CN106317715A - PVDF (polyvinylidene fluoride) pipe - Google Patents

PVDF (polyvinylidene fluoride) pipe Download PDF

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Publication number
CN106317715A
CN106317715A CN201610767984.5A CN201610767984A CN106317715A CN 106317715 A CN106317715 A CN 106317715A CN 201610767984 A CN201610767984 A CN 201610767984A CN 106317715 A CN106317715 A CN 106317715A
Authority
CN
China
Prior art keywords
parts
pvdf
trimethyl
polyethylene glycol
ammonium chloride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610767984.5A
Other languages
Chinese (zh)
Inventor
金飞
宗建青
邹建良
沈达
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshu Three Ai Fuzhenfu Novel Material Co Ltd
Original Assignee
Changshu Three Ai Fuzhenfu Novel Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changshu Three Ai Fuzhenfu Novel Material Co Ltd filed Critical Changshu Three Ai Fuzhenfu Novel Material Co Ltd
Priority to CN201610767984.5A priority Critical patent/CN106317715A/en
Publication of CN106317715A publication Critical patent/CN106317715A/en
Pending legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/16—Homopolymers or copolymers or vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/18—Applications used for pipes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The invention discloses a PVDF (polyvinylidene fluoride) pipe. The PVDF pipe is prepared from components in parts by weight as follows: 1-2 parts of sodium alkyl sulfosuccinate, 0.8 parts of N-methylpyrrolidone, 1.5 parts of hexabromocyclododecane, 1.3 parts of barium dinonyl decyl sulfonate, 0.4 parts of methyl benzotriazole, 2.2 parts of polyethylene glycol (n) monolaurate, 0.7 parts of polyoxyethylene trimethyl ammonium chloride, 1.1 parts of tetracarboxydiphthalic ether dianhydride, 2.3 parts of 2,2,4-trimethyl-1,3-pentanediolmono(2-methylpropanoate) and 28 parts of polyvinylidene fluoride. The PVDF pipe has excellent flame retardance, wear resistance, corrosion resistance, high temperature resistance, oxidation resistance, anti-static performance and weather fastness.

Description

PVDF manages
Technical field
The present invention relates to PVDF pipe.
Background technology
Existing PVDF manages, and it is fire-retardant, abrasion-resistant, corrosion-resistant, high temperature resistant, resistance to oxidation, antistatic, weatherability all need to be carried High.
Summary of the invention
It is an object of the invention to provide a kind of PVDF pipe, its have excellence fire-retardant, abrasion-resistant, corrosion-resistant, high temperature resistant, Resistance to oxidation, antistatic, weatherability performance.
For achieving the above object, the technical scheme is that design a kind of PVDF pipe, by weight by following components Make:
1～2 part of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
Preferably, PVDF manages, and is made up of following components by weight:
1 part of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
Preferably, PVDF manages, and is made up of following components by weight:
2 parts of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
Preferably, PVDF manages, and is made up of following components by weight:
1.2 parts of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
Advantages of the present invention and having the beneficial effects that: provide a kind of PVDF pipe, it has fire-retardant, the abrasion-resistant of excellence, resistance to Burn into is high temperature resistant, resistance to oxidation, antistatic, weatherability performance.
Performance and the purposes of " PVDF pipe " are determined by its component and proportioning, and the different component meeting in " PVDF pipe " Influencing each other, component and proportioning thereof can determine the final performance of " PVDF pipe ", as the most mutually coordinated in fruit component and proportioning thereof, single The beneficial effect that component is brought, even can be eliminated by other components abatement, and the when of serious, different component is mutually conflicted, and rises Less than whole synthesis effect, produce negative interaction and substandard products.The present invention passes through a large amount of creative works, repeatedly verifies, obtains " PVDF Pipe " optimal component and proportioning so that multiple components combine, mutually coordinated and produce forward comprehensive effect.
Detailed description of the invention
Below in conjunction with embodiment, the detailed description of the invention of the present invention is further described.Following example are only used for more Add and clearly demonstrate technical scheme, and can not limit the scope of the invention with this.
The technical scheme that the present invention is embodied as is:
Embodiment 1
PVDF manages, and is made up of following components by weight:
1～2 part of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
Embodiment 2
PVDF manages, and is made up of following components by weight:
1 part of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
Embodiment 3
PVDF manages, and is made up of following components by weight:
2 parts of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
Embodiment 4
PVDF manages, and is made up of following components by weight:
1.2 parts of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
The PVDF pipe of the various embodiments described above, has fire-retardant, the abrasion-resistant of excellence, corrosion-resistant, high temperature resistant, resistance to oxidation, anti-quiet Electricity, weatherability performance.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, on the premise of without departing from the technology of the present invention principle, it is also possible to make some improvements and modifications, these improvements and modifications Also should be regarded as protection scope of the present invention.

