CN107572970A - A kind of binding agent and preparation method for self-adhesion wet-laying waterproof roll - Google Patents

A kind of binding agent and preparation method for self-adhesion wet-laying waterproof roll Download PDF

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Publication number
CN107572970A
CN107572970A CN201710985140.2A CN201710985140A CN107572970A CN 107572970 A CN107572970 A CN 107572970A CN 201710985140 A CN201710985140 A CN 201710985140A CN 107572970 A CN107572970 A CN 107572970A
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CN
China
Prior art keywords
parts
self
binding agent
waterproof roll
laying waterproof
Prior art date
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Pending
Application number
CN201710985140.2A
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Chinese (zh)
Inventor
周玉梅
张娜
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN CITY YUHONG BUILDING WATERPROOF MATERIAL CO Ltd
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TIANJIN CITY YUHONG BUILDING WATERPROOF MATERIAL CO Ltd
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Application filed by TIANJIN CITY YUHONG BUILDING WATERPROOF MATERIAL CO Ltd filed Critical TIANJIN CITY YUHONG BUILDING WATERPROOF MATERIAL CO Ltd
Priority to CN201710985140.2A priority Critical patent/CN107572970A/en
Publication of CN107572970A publication Critical patent/CN107572970A/en
Pending legal-status Critical Current

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  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

The invention provides a kind of binding agent for self-adhesion wet-laying waterproof roll and preparation method thereof, the raw material that the binding agent includes following parts by weight is made:100 parts of high strength cement, 70 100 parts of quartz sand, 10~30 parts of active masterbatch, 12 28 parts of activation acrylic acid rubber powder, 5 14 parts of hydroxypropyl cellulose, reduction aqua:26 parts, early strength agent:26 parts.A kind of binding agent for self-adhesion wet-laying waterproof roll provided by the invention, overcome traditional lean concrete grout and be bonded insecure, easy to crack, peeling, influence the waterproof effect of waterproof roll.

