance to water
And acid resistance, result shows, after 7 days, after the sample in water is dried, quality is original 98.1%, in the sulphuric acid of 60%
Sample surfaces turn yellow, after drying, quality is original 97.1%.
Embodiment 2
A kind of have the elastic and Organic-inorganic composite adhesive of non-oxidizability, and it is made up of, wherein two kinds of components of A, B
The weight ratio of two kinds of components of A, B is 1:1, and by weight, the composition of two kinds of components of A, B is as follows:
The composition of component A and content: the waterglass of Baume degrees 38-42 98 parts, mixed rubber emulsion 30 parts, silane coupler
1.2 parts, sodium carboxymethyl cellulose 1.4 parts, 30 parts of water.Wherein mixed rubber emulsion by carboxylic acrylonitrile butadiene rubber latex and silicone acrylic emulsion according to
6.5:1 mass ratio mix.Silane coupler is KH-550.
The composition of B component and content: silicon dioxide 65 parts, prodan 22 parts, sodium tripolyphosphate 5 parts, polyacrylamide
0.6 part.
The B component of Organic-inorganic composite adhesive embodiment 2 prepared is added slowly to component A, and constantly stirs
Mix, until it reaches stopping during required proportioning adding B component, stirring and evenly mixing, then with a block plate and one piece of acid-proof ceramic tile
Test its adhesive property.Result shows, bonding force is relatively strong, and tack coat has certain elasticity, and fragility will not be occurred during stress to open
Split, use requirement can be met.Then remaining sample is divided into two parts at the beginning of standing solidification, 20min and solidifies, after drying being fully cured
Sample weigh respectively after be placed in water and 60% sulphuric acid in be placed in the calorstat of 60 DEG C in order to measure its resistance to water
And acid resistance, result shows, after 7 days, after the sample in water is dried, quality is original 98.2%, in the sulphuric acid of 60%
Sample surfaces turn yellow, after drying, quality is original 95.3%.
Embodiment 3
A kind of have the elastic and Organic-inorganic composite adhesive of non-oxidizability, and it is made up of, wherein two kinds of components of A, B
The weight ratio of two kinds of components of A, B is 1.1:1, and by weight, the composition of two kinds of components of A, B is as follows:
The composition of component A and content: the waterglass of Baume degrees 38-42 105 parts, mixed rubber emulsion 25 parts, silane coupled
Agent 1.3 parts, sodium carboxymethyl cellulose 1.3 parts, 35 parts of water.Wherein mixed rubber emulsion is pressed with silicone acrylic emulsion by carboxylic acrylonitrile butadiene rubber latex
Mass ratio according to 5.5:1 mixes.Silane coupler is KH-550.
The composition of B component and content: silicon dioxide 65 parts, prodan 20 parts, sodium tripolyphosphate 7 parts, polyacrylamide
0.6 part.
The B component of Organic-inorganic composite adhesive embodiment 3 prepared is added slowly to component A, and constantly stirs
Mix, until it reaches stopping during required proportioning adding B component, stirring and evenly mixing, then with a block plate and one piece of acid-proof ceramic tile
Test its adhesive property.Result shows, bonding force is relatively strong, and tack coat has certain elasticity, and fragility will not be occurred during stress to open
Split, use requirement can be met.Then remaining sample is divided into two parts at the beginning of standing solidification, 28min and solidifies, after drying being fully cured
Sample weigh respectively after be placed in water and 60% sulphuric acid in be placed in the calorstat of 60 DEG C in order to measure its resistance to water
And acid resistance, result shows, after 7 days, after the sample in water is dried, quality is original 97.9%, in the sulphuric acid of 60%
Sample surfaces turn yellow, after drying, quality is original 96.4%.
Embodiment 4
A kind of have the elastic and Organic-inorganic composite adhesive of non-oxidizability, and it is made up of, wherein two kinds of components of A, B
The weight ratio of two kinds of components of A, B is 1:1.2, and by weight, the composition of two kinds of components of A, B is as follows:
The composition of component A and content: the waterglass of Baume degrees 38-42 105 parts, mixed rubber emulsion 30 parts, silane coupled
Agent 1.4 parts, sodium carboxymethyl cellulose 1.6 parts, 38 parts of water.Wherein mixed rubber emulsion is pressed with silicone acrylic emulsion by carboxylic acrylonitrile butadiene rubber latex
Mass ratio according to 5.7:1 mixes.Silane coupler is KH-550.