Claims (4)

1.PVDF manages, it is characterised in that be made up of following components by weight:
1～2 part of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
PVDF the most according to claim 1 manages, it is characterised in that be made up of following components by weight:
1 part of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
PVDF the most according to claim 1 manages, it is characterised in that be made up of following components by weight:
2 parts of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
PVDF the most according to claim 1 manages, it is characterised in that be made up of following components by weight:
1.2 parts of succinic acid alkyl ester sulfonate sodium,
0.8 part of N-Methyl pyrrolidone,
1.5 parts of HBCDs,
1.3 part of two nonyl certain herbaceous plants with big flowers base barium sulfonate,
0.4 part of TTA,
2.2 parts of lauric acid polyoxyethylene ester,
0.7 part of polyethylene glycol oxide trimethyl ammonium chloride,
1.1 parts of oxydiphthalic,
2.3 part 2,2,4-trimethyl-1,3-pentanediol mono isobutyrate,
28 parts of Kynoar.
CN201610767984.5A 2016-08-30 2016-08-30 PVDF (polyvinylidene fluoride) pipe Pending CN106317715A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610767984.5A CN106317715A (en) 2016-08-30 2016-08-30 PVDF (polyvinylidene fluoride) pipe

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610767984.5A CN106317715A (en) 2016-08-30 2016-08-30 PVDF (polyvinylidene fluoride) pipe

Publications (1)

Publication Number Publication Date
CN106317715A true CN106317715A (en) 2017-01-11

Family

ID=57789957

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610767984.5A Pending CN106317715A (en) 2016-08-30 2016-08-30 PVDF (polyvinylidene fluoride) pipe

Country Status (1)

Country Link
CN (1) CN106317715A (en)

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532755A (en) * 2010-12-20 2012-07-04 深圳市宏商材料科技股份有限公司 Formula and processing technology for heat shrinkable tube
CN102634143A (en) * 2012-03-31 2012-08-15 苏州新区特氟龙塑料制品厂 Formula of chemical performance polyvinylidene fluoride
CN102634145A (en) * 2012-03-31 2012-08-15 苏州新区特氟龙塑料制品厂 Formula of weather-proof polyvinylidene fluoride
CN103756202A (en) * 2014-01-10 2014-04-30 长园电子（集团）有限公司 Elastic polyvinylidene fluoride heat-shrinkable sleeve and preparation method thereof
CN104144980A (en) * 2012-03-01 2014-11-12 阿克马法国公司 Vinylidene polyfluoride composition
CN105385077A (en) * 2015-12-21 2016-03-09 中国科学院长春应用化学研究所 Polyvinylidene fluoride composite material, preparation method and applications thereof
CN105683280A (en) * 2013-09-02 2016-06-15 阿肯马法国公司 Method for preparing a crosslinked fluorinated polymer composition

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102532755A (en) * 2010-12-20 2012-07-04 深圳市宏商材料科技股份有限公司 Formula and processing technology for heat shrinkable tube
CN104144980A (en) * 2012-03-01 2014-11-12 阿克马法国公司 Vinylidene polyfluoride composition
CN102634143A (en) * 2012-03-31 2012-08-15 苏州新区特氟龙塑料制品厂 Formula of chemical performance polyvinylidene fluoride
CN102634145A (en) * 2012-03-31 2012-08-15 苏州新区特氟龙塑料制品厂 Formula of weather-proof polyvinylidene fluoride
CN105683280A (en) * 2013-09-02 2016-06-15 阿肯马法国公司 Method for preparing a crosslinked fluorinated polymer composition
CN103756202A (en) * 2014-01-10 2014-04-30 长园电子（集团）有限公司 Elastic polyvinylidene fluoride heat-shrinkable sleeve and preparation method thereof
CN105385077A (en) * 2015-12-21 2016-03-09 中国科学院长春应用化学研究所 Polyvinylidene fluoride composite material, preparation method and applications thereof

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Application publication date: 20170111

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