Description

A kind of binding agent and preparation method for self-adhesion wet-laying waterproof roll
Technical field
The invention belongs to water-proof building material technical field, more particularly, to a kind of for the viscous of self-adhesion wet-laying waterproof roll Tie agent and preparation method.
Background technology
Adhesive waterproof coil is common by domestic university, Research Center expert, professor after 2009 introduce technology from Europe A kind of New Product developed, it is that instead of " exceptional function " waterproof material of various buildings waterproofs, and waterproof material is applied Infiltrate into the integral waterproofing layer that basic unit connects together forever after work chemically reactive, used go through within more than 20 years in Europe History, effect are fine.
Bonding agent currently used for wet-laying adhesive waterproof coil is all lean concrete grout category rigid material, when basic unit deforms When, it is rigid connect agent be easy to cracking with basal plane peeling, it is be bonded insecure, influence the waterproof effect of waterproof roll.
The content of the invention
In view of this, the present invention is directed to propose a kind of binding agent and preparation method of self-adhesion wet-laying waterproof roll.To overcome Common wet-laying self-adhesion bonding agent phenomenon easy to crack, the service life for extending wet-laying adhesive waterproof coil bonding agent, greatly Ground improves the security of engineering waterproofing.
To reach above-mentioned purpose, the technical proposal of the invention is realized in this way:
A kind of binding agent of self-adhesion wet-laying waterproof roll, is made up of the raw material including following parts by weight;High strength cement 100 parts, quartz sand 70-100 parts, 10~30 parts of active masterbatch, activation acrylic acid rubber powder 12-28 parts, hydroxypropyl cellulose 5-14 Part, reduce aqua:2-6 parts, early strength agent:2-6 parts.
Preferably, it is made up of the raw material including following parts by weight;100 parts of high strength cement, quartz sand 80-95 parts, work 15~25 parts of sexupara material, activation acrylic acid rubber powder 17-23 parts, hydroxypropyl cellulose 8-11 parts, reduction aqua:3-5 parts, morning are strong Agent:3-4 parts.
Preferably, the cement is PI42.5 portland cements;The quartz sand is 80-120 mesh;Described active masterbatch For with penetrant crystalline function;Described activation acrylic acid rubber powder is water-soluble acrylic rubber powder;Described early strength agent is lithium salts Class;Described active masterbatch be Nanjing can Rui Ma companies production TC-II types.
42.5 cement is preferably portland cement PI, is advantageous to improve the intensity of bonding sizing material, and its index is as follows:
Project Technical indicator
Outward appearance Without caking, foreign matter
Compression strength 3d 17MPa
Compression strength 28d 42.5MPa
Rupture strength 3d 3.5MPa
Rupture strength 28d 6.5MPa
Presetting period It is no earlier than 45min
Final setting time Earlier than 6.5h
The active masterbatch be preferably with crystallization and infiltration function, Nanjing can Rui Ma companies production TC-II types, it refers to Mark is as follows:
Project Technical indicator
Outward appearance Without caking, foreign matter
Impermeability pressure/MPa, 28d >= 1.0
Impermeability pressure ratio/%, 28d >= 250
Wet basis face adhesion strength/MPa, 28d >= 1.0
The quartz sand is silica, and its mesh number is:80-120 mesh, its index are as follows:
Project Technical indicator
Outward appearance Milky is granular
Mesh number (80-120 mesh) >= 95%
Moisture content≤ 1%
Described its index of activation acrylic acid rubber powder is as follows:
Project Technical indicator
Outward appearance Off-white powder
Apparent density g/L 450±100
Granule content (being more than 300 μm) %< 2
Tg DEG C of glass transition temperature 8
MFT DEG C of MFT 0
Described hydroxypropyl cellulose, mainly improves the adhesive property of bonding agent, and its index is as follows:
The present invention also provides a kind of method for preparing the binding agent as described above for self-adhesion wet-laying waterproof roll, including Following preparation process, including following preparation process, by high strength cement, quartz sand, active masterbatch, activation acrylic acid rubber powder, hydroxyl Propyl cellulose, reduction aqua and early strength agent are added in agitator tank after measuring respectively and mixed, and mixing time is 40min-60min carries out blowing packaging after being sufficiently mixed.
Present invention simultaneously provides the application method of the binding agent as described above for self-adhesion wet-laying waterproof roll, constructing Scene is by powder and water (8~12) in mass ratio:(3~5) are uniformly mixing to obtain the binding agent of self-adhesion wet-laying waterproof roll;It is preferred that , the mass ratio of powder and water is 10:4.
The present invention also provides is used for application of the binding agent of self-adhesion wet-laying waterproof roll in water proof building as described above.
The binding agent of self-adhesion wet-laying waterproof roll provided by the invention can make wet-laying self-adhesive coiled material body dissociate long-chain molecule Key can equally be stretched into the hole of adhesive surface equivalent to " claw " and firmly firmly grasped, and its microstructure formed is porous knot Structure contains abundant hydrophilic segment, and the hydrophilic segment that these segments are formed can directly infilter the hole of substrate concrete In.More high adhesiveness energy and preferable cracking resistance are made it have, is had relative to existing cement base bonding agent preferably viscous Connect performance, preferably adapt to basic unit's deformability, particularly suitable for larger roofing, underground waterproof engineering.Simultaneously because former material Material is easy to get, and preparation technology is easy, easy for construction, securely and reliably so that product integrated cost of the present invention is cheap, suitable for extensive Industrial production and widely use.
The binding agent of self-adhesion wet-laying waterproof roll provided by the invention and synthesis of the common cement-base bonding agent in performance Difference see the table below 1.
Table 1
Embodiment
In addition to being defined, technical term used has universal with those skilled in the art of the invention in following examples The identical meanings of understanding.Test reagent used, is routine biochemistry reagent unless otherwise specified in following examples;It is described Experimental method, it is conventional method unless otherwise specified.
The present invention is described in detail with reference to embodiment.
Embodiment 1
100 parts of high strength cement, 70 parts of quartz sand, 9 parts of active masterbatch, 15 parts of activation acrylic acid rubber powder, hydroxypropyl is fine 6 parts of dimension element, reduce aqua:3 parts, early strength agent:4 parts measure respectively after be added in agitator tank and mixed, mixing time Blowing packaging is carried out after being sufficiently mixed for 40min-60min, powder and water are pressed 10 at the construction field (site):4 ratios stir To the binding agent of self-adhesion wet-laying waterproof roll.
Embodiment 2
100 parts of high strength cement, 80 parts of quartz sand, 15 parts of active masterbatch, 17 parts of activation acrylic acid rubber powder, hydroxypropyl is fine 8 parts of dimension element, reduce aqua:3 parts, early strength agent:4 parts measure respectively after be added in agitator tank and mixed, mixing time Blowing packaging is carried out after being sufficiently mixed for 40min-60min, powder and water are pressed 10 at the construction field (site):4 ratios stir To the binding agent of self-adhesion wet-laying waterproof roll.
Embodiment 3
100 parts of high strength cement, 90 parts of quartz sand, 20 parts of active masterbatch, 20 parts of activation acrylic acid rubber powder, hydroxypropyl is fine 8 parts of dimension element, reduce aqua:4 parts, early strength agent:4 parts measure respectively after be added in agitator tank and mixed, mixing time Blowing packaging is carried out after being sufficiently mixed for 40min-60min, powder and water are pressed 10 at the construction field (site):4 ratios stir To the binding agent of self-adhesion wet-laying waterproof roll.
Comparative example 1
Using the preparation method of same embodiment 1, the binding agent of self-adhesion wet-laying waterproof roll.Other compositions are constant, will be formulated Middle masterbatch removes, and a kind of binding agent of the self-adhesion wet-laying waterproof roll obtained.
Comparative example 2
Using the preparation method of same embodiment 1, other compositions are constant, by the binder formula of self-adhesion wet-laying waterproof roll Activation acrylic acid rubber powder remove, and obtain self-adhesion wet-laying waterproof roll binding agent.
The performance test results for the product that the various embodiments described above and comparative example are obtained are as shown in the table.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.