The composition of B component and content: silicon dioxide 72 parts, prodan 23 parts, sodium tripolyphosphate 8 parts, polyacrylamide
0.7 part.
The B component of Organic-inorganic composite adhesive embodiment 4 prepared is added slowly to component A, and constantly stirs
Mix, until it reaches stopping during required proportioning adding B component, stirring and evenly mixing, then with a block plate and one piece of acid-proof ceramic tile
Test its adhesive property.Result shows, bonding force is relatively strong, and tack coat has certain elasticity, and fragility will not be occurred during stress to open
Split, use requirement can be met.Then remaining sample is divided into two parts at the beginning of standing solidification, 30min and solidifies, after drying being fully cured
Sample weigh respectively after be placed in water and 60% sulphuric acid in be placed in the calorstat of 60 DEG C in order to measure its resistance to water
And acid resistance, result shows, after 7 days, after the sample in water is dried, quality is original 98.3%, in the sulphuric acid of 60%
Sample surfaces turn yellow, after drying, quality is original 96.8%.
Embodiment 5
A kind of have the elastic and Organic-inorganic composite adhesive of non-oxidizability, and it is made up of, wherein two kinds of components of A, B
The weight ratio of two kinds of components of A, B is 1.2:1, and by weight, the composition of two kinds of components of A, B is as follows:
The composition of component A and content: the waterglass of Baume degrees 38-42 110 parts, mixed rubber emulsion 33 parts, silane coupled
Agent 1.5 parts, sodium carboxymethyl cellulose 1.8 parts, 40 parts of water.Wherein mixed rubber emulsion is pressed with silicone acrylic emulsion by carboxylic acrylonitrile butadiene rubber latex
Mass ratio according to 6.3:1 mixes.Silane coupler is KH-550.
The composition of B component and content: silicon dioxide 78 parts, prodan 25 parts, sodium tripolyphosphate 10 parts, polyacrylamide
1 part.
The B component of Organic-inorganic composite adhesive embodiment 5 prepared is added slowly to component A, and constantly stirs
Mix, until it reaches stopping during required proportioning adding B component, stirring and evenly mixing, then with a block plate and one piece of acid-proof ceramic tile
Test its adhesive property.Result shows, bonding force is relatively strong, and tack coat has certain elasticity, and fragility will not be occurred during stress to open
Split, use requirement can be met.Then remaining sample is divided into two parts at the beginning of standing solidification, 30min and solidifies, after drying being fully cured
Sample weigh respectively after be placed in water and 60% sulphuric acid in be placed in the calorstat of 60 DEG C in order to measure its resistance to water
And acid resistance, result shows, after 7 days, after the sample in water is dried, quality is original 98.5%, in the sulphuric acid of 60%
Sample surfaces turn yellow, after drying, quality is original 94.3%.
Comparative example 1
Comparative example 1 replaces the mixed rubber emulsion to embodiment 1 with carboxylic acrylonitrile butadiene rubber latex, and other compositions and consumption are all with real
Execute example 1 identical.The component A that comparative example 1 obtains is unstable, has a small amount of white flock precipitate in it, this is because lacked silicon the third breast
The hydrotropy effect of liquid, carboxylic acrylonitrile butadiene rubber latex generation breakdown of emulsion and carboxylic acrylonitrile butadiene rubber latex and waterglass compatibility poor, now, by B group
When point adding in component A, finds more difficult stirring and evenly mixing, and use steel plate and acid-proof ceramic tile to find it when testing its adhesive property
Cohesive force substantially reduces, and during stress, acid-proof ceramic tile is easy to fall off.
Comparative example 2
Carboxylic acrylonitrile butadiene rubber latex in comparative example 2 is 2:1 with the mass ratio of silicone acrylic emulsion, i.e. improves the ratio of silicone acrylic emulsion,
Other compositions and consumption are the most same as in Example 1.The B component of the Organic-inorganic composite adhesive that comparative example 2 obtains adds A group
Time in point, finding to be easier to mixing, bonding force is preferable, but tack coat is more crisp, the sample after having cracking phenomena, solidification to dry
Put in water or in the sulphuric acid of 60%, after 7 days, mass loss more than 10%.
From embodiment and comparative example, the Organic-inorganic composite adhesive that the proportioning provided according to the present invention obtains enters
During row bonding, cohesive force is relatively big, tack coat has certain elastic and do not ftractures, and resistance to water and acid resistance are all preferable, 60% sulfur simultaneously
Acid has certain oxidisability, puts in 60% sulphuric acid after 7 days after the adhesive solidification of the present invention, and only surface turns yellow, and shows it
There is certain non-oxidizability.Comparative example 1 and comparative example 2 show, the proportioning of the mixed rubber emulsion of the present invention is specific, when
The adhesive property of the composite adhesive finally given can be significantly affected during beyond its proportioning.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all spirit in the present invention and
Within principle, any modification, equivalent substitution and improvement etc. made, should be included within the scope of the present invention.
Claims (5)
1. one kind has the elastic and Organic-inorganic composite adhesive of non-oxidizability, it is characterised in that by two kinds of component groups of A, B
Becoming, component A is 1-1.2:1 with the mass ratio of B component, and component A and B component are made up of the raw material of following parts by weight respectively:
Component A: waterglass 90-110 part of Baume degrees 38-42, mixed rubber emulsion 20-35 part, silane coupler 1.0-1.5
Part, sodium carboxymethyl cellulose 1.0-2.0 part, water 25-40 part；
B component: silicon dioxide 50-80 part, prodan 15-25 part, sodium tripolyphosphate 5-10 part, polyacrylamide 0.5-1 part.
A kind of Organic-inorganic composite adhesive with elasticity and non-oxidizability the most according to claim 1, its feature exists
In, described mixed rubber emulsion is mixed according to the mass ratio of 5.5-6.5:1 with silicone acrylic emulsion by carboxylic acrylonitrile butadiene rubber latex.
A kind of Organic-inorganic composite adhesive with elasticity and non-oxidizability the most according to claim 2, its feature exists
In, described mixed rubber emulsion is mixed according to the mass ratio of 6:1 with silicone acrylic emulsion by carboxylic acrylonitrile butadiene rubber latex.
4. according to a kind of Organic-inorganic composite gluing with elasticity and non-oxidizability described in any one of claims 1 to 3
Agent, it is characterised in that described silane coupler is KH-550.
5. the Organic-inorganic composite adhesive with elastic and non-oxidizability as described in any one of Claims 1-4
Using method, it is characterised in that component A and B component are separately deposited, is slowly added into component A by the B component after mixing during use
In and be stirred continuously, until component A reach with B component corresponding quality than time stop add B component, stirring and evenly mixing, Ji Kejin
Row construction operation.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610707739.5A CN106318227A (en) | 2016-08-23 | 2016-08-23 | Organic-inorganic compound adhesive with elasticity and oxidization resistance and use method of organic-inorganic compound adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610707739.5A CN106318227A (en) | 2016-08-23 | 2016-08-23 | Organic-inorganic compound adhesive with elasticity and oxidization resistance and use method of organic-inorganic compound adhesive |
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| CN106318227A true CN106318227A (en) | 2017-01-11 |
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| CN201610707739.5A Pending CN106318227A (en) | 2016-08-23 | 2016-08-23 | Organic-inorganic compound adhesive with elasticity and oxidization resistance and use method of organic-inorganic compound adhesive |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107805468A (en) * | 2017-11-04 | 2018-03-16 | 临沂绿醛胶业有限公司 | A kind of glued board zero aldehyde adhesive and preparation method thereof |
| CN109465380A (en) * | 2019-01-04 | 2019-03-15 | 山东永创材料科技有限公司 | A kind of high-strength cast iron binder |
| CN114479517A (en) * | 2021-12-30 | 2022-05-13 | 湖北三棵树新材料科技有限公司 | Artificial colored sand for improving stone-like coating workability and preparation method thereof |
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| CN101591516A (en) * | 2008-05-28 | 2009-12-02 | 北京科技桥科贸有限公司 | Waterglass adhesive |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107805468A (en) * | 2017-11-04 | 2018-03-16 | 临沂绿醛胶业有限公司 | A kind of glued board zero aldehyde adhesive and preparation method thereof |
| CN109465380A (en) * | 2019-01-04 | 2019-03-15 | 山东永创材料科技有限公司 | A kind of high-strength cast iron binder |
| CN114479517A (en) * | 2021-12-30 | 2022-05-13 | 湖北三棵树新材料科技有限公司 | Artificial colored sand for improving stone-like coating workability and preparation method thereof |
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Application publication date: 20170111 |
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