Claims (9)

  1. A kind of 1. binding agent for self-adhesion wet-laying waterproof roll, it is characterised in that:By the raw material system for including following parts by weight Into 100 parts of high strength cement, quartz sand 70-100 parts, 10~30 parts of active masterbatch, activation acrylic acid rubber powder 12-28 parts, hydroxypropyl Base cellulose 5-14 parts, reduce aqua:2-6 parts, early strength agent:2-6 parts.
  2. 2. the binding agent according to claim 1 for self-adhesion wet-laying waterproof roll, it is characterised in that:By including following heavy The raw material of amount number is made;100 parts of high strength cement, quartz sand 80-95 parts, 15~25 parts of active masterbatch, activation acrylate glue Powder 17-23 parts, hydroxypropyl cellulose 8-11 parts, reduce aqua:3-5 parts, early strength agent:3-4 parts.
  3. 3. the binding agent according to claim 1 for self-adhesion wet-laying waterproof roll, it is characterised in that:Described cement is PI42.5 portland cements;Described quartz sand is 80-120 mesh.
  4. 4. the binding agent according to claim 1 for self-adhesion wet-laying waterproof roll, it is characterised in that:Described activity is female Expect for the active masterbatch with penetrant crystalline function, it is preferred that Nanjing can Rui Ma companies production TC-II types.
  5. 5. the binding agent according to claim 1 for self-adhesion wet-laying waterproof roll, it is characterised in that:Described activation third Olefin(e) acid rubber powder is water-soluble acrylic rubber powder.
  6. 6. the binding agent according to claim 1 for self-adhesion wet-laying waterproof roll, it is characterised in that:Described early strength agent For salts early strength agent.
  7. 7. a kind of method for preparing the binding agent for self-adhesion wet-laying waterproof roll as described in any one of claim 1~6, its It is characterised by:Including following preparation process, by high strength cement, quartz sand, active masterbatch, activation acrylic acid rubber powder, hydroxypropyl Cellulose, reduction aqua and early strength agent are added in agitator tank after measuring respectively and mixed, and mixing time is 40min-60min carries out blowing packaging after being sufficiently mixed.
  8. 8. the application method of the binding agent for self-adhesion wet-laying waterproof roll according to any one of claim 1~6, it is special Sign is:At the construction field (site) by powder and water (8~12) in mass ratio:(3~5) are uniformly mixing to obtain self-adhesion wet-laying waterproof roll Binding agent;Preferably, the mass ratio of powder and water is 10:4.
  9. 9. the binding agent for self-adhesion wet-laying waterproof roll according to any one of claim 1~6 is in water proof building Using.
CN201710985140.2A 2017-10-20 2017-10-20 A kind of binding agent and preparation method for self-adhesion wet-laying waterproof roll Pending CN107572970A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109180105A (en) * 2018-09-27 2019-01-11 天津市禹红建筑防水材料有限公司 A kind of flexible adhesion powder and preparation method for polyethylene polypropylene fiber waterproof coiled material
CN113372839A (en) * 2021-05-17 2021-09-10 福建捷嘉实业有限公司 Breathable sealed type wet-laid double-sided butyl rubber waterproof roll and waterproof system
CN113773112A (en) * 2021-09-03 2021-12-10 天津市禹神建筑防水材料有限公司 Rigid waterproof type isolation sand special for pre-paved waterproof coiled material and preparation method thereof

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CA2269513A1 (en) * 1999-04-22 2000-10-22 Daubois Inc. Sculptable and breathable wall coating mortar compound
CN101074158A (en) * 2007-07-23 2007-11-21 康跃金 Efficient thermal-insulating and anti-cracking daub of crystallized waterproofing
CN101885597A (en) * 2010-06-30 2010-11-17 新疆天诚防水材料有限公司 Cement based permeable crystallization type waterproof material
CN102515667A (en) * 2011-12-16 2012-06-27 吴江市利达上光制品有限公司 Adhesive powder for ceramic tile
CN102718455A (en) * 2012-07-02 2012-10-10 安徽朗凯奇建材有限公司 Cement based capillary crystalline high-performance waterproofing powder and application thereof
BRPI1103860A2 (en) * 2011-06-20 2013-07-23 Dow Global Technologies Llc cement, and method of sealing, bonding or coating a substrate
CN103304205A (en) * 2013-07-04 2013-09-18 重庆久圣成防水材料有限公司 Capillary crystalline patch plaster
CN106145823A (en) * 2016-07-05 2016-11-23 唐山东方雨虹防水技术有限责任公司 A kind of self-healing polymer-modified cement-based waterproofing slurry of environmental protection osmosis type
CN106810160A (en) * 2017-01-22 2017-06-09 北京朗坤防水材料有限公司 Cement-base infiltration crystallization waterproofing agent and preparation method thereof
CN106810162A (en) * 2017-01-23 2017-06-09 中建八局第建设有限公司 A kind of binding paste of wet-laid process laying self-adhesive coiled material and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2269513A1 (en) * 1999-04-22 2000-10-22 Daubois Inc. Sculptable and breathable wall coating mortar compound
CN101074158A (en) * 2007-07-23 2007-11-21 康跃金 Efficient thermal-insulating and anti-cracking daub of crystallized waterproofing
CN101885597A (en) * 2010-06-30 2010-11-17 新疆天诚防水材料有限公司 Cement based permeable crystallization type waterproof material
BRPI1103860A2 (en) * 2011-06-20 2013-07-23 Dow Global Technologies Llc cement, and method of sealing, bonding or coating a substrate
CN102515667A (en) * 2011-12-16 2012-06-27 吴江市利达上光制品有限公司 Adhesive powder for ceramic tile
CN102718455A (en) * 2012-07-02 2012-10-10 安徽朗凯奇建材有限公司 Cement based capillary crystalline high-performance waterproofing powder and application thereof
CN103304205A (en) * 2013-07-04 2013-09-18 重庆久圣成防水材料有限公司 Capillary crystalline patch plaster
CN106145823A (en) * 2016-07-05 2016-11-23 唐山东方雨虹防水技术有限责任公司 A kind of self-healing polymer-modified cement-based waterproofing slurry of environmental protection osmosis type
CN106810160A (en) * 2017-01-22 2017-06-09 北京朗坤防水材料有限公司 Cement-base infiltration crystallization waterproofing agent and preparation method thereof
CN106810162A (en) * 2017-01-23 2017-06-09 中建八局第建设有限公司 A kind of binding paste of wet-laid process laying self-adhesive coiled material and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109180105A (en) * 2018-09-27 2019-01-11 天津市禹红建筑防水材料有限公司 A kind of flexible adhesion powder and preparation method for polyethylene polypropylene fiber waterproof coiled material
CN113372839A (en) * 2021-05-17 2021-09-10 福建捷嘉实业有限公司 Breathable sealed type wet-laid double-sided butyl rubber waterproof roll and waterproof system
CN113773112A (en) * 2021-09-03 2021-12-10 天津市禹神建筑防水材料有限公司 Rigid waterproof type isolation sand special for pre-paved waterproof coiled material and preparation method thereof

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